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1.
本文提出一种大尺度的金属-电介质复合微纳结构(银-硅结构),用于提高荧光生物检测的灵敏度及解决荧光物质距离结构远场范围时荧光增强的近场局限。这种大尺度的金属-电介质复合微纳结构与之前的金属-电介质复合微纳结构不同,其通过光的散射和干涉实现了荧光物质距离结构远场范围时的荧光增强。在本文中,通过采用时域有限差分法,主要从荧光激发和荧光发射两个过程研究银-硅结构。结果表明,在激发过程中,银-硅结构的荧光强度高于玻璃结构且位于银-硅结构两柱之间的狭缝中的电场分布比金属结构(银结构)更均匀,因此在银-硅结构中可以实现荧光增强,而且分子运动行为的检测更准确。在发射过程中,当荧光纳米粒子距离结构远场范围内时,与玻璃相比,银-硅结构可以实现更好的荧光增强效果。利用银-硅结构实现荧光增强的机理是光的散射和干涉,荧光被银膜向上散射,同时,结构两侧的银/硅柱也散射一部分荧光,荧光相互干涉传播至远场实现荧光增强。此外,银-硅结构易于制备和集成。因此,其可以很好地应用于生物传感领域。  相似文献   

2.
在纳米光子学中,提高荧光物质的定向发光强度是许多应用要解决的关键问题。为了优化电介质纳米天线的荧光增强能力,本文提出了一种由硅纳米球二聚体与TiO 2微球组成的电介质球复合纳米天线。通过时域有限差分法,本文分别从量子产率增强、荧光收集效率增强以及荧光激发率增强3个方面研究了该复合纳米天线对荧光的增强效果。结果表明,这种复合纳米天线不仅可以解决单个TiO 2微球增强荧光时量子产率较低的问题,还可以弥补单个硅纳米球二聚体增强荧光时荧光收集效率较差的不足。该复合纳米天线可使CdSe量子点的量子产率增强约4倍、荧光收集效率增强约2倍。此外,由于硅纳米球二聚体与TiO 2微球对荧光激发过程具有增强效果,该复合天线最终可以产生较高的荧光定向增强倍数。在量子点发光的中心波长523 nm处,荧光定向增强约为3064倍。  相似文献   

3.
金属表面等离子体(surface plasmon)是金属与介质界面处传播的电荷振荡密度波。当振荡频率与激发光频率相匹配时将产生金属表面等离子体共振,从而能够在金属结构附近产生强烈的消光和近场增强效应, 该效应在表面等离子共振成像、表面等离子体波导、生物传感、光谱增强等方面有着重要的应用前景。本文综述了金属结构的表面等离子共振效应在增强荧光光谱方面的研究进展。论文首先介绍了金属表面等离子体增强荧光的机理以及影响荧光增强效果的因素;其次,从用于荧光增强的各类金属纳米结构的角度分别综述了荧光增强研究的最新进展;最后,介绍了荧光增强在食品检测、环境监测、光学成像、光电器件、荧光上转换等领域的最新应用情况。  相似文献   

4.
本文提出了一种由电介质微球和金属平面纳米层组成的复合结构,用于增强荧光远场定向发射强度和提高荧光收集效率.通过时域有限差分法研究了位于电介质微球和金层之间量子点的激发和发射过程.量子点作为荧光材料涂敷于聚甲基丙烯酸甲酯中,用于控制和金层的距离从而调控荧光增强.该结构基于等离激元耦合、回音壁模式以及光子纳米射流之间的协同效应,使远场荧光强度增强230倍,荧光收集效率高达70%.与电介质微球和金球二聚体复合结构增强荧光相比,金球二聚体之间的间距不易控制,此外量子点要放在金球之间特定的位置.而本文提出的三维平面复合纳米结构相对更方便实现.以上结果在提高荧光生物检测灵敏度、成像质量以及发光器件效率等领域具有非常重要的应用意义.  相似文献   

5.
本文提出一种大尺度的金属-电介质复合微纳结构(银-硅结构),用于提高荧光生物检测的灵敏度及解决荧光物质距离结构远场范围时荧光增强的近场局限。这种大尺度的金属-电介质复合微纳结构与之前的金属-电介质复合微纳结构不同,其通过光的散射和干涉实现了荧光物质距离结构远场范围时的荧光增强。在本文中,通过采用时域有限差分法,主要从荧光激发和荧光发射两个过程研究银-硅结构。结果表明,在激发过程中,银-硅结构的荧光强度高于玻璃结构且位于银-硅结构两柱之间的狭缝中的电场分布比金属结构(银结构)更均匀,因此在银-硅结构中可以实现荧光增强,而且分子运动行为的检测更准确。在发射过程中,当荧光纳米粒子距离结构远场范围内时,与玻璃相比,银-硅结构可以实现更好的荧光增强效果。利用银-硅结构实现荧光增强的机理是光的散射和干涉,荧光被银膜向上散射,同时,结构两侧的银/硅柱也散射一部分荧光,荧光相互干涉传播至远场实现荧光增强。此外,银-硅结构易于制备和集成。因此,其可以很好地应用于生物传感领域。  相似文献   

