New pattern recognition system in the e-nose for Chinese spirit identification

This paper presents a new pattern recognition system for Chinese spirit identification by using the polymer quartz piezoelectric crystal sensor based e-nose. The sensors are designed based on quartz crystal microbalance(QCM) principle,and they could capture different vibration frequency signal values for Chinese spirit identification. For each sensor in an8-channel sensor array, seven characteristic values of the original vibration frequency signal values, i.e., average value(A),root-mean-square value(RMS), shape factor value(S_f), crest factor value(C_f), impulse factor value(I_f), clearance factor value(CL_f), kurtosis factor value(K_v) are first extracted. Then the dimension of the characteristic values is reduced by the principle components analysis(PCA) method. Finally the back propagation(BP) neutral network algorithm is used to recognize Chinese spirits. The experimental results show that the recognition rate of six kinds of Chinese spirits is 93.33% and our proposed new pattern recognition system can identify Chinese spirits effectively.     

石英晶振的储能特性

针对微弱环境能量难以直接快速存储的问题, 采用石英晶振作为储能元件设计了一种高效储能瞬放电路. 石英晶振的高品质因数特性使其能在较小的输入电压下产生剧烈的机械振动, 从而将微弱的电能转换成机械能存储在石英晶振中. 通过对石英晶振的储能原理与能量释放特性进行理论分析, 推导出石英晶振充放电过程中输出电压与时间的关系式, 以及石英晶振释放能量时最大瞬时输出功率与负载的关系式. 并对石英晶振的储能特性进行了实验验证. 结果表明: 实验与理论相符, 且在输入电压幅值为100 mV, 谐振频率f=1 MHz石英晶振的条件下, 石英晶振的储能效率可以达到77%, 能量释放效率为71.4%.     

电场作用下5CB液晶分子的近壁面层黏弹性的QCM研究

利用石英晶体微天平(quartz crystal microbalance,QCM)研究了电场对5CB液晶分子的近壁面层黏弹性的影响.对QCM结果的分析发现,电场作用对液晶的黏度影响分为两部分,通过建立含吸附膜的双层膜模型,分析了QCM的两部分结果,发现电场对近壁面吸附层及体相层的影响是不同的.根据QCM的双层膜模型,对近壁面层液晶分子的黏弹性及膜厚进行了定量的分析计算,结果表明5CB在石英晶体上电极附近有一层约100nm厚的近壁面吸附层,其复剪切黏度随电场强度的增加而减小,这与5CB液晶的体相黏度变化规 关键词： 5CB液晶 石英晶体微天平 近壁面 黏弹性     

LCR分流电路下压电声子晶体智能材料的带隙

将带有LCR分流电路的压电陶瓷片对贴在铝和环氧树脂组成的声子晶体结构中.使智能材料的机械振动与压电陶瓷的压电效应耦合起来,推导出机械振动在压电陶瓷片上的等效附加应力;使LCR分流电路中的电磁振荡效应和声子晶体的能带特性有机结合,计算了在分流电路作用下智能材料扭转和弯曲振动的带隙特性,研究了电阻、电感、电容元件的改变对压电声子晶体智能材料带隙的影响.研究结果表明:在合理尺寸下,随着分流电路中电阻值的增大,带隙的频率范围变宽,但衰减幅值有所降低;电感和电容值的增大都可以使带隙向低频移动,带隙的衰减幅值随着电感值的增大而升高,但随着电容值的增大而降低.从而给压电声子晶体智能材料减震降噪的控制提供了一种新思路.     

伸缩-剪切模式自偏置铌酸锂基复合材料的磁电性能和高频谐振响应

选用多种切型铌酸锂(LiNbO_3)单晶,研究了铁基非晶合金(Metglas)/LiNbO_3叠层复合材料基于伸缩-剪切模式的磁电耦合性能,揭示了铌酸锂单晶压电系数与复合材料剪切磁电耦合系数的对应关系,在使用铌酸锂xzt/30~?切型时得到了最优化剪切磁电系数.通过SrFe12O19薄磁带提供偏置磁场,Metglas/LiNbO_3磁电复合材料可在没有外加直流磁场时实现剪切磁电响应,并在0.991 MHz和3.51 MHz频率时分别测出了谐振磁电系数,有望将铌酸锂基剪切磁电复合材料用于高频磁场探测.     

