Neutron halo in 8He

The structure of ⁸He is investigated within a three-cluster microscopic model. The threecluster configuration α+² n+₂ n is used to describe the properties of the ground state of this nucleus. The results obtained evidently indicate the existence of a neutron halo in ⁸He.     

Three-body continuum structure and response functions of halo nuclei (I): 6He

Three-body scattering states of the Borromean two-neutron halo nuclei are explored in a core + n + n model using the method of hyperspherical harmonics. We analyse the continuum structure (the properties of the continuum wave functions) separately from the continuum response (the magnitudes of one-step transitions from the ground state to the continuum). Predictions are made for the positions and strengths of the isoscalar monopole, electric dipole and quadrupole excitations, as well as for nuclear inelastic and charge-exchange response functions, for the ⁶He nucleus. The known 2⁺ resonance in ⁶He is reproduced. We find 1⁻ strength concentrations at lower energies in the proximity of the three-body threshold, and predict new 2⁺, 1⁺ (and possibly 0⁺) resonances at slightly higher energies in ⁶He.     

Low-energy spectrum of one-neutron halo nucleus 11Be

We investigate the low-energy spectrum of the one-neutron halo nucleus ¹¹Be using the complex scaled coupled channel method for a ¹⁰Be + n model, paying attention to the effects of the deformation of the ¹⁰Be-core and the Pauli principle between the core and a valence neutron. For positive parity states of ¹¹Be, our calculation well reproduces the experimental results, but for negative parity states, not so well. With reducing the coupling between the core deformation and a valence neutron, the negative parity levels of the ¹¹Be nucleus are much improved.     

A Systematic Study on 1neutron and 2neutron Halo Nuclei Using Coulomb and Nuclear Proximity Potential

The halo-structure of a nucleus is analyzed on the basis of potential energy consideration and separation energy calculations and thereby characterized a nucleus as a halo nucleus. The separation energy analysis showed that ¹¹Be, ¹⁴B, ^{15, 17, 19}C, ²²N, ²³O, ^{24, 26}F, and ²⁹Ne are 1n-halo nuclei since the 1n separation energy S(n) is the lowest and ^{6, 8}He, ¹¹Li, ¹⁴Be, ¹⁷B, ²²C, and ²⁹F are 2n-halo candidates as 2n separation energy S(2n) is the lowest. The potential energy calculations are consistent with the predictions based on separation energy calculations except for ¹²Be, ¹⁹B, and ²⁷F which can be considered as 2n-halo candidates by potential energy consideration. Also, a discrepancy is noticed in the case of the proposed 2n-halo ⁸He and ¹⁷B nuclei. Further, the possibility of emitting halo nucleus via heavy particle decay of heavy nuclei, within the range 82?≤?Z?≤?102, has been studied using the Coulomb and proximity potential model (CPPM). It is observed that the probability of emission of a halo nucleus is lower than that of a normal cluster Nevertheless, there is a finite chance of emission of a halo nucleus in the decay of a heavy nucleus.     

Generation of CdS clusters using laser ablation: the role of wavelength and fluence

The formation of cationic clusters in the laser ablation of CdS targets has been investigated as a function of wavelength and fluence by mass spectrometric analysis of the plume. Ablation was carried out at the laser wavelengths of 1064, 532, 355, and 266 nm in order to scan the interaction regimes below and above the energy band gap of the material. In all cases, the mass spectra showed stoichiometric Cd _n S _n ⁺ and nonstoichiometric Cd _n S _n−1⁺, Cd _n S _n+1⁺, and Cd _n S _n+2⁺ clusters up to 4900 amu. Cluster size distributions were well represented by a log-normal function, although larger relative abundance for clusters with n=13, 16, 19, 34 was observed (magic numbers). The laser threshold fluence for cluster observation was strongly dependent on wavelength, ranging from around 16 mJ/cm² at 266 nm to more than 300 mJ/cm² at 532 and 1064 nm. According to the behavior of the detected species as a function of fluence, two distinct families were identified: the “light” family containing S₂⁺ and Cd⁺ and the “heavy” clusterized family grouping Cd₂⁺ and Cd _n S _m ⁺. In terms of fluence, it has been determined that the best ratio for clusterization is achieved close to the threshold of appearance of clusters at all wavelengths. At 1064, 532, and 355 nm, the production of “heavy” cations as a function of fluence showed a maximum, indicating the participation of competitive effects, whereas saturation is observed at 266 nm. In terms of relative production, the contribution of the “heavy” family to the total cation signal was significantly lower for 266 nm than for the longer wavelengths. Irradiation at 355 nm in the fluence region of 200 mJ/cm² has been identified as the optimum for the generation of large clusters in CdS.     

