Description of the torsional motion in the isotopically asymmetric ionic complexes ArH<Subscript>2</Subscript>D<Superscript>+</Superscript> and ArD<Subscript>2</Subscript>H<Superscript>+</Superscript>

The internal dynamics of the isotopically asymmetric ionic complexes ArH₂D⁺ and ArD₂H⁺ is considered to be a distorted dynamics of the isotopically symmetric ArH₃⁺ complex. By using the group chain methods, a rigorous algebraic model is constructed to describe the spectrum of the asymmetric complexes with an allowance for the torsional motion of the structure of hydrogen nuclei. The model is based on the geometrical group of symmetry of internal dynamics of the isotopically symmetric ionic complex, which is used here as a noninvariant group.     

Photoionization of the C<Subscript>60</Subscript> and C<Subscript>240</Subscript> fullerenes by ultrashort electromagnetic pulses

The photoionization of the C₆₀ and C₂₄₀ fullerenes by ultrashort electromagnetic pulses of subfemtosecond duration is studied. The probability for the process to occur during the action of the pulse as a function of the pulse duration is calculated for different carrier frequencies. The spectrum of photoelectrons emitted during the ionization of the fullerenes by a pulse with a corrected Gaussian shape is calculated.     

EPR of Yb<Superscript>3+</Superscript> ions in a monoclinic KY(WO<Subscript>4</Subscript>)<Subscript>2</Subscript> single crystal

The electron paramagnetic resonance (EPR) of Yb³⁺ ions in a KY(WO₄)₂ single crystal was investigated at T=4.2 K and fixed frequency of 9.38 GHz. The resonance absorption observed on the lowest Kramers doublet represents the complex superposition of three spectra, corresponding to the ytterbium isotopes with different nuclear moments. The EPR spectrum is characterized by a strong anisotropy of the g-factors. The temperature dependence of the g-factors is shown to be caused by the strong spin-orbital and orbital-lattice coupling. The resonance lines broaden with increasing temperature due to the short spin-lattice relaxation times.     

Static displacement of a guest atom in filled skutterudites MFe<Subscript>4</Subscript>Sb<Subscript>12</Subscript> (M = La,Ca, Na)

The properties of filled skutterudites MFe₄Sb₁₂ (M = La, Ca, Na) have been analyzed using the nuclear magnetic resonance (NMR) and nuclear quadrupole resonance (NQR) methods. Two lines have been observed on the ¹³⁹La NMR spectrum of the LaFe₄Sb₁₂ compound and a substructure has been revealed in the ¹²¹Sb and ¹²³Sb lines in the NQR spectra of LaFe₄Sb₁₂ and CaFe₄Sb₁₂. The concept of the partial static displacement of guest atoms (M) in LaFe₄Sb₁₂ and CaFe₄Sb₁₂ has been proposed. The ab initio calculations confirm this assumption as well as give the displacement of a guest atom and indicate the absence of the splitting of the ¹³⁹La NMR line in the LaFe₄Sb₁₂ spectrum.     

Magnetic structure of the Sr<Subscript>2</Subscript>Cu<Subscript>3</Subscript>O<Subscript>4</Subscript>Cl<Subscript>2</Subscript> two-subsystem antiferromagnet according to nuclear quadrupole resonance data

The magnetic structure of the Sr₂Cu₃O₄Cl₂ two-subsystem antiferromagnet is studied by the nuclear quadrupole resonance (NQR) method on the ^{63, 65}Cu and ³⁵Cl nuclei. The resonance spectrum above T _N2 = 40 K is determined by the Zeeman splitting of the levels of the ^{63, 65}Cu nuclei of the copper atoms at the Cu1 site with the first-order quadrupole perturbation. The magnetic field on the copper nuclei is equal to 93 kOe. The spectrum below n is significantly different: it includes a low-frequency part, which is associated with the ordering of the second magnetic subsystem Cu2. The splitting of the NQR lines of ³⁵Cl is observed above and below T _N2. This fact indicates the ferromagnetic ordering of the moments of the Cu1 subsystem, which are located along the c axis of the crystal, and makes it possible to determine the direction of the magnetic field on Cu1 copper as (110).     

Optical phonons in Rb<Subscript>2</Subscript>TeBr<Subscript>6</Subscript> and Cs<Subscript>2</Subscript>TeBr<Subscript>6</Subscript> crystals

Raman scattering in Rb₂TeBr₆ and Cs₂TeBr₆ crystals is studied. The phonon spectra of the crystals are calculated using the factor group method. The number of Raman-active modes, their symmetries, and selection rules are found. Observed Raman spectrum lines are identified with atomic vibration modes of the crystal.     

Geometry of the internal dynamics of C<Subscript>2</Subscript>H<Stack><Subscript>3</Subscript><Superscript>+</Superscript></Stack> carbocation

Using the symmetry group chain methods, the internal dynamics of the simplest carbocation, C₂H ₃ ⁺ , is analyzed under the traditional assumptions that the equilibrium structures of the carbocation are planar and that the nonrigid motion between them is in-plane. This geometry of the internal dynamics is shown to agree with the data of the microwave spectroscopy on the splittings of rotational energy levels caused by the nonrigid motion. Previously, this statement was based on the model that violated the requirement of self-adjointness of operators of physical quantities.     