6.
表面增强荧光是一种跨空间的相互作用,受荧光分子和金属纳米颗粒之间距离的影响。核壳结构因其制备方法简便、壳层厚度易调节等特点而成为近几年备受关注的研究课题。本文介绍了几种广泛应用于表面增强荧光研究的核壳结构及其国内外研究进展,主要包括金属纳米颗粒作为核心的壳层结构、金属纳米颗粒作为壳层的壳层结构以及一些其他核壳结构,并结合研究现状对核壳结构的未来发展做出展望。  相似文献   

7.
荧光发射强度在荧光显微术科学观测中至关重要。理论分析了三大影响荧光发射强度的重要因素:分子吸收激发光光子的能力、荧光量子产量及其荧光饱和与荧光猝灭,指出选择具有大光吸收截面和高量子产量的荧光分子,能有效保证荧光发射强度;确定合理的激发光强度范围,可避免不必要的荧光饱和现象。进一步实验研究了超高真空和大气环境下的荧光猝灭现象,得出超高真空时荧光分子的荧光猝灭现象极不明显,而大气环境可造成荧光光强指数递减的结论。  相似文献   

8.
1,8-萘酰亚胺荧光单体的合成及光谱的量子化学研究   总被引:3,自引:2,他引:1       下载免费PDF全文
以4-溴-1,8-萘二甲酸酐和N-甲基哌嗪为原料,合成了3种水溶性1,8-萘酰亚胺荧光单体,并以红外光谱、氢核磁共振谱、质谱及元素分析对产物进行了表征,测定了它们的激发光谱和发射光谱.运用PM3方法对这3种化合物的基态和激发态进行了几何构型全优化.结构分析表明:基态下,3种荧光单体的环均处于同一平面,且体系为较大的共轭...  相似文献   

9.
建立一种测定噻菌灵的荧光分析新方法.铽(Ⅲ)为弱荧光物质,噻菌灵的加入对其荧光强度有显著的增强效应.实验结果表明,荧光增强值△F与噻菌灵的浓度在2-200nmol/L内呈良好的线性关系,r=0.9970,检出限为0.83nmol/L.本法用于实际样本中噻菌灵的测定,结果令人满意.  相似文献   

10.
增强荧光辐射在生物成像、高灵敏探测、集成光源等方面都具有重要的应用价值.金属纳米颗粒的周围或者金属纳米结构的间隙都可以产生强的电磁场,相应的,这些结构附近的局域态密度也被极大地增强.虽然增强荧光辐射已经在多种金属纳米颗粒和颗粒对中被证明,但是利用金属纳米结构对荧光分子的吸收和辐射过程同时进行调制仍然是一个有挑战的问题.本文研究了金属-介质-金属超表面对荧光辐射的调控,其中局域表面等离激元(LSP)和磁等离激元(MPP)分別与于分子的吸收和辐射过程发中耦合相互作用.对于吸收过程,LSP的耦合作用使得可以通过旋转泵浦激光的偏振态来实现荧光分子的空间选择激发.此外,MPP模式的偏振依赖特性使得矩形渔网结构中的荧光分子的辐射波长和偏振态也受到调控.实验观测结果经过了时域有限差分模拟的验证.本文报道的纳米结构在光辐射器件和纳米尺度集成光源等方面都具有潜在的应用价值.  相似文献   

11.
为了拓展荧光辐射差分(Fluorescence Emission Difference,FED)显微术的应用,使得该方法可以同时对生物样品的不同组织结构进行超分辨成像,本文对双色FED显微系统展开了研究。FED的基本原理是将实心光斑扫描得到的共焦显微图像减去空心光斑扫描得到的负共焦图像,以此获得超分辨显微图像。在对单色FED显微系统进行研究后,本文提出了一种可行的双色FED显微成像系统方案。实验结果表明,在488 nm和640 nm激发光下,该系统在荧光颗粒上分别实现了135 nm和160 nm的空间分辨率,另外也能对生物样品的不同组织进行多色同时超分辨显微成像,满足了实际应用的要求。  相似文献   

12.
应用激光光谱学技术,探讨了Tm3+离子掺杂透明氟氧化物玻璃陶瓷体系中声子调控对红色激光抽运荧光辐射性质的影响. 研究了基质结构和样品环境温度与电声子相互作用的联系以及声子变化对于荧光辐射产生的影响. 发现改变基质材料的SiO2含量能影响蓝色上转换荧光效率. 另外,依据温度与声子能量之间的联系,通过改变样品环境温度可明显调节低声子基质材料中掺杂离子激发态能级的布居速率,改变上转换效率. 关键词: 荧光辐射 声子 无辐射弛豫 荧光寿命  相似文献   

