Optically detected electron resonance in phosphorus-doped ZnTe

Samples of ZnTe showing near gap edge luminescence predominantly due to exciton recombination at shallow neutral acceptors and donor- acceptor pair recombination have been investigated using optically detected magnetic resonance (ODMR). Emission polarization changes at 2.318 eV were observed due to magnetic resonance of electrons at g_e = + 0.401 ± 0.004. The observations are consistent with the donor trapped electron resonance resulting from microwave induced changes in donor-acceptor pair photoluminescence.     

Quantum interference effects in a multi-driven transition Fg = 3 ↔ Fe = 2

We calculated and studied the quantum coherence effects of a degenerate transition F_g = 3 ↔ F_e = 2 system interacting with a weak linearly polarized (with σ_± components) probe light and a strong linearly polarized (with σ_± components) coupling field. Due to the competition between the drive Rabi frequency and the Zeeman splitting, electromagnetically induced transparency (EIT) and electromagnetically induced absorption (EIA) are appeared at the different values of applied magnetic field in both cases that the Zeeman splitting of excited state Δe is smaller than the Zeeman splitting of ground state Δg (i.e., Δe < Δg) and Δe > Δg. It is shown that the resonance is broader and contrasts are higher for Δe < Δg than that for Δe > Δg at the same Rabi frequencies of probe and coupling fields.     

E0/E2 and E2/M1 multipole mixing amplitudes of γ-transitions in 192Pt

Angular correlation measurements of conversion electrons and γ-rays in ¹⁹²Pt following the decay of ¹⁹²Ir (74 d) have been made. In particular, the 296 keV e^?-316 keV γ correlation was measured in order that the electric monopole admixture in the 296 keV transition could be determined. The results of the angular correlation coefficients measured here and the ratio of K-shell to L_III shell conversion electrons measured by others are: ?0.09 < q < +0.26 as +62 < λ < +92 or ?0.29 < q < ?0.06 as ?5 < λ < +45. A possible explanation of the disagreement between two earlier measurements is suggested. The angular correlation coefficients for the measured e^?-γ and γ-γ cascades and the derived multipole mixing ratios are tabulated and compared with other recent measurements and with the predictions of the Kumar-Baranger nuclear model.     

Zeeman spectroscopy of exciton bound to trigonal acceptor center in ZnTe

Zeeman effects have been measured for the A^c₁ line at 2.368 eV in ZnTe. The results are interpreted in terms of exciton recombination at a neutral acceptor center in a strong trigonal crystal field. The relevant g-factors are : g_e = -0.50 ± 0.05 for the electron ; g_h = +0.90 ± 0.05 for the hole.     

The influence of phonons on the optical properties and the conductivity of quasi-one-dimensional metals

The frequency dependent conductivity σ(ω) completely taking into account the interaction between electrons is studied. The shape and the temperature dependence of optical absorption near the frequency of a molecular phonon activated due to the interaction with electrons are found. For a system with attractive sign of the e-e backward scattering amplitude g₁<0 an absorption edge near the gap 2Δ in the electronic spectrum is studied. A low frequency conductivity is discussed. The properties under consideration depend essentially on the magnitudes of e-e interactions and are critical to the sign of g₁.     

Magneto-optical study of the I2 bound exciton in ZnTe

The 1L0-phonon replica of the I₂ bound exciton in ZnTe at 2.374 eV is fully resolved into a quintet at fields of 130 kG. Analysis of the data shows that the I₂ complex consists of an exciton bound to an $\text{ionized}$ donor or acceptor; the electron and hole gyromagnetic ratios deduced, $\text{g}{}_{\mathrm{h}}\text{= ? 1.2}$ and g_e = ± 1.7, are in excellent agreement with the values determined from recent spin-flip scattering experiments, viz. g_h = 1.07 ± 0.1, g_e = 1.74 ± 0.05.     

