Etude des proprietes thermodynamiques d'un groupement tetranucleaire: Application au compose Na3RuO4

The exact eigenvalues spectrum of the spin hamiltonian $\text{H}\text{= ?2}\text{∑}\text{(i, j)}\text{J}{}_{\mathrm{ij}}\text{S}\text{?}{}_{\mathrm{i}}\text{S}\text{?}{}_{\mathrm{j}}$ have been calculated for a tetranuclear cluster formed by four spins 3/2 at the vertices of a lozenge. Two isotrope exchange interactions J₁ and J₂ are able to explain the thermodynamic properties (magnetic susceptibility, entropy, specific heat). A ground state transition from singlet to triplet state occurs when the $\text{J}{}_2\text{J}{}_1$ ratio reaches the value $\text{4}\text{3}$. The magnetic susceptibility data of Na₃RuO₄ fit well with the theoretical values proposed for $\text{J}{}_1\text{K}\text{= (?19,5 K)}$ and J₂/k (?22,5 K).     

Spin wave spectrum of Ca2MnO4 at 4.2K

The spin-wave spectrum of Ca₂MnO₄ has been measured at 4.2K. It can be fully built from two exchange integrals in the (001) plane $\text{J}{}_{\mathrm{<mtext>1</mtext>}}\text{=}\text{5.9}$ meV and $\text{J}{}_{\mathrm{<mtext>2=1.7\; meV</mtext>}}$, and in out-of plane exchange integral $\text{J}\text{′}{}_{\mathrm{<mtext>1</mtext>}}\text{=}\text{0.6}\text{meV}$. This latter explains quite well the splitting of the magnon dispersion curve.     

Exact approach to equilibrium for the glauber model of a one-dimensional Ising system with random ±J bonds

The (discrete-time) Glauber model is considered for a one-dimensional system of spins s_j = ±1 with nearest-neighbor Ising interaction $\text{H}\text{= -Σ}{}_{\mathrm{j}}\text{J}{}_{\mathrm{j}}\text{s}{}_{\mathrm{j}}\text{s}{}_{\mathrm{j+1}}$. The J_j = ±J are treated as random variables with an arbitrary joint probability p(J). The exact time-dependent average 〈s_j〉_t is determined, and from it the “quenched” average $\text{〈〈s}{}_{\mathrm{j}}\text{〉}{}_{\mathrm{t}}\text{〉}{}_{\mathrm{<mtext>av</mtext>}}\text{=Σ}{}_{\mathrm{<mtext>J</mtext>}}\text{p}\text{(}\text{J}\text{)〈s}{}_{\mathrm{j}}\text{〉}{}_{\mathrm{t}}$ is explicitly found.     

Coupling supersymmetric Yang-Mills theories to supergravity

We extend the technique of Cremmer et al. to couple arbitrary chiral multiplets with supersymmetric Yang-Mills interactions to N = 1 supergravity. We present the general form of the lagrangian and the detailed form of the scalar potential is spelled out. In the case of N chiral multiplets, “minimally” coupled to supergravity, we derive, in the absence of gauge interactions, a model-independent mass formula Supertrace $\text{M}{}^2\text{= Σ}{}_{\mathrm{J}}\text{(?)}{}^{\mathrm{2J}}\text{(2J + 1)m}{}_{\mathrm{J}}{}^2\text{= 2(N ? 1)m}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}{}^2$, where $\text{m}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}$ is the gravitino mass. A concrete example of the super Higgs effect involving N chiral multiplets is exhibited.     

Angular momentum fluctuation energy in the cranking model

Angular momentum is approximately projected from Hartree-Fock-Bogoliubov cranked (HFBC) wave functions. At each J the projected energy is $\text{E}{}_{\mathrm{<mtext>proj</mtext>}}\text{≈ E}{}_{\mathrm{<mtext>HFBC</mtext>}}\text{? (Δ}\text{J}\text{)}{}^2\text{/2}\text{J}{}_{\mathrm{<mtext>HFBC</mtext>}}$. The spin-dependent fluctuation $\text{Δ}\text{J}$ includes contributions from J_y and J_z as well as J_x. There are no correlations in the three angular momentum components. Projected energies are calculated for ^{168, 170}Yb and ¹⁷⁴Hf. When compared to experimental energies, the projected spectra are less compressed than the HFBC spectra. At low spins the projected and experimental energies are in good agreement.     

