Emission of circularly polarized recombination radiation from p-doped GaAsP bombarded with longitudinally polarized electrons

We report measurements of circularly polarized recombination radiation from a GaAs_0.6P_0.4 crystal bombarded with longitudinally spin polarized electrons of 10 eV energy. Qualitatively, this process can be considered as the inverse of the photoemission utilized in GaAs and GaAsP polarized-electron sources. The measured degree of circular polarization is 0.29%±0.06% if the crystal is cooled with liquid nitrogen and the incident electrons are 15%±3% polarized.     

Calculation of electron-spin polarization in photoemission from Au(110)

We have calculated the spin polarization of electrons photoemitted by circularly polarized light from Au(110). Results for the spin polarization of the angular resolved photoyield are given for clean and contaminated surfaces for photon energies ?Ω up to 10 eV. In addition we calculated the spectrum for energy resolved photoelectrons for $\text{?Ω = 8.5 eV}$. Our calculations demonstrate that from an analysis of the spin polarization of energy resolved photoelectrons detailed information on the electronic structure of solids follows.     

Neutron diffraction study on the hyperfine-induced nuclear spin order in the antiferromagnet PrSn3

At several $\text{(h+}\text{1}\text{2}\text{0 0)}$ reciprocal lattice positions of PrSn₃, we observed Bragg scattering of neutrons which is purely due to the nuclear spin polarization of ¹⁴¹Pr, and could measure the temperature dependence of the polarization between 10 mK and 4.2 K. From the perfectly polarized state of the nuclear spins, the difference between the spin-dependent nuclear scattering lengths b⁺ and b^- has been determined to be b⁺ - b^- = -0.110 ± 0.006 × 10^-12 cm, which is significantly larger in magnitude than the previously reported value. An additional electronic polarization which is linearly proportional to the nuclear spin polarization has also been observed.     

Transmission of electrons through ferromagnetic material and applications to detection of electron spin polarization

The salient features of the total low energy inelastic electron scattering cross section in transition metals are described by a constant term σ₀ plus a term σ_d that is proportional to the number of unoccupied d-orbitals. This simple model predicts that low energy electrons transmitted through a ferromagnetic ultrathin film acquire a transport spin polarization a(χ). Using the ratio σ₀/σ_d as the only adjustable parameter, the model predicts the enhancement of the spin polarization of the low energy cascade electrons as well as a(χ) in reasonable agreement with the existing observations on Fe, Co and Ni. A detector for electron spin polarization P based on the spin dependent transmission of electrons through ferromagnetic material is proposed which should be superior to existing P-detectors by 1–2 orders of magnitude.     

Quantum size effect in electron transmission through Cu and Ag films on W(110)

The transmission coefficient of very low energy electrons ( ? 10 eV) normally incident on (111) epitaxial films of Cu and Ag on W(110) is modulated by interference between scattering from the vacuum/metal and metal/metal interfaces. Comparison with calculations of free-electron scattering from a one-dimensional potential model, in which grading of the metal/metal interface is represented by a smoothing of the potential step, indicates that this interface is abrupt within approximately one layer spacing. We obtain a value of 11.0 (8.0) ± 1.0 eV for the inner potential of Cu (Ag) and mean free path lengths of $\text{39 ± 8}\text{A}\text{?}$ at an energy of 7.0 eV relative to the Fermi energy and $\text{29 ± 11}\text{A}\text{?}$ at 9.0 eV for Cu, and $\text{25 ± 10}\text{A}\text{?}$ at 7.5 eV for Ag. Work function values are obtained by the field emission retarding potential technique. We investigate the effects of the surface potential barrier, inelastic scattering and surface roughness, and evaluate the validity of the one-dimensional model presented.     

The magnetic dipole moment of 55Co

The ground state g-factor for ⁵⁵Co has been measured as $\text{¦g¦= 1.378±0.001}$ by the technique of nuclear magnetic resonance on oriented nuclei. The temperature dependence of γ-ray anisotropy in the ⁵⁵Fe daughter decay determines both the 1408 keV level spin and the ⁵⁵Co ground state spin to be $\text{7}\text{2}$, and yields values of mixing ratios in the 1037 keV β-transition and the 477 keV γ-transition. The configuration mixing model is used to discuss 1f_{$\text{7}\text{2}$} moment systematics.     