Electronic properties of charged fullerenes characterized by EPR and Vis-NIR spectroscopy

EPR and Vis-NIR absorption spectra have both been measured for clarification of contradictory statements about the para-and diamagnetic states of fullerenes. Thereby identification of one sharp EPR signal in solution at room temperature to C ₆₀ ^? (g=2.000±4.0001; ΔB=0.07±0.01 mT) could be made upon using different fullerene sources (TechnoCarbo, Hoechst) and methods of anion generation (chemically, electrochemically, and photochemically). This fact is also supported by the similar observation for a monosubstituted derivative (g=1.9999; ΔB=0.10 mT), in which a small broadening of this sharp signal is found originating from additional¹H hyperfine interactions. Furthermore theg-values of the radical anions of C₆₀ increase with charge (g(C ₆₀ ^? <g(C ₆₀ ^2? ) < <g(C ₆₀ ^3? ) <g(C ₆₀ ^5? )) indicating largest contributions from spin-orbit coupling for the monoanion. No diamagnetic states for the dianions of [60]- and [70]- fullerenes could be found so far but biradical species with largest zero field splittingsD=2.7 mT (C ₆₀ ^2? ), andD=3.1 mT (C ₇₀ ^2? ), respectively. The cation formation of C₆₀ (g=2.0023-2.0029; ΔB=0.15-0.20 mT) with antimony pentachloride was controlled by mass spectrometry. Stable cations were found only in methylenechloride. In other solvents like toluene addition reactions seem to occur.     

Second order QCD contributions to thrust and spherocity

In e⁺e^? annihilation there are regions of high spherocity S and low thrust $\text{T(S >}\text{16}\text{3π}{}^2\text{and}\text{T <}\text{2}\text{3}$ in which these distributions are given in QCD perturbation theory by the subprocesses e⁺e^? → qq?GG and e⁺e^? → qq?qq? neglecting only cubic and higher order terms in α_S. We give the corresponding QCD predictions which suggest that the calculable corrections to these variables may be slowly convergent.     

Type-III and IV interacting Weyl points

3+1-dimensional Weyl fermions in interacting systems are described by effective quasi-relativistic Green’s functions parametrized by a 16-element matrix e _α ^μ in an expansion around the Weyl point. The matrix e _α ^μ can be naturally identified as an effective tetrad field for the fermions. The correspondence between the tetrad field and an effective quasi-relativistic metric g_μν governing the Weyl fermions allows for the possibility to simulate different classes of metric fields emerging in general relativity in interacting Weyl semimetals. According to this correspondence, there can be four types of Weyl fermions, depending on the signs of the components g ⁰⁰ and g ₀₀ of the effective metric. In addition to the conventional type-I fermions with a tilted Weyl cone and type-II fermions with an overtilted Weyl cone for g ⁰⁰ > 0 and, respectively, g ₀₀ > 0 or g ₀₀ < 0, we find additional “type-III” and “type-IV” Weyl fermions with instabilities (complex frequencies) for g ⁰⁰ < 0 and g ₀₀ > 0 or g ₀₀ < 0, respectively. While the type-I and type-II Weyl points allow us to simulate the black hole event horizon at an interface where g ⁰⁰ changes sign, the type-III Weyl point leads to effective spacetimes with closed timelike curves.     

Magnetoreflectance of the Γ6 – Γ8 exciton ground state in cubic ZnSe

Magnetoreflectance measurements on the ground state of the Γ₆ – Γ₈ free exciton in cubic ZnSe in magnetic fields up to 18 T are reported. The splitting between the |1, ±1〉 states was derived from the measured difference spectrum between σ⁺ and σ^--polarized reflectance in Faraday configuration. The splitting between the two states corresponding to |2, 0〉 and |1, 0〉 at B = 0 was determined by means of a lineshape analysis. We derive an electron g-factor g = 1.48 ± 0.25, in reasonable agreement with existing k · p calculations, and obtain an effective hole g-value $\text{K}\text{?}\text{= -0.26±0.06}$. In addition, we find an upper limit for the short range electron-hole spin exchange energy Δ ? 0.1 meV, which is considerably smaller than values, which is considerably smaller than values reported in the literature, but agrees with recent results on ZnTe obtained by uniaxial stress and also magnetoreflectance measurements.     