Electron paramagnetic resonance in YbNiAl<Subscript>2</Subscript> single crystals with strong magnetic anisotropy

Anisotropy in the magnetic properties of YbNiAl₂ intermetallide has been studied. Electron paramagnetic resonance (EPR) signals assigned to the localized magnetic moments of trivalent ytterbium have been detected at temperatures below 20 K. Spin–lattice relaxation processes like the Orbach–Aminov process with participation of the first excited Stark sublevel of the Yb³⁺ ion with an energy of 96 K govern electron–spin dynamics and the disappearance of spectrum lines with a further increase in temperature. Strong magnetic anisotropy effects are discussed as a main reason for the appearance of electron paramagnetic resonance.     

Spectroscopic diagnostics of the laser erosion plasma of an AgGaS<Subscript>2</Subscript> polycrystalline target

Results are presented from experimental studies of the radiation emitted from a plasma produced in vacuum after irradiating a polycrystalline target by 1.06-μm laser radiation with an intensity of (3–5)×10⁸ W/cm². Plasma radiation from regions located at distances of 1 and 7 mm from the target is analyzed. It is shown that the main contribution to the plasma radiation in the 220–600 nm spectral range is made by transitions from the excited states of single-charged Ag⁺ and S⁺ ions. The atomic component of plasma radiation is represented by intense spectral lines corresponding to transitions from the Rydberg states of Ag and Ga atoms, whereas no resonance lines of these atoms are observed.     

Chaos in intrinsic motion of nuclei and its role in dissipative collective dynamics

We shall discuss the role of chaotic intrinsic motion in dissipative dynamics of the collective coordinates for nuclear systems. Using the formalism of linear response theory, it will be shown that the dissipation in adiabatic collective motion depends on the degree of chaos in the intrinsic dynamics of a system. This gives rise to a shape dependent dissipation rate for collective coordinates when the intrinsic motion is described by the independent particle model in a nucleus. The shape dependent chaos parameter measuring the degree of chaos in the intrinsic dynamics of the nuclear system will be obtained using the interpolating Brody distribution of nearest neighbour spacings in the single particle energy spectrum. A similar shape dependence is also found to be essential for phenomenological dissipation rates used in fission dynamics calculations.     

Excitation dynamics of Rydberg states in C<Subscript>60</Subscript>

The electron and nuclear dynamics of C₆₀ fullerenes irradiated with femtosecond laser pulses are investigated with photoelectron and photoion spectroscopy. The focus of this work is the detailed exploration of the population mechanism of Rydberg levels within the excitation process of neutral C₆₀. The effect of excitation wavelength, intensity, chirp, and polarization on the kinetic energy distribution of photoelectrons in single-pulse experiments gives first insight into the underlying processes. In combination with time-resolved two-color pump-probe spectroscopy depending on either pump, or probe pulse intensity, a more complete picture of the interaction can be drawn. The results point towards a very interesting but nevertheless complex behavior including four steps: (i) non-adiabatic multielectron excitation of the HOMO (h_u) → LUMO+1 (t_1g) transition; (ii) thermalization within the hot electron cloud on a time scale below 100 fs, followed by a coupling of energy to vibrational modes of the molecule via doorway state(s); (iii) population of electronically excited Rydberg states by multiphoton absorption, and (iv) single photon ionization from the excited Rydberg states. This excitation process results in a characteristic sequence of photoelectron lines in the photoemission spectra. The comparison of the experimental results with recent theoretical work gives convincing evidence that non-adiabatic multielectron dynamics (NMED) plays a key role for the understanding of the response of C₆₀ to short-pulse laser radiation.     

Atomic dynamics of an Al<Subscript>0.62</Subscript>Cu<Subscript>0.255</Subscript>Fe<Subscript>0.125</Subscript> icosahedral quasicrystal

The atomic dynamics of an Al_0.62Cu_0.255Fe_0.125 icosahedral quasicrystal is investigated using inelastic neutron scattering (the isotopic contrast method). The partial vibrational spectra of copper, iron, and aluminum atoms in the icosahedral quasicrystal and the total spectrum of thermal vibrations of the compound are directly reconstructed from the experimental data for the first time. It is found that the vibrational energies of copper and iron atoms fall in relatively narrow ranges near 16 and 30 meV, respectively, whereas the vibrational energies of aluminum atoms lie in a wide range (up to 60 meV).     