13.
Ultracompact directional optical nanoantennas are rapidly gaining popularity yet still challenging tasks to construct at the nanoscale. Here, we experimentally demonstrate unidirectional emission from a fluorescent nanodiamond coupled with a single gold nanorod. Different configurations of the assembled hybrid nanostructures were realized via step‐by‐step atomic force microscope nanomanipulation. The emission patterns can be controlled by adjusting the configurations, i.e., the gold nanorod orientation and separation with respect to the nanodiamond. Numerical simulation results reveal that the unidirectional emission can be ascribed to the interference between the electromagnetic fields produced by the dipole‐like source and the out‐of‐phase dipole induced in the gold nanorod. The proposed hybrid nanostructures remarkably exhibit highly unidirectional emission even when the emitter is positioned up to 50 nm away from the nanorod antenna and present a broad working spectral bandwidth of ∼200 nm. The distinct features of this hybrid structure suggest potential applications for novel nanoscale light sources, sensing, and quantum information.

  相似文献   


14.
A fully transparent and flexible field emission device (FED) has been demonstrated. Single‐walled carbon nanotubes (SWCNTs) coated on arylite substrate were used as electron emitters for the FED and a novel metavanadate phosphor coated on the SWCNTs/arylite film was used as transparent and flexible screen. The SWCNTs/arylite based emitters and the SWCNTs/arylite/metal‐vanadate‐based phosphor showed a transmittance value of 92.6% and 54%, respectively. The assembled device also showed satisfactory transparency and flexibility as well as producing significant current. Metavanadate phosphor is considered to be an excellent candidate due to its superior luminescence properties and easy fabrication onto transparent and flexible conductive substrate at room temperature while retaining reasonable transparency of the substrate. Thus, its transparency and flexibility will open the door to next‐generation FEDs. (© 2012 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献   

15.
Transparent and flexible carbon doped ZnO (C:ZnO) field emission device was successfully fabricated on an arylite substrate. Excellent adhesion of deposited C:ZnO on the flexible substrate was achieved with low sputtering power and Ar flow rate. In the fabricated device, nanostructured C:ZnO and as‐deposited thin films were used as field emitter and phosphor screen, respectively. The C:ZnO thin film showed a transparency of about 80% at 550 nm wavelength and average sheet resistance of 1.96 kΩ/□. The C:ZnO phosphor screen emitted red light during the field emission measurement, correlating the dominant cathodoluminescence peak at 646 nm. Thus, a promising transparent and flexible field emission display can be realized with C:ZnO based material.

Transparent and flexible C:ZnO film phosphor screen (anode) and nanocone emitters (cathode) for field emission device.  相似文献   


16.
《Physics letters. A》2020,384(28):126742
We propose a ring-groove nanostructure which can achieve toroidal dipolar resonance under normal incidence, and find that this design, due to the strong field confinement for this dipolar resonance, can simultaneously enhance the radiative decay rate and achieve high degree of linear polarization of the fluorescence emission. In addition, both radiation enhancement and degree of linear polarization are higher than those by other structure that cannot obtain toroidal dipolar resonance. It is expected that this design can promote the development of polarized light-emitting devices with enhanced emission intensity and potentially functional toroidal metasurface lasers.  相似文献   

17.
Metasurfaces, which consist of resonant metamaterial elements in the form of two‐dimensional thin planar structures, retain great capabilities in manipulating electromagnetic wave and potential applications in modifying interaction with fluorescent molecules. The metasurfaces with magnetic responses are favorable to weakening fluorescence quenching while less investigated in controlling fluorescence. In this paper, we demonstrate control over fluorescence emission by engineering the magnetic and electric modes in plasmonic metasurfaces consisting of 45‐nm‐thick gold split‐ring‐resonators (SRRs). The fluorescence emission exhibits an enhancement factor of ∼18 and is predominantly x‐polarized with assistance of the magnetic mode excited by oblique incidence with an x‐polarized electric field. The magnetic and electric modes excited by oblique incidence with a y‐polarized electric field contribute to the rotation of emission polarization with respect to the incident polarization. The results demonstrate manipulating the interaction of fluorescent emitters with different resonant modes of the SRR‐based metasurface at the nanoscale by the polarization of incident light, providing potential applications of metasurfaces in a wide variety of areas, including optical nanosources, fluorescence spectroscopy and compact biosensors.

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18.
The direct fabrication of fully transparent conical nanocarbon structures (CNCSs) of controlled nanoscopic dimension on a flexible nafion substrate was achieved, using field electron source, by a novel room temperature ion irradiation technique. By controlling the sizes (below the wavelength of visible light) of the CNCSs, the transparency of the substrate can be tailored satisfactorily. The transparency of the CNCSs was observed to be around 90% in the visible regime depending on the ion irradiation time. Our results suggest that the direct fabrication of well controlled fully transparent CNCSs on any transparent and flexible substrate at room temperature could open a novel route for potential applications in future highly transparent, flexible (bendable), low weight and portable field emission displays (FEDs). (© 2012 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献   

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