Contribution of gluons and coloured Higgs bosons to e+-e− annihilation into three jets

Three-jet thrust and angular distributions in e⁺e^? annihilation are calculated in the integer-charge quark model. The complete contributions of gluons and Higgs scalars are presented. Deviations from QCD results are in general less than or comparable to the experimental errors, except for m_g ? 2 GeV and m_H ? 30 GeV.     

Valence band contributions to photoluminescence excitation spectra of tightly bound holes in zincblende semiconductors

Photoluminescence excitation (PLE) spectra of deep acceptor states in ZnSe, for example the Cu-related luminescence band at ≈1.95 eV, contain a prominent excitation band at ≈3.25 eV. This band lies above the structure marking the lowest direct E_O band gap E_g by the spin-orbit splitting energy Δ of the valence bands at Γ. The higher energy feature is either absent or greatly de-emphasised in the PLE spectra of shallow acceptor states in ZnSe and of the oxygen iso-electronic trap in ZnTe, where the electron rather than the hole is tightly bound. However, a significant PLE component at E_g + Δ is observed for deep acceptor-like states in ZnTe, where Δ is ≈0.95 eV. Efficient PLE at E + Δ for luminescence from deep acceptor-like states is shown to be consistent with the extended wave-vector contributions to the bound state wave-functions of holes of binding energies ≈Δ.     

Electronic and structural transitions in stoichiometric and nearly-stoichiometric lanthanum trihydride and trideuteride. A 139La and 1H nuclear magnetic resonance study.

We report the results of NMR measurements of the ¹³⁹La and 1p resonances in stoichiometric and nearly-stoichiometric lanthanum trihydride, LaH_x, and trideuteride, LaD_x, 2.89?x?3.00, covering the temperature range, 4.2 K?T?350 K. The Knight shift of the ¹³⁹La resonance is consistent with metallic behavior for T?210 K and with semiconducting behavior characterized by a band gap, E_g=0.10 eV, for T<210 K. In contrast, the ¹H T₁ follows T₁T=constant, consistent with metallic behavior, at least down to 77 K. Both the ¹³⁹La lineshape at T<210 K and the second moment of the ¹H resonance at 4.2 K confirm that the octahedral site hydrogen (deuterium) are randomly displaced from the geometrical centers of the octahedral sites.     

Monte Carlo study of the critical behavior and magnetic properties of La2/3Ca1/3MnO3 thin films

Critical exponents offer important information concerning the interaction mechanisms near the paramagnetic to ferromagnetic transition. In this work a Monte Carlo-Metropolis simulation of the critical behavior in La_2/3Ca_1/3MnO₃ thin films is addressed. Canonical ensemble averages for magnetization per site, magnetic susceptibility and specific heat of stoichiometric manganite within a three-dimensional classical Heisenberg model with nearest magnetic neighbor interactions are computed. The La_2/3Ca_1/3MnO₃ thin films were simulated addressing the thickness influence and thermal dependence. In the model, Mn magnetic ions are distributed on a simple cubic lattice according to the perovskite structure of this manganite. Ferromagnetic coupling for the bonds Mn³⁺-Mn³⁺(e_g-e_g′), Mn³⁺-Mn⁴⁺(e_g-d³) and Mn³⁺-Mn⁴⁺(e_g′-d³) were taken into account. On the basis of finite-size scaling theory, our best estimates of critical exponents, linked to the ferromagnetic to paramagnetic transition, for the correlation length, specific heat, magnetization and susceptibility are, respectively: v=0.56±0.01, α=0.16±0.03, β=0.34±0.04γ and γ=1.17±0.05. These theoretical results are consistent with the Rushbrooke equalitiy α+2β+γ=2.     