Virasoro type Lie algebras and deformations

The first and second cohomologies of Cartan Type Lie algebras with coefficients in irreducible tensor modules are calculated. The spaceH ¹(L, U) is interpreted as a space of deformations of (L, U)-modules.H ²(L, L)≠0 ifL=S ₂,S ₂ ⁺ orL=H _n ,H _n ⁺ . Lie algebra of divergenceless vector fieldsS ₂ ⁺ has only one nontrivial local deformation. The two-sided simple hamiltonian algebraH _n has 2n ²+n new local deformations in addition to Moyal cocycle. The Lie algebrasL=W _n (n>3),S _n?1(n>2),H _n (n>1),K _n+1(n>1) have 3, 1, 1, 3 nonisomorphic tensor modules with irreducible bases and nonzero 1-cohomologies; respectively, the corresponding numbers for 2-cohomologies are 9, 6, 7 and 9.     

Study of S ion-assisted sulfurization of n-GaAs (1 0 0) surface

The chemical structure and site location of sulfur atoms on n-GaAs (1 0 0) surface treated by bombardment of S⁺ ions over their energy range from 10 to 100 eV have been studied by X-ray photoelectron spectroscopy and low energy electron diffraction. The formation of Ga-S and As-S species on the S⁺ ion bombarded n-GaAs surface is observed. An apparent donor doping effect is observed for the n-GaAs by the 100 eV S⁺ ion bombardment. It is found that the S⁺ ions with higher energy are more effective in the formation of Ga-S species, which assists the n-GaAs (1 0 0) surface in reconstruction into an ordered (1 × 1) structure upon subsequent annealing. The treatment is further extended to repair Ar⁺ ion damaged n-GaAs (1 0 0) surface. It is found that after a n-GaAs (1 0 0) sample is damaged by 150 eV Ar⁺ ion bombardment, and followed by 50 eV S⁺ ion treatment and subsequent annealing process, finally an (1 × 1) ordering GaAs (1 0 0) surface with low surface states is obtained.     

Structural and thermoelectric power properties of Na-doped V2O5·nH2O nanocrystalline thin films

X-ray diffraction (XRD), thermoelectric power (S) and at room temperature electrical conductivity (σ) of Na⁺¹-doped V₂O₅·nH₂O nanocrystalline thin films fabricated by sol gel technique (colloid route) were studied. XRD showed that the Na₂O–V₂O₅·nH₂O thin films are highly oriented nanocrystals. The average value of particle size was found to be about 7.5 nm. The thermoelectric power showed that the thermoelectric power for all present nanocrystalline thin films samples decreased with increasing Na⁺¹ content. However, the electrical conductivity increased with increasing Na⁺¹ content. There is evidence that small polarons are responsible for determining the transport properties of the Na⁺¹ doped V₂O₅·nH₂O nanocrystalline thin films samples. The high value of electrical conductivity and small value of thermoelectric power is ideal for device applications, where device to device variation of the thermoelectric power must be small. This preparation technique was demonstrated to fabricate high quality Na₂O–V₂O₅·nH₂O nanocrystalline thin films for thermoelectric device applications. However, this may be further used for deposition with an ink-jet printer.     