Hybrid temperature effect on a quartz crystal microbalance resonator in aqueous solutions

The quartz crystal microbalance(QCM) is an important tool that can sense nanogram changes in mass. The hybrid temperature effect on a QCM resonator in aqueous solutions leads to unconvincing detection results. Control of the temperature effect is one of the keys when using the QCM for high precision measurements. Based on the Sauerbrey's and Kanazawa's theories, we proposed a method for enhancing the accuracy of the QCM measurement, which takes into account not only the thermal variations of viscosity and density but also the thermal behavior of the QCM resonator. We presented an improved Sauerbrey equation that can be used to effectively compensate the drift of the QCM resonator. These results will play a significant role when applying the QCM at the room temperature.     

An erosion sensor based on a quartz crystal microbalance for quantitative determination of the cleaning efficiency in an ultrasonic vessel

The efficiency of ultrasonic cleaning vessels cannot be measured directly in an easy way. In the presented work, a sensor is developed which quantitatively measures the ablation of a test layer. The sensor element is a quartz crystal which is coated with a sacrificial layer. Small changes in mass of this layer can be measured by a frequency shift of the crystal oscillation. For measurements, a 10 MHz AT-cut quartz crystal was used in a cleaning vessel working at 44.9 kHz. To determine the frequency shift by the ablation of the test layer, the quartz crystal was driven by a frequency generator sweeping the frequency in the range of the resonance frequency and a characteristic frequency was determined. The test layer which was applied to the quartz crystal consisted of silica microparticles suspended in varnish. In a preliminary experiment using a commercial cleaner it could be shown that significant changes in resonance frequency by cavitation effect could be detected. The initial frequency shift of the sacrificial layer is reproducible within 10%. The test layer can be adapted to the conditions of the cleaning vessel. By changing the electrical input power of the vessel, a threshold in the cavitation erosion was found.     

介观压电石英晶体等效电路的量子化

借鉴阻尼谐振子作量子力学处理的研究思想,将介观压电石英晶体等效电路量子化,在此基础上研究了真空态和压缩真空态下,各支路电流和电压的量子涨落. 关键词： 介观压电石英晶体 等效电路 阻尼谐振子 量子涨落     

Electrochemical and surface characterisation of carbon-film-coated piezoelectric quartz crystals

The electrochemical properties of carbon films, of thickness between 200 and 500 nm, sputter-coated on gold- and platinum-coated 6 MHz piezoelectric quartz crystal oscillators, as new electrode materials have been investigated. Comparative studies under the same experimental conditions were performed on bulk electrodes. Cyclic voltammetry was carried out in 0.1 M KCl electrolyte solution, and kinetic parameters of the model redox systems Fe(CN)₆^3−/4− and [Ru(NH₃)₆]^3+/2+ as well as the electroactive area of the electrodes were obtained. Atomic force microscopy was used in order to examine the surface morphology of the films, and the properties of the carbon films and the electrode-solution interface were studied by electrochemical impedance spectroscopy. The results obtained demonstrate the feasibility of the preparation and development of nanometer thick carbon film modified quartz crystals. Such modified crystals should open up new opportunities for the investigation of electrode processes at carbon electrodes and for the application of electrochemical sensing associated with the EQCM.     

一种用于铷原子频标的小型化低噪声10 MHz晶体振荡器设计

本文设计了一种应用于铷原子频标的小型化低噪声石英晶体振荡器,其振荡电路采用柯尔匹兹并联形式和SC切晶体谐振器．基于Leeson模型对石英晶体振荡器相位噪声进行分析,并利用ADS射频仿真软件对振荡电路进行仿真模拟,为振荡器设计与调试提供指导．最终实现体积为22 mm×28.5 mm×13 mm低噪声晶体振荡器,它具有良好的相位噪声特性,其近端相噪为-102.7 dBc/Hz@1 Hz、远端相噪为-164.2 dBc/Hz@10 kHz,且实测短期频率稳定度为1.73×10^-12/s.     