Positive spin polarization in field emission from Ni (110) and demagnetization by hydrogen adsorption

The spin polarization of field-emitted electrons from the (110)-surface of ferromagnetic Ni was observed to be P = (+ 5 ± 2)% (majority spin electrons predominant). This result can be understood qualitatively in the framework of the Stoner-Wohlfarth-Slater model, using hybridized s-d bands. Adsorption of hydrogen (saturation coverage) was found to reduce the spin polarization of electrons emitted along [110] to P (H₂) = (+ 1 ± 2)%, suggesting a demagnetization of the (110)-surface of Ni by hydrogen chemisorption.     

Electron spectroscopic studies of clean and oxidized iron

X-ray photoelectron spectroscopy (XPS) and soft X-ray appearance potential spectroscopy (APS) together with Auger electron spectroscopy (AES) were used to study the electronic properties of clean and oxidized (Fe₃O₄) iron surfaces. The features arising from excitations of electrons from Fe 2p core levels are discussed consistently within the common one-electron picture (i.e. neglecting final state effects). For pure Fe the shape of the APS L₃ peak is evaluated taking into consideration the theoretical density of states above the Fermi level and is found to agree well with that observed. As a consequence it is shown that in this case the appearance potential is about 1 eV larger than the threshold energy for the excitation of a core electron to the Fermi level. Thus for $\text{2p}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}$ electrons this quantity results to be 704.8 eV from both XPS and APS techniques. Successive oxidation at 500°C leads to an increase of the appearance potentials of the Fe 2p levels by only 0.5 eV, whereas the positions of the corresponding XPS peaks are shifted by as much as 3.5 eV. However this apparent disagreement can be eliminated by taking into account the above mentioned effect concerning the appearance potentials from pure Fe and the fact that the threshold energies (which determine the appearance potentials) of the XPS signals are shifted only by 1.7 eV. This example demonstrates that considerable care has to be taken in discussing “binding energies” or “chemical shifts” as derived from different electron spectroscopic techniques. The observed splitting of the MVV Auger transition of Fe at 47 eV upon oxidation is interpreted in terms of the qualitative features of the valence band structure of Fe₃O₄ and ascribed to the participation of a cross-transition between O 2p and Fe 3p states.     

Spectroscopy of 41K by thermal neutron capture in 40K

The γ-ray spectrum emitted after thermal neutron capture in ⁴⁰K has been studied at the ILL high flux reactor with curved crystal Bragg, pair and Ge(Li) spectometers. 585 transitions were assigned to the reaction ⁴⁰K(n, γ)⁴¹K and 490 of them were placed into a ⁴¹K level scheme; 68 new states are proposed. On the basis of γ-ray branches to states with established spin and parity, many new spin-parity assignments were made. The level energies up to 4 MeV were measured with a precision of 8–50 eV relative to the 411.8 keV ¹⁹⁸Au standard, those above 4 MeV with a precision of 50–100 eV. The spin of the capture state was found to be $\text{I =}\text{7}\text{2}$; the neutron binding energy was determined to E_B = 10095.25(10) keV. The level density of $\text{I}{}^{\mathrm{\pi }}\text{=}\text{5}\text{2}{}^{\mathrm{\pm }}\text{,}\text{7}\text{2}{}^{\mathrm{\pm }}\text{,}\text{9}\text{2}{}^{\mathrm{\pm }}$ states was analyzed in terms of the constant-temperature Fermi gas model. It was shown that in this spin window the level scheme is almost complete up to an excitation energy of 5 MeV.     

Spin-wave scattering from A γ-Fe47Mn53alloy

Spin waves in the antiferromagnetic alloy γ-Fe_0.5Mn_0.5 have been studied at $\text{295° K(}\text{T}\text{T}{}_{\mathrm{N}}\text{= 0.63)}$ by the inelastic neutron scattering technique. We observed an isotropic dispersion and obtained a value for the spin-wave velocity of 255 ± 30 meV Å (3.88 ± 0.50 × 10⁶ cm/sec), which is the order of the spin-wave velocity in Cr (a typical itinerant antiferromagnet). The energy gap at q = 0 was found to be 7.0 ± 0.5 meV. These results suggest the existence of a long-range spin ordering in the conduction electrons of this alloy.     