New evaluation of muon (g − 2) hadronic anomaly

The hadronic part a_H of the muon g-factor anomaly $\text{a ≡}\text{(g ? 2)}\text{2}$ is evaluated from latest data on σ(e⁺e^? → hadrons). For a p-wave ππ scattering length of a₁ = 0.04±0.005 we calculate a_H = (66±10) × 10^?9, compared to a(experiment) ? a(QED) = (60±29) × 10^?9. Half of the uncertainty on a_H is associated with the energy interval $\text{0.92 <}\text{s}\text{< 2}\text{GeV}$.     

Negative boron isotope effect of a ‘2Δ’ gap peak in Raman spectra from non-magnetic borocarbide superconductors

The nickel borocarbides RNi₂B₂C, R=Y or Lu, have a superconducting T_c of 15-16 K and exhibit properties consistent with an anisotropic s-wave gap. We briefly review their properties. Electronic Raman scattering results are presented on YNi₂B₂C containing ¹¹B or ¹⁰B. In A_1g and B_1g Raman symmetries, there is no shift in the position of the ‘2Δ’ peak with B-isotope. There is a distinct negative shift, however, in B_2g symmetry. This is interpreted as a negative isotope shift for the gap Δ on that portion of the Fermi surface where the magnitude of the B_2g Raman vertex is large.     

Electron temperature measurements in low-density plasmas by helium spectroscopy

Methods of measuring the electron temperature in low-density plasmas by He spectroscopy are examined. These utilize either the relative intensities of singlet and triplet lines or the absolute intensities of single lines. Calculations from measured and theoretical data show that both methods are seriously influenced by secondary processes, the most important of which are excitation from the metastable levels 2¹S and 2³S, and excitation transfer in electron-atom collisions combined with imprisonment of resonance radiation. The calculations give parameter limits for the validity of different methods and combinations of lines. Due to the secondary processes, the determination of T_e from relative line intensities is restricted to low-density, short-duration plasmas (typically n_e < 2 × 10¹⁶ m^-3, t_ex < 5 × 10^-6 s) or to even lower densities that depend on the apparatus dimensions (typically n_e < 3 × 10¹⁵ m^-3, L ≈ 0.1 m). For the determination of T_e from absolute line intensities, the situation is more favourable and, with a suitable choice of lines, typical restrictions on n_e and t_ex are n_e < 5 × 10¹⁷ m^-3, t_ex < 10^-5 s or n_e < 10¹⁷ m^-3, L ≈ 0.1 m for electron temperatures above 10 eV. For temperatures below 10 eV and degrees of imprisonment below 7% measurements are possible for electron densities up to 10¹⁹–10²⁰ m^-3, without any limits on t_ex or L.     

Gravity modulation study on opposed flame spread over thin solid fuels

In this work a numerical investigation has been carried out to study the effect of g-jitter on zero-gravity (0g_e) opposed flow spreading flame over thin solid fuels. For comparison simulations have also been carried out for normal gravity (1g_e) downward spreading flames. G-jitter is emulated by gravity modulation of sinusoidal (A_ge sin(2πt/T_ge)) gravity perturbation (g-perturbation) of a particular time-period (T_ge) and amplitude (A_ge) over a selected base gravity level (0g_e or 1g_e). The response of flames at 0g_e base gravity and at 1g_e base gravity was different to the imposed g-perturbation. While at 0g_e the mean and the amplitude of the oscillatory flame spread rate (FSR) magnified with increase in the time period of g-perturbation, interestingly for the 1g_e flame a maximum mean FSR and oscillation amplitude occurs at certain perturbation time period. Further, at very small perturbation time-periods (T_ge) the FSR at 1g_e was lower than the steady state FSR. The amplitude of oscillatory FSR increased with increase in perturbation amplitude (A_ge). However, the 0g_e flame which is little affected (compared to 1g_e flame) at small perturbation amplitude (A_ge) is affected severely at large perturbation amplitude (A_ge). Both the gas phase and fuel pyrolysis (or fuel response) follow perturbation signal with a lag but fuel pyrolysis is more sluggish and lags behind gas phase. The phase lag between fuel pyrolysis and gas increases at smaller time-periods (T_ge) and tends to enhance the effect of external perturbation whereas at larger time-periods (T_ge) this lag inhibits the effect of external perturbation.