The determination of electrical parameters of quartz crystal resonators with the consideration of dissipation

Recently, as the dissipation of quartz crystal through material viscosity is being considered in vibrations of piezoelectric plates, we have the opportunity to obtain electrical parameters from vibration solutions of a crystal plate representing an ideal resonator. Since the solutions are readily available with complex elastic constants from Mindlin plate equations for thickness-shear vibrations, the calculation of resistance and other parameters related to both mechanical deformation and electrical potential is straightforward. We start with the first-order Mindlin plate equations of a piezoelectric plate for the thickness-shear vibration analysis of a simple resonator model. The electrical parameters are derived with emphasis on the resistance that is related to the imaginary part of complex elastic constants, or the viscosity. All the electrical parameters are frequency dependent, enabling the study of the frequency behavior of crystal resonators with a direct formulation. Through the full consideration of complications like partial electrodes and supporting structures, we should be able obtain electrical parameters for practical applications in resonator design.     

声表面波生物传感器质量灵敏度的理论与实验验证

针对声表面波传感器在生物检测中的性能评价与优化,提出一种快捷验证适用于生物传感器的声表面波器件质量负载灵敏度的实时检测方法。首先基于二维近似假设和周期性边界条件,建立了以石英为压电基底材料、SiO₂为波导层的Love波传感器的三维有限元分析模型,从理论上验证了波导层对Love波传感器灵敏度的影响。在实验上,通过MEMS工艺制备以ST-90°X石英为基底的声表面波传感器,通过磁控溅射镀膜技术在其表面生长不同厚度的SiO₂波导层。利用热蒸镀技术在器件延迟线区域生长铝薄膜作为质量负载效应,利用Tetramethylammonium Hydroxide (TMAH)溶液对铝的缓慢腐蚀效果,模拟质量负载从有到无的逆过程,从而实现对声表面波传感器的灵敏度验证与评价,并从实验上探究不同厚度波导层对Love波传感器灵敏度的影响及其最佳波导层厚度。     

QCM based sensor for detecting volumetric properties of liquids

We introduce a microacoustic sensor, which combines the quartz crystal microbalance, a liquid-filled cavity and an intermediate artificial layer with effective acoustic properties. Each of the three components fulfils a specific task. The quartz vibrates in its thickness shear mode and acts as source and detector of shear waves, which penetrate the intermediate artificial layer and excite a resonance in the liquid-filled cavity. Both the piezoelectric transducer and the liquid-filled cavity are high-Q resonators with well-adjusted resonance frequencies very close to each other. The intermediate artificial layer couples the two resonators in a distinct manner via control of the propagation of acoustic waves between the quartz crystal and the liquid-filled cavity layer. The origin of the sensor signal is a change of the resonance frequency of the liquid-filled cavity caused by variations of acoustic properties of the liquid analyte inside the cavity, first of all speed of sound. This resonance appears as second resonance peak in the admittance spectrum of the quartz crystal.     

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为了检测HL-2A偏滤器靶板的背后沉积层的沉积情况和深入了解其等离子体与第一壁的相互作用过程,国内首次研制了用于托卡马克装置的偏滤器沉积测量系统,其中包括石英晶体、测量探头、频率测量以及控制系统等.经过初步检测,该沉积系统平均采样速率为13~14s-1;测量的石英晶体共振频率分辨率为0.01Hz;石英晶体共振频率的变化正比于沉积在石英晶体表面的质量的变化,这与Sauerbrey方程的线性关系吻合;实验室检测过程中该沉积系统的平均沉积率约为2.0ng?s-1,显示该沉积系统具有纳克级质量检测能力,表明了该偏滤器沉积系统的测量性能和有效性.     

HL-2A偏滤器沉积测量系统的研制

为了检测HL-2A偏滤器靶板的背后沉积层的沉积情况和深入了解其等离子体与第一壁的相互作用过程,国内首次研制了用于托卡马克装置的偏滤器沉积测量系统,其中包括石英晶体、测量探头、频率测量以及控制系统等。经过初步检测,该沉积系统平均采样速率为13~14s^-1;测量的石英晶体共振频率分辨率为0.01Hz;石英晶体共振频率的变化正比于沉积在石英晶体表面的质量的变化,这与Sauerbrey方程的线性关系吻合;实验室检测过程中该沉积系统的平均沉积率约为2.0ng•s^-1,显示该沉积系统具有纳克级质量检测能力,表明了该偏滤器沉积系统的测量性能和有效性。     

Wireless-electrodeless quartz-crystal-microbalance biosensors for studying interactions among biomolecules: A review

The mass sensitivity of quartz-crystal microbalance (QCM) was drastically improved by removing electrodes and wires attached on the quartz surfaces. Instead of wire connections, intended vibrations of quartz oscillators were excited and detected by antennas through electromagnetic waves. This noncontacting measurement is the key for ultrahigh-sensitive detection of proteins in liquids as well as quantitative measurements. This review shows the principle of wireless QCMs, their applications to studying interactions among biomolecules and aggregation reactions of amyloid β peptides, and the next-generation MEMS QCM, the resonance acoustic microbalance with naked embedded quartz (RAMNE-Q).     

