Thermal Radiation of Graphene

Optics and Spectroscopy - The problem of thermal radiation of ideal graphene is considered based on the theoretical concepts of surface electromagnetic waves and surface impedance. The intensity of...     

利用尿素热退火方法制备氮掺杂石墨

在尿素气氛中,通过热退火实验实现石墨烯的氮掺杂. 结合光电子能谱和拉曼光谱,确定了氮在石墨烯中的掺杂构型,并发现掺杂量可以通过退火温度和时间加以调控. 电性测量表明掺杂石墨烯的电导同氮掺杂量有很好的关联性.     

热补偿腔镜热变形的研究

采用ANSYS有限元软件,系统模拟了强激光作用下的热补偿全反射硅镜的温度场分布和热变形.详细地研究了不同区域的热补偿和不同的热补偿功率大小对镜面变形峰谷值的影响.结果表明有效的热补偿对镜面变形峰谷值有很大的影响,在非光照区进行热补偿可以大大降低镜体的温度梯度,从而明显减小镜面变形的峰谷值.热补偿腔镜特别适合于机载或车载军用强激光器.     

氧化石墨烯膜各向异性热传输特性研究

氧化石墨烯膜是一类新型的层状材料。本文报道了氧化石墨烯膜的面内和垂直于面方向的热扩散率和热导率,发现垂直于面方向的热导率比面内热导率低一个数量级,展示了明显的各向异性特征。氧化石墨烯膜的导热系数远低于单层石墨烯的导热系数,其原因主要是由于氧化石墨烯膜间的接触热租和氧化石墨烯膜本身导热系数较低造成的。     

Thermal Expansion Coefficients of Thin Crystal Films

The formulas for atomic displacements and Hamiltonian of a thin crystal film in phonon occupation number representation are obtained with the aid of Green‘s function theory. On the basis of these results, the formulas for thermal expansion coefficients of the thin crystal film are derived with the perturbation theory, and the numerical calculations are carried out. The results show that the thinner films have larger thermal expansion coefficients.     

Thermal Expansion Coefficients of Thin Crystal Films

The formulas for atomic displacements and Hamiltonian of a thin crystal film in phonon occupation number representation are obtained with the aid of Green＇s function theory. On the basis of these results, the formulas for thermal expansion coefficients of the thin crystal film are derived with the perturbation theory, and the numerical calculations are carried out. The results show that the thinner films have larger thermal expansion coefficients.     

碳纳米管与石墨烯协同提高导热硅脂热性能

以甲基硅油为基础油,碳纳米管、石墨烯或碳纳米管/石墨烯混杂物为导热填料,制备复合导热硅脂.研究结果表明:以碳纳米管为单一导热填料,碳纳米管管径越小,管长越长,越有利于导热硅脂的导热性能提升.当总填充量在6％、碳纳米管和石墨烯配比为2 ∶1时,导热硅脂的热导率提高19％.碳纳米管对石墨烯纳米片起到了分隔和桥连的作用,提高...     

Size- and Temperature-Dependent Thermal Expansion Coefficient of a Nanofilm

The thermal expansion coefficient （TEC） of an ideal crystal is derived by using a method of Boltzmann statistics. The Morse potential energy function is adopted to show the dependence of the TEC on the temperature. By taking the effects of the surface relaxation and the surface energy into consideration, the dimensionless TEC of a nanofilm is derived. It is shown that with decreasing thickness, the TEC can increase or decrease, depending on the surface relaxation of the nanofilm.     

用激光测量高热可靠性电子器件的热变形

本文提出了一种测量大功率电子器件热变形的双曙光激光全息干涉法，针对一种可靠性要求很高的电子器件-火箭点火用固态继电器进行实际测试，试验结果表明，固态继电器在大负载功率工作状态时，芯片表面的干涉条纹较多，条纹弯曲程度较大，因此反映了芯片热变形和热应力增大趋势较为明显。     

高温还原氧化石墨烯膜及其导热性能

采用氧化还原法制备了结构致密且具有较高柔韧性的石墨烯薄膜,探究了薄膜经过较高退火温度还原后结构变化,并通过T型稳态法测量了其热导率,研究了还原温度对薄膜热导率和力学性能的影响。结果表明,高温还原有助于氧化石墨烯中含氧官能团的去除和sp2杂化碳晶格的恢复,并且温度越高还原效果越好。当还原温度高达2800℃时,在200~350 K温度范围内石墨烯膜的热导率在336.9~436 W·m^-1·K^-1之间,伴随着温度的升高,热导率有先增大后减小的趋势。     

