Does power ultrasound affect Nafion® dispersions?

The effect of low frequency power ultrasound on Nafion® ionomer used for fabricating proton exchange membrane fuel cell (PEMFC) and water electrolyzer (PEMWE) catalyst inks was investigated. In this study, a series of Nafion® dispersions having three concentrations (10, 5, and 2.5% w/v) were studied under various irradiation durations (t_us), at fixed ultrasonic frequency (f = 42 kHz) and ultrasonic power (P > 2 W), under either controlled or unregulated bulk solution temperature conditions using a laboratory ultrasonic cleaning bath. Viscosity (η), thermal degradation, and glass transition temperature (T_g) for all Nafion® dispersion samples was measured and compared to untreated Nafion® samples. In our conditions, it was found that power ultrasound lowered the viscosity of all tested Nafion® dispersion samples; whilst thermogravimetric and differential scanning calorimetry analyses showed that for all ultrasonically irradiated samples, a negligible overall polymer degradation and no obvious change in T_g was observed under controlled and unregulated bulk temperature conditions. It was found that it is possible that acoustic cavitation causes depolymerisation followed by a polymerisation initiation step during ultrasonication. By comparing the ultrasonically treated and high-shear mixed samples, it was also observed that acoustic and hydrodynamic cavitation played an important role in the reduction of dispersion viscosity.     

Does power ultrasound (26 kHz) affect the hydrogen evolution reaction (HER) on Pt polycrystalline electrode in a mild acidic electrolyte?

In this study, we investigated the effects of power ultrasound (26 kHz, up to ∼75 W/cm², up to 100% acoustic amplitude, ultrasonic horn) on the hydrogen evolution reaction (HER) on a platinum (Pt) polycrystalline disc electrode in 0.5 M H₂SO₄ by cyclic and linear sweep voltammetry at 298 K. We also studied the formation of molecular hydrogen (H₂) bubbles on a Pt wire in the absence and presence of power ultrasound using ultra-fast camera imaging. It was found that ultrasound significantly increases currents towards the HER i.e. a ∼250% increase in current density was achieved at maximum ultrasonic power. The potential at a current density of −10 mA/cm² under silent conditions was found to be −46 mV and decreased to −27 mV at 100% acoustic amplitude i.e. a ΔE shift of ∼+20 mV, indicating the influence of ultrasound on improving the HER activity. A nearly 100% increase in the exchange current density (j_o) and a 30% decrease in the Tafel slope (b) at maximum ultrasonic power, was observed in the low overpotential region, although in the high overpotential region, the Tafel slopes (b) were not significantly affected when compared to silent conditions. In our conditions, ultrasound did not greatly affect the “real” surface area (A_r) and roughness factor (R) i.e. the microscopic surface area available for electron transfer. Overall, it was found that ultrasound did not dramatically change the mechanism of HER but instead, increased currents at the Pt surface area through effective hydrogen bubble removal.     

Output power enhancement of all gas-phase iodine laser by?addition of hydrocarbon gases

In this work, we studied the output power enhancement of an all gas-phase iodine laser (AGIL) by the addition of hydrocarbon gases. Enhancement is expected because hydrocarbon gases might scavenge Cl atoms, which are strong quenchers of the upper state of the laser medium, I(² P _1/2). In AGILs, suppression of the Cl atom concentration is the key to improving the efficiency of the operation of the laser because Cl atoms are inherently generated by the self-annihilation of the energy donor, NCl(a¹ Δ). We found that the addition of CH₄ gave the best results, because of its high scavenging rate constant and inertness to I(² P _1/2). An enhancement of 10% was observed in the output power when CH₄ was added at a flow rate twice that of NCl₃. On the other hand, when C₂H₄ or C₂H₂ were added at the same flow rate as that of CH₄, the output power reduced despite their fast removal rate of Cl atoms. The reason for the reduced output power was that the unsaturated bonds scavenged not only the Cl atoms but also the H atoms, resulting in a low density of H atoms, and this decelerated the production of NCl(a¹ Δ). The observed laser characteristics could reasonably be explained by numerical model calculations. To our knowledge, this is the first report of successful output power enhancement of an AGIL using a chemical agent.     

Does molecular rotation affect the transition Reynolds number?

We examine recent claims that the molecular rotation, which manifests itself in the form of bulk viscosity, has a measurable effect on the transition Reynolds number in pipe flow. We also conduct new experiments using argon. We conclude that the effects, if they exist at all, are negligibly small for the conditions of the experiment.     

Does a single zealot affect an infinite group of voters?