Evidence for Mn clustering in dilute CuMn alloys from high-field (40 T) magnetization curves at 4.2 K

Magnetization curves of CuMn alloys with Mn concentration between 1.5 and 10 at.% have been measured at 4.2 K in fields up to 40 T, using a pulsed-field method.The results found for different concentrations can be scaled upon one another, which is a clear indication for the occurance of magnetic clusters. Analysis of this universal curve in terms of Brillouin functions yields the values $\text{z}{}_{\mathrm{I}}\text{J}{}_{\mathrm{I}}\text{/k??44K}$, $\text{z}{}_{\mathrm{II}}\text{J}{}_{\mathrm{II}}\text{/k??10K}$ and $\text{z}{}_{\mathrm{III}}\text{J}{}_{\mathrm{III}}\text{/k??0.5K}$, for the largest three interactions within each cluster.     

“Forbidden” rotational spectra of symmetric-top molecules: PH3 and PD3

A millimeter-wave spectrometer having a sensitivity of 4 × 10^?10 cm^?1 in the 2-mm region has been constructed for observation of extremely weak millimeter-wave spectra of gases. It has been used to measure J → J, K = 0 ← 3 transitions in PH₃ and J → J, K = 0 ← 3 as well as K = ±1 ← ±4 transitions in PD₃. The B₀ and C₀ spectral constants (in MHz) are: for PH₃, B₀ = 133 480.15 ± 0.12 and C₀ = 117 488.85 ± 0.16; for PD₃, B₀ = 69 471.10 ± 0.03 and C₀ = 58 974.37 ± 0.05. The effective ground-state values obtained for the bond angle and bond length are: for PH₃, $\text{r}{}_0\text{(}\text{A}\text{?}\text{) = 1.420}{}_0$ and $\text{α}{}_0\text{(}{}^{\mathrm{o}}\text{) = 93.34}{}_5$; for PD₃, $\text{r}{}_0\text{(}\text{A}\text{?}\text{) = 1.417}{}_6$ and $\text{α}{}_0\text{(}{}^{\mathrm{o}}\text{) = 93.35}{}_9$. The corresponding zero-point-average values were calculated to be: for PH₃, $\text{r}{}_{\mathrm{z}}\text{(}\text{A}\text{?}\text{) = 1.4269}{}_9\text{± 0.0002}$ and $\text{α}{}_{\mathrm{z}}\text{(}{}^{\mathrm{o}}\text{) = 93.228}{}_7$; for PD₃, $\text{r}{}_{\mathrm{z}}\text{(}\text{A}\text{?}\text{) = 1.4226}{}_5\text{± 0.0001}$ and $\text{α}{}_{\mathrm{z}}\text{(}{}^{\mathrm{o}}\text{) = 93.256}{}_7\text{± 0.004}$. For both species, the equilibrium values are $\text{r}{}_{\mathrm{e}}\text{(}\text{A}\text{?}\text{) = 1.4115}{}_9\text{± 0.0006}$ and $\text{α}{}_{\mathrm{e}}\text{(}{}^{\mathrm{o}}\text{) = 93.32}{}_8\text{± 0.02}$.     

Collective properties of A = 117−127 odd-A I nuclei

Systematic ΔJ = 2 bands have been observed on the $\text{d}{}_{\mathrm{<mtext>5</mtext><mtext>2</mtext>}}$, $\text{g}{}_{\mathrm{<mtext>7</mtext><mtext>2</mtext>}}$ and $\text{h}{}_{\mathrm{<mtext>11</mtext><mtext>2</mtext>}}$ quasi-proton states in A = 117?127 odd-I nuclei. The ΔJ = 2 energy spacings decrease (relative to the Te cores) as A decreases for the $\text{h}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ band but not for the others. Also ΔJ = 1 bands on unsually low-lying $\text{g}{}_{\mathrm{<mtext>9</mtext><mtext>2</mtext>}}$ proton-hole states exist.     