SPM analysis of fibrinogen adsorption on solid surfaces

The adsorption kinetics, adhesion and orientation of human fibrinogen on solid surfaces have been studied by surface probe microscopy (SPM) and quartz crystal microbalance techniques (QCM). CF₃-, NH₂-terminated organo-silane self-assembled monolayers (SAM) and OH-terminated silicon dioxide have been used as model surfaces. Furthermore, the interaction of fibrinogen with nanocomposite Ti/hydrocarbon plasma polymer films (Ti/ppCH) deposited by dc magnetron sputtering has also been studied.     

0.7Pb(Mg1/3Nb2/3)O3-0.3PbTiO3单晶/环氧树脂1-3型复合材料的压电性能研究

模拟了0.7Pb(Mg_1/3Nb_2/3)O₃-0.3PbTiO₃(PMN-0.3PT)单晶1-3型压电复合材料的性能与单晶体积分数的关系,得出性能最优时压电相的体积分数为64%, 在这一体积分数下,采用切割-填充法,并使用了不同类型的环氧树脂填充制备复合材料.系统地研究了聚合物相对复合材料性能的影响,研究表明,减小聚合物相的刚度系数c和密度ρ有利于提高复合材料的性能,且聚合物相与压电相的结合强度对性能的影响非常明显,制备的PMN-0.3 PT单晶1-3型复合材料的厚度伸缩机电耦合系数k_t高达90.1%,压电系数d₃₃大于1000pC/N,机械品质因数Q_m为10.39,声阻抗Z也大大降低,性能明显优于传统的Pb(Zr_xTi_1-x)O₃(PZT)陶瓷及其1-3复合材料,在压电换能器和传感器中显示出广阔的前景. 关键词： PMN-PT单晶 压电复合材料 压电相 聚合物相     

The frequency characteristics analysis of series photodetector frequency circuit system based on circuit parameters of quartz crystal and its application for bacterial DNA identification

The circuit parameters of quartz crystal were employed for frequency sensitivity analysis of series photodetector frequency circuit system. The influence of circuit parameters of quartz crystal on the oscillation frequency and response sensitivity were theoretically derived and experimentally verified. On the basis of optimal circuit parameters, the DNA probe detection limit 2 pmol/L can be measured by 49.4 MHz sensor system. In comparison with the conventional fluorescence technique, the frequency method showed that the detection limits of DNA probe AH642 with Cy5 fluorescence dye and DNA probe VA180 with Cy5 fluorescence dye were lower than the conventional fluorescence technique by 2–3 orders; meanwhile, through the feature of probe uniqueness, Aeromonas hydrophila DNA and fluorescence probe AH642-Cy5 can be successfully judged for hybridization reaction. Moreover, Vibro alginolyticus DNA and fluorescence probe VA180-Cy5 can be successfully judged for hybridization reaction.     

AgNbO_3压电纳米材料压-电-化学耦合研究

采用水热法合成了AgNb0_3压电纳米材料,表征了其压-电-化学耦合用于机械催化的物理机理.该耦合是压电效应和电化学氧化还原效应的乘积效应.经历60 min的机械振动后,AgNb0_3纳米材料机械催化振动降解罗丹明B(～5mg/L)的降解率达70%以上.压-电-化学耦合效应的中间产物——强氧化的羟基自由基也被检测到,这表明压-电-化学耦合效应在实现机械催化过程中的关键作用.经过5次回收再利用,AgNb0_3纳米材料的机械催化活性无明显降低.AgNb0_3压电纳米材料具有高的压-电-化学耦合、高的机械催化降解率、可多次重复使用等优点,在振动降解有机染料方面具有重要的应用前景.