A computer study of the Raman spectra of the (GaN)<Subscript>129</Subscript>, (SiO<Subscript>2</Subscript>)<Subscript>86</Subscript>, and (GaN)<Subscript>54</Subscript>(SiO<Subscript>2</Subscript>)<Subscript>50</Subscript> nanoparticles

The Raman spectra of the (GaN)₁₂₉, (SiO₂)₈₆, and (GaN)₅₄(SiO₂)₅₀ nanoparticles were calculated using the molecular dynamics method. The spectrum of (SiO₂)₈₆ had three broad bands only, whereas the Raman spectrum of (GaN)₁₂₉ contained a large number of overlapping bands. The form of the Raman spectrum of (GaN)₅₄(SiO₂)₅₀ was determined by the arrangement of the GaN and SiO₂ components in it. The nanoparticle with a GaN nucleus had a continuous fairly smooth spectrum over the frequency range 0 ≤ ω ≤ 600 cm⁻¹, whereas the spectrum of the nanoparticle with a SiO₂ nucleus contained well-defined bands caused by vibrations of groups of atoms of different kinds and atoms of the same kind.     

量子无规运动与核耗散

从动力学对称性观点出发考察了量子规则运动与无规运动 .用能级动力学研究了从量子规则运动向量子无规运动的过渡 ,给出了导致能级混沌的条件 ,揭示了造成能级混沌的机制 .用混沌态矢的特征解释了原子核的各态历经集体态的衰变特性 .研究了重离子碰撞中核耗散与动力学对称性破坏之间的关系. Quantum regular and irregular motions are investigated from the viewpoint of dynamical symmetry. The transition from quantum regular motion to chaotic motion is studied by level dynamics and computer experiments. The conditions for onset of quantum chaos are presented.The mechanism for causing chaotic level spectrum is unveiled. The decay behavior of the nuclear ergodic collective states is explained in terms of the peculiar property of chaotic states. The connection between nuclear...     

Resonant-Optical Detection of Nuclear Magnetization in the Si/CaF<Subscript>2</Subscript> Nanostructure

We have considered theoretically the characteristic features of optical detection of nuclear magnetization in the Si/CaF₂ structure under the conditions of EPR and NMR by measuring luminescence polarization. We show that application of EPR makes it possible to detect weak nuclear fields, but the time of spin relaxation of electrons imposes its constraint. The application of NMR is limited by nuclear fields of no less than 15–20 Gs. The possibility of using optical NMR for direct measurement of the nuclear field from changes in the luminescence polarization spectrum is shown. __________ Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 72, No. 5, pp. 644–649, September–October, 2005.     

Luminescence in collisions of low-energy ions with graphite and Al<Subscript>2</Subscript>O<Subscript>3</Subscript>

Excitation of H⁺, H₂ ⁺, H₃ ⁺, He⁺, and Ar⁺ ions by impact on graphite and Al₂O₃ was investigated by means of emission spectroscopy in the 50–1000 eV energy range of the projectiles. Emission of Balmer series from excited neutral hydrogen is observed for both targets. In addition, for the Al₂O₃ target a continuum emission is observed. The continuum probably originates from excited M_nO_m molecules produced in the collision cascade, when surface atoms bound by ionic bonds are released after the bond breaking caused by neutralization. The spectra obtained under Ar⁺ -bombardment show Ar II lines emitted by backscattered ions.     

Raman spectroscopic study of structural disordering in YVO<Subscript>4</Subscript>, GdVO<Subscript>4</Subscript>, and CaWO<Subscript>4</Subscript> crystals

The Raman spectra of single-crystal YVO₄, GdVO₄, and ZrSiO₄ with a zircon structure, as well as CaWO₄ and BaWO₄ with a scheelite structure, are studied in detail over a wide temperature range 14–800 K. An inhomogeneous splitting of the A _1g (ν₂) vibrational lines in the Raman spectra of YVO₄ and GdVO₄ and the A _g (ν₁) vibrational lines in the spectrum of CaWO₄ is detected. It is shown that the profiles of these lines can be decomposed into two components, whose integrated intensities are redistributed with temperature and also depend on the matrix kind in which they are detected. The phenomenon observed is associated with the thermally activated processes of disorientation of the tetrahedral anions in the zircon and scheelite structures.     

Dynamics of the magnetic flux component normal to the layers of Bi<Subscript>2</Subscript>Sr<Subscript>2</Subscript>CaCu<Subscript>2</Subscript>O<Subscript>8</Subscript> in a tilted field

High-frequency losses in the strongly anisotropic layered superconductor Bi₂Sr₂CaCu₂O₈ are measured at 600 MHz under a magnetic field rocking about the ab plane. Anomalies in losses and hysteretic phenomena are found while performing periodic rocking, i.e., cycling the magnetic field component normal to the sample surface. Based on these observations, conclusions are drawn about the nature of magnetic-flux penetration into the superconductor. It is found that, in the range between 60 K and T _c , the dynamics of magnetic-flux vortex lines normal to the ab plane in the presence of a constant magnetic field applied parallel to this plane is governed by the critical penetration field H _c ^⊥* and the surface barrier in the presence of thermally activated vortex motion (giant flux creep). The dependences of H _c1 ^⊥* and the characteristic field of the surface barrier on the magnitude of the parallel magnetic field are measured.