Johnson noise and absolute temperature

Experimental evidence using Josephson junction devices has suggested that Johnson noise in copper fails to be proportional to absolute temperature below 10 millikelvin. A microscopic theory is presented which gives the Johnson noise temperature $\text{T}{}_{\mathrm{<mtext>J</mtext>}}\text{= ?}{}_0{}^1\text{XT}{}_0$ coth ($\text{XT}{}_0\text{T}$) dX where $\text{T}{}_0\text{=}\text{hν}{}_{\mathrm{<mtext>F</mtext>}}\text{2kN}$. For copper, the calculated T₀ = 3.84 mK agrees closely with the value extracted from experimental data, 3.89 mK. Within a few percent, $\text{T}{}_{\mathrm{<mtext>J</mtext>}}\text{? (}\text{T}{}_0\text{2}\text{)}$ coth ($\text{T}{}_0\text{2T}$), and this adequately fits the available experimental data. ν_F is the fermi velocity and N is the length of the resistor. The Johnson noise parameter “T₀” presumably can measure ν_F along different crystal orientations.     

The measurement of the rotational relaxation times of OCS from the nutation signals

The time dependence of microwave absorption was measured for the J = 2-1 and J = 3-2 transitions of OCS under on- and off-resonant conditions utilizing Stark and source modulation, respectively. The two effective pressure parameters obtained under the two conditions, which correspond to $\text{(T}{}_2{}^{\mathrm{?1}}\text{+ T}{}_1{}^{\mathrm{?1}}\text{)}\text{4πP}$ and $\text{(2πT}{}_2\text{P)}{}^{\mathrm{?1}}$, respectively, according to the Bloch equation, are different beyond experimental error; the difference $\text{(T}{}_2{}^{\mathrm{?1}}\text{? T}{}_1{}^{\mathrm{?1}}\text{)}\text{2πP}$ is 0.94 ± 0.38 (2.5σ) MHz/Torr for J = 2?1. This difference was also determined to be 1.19 ± 0.30 MHz/Torr from the dependence of the nutation frequency on the microwave power.     

Structure of positive parity states in 29P and two-step processes in (p,t) reactions

From a study of (p,t) reactions on ³¹P and ³⁰Si it is suggested that in ²⁹P the states with $\text{J}{}^{\mathrm{\pi }}\text{=}\text{1}\text{2}{}_1{}^{\mathrm{+}}$ and $\text{1}\text{2}{}_2{}^{\mathrm{+}}$, the pair $\text{3}\text{2}{}_2{}^{\mathrm{+}}$, $\text{5}\text{2}{}_1{}^{\mathrm{+}}$, and the pair $\text{7}\text{2}{}_3{}^{\mathrm{+}}$, $\text{9}\text{2}{}_1{}^{\mathrm{+}}$ are related by weak coupling of a s${}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ proton with the states 0₁⁺, 0₂⁺, 2₁⁺ and 4₁⁺ respectively of ²⁸Si. Completely atypical L = 2 angular distributions have been obtained for the $\text{3}\text{2}{}_1{}^{\mathrm{+}}$ and $\text{5}\text{2}{}_2{}^{\mathrm{+}}$ states in ²⁹P and it is suggested that this is due to contribution by two-step processes.     

Susceptibilities of the S = 12 XY model on the square lattice at T = 0

For the $\text{S =}\text{1}\text{2}\text{XY}$ model at T = 0 four susceptibilities have been calculated exactly on a sequence of finite square lattices and extrapolated to the infinite square lattice. For the ferromagnet χ_zz = 0 while χ_xx ～ N^2.9; for the antiferromagnet $\text{J}{}_{\mathrm{\chi xx}}\text{N(gμ}{}_{\mathrm{<mtext>B</mtext>}}\text{)}{}^2\text{= 0.025 ± 0.002}$ and $\text{J}{}_{\mathrm{\chi xx}}\text{N(gμ}{}_{\mathrm{<mtext>B</mtext>}}\text{)}{}^2\text{= 0.13 ± 0.03}$.     

A cubic antiferromagnet for which the ground state is known exactly

Nearest neighbour anisotropic exchange is characterized by $\text{K}{}_{\mathrm{ij}}\text{= J}{}_6\text{S}{}_{\mathrm{ix}}\text{S}{}_{\mathrm{jx}}\text{+ J}{}_{\mathrm{\perp }}\text{(S}{}_{\mathrm{iy}}\text{S}{}_{\mathrm{jy}}\text{+S}{}_{\mathrm{iz}}\text{S}{}_{\mathrm{jz}}\text{)}$ for a bond along the x-axis. For J₆ = ?J_⊥ < 0 the ground configuration of the total exchange hamiltonian is a two-sublattice antiferromagnet which is an eigenstate of the problem.     