Spatial periphery of lithium isotopes

The spatial structure of lithium isotopes is studied with the aid of the charge-exchange and (t, p) reactions on lithium nuclei. It is shown that an excited isobaric-analog state of ⁶Li (0⁺, 3.56MeV) has a halo structure formed by a proton and a neutron, that, in the ⁹Li nucleus, there is virtually no neutron halo, and that ¹¹Li is a Borromean nucleus formed by a ⁹Li core and a two-neutron halo manifesting itself in cigar-like and dineutron configurations.     

Electron scattering on two-neutron halo nuclei: The case of 6He

The formalism to describe electron scattering reactions on two-neutron halo nuclei is developed. The halo nucleus is described as a three-body system (core +n + n), and the wave function is obtained by solving the Faddeev equations in coordinate space. We discuss elastic and quasielastic scattering using the impulse approximation to describe the reaction mechanism. We apply the method to investigate the case of electron scattering on ⁶He. Spectral functions, response functions, and differential cross sections are calculated for both neutron knockout and α knockout by the electron.     

Spatial periphery of lithium and beryllium isotopes

The spatial structure of the periphery of lithium and beryllium isotopes is studied by means of charge-exchange reactions and the (t, p) and (d, p) reactions on their nuclei. It is shown that the 0⁺ isobaric-analog state of ⁶Li at 3.56 MeV has a halo structure formed by a proton and a neutron, that there is virtually no manifestation of a neutron halo in the ground state of the ⁹Li nucleus, and that the ¹¹Li nucleus has a Borromean halo structure that two neutrons form with respect to the ⁹Li core and which manifests itself in cigar and dineutron configurations. The ¹⁰Be nucleus has a substantial two-neutron periphery in either configuration both in the ground and in the 2⁺ excited state at 3.37MeV.     

Structural and lithium ion transport studies in borophosphate glasses

Lithium ion transport process and glass network modification upon the variation of network modifier (M) to former (F) ratio (M/F) in 30% LiBO₂–70% [(M Li₂O–F P₂O₅)] glasses have been investigated. The glasses with different M/F ratios (0.42–1.0) were prepared by melt quenching technique and characterized by X-ray diffraction (XRD), differential scanning calorimetry (DSC), Raman and impedance spectroscopy techniques. The glass transition temperature, T_g increased with increasing M/F ratio suggesting an increase in overall connectivity of the network structure. Dc conductivity showed an enhancement of three orders of magnitude with increasing M/F. The observed increase in T_g and dc conductivity with modifier concentration has been explained on the basis of the competition between network breaking/forming events, leading to an increase in overall connectivity of the network and the formation of continuous channels for ion migration. Ac conductivity data were analyzed by fitting the data to Almond-West type power law equation, σ′(ω) = σ(0) + Aωⁿ. The power law exponent, n, was found to be temperature dependent and exhibited a minimum, n_min. The observation of n_min has been explained in the light of diffusion controlled relaxation (DCR) model. Furthermore, the scaling of both ac conductivity and electrical modulus data showed an excellent collapse on to a single master curve indicating that there is a good time–temperature superposition and that conduction mechanism remains unchanged in this glass system.     

Parameter-dependent quasispin group

A nonconventional generalization of the quasispin formalism for N identical particles is presented. The generators S₊ = Σ_ip_iS₊ⁱ, S_? = Σ_ip_i^?1S_?ⁱ, S_z = Σ_iS_zⁱ of this quasispin group depend on the dynamical parameters p_i. This parameter-dependent quasispin group appears as a deformation of the conventional quasispin group (p_i = 1). With such a definition of the quasispin group, the 2n-projection S₊ⁿ|0> of the BCS state is seen to be an exact generalized seniority zero state. More precisely, this dynamical quasispin group provides the mathematical framework to discuss the earlier generalization of Talmi et al. Theoretical and numerical calculations of the generalized seniority zero multiplet have been carried out for the nickel and tin isotopes.     