A method for studying the exact properties of a class of inhomogeneous stochastic many-body systems is developed and presented in the framework of a voter model perturbed by the presence of a "zealot," an individual allowed to favor an "opinion." We compute exactly the magnetization of this model and find that in one (1D) and two dimensions (2D) it evolves, algebraically ( approximately t(-1/2)) in 1D and much slower ( approximately 1/ln(t) in 2D, towards the unanimity state chosen by the zealot. In higher dimensions the stationary magnetization is no longer uniform: the zealot cannot influence all the individuals. The implications to other physical problems are also pointed out.     

Quo vadis medical ultrasound?

The last three decades of development in diagnostic ultrasound imaging and technology are briefly reviewed and the impact of the crucial link between the two apparently independent research efforts, which eventually facilitated implementation of harmonic imaging modality is explored. These two efforts included the experiments with piezoelectric PVDF polymer material and studies of the interaction between ultrasound energy and biological tissue. Harmonic imaging and its subsequent improvements revolutionized the diagnostic power of clinical ultrasound and brought along images of unparalleled resolution, close to that of magnetic resonance imaging (MRI) quality. The nonlinear propagation effects and their implications for both diagnostic and therapeutic applications of ultrasound are also briefly addressed. In diagnostic applications, the impact of these effects on image resolution and tissue characterization is reviewed; in therapeutic applications, the influence of nonlinear propagation effects on highly localized tissue ablation and cauterization is examined. Next, the most likely developments and future trends in clinical ultrasound technology, including 3D and 4D imaging, distant palpation, image enhancement using contrast agents, monitoring, and merger of diagnostic and therapeutic applications by e.g. introducing ultrasonically controlled targeted drug delivery are reviewed. Finally, a possible competition from other imaging modalities is discussed.     

Does break-up affect 9Be +209Bi fusion at the barrier?

The ⁹Be +²⁰⁹Bi fusion cross sections were measured in the 36.0 MeV ≤ E_lab≤ 50.0 MeV range, down to 0.6 mb, with high accuracy via in-beam detection of the ground state α-decay of the evaporation residues produced. The elastic scattering cross sections around 150° and 135° were also obtained with moderate angular resolution. The cross sections below the barrier are reproduced by coupled channel calculations which include only one break-up channel with a moderate strength and a phenomenological renormalization of the potential depth. These simple calculations overestimate the cross sections above the barrier most likely due to the fact that the ⁹Be break-up process becomes much stronger. The barrier distributions extracted do not have evident break-up signature since they show one-barrier structure. Received: 22 February 1999 / Revised version: 26 March 1999     

Does “game participation cost” affect the advantage of heterogeneous networks for evolving cooperation?

Masuda [N. Masuda, Participation costs dismiss the advantage of heterogeneous networks in evolution of cooperation, Proceedings of the Royal Society B 274 (2007) 1815-1821] reported that a game participation cost (expressed by adding same negative values to all four elements in a 2 × 2 payoff matrix) affects the advantage of heterogeneous networks in the evolution of cooperation. We show that this finding is not always true depending on the features of the network, indicating that participation costs help cooperation in certain situations rather than destroy it. In a weaker dilemma game on a scale free network derived from the Barabasi & Albert algorithm with a larger average degree, game participation cost helps rather than destroy the network reciprocity.     

Kinetic improvement of olive leaves’ bioactive compounds extraction by using power ultrasound in a wide temperature range

In this study, the effect of temperature and ultrasonic application on extraction kinetics of polyphenols from dried olive leaf was investigated. Conventional (CVE) and ultrasonic-assisted extraction (UAE) were performed at 10, 20, 30, 50 and 70 °C using water as solvent. Extracts were characterized by measuring the total phenolic content, the antioxidant capacity and the oleuropein content (HPLC–DAD/MS–MS). Moreover, Naik’s model was used to mathematically describe the extraction kinetics. The experimental results showed that phenolic extraction was faster in UAE (ultrasonic-assisted extraction) than in CVE (conventional extraction), being extraction kinetics satisfactorily described using Naik model (include VAR > 98%). Besides, the total phenolic content, the antioxidant capacity and the oleuropein content were significantly (p < 0.05) improved by increasing the temperature in both CVE and UAE. Oleuropein content reached 6.57 ± 0.18 being extracted approximately 88% in the first minute for UAE experiments.     

Injection-locked single-frequency laser with an output power of?220?W

A solid-state laser system for the next generation of gravitational wave detectors with an output power of 220?W at the wavelength of 1064?nm is presented. Single-frequency operation of the laser was achieved by injection-locking of a high-power ring oscillator to an amplified non-planar ring oscillator (NPRO) following the Pound?CDrever?CHall scheme. The high-power stage which features four longitudinally pumped Nd:YAG laser crystals as active media in a ring resonator configuration was designed for reliable long term operation. Using a non-confocal ring cavity to filter the output beam, a pure TEM₀₀ mode with 168 W output power was obtained.     