Low temperature specific heats of nearly one-dimensional antiferromagnet: CuCl2·2NC5H5

Transition temperature to LRO state was found at T_N=1.14K for nearly one-dimensional antiferromagnet CuCl₂ · 2NC₅H₅. Intra- and inter-chain exchange constants J and J′ were estimated, $\text{kT}{}_{\mathrm{<mtext>N</mtext>}}\text{J}\text{=0.082}$ and $\text{J′}\text{J}\text{=3×10}{}^{\mathrm{?3}}$, respectively. Comparison with those of TMMC implies highly one-dimensional character.     

Comparison of three-jet and two-jet cross sections in pp̄ collisions at the CERN SPS pp̄ collider

Results are presented on two-jet and three-jet cross sections, measured in the UA1 experiment at the CERN Super Proton Synchrotron (SPS) pp? Collider, at the highest available subprocess cms energies ($\text{s}\text{?}\text{>150}\text{GeV}$). Precise measurements of the two-jet angular distribution are consistent with previous results but show significant scale-breaking effects. The three-jet Dalitz plot and the three-jet angular distributions show evidence for final- and initial-state bremsstrahlung processes, in agreement with the leading-order QCD predictions. A comparison of the yield of wide-angle three-jet events with the yield of two-jet events at smaller scattering angles gives for the strong interaction coupling constant: $\text{α}{}_{\mathrm{<mtext>s</mtext>}}\text{(}\text{K}{}_{\mathrm{3J}}\text{K}{}_{\mathrm{2J}}\text{)=0.16±0.02±0.03}$ at Q²≈4000 GeV², where the factor $\text{K}{}_{\mathrm{3J}}\text{K}{}_{\mathrm{2J}}$ may plausibly be assumed to be close to unity.     

Hyperfine structure of CH3OH

Hyperfine structure of the (0, 0, 1) - (1, 0, 1) transition of methanol has been investigated by beam absorption and of the (J, 1, 3?) → (J, 1, 3+) transitions for J = 2, 3, and 6 by beam-maser spectroscopy. The best-fit results for the spin-rotation and spin-spin coupling constants $\text{C}{}_{\mathrm{JK\tau \pm }}{}^{\mathrm{(i)}}$ and $\text{D}{}_{\mathrm{JK\tau \pm }}{}^{\mathrm{(i)}}$, respectively, are in kHz¹: $\text{C}{}_{101}{}^{\mathrm{(1)}}\text{= 2.4(10)}$, $\text{C}{}_{101}{}^{\mathrm{(2)}}\text{= ?0.6(10)}$, $\text{D}{}_{101}{}^{\mathrm{(1)}}\text{= ?13.8(9)}$, $\text{D}{}_{101}{}^{\mathrm{(2)}}\text{= 7.0(9)}$, $\text{C}{}_{\mathrm{213?}}{}^{\mathrm{(1)}}\text{= ?5.0(10)}$, $\text{C}{}_{\mathrm{213?}}{}^{\mathrm{(2)}}\text{= ?5.5(10)}$ and ($\text{C}{}_{\mathrm{J13?}}{}^{\mathrm{(2)}}\text{- C}{}_{\mathrm{J13+}}{}^{\mathrm{(2)}}\text{) = 0.98(9)}$.     

Two-magnon Raman scattering in the two-dimensional antiferromagnet K2FeF4

Two-magnon Raman scattering in the planar quadratic antiferromagnet K₂FeF₄ is investigated. The temperature dependence of the energy shift is in good agreement with second-order Green-function theory, as is the linewidth at low temperature. Numerical results, including renormalization, are the Heisenberg exchange $\text{J}\text{k}{}_{\mathrm{B}}\text{= ?14.5 ± 0.7}\text{K}$ and the anisotropy $\text{Δ(T = 0) = gμ}{}_{\mathrm{B}}\text{H}{}_{\mathrm{A}}\text{4|J|S = 0.18 ± 0.05}$, but with $\text{J[1 + Δ(T = 0)]}\text{k}{}_{\mathrm{B}}\text{= ?17.06 ± 0.10}\text{K}$.     