高阶群速度色散引起的高斯超短脉冲宽度的展宽和形变

基于动量守恒和光参变过程中的三波耦合波方程,和负单轴非线性光学晶体CsLiB6O10的色散方程,研究了在光参变效应中超短激光脉冲由于群速度色散引起的展宽和形变。数值模拟显示,在超短脉冲波形为双曲正割形和无啁啾调制时,高阶群速度色散引起的超短脉冲为50fs时,晶体长度为10mm,紫外光213nm作为基波入射时的脉冲展宽是波长为532nm绿光在同等条件下的1.6倍。脉冲展宽程度与入射波长和晶体长度有关,波长越短和晶体长度越长则脉冲展宽和波形变化越严重,高阶色散引起的超短高斯脉冲展宽,将破坏其波形对称性并引起旁瓣现象。     

利用同位素掺杂与分形结构调控石墨烯热导率

本研究采用非平衡分子动力学方法对用Rectangle Carpet(RC)和Sierpinski Carpet(SC)分形结构布局的同位素掺杂石墨烯的热导率进行系统研究.研究表明,RC和SC结构的热导率均随分形数(m)的增加先减小后略微升高,且SC结构的热导率要低于RC结构的热导率.同时,我们通过计算声子谱、声子群速度...     

Molecular Dynamics Studies on Ballistic Thermal Resistance of Graphene Nano-Junctions

Ballistic thermal resistance of graphene nano-junctions is investigated using non-equilibrium molecular dynamics simulation. The simulation system is consisted of two symmetrical trapezoidal or rectangular graphene nanoribbons(GNRs) and a connecting nanoscale constriction in between. From the simulated temperature profile, a big temperature jump resulted from the constriction is found, which is proportional to the heat current and corresponds to a local ballistic thermal resistance. Fixing the constriction width and the length of GNRs, this ballistic thermal resistance is independent of the width of the GNRs bottom layer, i.e., the convex angle. But interestingly, this thermal resistance has obvious size effect. It is inversely proportional to the constriction width and will disappear with the constriction being wider. Moreover, based on the phonon dynamics theory, a theoretical model of the ballistic thermal resistance in two-dimensional nano-systems is developed, which gives a good explanation on microcosmic level and agrees well with the simulation result quantitatively and qualitatively.     

Thermal Conductivity of Graphene Oxide: A Molecular Dynamics Study

JETP Letters - The thermal properties of graphene oxide containing hydroxyl and epoxy functional groups were studied using non-equilibrium molecular dynamics to understand the thermal transport...     

Scaling Behavior between Heat Capacity and Thermal Expansion in Solids

We experimentally analyze the heat capacity and thermal expansion of reference solids in a wide temperature range from several Kelvin to melting temperature,and establish a universal double-linear relation between the experimental heat capacity C_p and thermal expansion β,which is different from the previous models.The universal behavior between heat capacity and thermal expansion is important to predict the thermodynamic parameters at constant pressure,and is helpful for understanding the nature of thermal properties in solids.     

A Free-Volume Model for Thermal Expansion of Metallic Glass

Many mechanical,thermal and transport behaviors of polymers and metallic glasses are interpreted by the freevolume model,whereas their applications on thermal expansion behaviors of glasses is rarely seen.Metallic glass has a range of glassy states depending on cooling rate,making their coefficients of thermal expansion vary with the glassy states.Anharmonicity in the interatomic potential is often used to explain different coefficients of thermal expansion in crystalline metals or in different ...     

大型干涉仪镜子的支承设计与温度变形分析

在星间激光通信中,涉及对大口径衍射极限激光波面的检测,为保证测量精度,必须严格控制波面干涉仪镜子的自重和温度变形。采用有限元方法对大型干涉仪镜子在不同支承方式下的表面变形进行了分析,结果表明,接触角为180°的钢带支承是较好的支承方式,反射镜表面变形峰谷(PV)值仅为1.35nm,均方根(RMS)值为0.363nm。根据这一结论,设计了一个固定支承点与浮动支承相结合的超静定钢带支承结构。在该结构下,分析了镜子轴向、径向、周向的温度梯度效应,分析数据表明,镜子的热弹性变形远大于自重变形,建议采取一定的温控措施,并采用平均效应的方法降低热效应的影响。     

热力膨胀阀感温包刚度测试系统设计

针对工业中热力膨胀阀感温包刚度测试自动化程度低,检测效率低,结果不准确等缺点,设计了一套以PLC为核心控制器的新型热力膨胀阀感温包刚度测试系统。提出了测试系统的设计目标和系统结构,并详细阐述了硬件设计和软件设计。实验结果表明：各项参数均达到预期的设计目标,系统具有较好的准确性、稳定性和工位间一致性。