Spinpolarisation und Winkelverteilung der Elektronen nach Anregung verschiedener Zustände des Hg-Atoms

At energies above ～ 50 eV, electrons scattered inelastically from mercury atoms show a similarity to elastically scattered electrons in both spin polarization and angular distribution. This similarity vanishes at primary energies below ～ 30 eV for the 6p′³ P ₁-channel (11.0 eV energy loss) and below～ 25 eV for the 6¹ P ₁-channel (6.7 eV energy loss).     

X-ray photoelectron spectroscopic study of perovskite titanates and related compounds: An example of the effect of polarization on chemical shifts

The differences of the binding energy of the Ti 2P_{$\text{3}\text{2}$} electrons obtained by X-ray photoelectron spectroscopy in various perovskite type titanates and related compounds have been studied. The titanium compounds studied were titanium dioxide (anatase and rutile), calcium titanate, strontium titanate, lead titanate and barium titanate. The oxidation number of the titanium ion for all of these compounds is formally 4+. However, the X-ray photoelectron spectra show small shifts in the Ti 2p_{$\text{3}\text{2}$} binding energy as the cation is varied. An analysis of data led to the conclusion that this shift is mainly due to differences in polarization energy between these compounds.     

Spin-resolved photoemission study of in situ grown epitaxial Fe layers on W(110)

Spin- and angle-resolved photoemission spectroscopy of in situ grown epitaxial Fe layers on W(110) shows bulk-like behavior for more than two atomic Fe layers. For about ten and more atomic layers of Fe we find a spin polarization to be about -100% near the Fermi energy and +80 % between 1 eV and 3 eV binding energy. For the bilayer of Fe drastic changes in the spin-resolved spectra and a 20 % enhancement of the spin polarization compared to the bulk value are observed. The monolayer of Fe is ferromagnetically ordered with a spin polarization reduced by about 50%. A switching of the easy magnetization axis from [001] to [11&#x0304;0] is observed in the spin polarization with decreasing Fe layer thickness near d = (65±5) Å.     

Electrical charging of non-conductors in a photoelectron spectrometer; effect of X-ray source voltage

The electrical charging on samples of gadolinium trifluoride, sodium fluoride and fused silica, has been investigated as a function of the voltage in the X-ray source of a photoelectron spectrometer. The results can be expressed in the form,E_c = d + c(V – V₀) + a(1 - e^{?b(V – V₀)}) an equation which expresses the linear dependence of the intensity of the photoelectrons on X-ray intensity and the dependence of the low energy electrons as that corresponding to the equivalent electrical circuit consisting of an emf, a capacitor, and a resistor. With gadolinium trifluoride and sodium fluoride, both of which have a relatively high photoconversion, the electrical potential is positive for all voltages. With fused silica, which has a relatively low photoemission, the electrical potential is negative for the lower voltages. Relative to an assumed value of 83.8 eV for the binding energy for Au(4f_{$\text{7}\text{2}$}) of gold deposited on NaF and GdF₃, the charge corrected values for F(1s) and the Gd(4f_{$\text{sol7}\text{2}$}) orbital binding energies are determined to be 684.57 ± .07 and 10.1 eV, respectively.     

A new spin effect in photoemission with unpolarized light: Experimental evidence of spin polarized electrons in normal emission from Pt(111) and Au(111)

Unpolarized light ejects spin polarized electrons from Pt(111) and Au(111) even if the electron emission occurs normal to the surface. For off normal incidence of 11.8 eV, 16.9 eV, and 21.2 eV radiation, and for the main peaks in the photoemission spectra, a degree of spin polarization of up to 30% or more is found for the spin polarization component P _y perpendicular to the reaction plane. A crystal rotation about its surface normal does not change P _y . P _y is largest for transitions from bands with symmetry ₆ ³ . All these experimental findings agree with a recent theoretical prediction [1] of a new spin effect by Tamura and Feder.     