Electron exchange between Fe2+ and Fe3+ ions on octahedral sites in spinels studied by means of paramagnetic Mössbauer spectra and susceptibility measurements

Mössbauer spectra were obtained of the paramagnetic spinels $\text{Zn}{}^{\mathrm{2+}}\text{|}\text{Zn}{}^{\mathrm{2+}}{}_{\mathrm{<mtext>(1?x)</mtext><mtext>2</mtext>}}\text{Ti}{}^{\mathrm{4+}}{}_{\mathrm{<mtext>(1+x)</mtext><mtext>2</mtext>}}\text{Fe}{}^{\mathrm{3+}}{}_{\mathrm{<mtext>(1?</mtext><mtext>x)</mtext>}}\text{Fe}{}^{\mathrm{2+}}{}_{\mathrm{x}}\text{|}\text{O}{}_4$ and susceptibilities were measured. The strong difference between the paramagnetic Fe²⁺ and Fe³⁺ spectrum, due to the different quadrupole splitting, is used for the distinction between the two species. At 300 K a superposition of the Fe³⁺ and the Fe²⁺ spectra is found for most of the iron and, in addition, some continuous absorption. The latter is strongest for equal Fe³⁺ and Fe²⁺ concentration $\text{(x =}\text{1}\text{2}\text{)}$ while it disappears towards the end members (Fe³⁺ only or Fe²⁺ only) as well as with decreasing temperature (between 78 and 200 K). From this it is concluded that it arises from thermally activated electron exchange, the frequency of which passes a “critical” value of ～10⁸ sec^?1 for increasing temperature. Paramagnetic susceptibilities are found to obey a Curie-Weiss law down to low temperatures. From the dependence of the asymptotic Curie temperature on the composition the magnetic interaction parameters J₁₁ = ?1.4 K, J₂₂ = ?3.3 K and J₁₂ = + 1.6 K for the Fe³⁺Fe³⁺, Fe²⁺Fe²⁺ and Fe³⁺Fe²⁺ interactions are derived. The experimental results are discussed in terms of a hopping model with an activation energy q ～- 0.12eV and a non-equivalence of the octahedral sites expressed by a varying potential energy difference U₀ between neighbouring sites. The continuous absorption at 300 K for $\text{x =}\text{1}\text{2}$ is attributed to about 17% of the iron on sites with U₀ running from 0 to ??0.06 eV. The ferromagnetic Fe³⁺, Fe²⁺ interaction (J₁₂) is attributed to electron transfer from localized Fe²⁺ ions to Fe³⁺ neighbours via a transfer integral b of the order of 0.05 eV. The magnitudes of J₁₂ and b are tentatively explained.     

A study of the K = 3nA1 - A2 centrifugal splitting in the 3ν2 and 4ν2 states of PH3 using a difference-frequency laser system

A frequency tunable infrared source has been constructed by using the (Ar-laser) - (dyelaser) difference frequency method developed by Pine and applied to the observation of the overtone bands of PH₃ 3ν₂ ← 0 and 4ν₂ ← ν₂ in the 3.4 μm region and 4ν₂ ← 0 in the 1.6-μm region. A Stark modulation method was used to increase the sensitivity of detection. For transitions which were well modulated, the minimum detectable absorption coefficient was estimated to be ～3 × 10^?7 cm^?1 using a 3-m cell. Emphasis was placed on the observation of the A₁-A₂ splitting for K = 3n rotational levels. For the 3ν₂ state splittings were observed for K = 3, 6, and 9 because PH₃ is a very nearly spherical top in this state. The magnitude and the J dependence of the observed K = 3n splittings have been analyzed by using a normal symmetric rotor Hamiltonian and a centrifugal distortion term of the form $\text{τ}{}_{\mathrm{xxxz}}\text{[(J}{}_{\mathrm{+}}{}^3\text{+ J}{}_{\mathrm{?}}{}^3\text{)J}{}_{\mathrm{z}}\text{+ J}{}_{\mathrm{z}}\text{(J}{}_{\mathrm{+}}{}^3\text{+ J}{}_{\mathrm{?}}{}^3\text{)]}\text{4}$.