Does Σ–Σ–α Form Quasi-Bound States?

For the Σ–Σ–α system we theoretically look into the possible existence of a quasi-bound state in the framework of Faddeev calculations. We are particularly interested in the state of total iso-spin T=2, because there is no strong conversion between Ξ–N–α and ${\Lambda-\Lambda-\alpha}$ . An analytic continuation using the point method is applied to search the eigenvalue in the complex energy plane. In our results the Σ–Σ–α three-body system has two quasi-bound states (J ^π  = 0⁺) where, depending on the potential parameters in the Nijmegen NSC97 model potential, the energy ranges between ?1.4 and ?2.4 MeV and the level width is about 0.4 MeV for the ground state. In addition, we obtained the excited state at ?0.15 MeV (width 4 MeV).     

Does Chaplygin gas have salvation?

A mechanism capable to provide a natural solution to two major cosmological problems, i.e. the cosmic acceleration and the coincidence problem, is proposed. A specific brane–bulk energy exchange mechanism produces a total dark pressure, arising when adding all normal to the brane negative pressures in the interior of galactic core black holes. This astrophysically produced negative dark pressure explains cosmic acceleration and why the dark energy today is of the same order to the matter density for a wide range of the involved parameters. An exciting result of the analysis is that the recent rise of the galactic core black hole mass density causes the recent passage from cosmic deceleration to acceleration. Finally, it is worth mentioning that this work corrects a wide spread fallacy among brane cosmologists, i.e. that escaping gravitons result in positive dark pressure.     

How can soundscapes affect the preferred walking pace?

In this paper we describe an experiment whose goal is to investigate the role of the footstep sounds and soundscapes to affect the pace of a person walking in place (mimicking the act of walking without leaving the current position). Subjects were exposed to different simulated footstep sounds and soundscapes, generated in realtime while walking in place. The results show that, indeed, participants adapted their walking pace to the presented sounds, and not only footstep sounds but also soundscapes affect the walking pace. We could observe as well that perceived ease of walking correlates with the perceived naturalness of ambient sounds.     

Is the intrinsic thermoelectric power of carbon nanotubes positive?

The thermoelectric power (TEP) of single-walled carbon nanotubes (SWNTs) is extremely sensitive to gas exposure history. Samples exposed to air or oxygen have an always positive TEP, suggestive of holelike carriers. However, at fixed temperature the TEP crosses zero and becomes progressively more negative as the SWNTs are stripped of oxygen. The time constant for oxygen adsorption/desorption is strongly temperature dependent and ranges from seconds to many days, leading to apparently "variable" TEP for a given sample at a given temperature. The saturated TEP can be accounted for within a model of strong oxygen doping of the semiconducting nanotubes.     

Synthesis of titanium dioxide by ultrasound assisted sol–gel technique: Effect of amplitude (power density) variation

Titanium dioxide was successfully synthesized by utilizing sol–gel technique modified by incorporation of ultrasound as a reaction aid. The effect of amplitude of irradiation (power input varied from 19.9 to 80.8 W) on % Rutile, % yield, % crystallinity, crystallite size and morphological (scanning electron microscopy) properties of the obtained nano-TiO₂ was studied. Calcination temperatures of all the samples were kept constant at 750 °C. With increasing ultrasonic irradiation amplitude it is observed that the values of % Rutile (after calcination) increased and reached a peak value after which further increase in amplitude resulted in a decrease in the % Rutile. A similar trend was observed in the case of % crystallinity and % yield of the reaction. On the basis of these results an optimum operating ultrasonic irradiation amplitude for the reaction has been suitably established.     

Does the electron have a structure?

... it ain't likely to have a radius of exactly zero, is the conclusion of H. G. Dehmelt⁽¹⁾ from his Nobel Prize (1989) winning observations on trapped electrons. There are small discrepancies between Dehmelt's observations and the theoretical predictions of quantum electrodynamics (QED), which assumes that the electron is a point particle. Here we present evidence in support of Dehmelt's contention that the electron has a structure. Essentially, we point out that the nonrelativistic limit of QED is at variance with a fundamental principle underlying all of physics, viz. the second law of thermodynamics.     

How Does Pressure Fluctuate in Equilibrium?

We study fluctuations of pressure in equilibrium for classical particle systems. In equilibrium statistical mechanics, pressure for a microscopic state is defined by the derivative of a thermodynamic function or, more mechanically, through the momentum current. We show that although the two expectation values converge to the same equilibrium value in the thermodynamic limit, the variance of the mechanical pressure is in general greater than that of the pressure defined through the thermodynamic relation. We also present a condition for experimentally detecting the difference between them in an idealized measurement of momentum transfer.