Trapping probabilities and desorption energies of alkali atoms on a clean and an oxygen covered tungsten (110) surface

Alkali atoms were scattered with hyperthermal energies from a clean and an oxygen covered (θ ≈ 0.5 ML) W(110) surface. The trapping probability of K and Na atoms on oxygen covered W(110) has been measured as a function of incoming energy (0–30 eV) and incident angle. A considerable enhancement of trapping on the oxygen covered surface compared to a clean surface was observed. At energies above 25 eV there are still K and Na atoms being trapped by the oxygen covered surface. From the temperature dependence of the mean residence time τ of the initially trapped atoms the pre-exponential factor τ₀ and the desorption energy Q were derived using the relation: $\text{τ = τ}{}_0\text{exp}\text{(}\text{Q}\text{kT}{}_{\mathrm{<mtext>s</mtext>}}\text{)}$. On clean W(110) we obtained for Li: $\text{τ}{}_0\text{= (8 ±}\text{8}\text{4}\text{) × 10}{}^{\mathrm{?14}}\text{sec}$, Q = (2.78 ± 0.09) eV; for Na: τ₀ = (9 ± 3) × 10^?14 sec, Q = (2.55 ± 0.04) eV; and for K: τ₀ = (4 ± 1) × 10^?13 sec, Q = (2.05 ± 0.02) eV. Oxygen covered W(110) gave for Na: τ₀ = (7 ±3) × 10^?15 sec, Q = (2.88 ± 0.05) eV; and for K: $\text{τ}{}_0\text{= (1.3 ±}\text{0.9}\text{0.6}\text{) × 10}{}^{\mathrm{?14}}\text{sec}$, Q = (2.48 ±0.05) eV. The adsorption on clean W(110) has the features of a supermobile two-dimentional gas; on the oxygen covered W(110) adsorbed atoms have the partition function of a one-dimen-sional gas. The binding of the adatoms to the surface has a highly ionic character in the systems of the present experiment. An estimate is given for the screening length of the non-perfect conductor W(110):k_s^?1≈ 0.5 Å.     

Anomalous two-electron auger resonance in thorium near the 5d(O5) photothreshold

The photoexcited $\text{O}{}_5\text{P}{}_3\text{V (5d}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}\text{6p}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}\text{valence}\text{)}$ Auger emission line for thorium metal shows an anomalous increase in kinetic energy of ～ 1 eV as the photon energy hv is increased through the atomic-like 5d → 5f resonant excitation at hv_r = 89 eV. Possible mechanisms for this anomalous behavior are discussed, and it is suggested that it can be interpreted as a two-electron resonance involving the O₅P₃V Auger excitation and a shake-up satellite of the $\text{6p}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}$ core level excitation.     

Delayed onset of 4d photoemission relative to the giant 4d photoabsorption of La

For the giant 4d photoabsorption of La, both the total photoabsorption spectrum and the N_4.5-derived Auger emission intensity spectrum increase significantly above hν ? 112 eV, with spectral peaks at hν = 118 and 119 eV, respectively. However, the predominant 4d photoemission partial cross section shows a delayed onset of ～ 4 eV, with a peak at hν = 121 eV, while the 5s, 5p, and 5d partial cross sections all show a strong resonant enhancement at lower energies, with spectral peaks at hν = 116.6 eV. These results are compared with a recent many-body calculation for Ce. The photon energy dependence of the La 4d_{$\text{5}\text{2}$}/4d_{$\text{3}\text{2}$} photo-emission branching ratio is consistent with a “final-state model.”     

Low-temperature electron radiation damage in scandium

Electron irradiation of hcp scandium at T ? 12 K allowed to determine the energy threshold for Frenkel-pair creation, T_d = 13.8 ± 0.5 eV, and the defect resistivity, $\text{?}{}_{\mathrm{<mtext>F</mtext>}}\text{≈ 5 × 10}{}^{\mathrm{?3}}\text{Ω}\text{cm/F.P}$. The annealing spectrum exhibits four substages between 20 and 70 K, a broad substage centered at 105 K attributed to interstitial long-range migration, and a stage III between 240 and 300 K.