Velocity dependence of the chemi-ionization of H2O and D2O on impact of 21S and 23S helium atoms

The velocity dependence for the ionization of H₂O and D₂O to form H₂O⁺ and D₂O⁺ in collisions with both 2³S and 2¹S metastable helium atoms has been measured in a crossed molecular beam apparatus using a mechanical velocity-selector on the metastable beam. The cross-sections are found to be proportional to the —n power of the relative collision energy, with n ? 0.4 for both metastable atoms in both gases. The branching ratios H₂O⁺/OH⁺ and D₂O⁺/OD⁺ were both found to be 4.3 for both metastable helium atoms, and to be independent of the relative collision energy.     

Structural,ferroelectric, optical properties of A-site-modified Bi0.5(Na0.78K0.22)0.5Ti0.97Zr0.03O3 lead-free piezoceramics

We reported the role of A-site modification on the structural, ferroelectric, optical and electrical field-induced strain properties of Bi_0.5(Na_0.78K_0.22)_0.5Ti_0.97Zr_0.03O₃ lead-free piezoceramics. The Li⁺ ions with concentration from 0 to 5 mol% were used to substitute at A-site. There was no phase transition when Li⁺ ions was added up to 5 mol%. The electric field-induced strain (S_max/E_max) values increased from 600 to 643 pm/V for 2 mol% Li⁺-added which results from distortion both rhombohedral and tetragonal phase structures. The band gap reduced from 2.88 to 2.68 eV and the saturation polarization decreased from 46.2 to 26.1 μC/cm² when Li⁺ ions concentration increased from 0 to 5 mol% respectively. We expect that this work could be helpful for further understanding the role of A-site dopants in comparison with B-site modification in lead-free Bi_0.5(Na,K)_0.5TiO₃-based ceramics.     

Microhydration of the methylene blue cation in an electrospray ion source

Microhydrated methylene blue cations, MB⁺(H₂O) _n , are produced in an electrospray ion source and their size-distributions are measured as a function of the source temperature. A series of MB⁺(H₂O) _n ions is observed up to n ≃ 60. A striking feature observed in the mass spectra is that the series of hydrated ions starts at n = 4; intensities of n = 1–3 are extremely suppressed. The absence of n = 1–3 ions is well explained by the energetics concerning evaporation processes of water molecules, based on stable structures and the binding energies of MB⁺(H₂O) _n ions calculated by DFT calculations up to n = 5. MB⁺(H₂O) _n ions for n > 4 evaporate a single water molecule sequentially, while MB⁺(H₂O)₄ tends to fragment into MB⁺ and (H₂O)₄ rather than MB⁺(H₂O)₃ and an H₂O molecule. We have observed a clear magic peak at n = 24, which strongly suggests that the MB⁺(H₂O)₂₄ ion is formed by attaching a neutral (H₂O)₂₀ cage onto an MB⁺(H₂O)₄ ion.     

Universal properties and structure of halo nuclei

The universal properties and structure of halo nuclei composed of two neutrons (2n) and a core are investigated within an effective quantum mechanics framework. We construct an effective interaction potential that exploits the separation of scales in halo nuclei and treat the nucleus as an effective three-body system. The uncertainty from higher orders in the expansion is quantified through theoretical error bands. First, we investigate the possibility to observe excited Efimov states in 2n halo nuclei. Based on the experimental data, ²⁰C is the only halo nucleus candidate to possibly have an Efimov excited state, with an energy less than 7 keV below the scattering threshold. Second, we study the structure of ²⁰C and other 2n halo nuclei. In particular, we calculate their matter form factors, radii, and two-neutron opening angles.     

Laser ablation time-of-flight mass spectrometry (LA-TOF-MS) of “nitrogen doped diamond-like carbon (DLN) nano-layers”

Nitrogen-doped diamond-like carbon (DLC) layers (a-C:H:N, N-DLC or DLN) were prepared by the plasma-enhanced chemical vapor deposition (PECVD) technique, using a RF capacitive discharge (13.56 MHz), at low pressures (20 Pa), produced from a mixture of methane, nitrogen and hexamethyldisiloxane (HMDSO), deposited on single-crystalline silicon wafers placed on steel samples. The films, of differing deposition times, were subjected to laser ablation time-of-flight (LA-TOF) mass spectrometric measurements, using different commercial instrumentation to characterize their structures. The analysis of mass spectra was made and the following positively singly charged species were detected and identified: C_n⁺ (n=4–30), Si_n⁺ (n=2, 3), Si_nH⁺ (n=2, 3), SiOK⁺, Si₃H₄⁺, Si₂N⁺, Si₂NH₂⁺, and Si₃C⁺. The later three species could reflect the presence of nitrogen–silica and carbon–silica chemical bonds in the structure of the DLN layer. The stoichiometry of all species was confirmed by isotopic pattern simulation. In the negative detection mode, the C_n⁻ (n=2–12) clusters were observed. The findings are discussed in the light of the current research concerning analysis of the DLN thin layers and it is concluded that namely Si₂N⁺, Si₂NH₂⁺ and Si₃C⁺ species are reflecting the chemical structure of the DLN layer. LA-TOF-MS was found useful supplementary method for the characterization of DLN nano-layers.     

Fission barriers and other characteristics of nuclei from the uranium region

Fission barriers in nuclei belonging to the uranium region and their other characteristics are calculated on the basis of the FaNDF⁰ energy density functional. In particular, the neutron-separation energies S _n and S _2n, the proton-separation energies S _p, and the beta-transition energiesQ _β are calculated for uranium, neptunium, and plutonium isotopes. In addition, the deformation energies and parameters of these nuclei are presented along with their radii. A comparison with the predictions of the Skyrme–Hartree–Fock method implemented with several versions of the Skyrme energy density functionals is performed. The role of the octupole deformation β ₃ is studied for the ²³⁸U nucleus. It is shown that this deformation does not have any significant effect on the first-barrier height B ⁽¹⁾ _f or ground-state properties. At the same time, the second-barrier height B(2) f decreases by a factor of about two upon taking into account β ₃. A phase transition at A ~ 260 is found for the three isotopic chains being considered: this point is a bifurcation point at which B ⁽¹⁾ _f (A) forks into two curves. Of these, the curve B ⁽²⁾ _f (A) splits from it, prolonging the former curve for B ⁽¹⁾ _f (A) almost continuously, whereas the curve for B ⁽¹⁾ _f (A) itself goes down sharply.     

Photoelectron spectra of pyromellitic dianhydride,dithioanhydride and diimide and of trimellitic anhydride

The photoelectron (He(I)) spectra of the tricyclic tetracarbonyl compounds pyromellitic dianhydride, dithioanhydride and diimide and of the tetracyclic hexacarbonyl compound trimellitic anhydride have been investigated. To aid the interpretation of the main features of the spectra, i.e. the ordering and splitting of the ⁿCO ionisations and the behaviour of the ‘benzenic’ and heteroatom π ionisations, MO calculations based on a ZDO pragmatic model and semiempirical SCF-PP calculations have been carried out. The evolution of the ⁿCO and π_X ionisations upon progressive fusion of anhydride moieties with a benzene nucleus is analysed in detail. The proposed orbital sequences for the n orbitals are: a_g(S⁺) $\text{\$}\text{?}$b_1u(AS⁺) $\text{\$}\text{?}$b_2u(S^?) $\text{\$}\text{?}$b_3g(AS^?) for the tetracarbonyls and a′₁(S⁺) $\text{\$}\text{?}$e′(AS⁺) $\text{\$}\text{?}$a′₂ (AS^?) ≈ e′(S^?) for the hexacarbonyl.