Confinement of an Electron in an Image Potential and an External Electrostatic Field

The quasi-classical approximation is used to determine the positions of the classical turning points upon motion of an electron that is bound by an image field and a constant homogeneous electric field of the same direction. Power expansions of the coordinates of the turning points in a wide range of electron energies and field strengths are obtained. The mechanism of one-dimensional confinement of an electron, which determines a completely discrete spectrum of states, is described. The dependence of the spatial width of the confinement region on the field strength and electron energy is determined. The dependences of the electron energy in different states on the external field strength are calculated numerically. Quasi-classical quantization is performed, and the dependence of the electron energy on the width of the confinement region is determined. The energy interval of a maximum density of electron states is found, which is determined by the dependence of the width of the confinement region on the electric field strength.     

正交非均匀电场中氢原子的高激发态

用数学软件Mathematica研究正交非均匀电场中氢原子两个高激发态(n=4和5)的能级和波函数.讨论能级分裂,并绘制零级近似下氢原子的电子概率角分布图.     

Metal-neon compound ions in slow field evaporation

A magnetic sector atom-probe has been employed to study slow field evaporation of most of the transition metals in vacuum, in neon and in a mixture of neon and hydrogen. Various metals were found to form metal-neon molecular ions. Slow field evaporation and the presence of hydrogen are favorable for their formation. All the experiments were done at 78 K. The metals that evaporate as nei'des abundantly are Ti, Zn, Zr, Nb, Mo, Pd and Ta, of which Ti, Nb and Pd produce neïde ions as much as 80 to 90%. There were also some neïdes with W, Re, Ir and Rh, definitely above the detection limit estimated to be 3% of the field evaporating metal ions. The role of hydrogen is thought to be two-fold: At the surface, hydrogen adsorption is assumed to cause a stronger metal-neon bond, while the electron shower from free space ionization of the auxiliary gas excites or ionizes the complex by electron impact to allow evaporation at a reduced field.     

氢团簇在飞秒强激光场中的动力学行为

利用分子动力学方法研究了氢团簇在飞秒强激光场中的动力学行为. 与库仑爆炸模型所预言的不同, 团簇的膨胀是各向异性的, 质子平均动能沿激光场极化方向上的分量要明显大于垂直于激光场极化方向上的分量. 讨论了团簇各向异性膨胀产生的原因, 分析了激光和团簇参数对各向异性程度的影响.     

光电子离开氢术核的方向

基态氢原子在电磁波的作用下发生电离，这主不是氢原子的光电效应，本文讨论氢原子的电子离开氢核的方向与电磁波的电场强度Ｅ的方向之间的关系。     

外电场中金属表面附近里德堡氢原子的动力学行为

利用相空间分析方法研究了外电场中金属表面附近里德堡氢原子的动力学性质. 结果表明, 体系的动力学性质敏感地依赖于原子与金属表面间的距离和电场强度.通过固定原子与金属表面间的距离, 分析了外加电场作用下里德堡电子的Poincaré 截面和运动轨迹的演化过程. 研究表明: 电场的出现加速了金属表面对电子的吸附, 随着电场强度的增加,体系的动力学性质由原子与金 属表面间的距离控制逐渐变为由电场起主导作用,体系逐渐由不可积变为可积, 电子的运动轨道最终全部变为振动型轨道. 关键词： Poincaré截面 相空间分析方法 里德堡氢原子     

Nuclear magnetic shielding of a hydrogen atom in an electric field

The nuclear magnetic screening constant of a hydrogen atom in a uniform electric field is calculated, neglecting any effect of electron spin. The screening is found to be reduced by the electric field for all directions of the applied magnetic field, the reduction being greatest if the two fields are perpendicular.     

Investigations on ionic processes and dynamics in the sheath region of helium and hydrogen discharges by laser spectroscopic electric field measurements

Temporally and spatially resolved measurements of the electric field distribution in the sheath region of RF and dc discharges provide a detailed insight into the sheath and ion dynamics. The electric field is directly related to the sheath ion and electron densities, the sheath voltage, and the displacement current density. Under certain assumptions also the electron and ion conduction current densities at the electrode, the ion current density into the sheath from the plasma bulk, the ion energy distribution function, and the power dissipated in the discharge can be inferred. Furthermore, the electric field distribution can give an indication of the collision-induced conversion between different ion species in the sheath. Laser spectroscopic techniques allow the noninvasive in situ measurement of the electric field with high spatial and temporal resolution. These techniques are based on the spectroscopic measurement of the Stark splitting of Rydberg states of helium and hydrogen atoms. Two alternative techniques are applied to RF discharges at 13.56 MHz in helium and hydrogen and a pulsed dc discharge in hydrogen. The measured electric field profiles are analyzed, and the results discussed with respect to the ion densities, currents, energies, temporal dynamics and species composition. Received: 26 July 2000 / Accepted: 12 December 2000 / Published online: 3 April 2001     

Pressure dependence of the electrical potential and electrontemperature in a microwave-generated plasma

The electron temperature in a stationary hydrogen plasma has been studied using a Langmuir probe. The measurements have been carried out over the pressure range from 3 mbar (2.25 torr) to 25 mbar (18.75 torr). The applied microwave power was varied from 50 to 450 W. The electron temperature shows a linear dependence on the applied microwave power. The self-space-charge field (in volts) of a hydrogen plasma shows a saturation behavior at higher microwave powers. The maximum value at the saturation of the field equals 6.8 V at a gas pressure of 15 mbar (11.25 torr) for all values of the input microwave radiation power. The polarities of the self-space-charge electric field are similar above this value and below it     

The Impact of Direct Ionization by Beam Electrons on the Electron Kinetics of the Beam Discharge Plasma in Molecular Hydrogen

In a recent paper the stationary beam plasma discharge in partially dissociated hydrogen was investigated where the electron component was described by the Boltzmann equation for a mixture of atomic and molecular hydrogen and the main heavy charged and neutral particles by balance equations. It was assumed that, via the quasilinear beam plasma interaction, the electron beam produces only the turbulent electric field whilst an additional production of plasma electrons due to direct ionization by the beam and thus a direct influence on the balances of charge carriers were neglected. Now the additional production of plasma electrons due to direct ionization by the beam is studied on the basis of a generalized Boltzmann equation but for the simpler model of a purely molecular hydrogen plasma. For experimentally obtainable values of the turbulence energy density, beam energy, beam ionization degree and electron life time the calculation of the electron energy distribution function and of the direct beam contribution to the electron particle balance shows a marked influence of the direct beam ionization with increasing degree of beam ionization.     

Circular Rydberg States of Atomic Hydrogen in an ArbitraryMagnetic Field

We report a theoretical scheme using a B-spline basis set to improve the poor computational accuracy of circular Rydberg states of hydrogen atoms in the intermediate magnetic field. This scheme can produce high accuracy energy levels and valid for an arbitrary magnetic field. Energy levels of hydrogen are presented for circular Rydberg states with azimuthal quantum numbers |m| = 10--70 as a function of magnetic field strengths ranging from zero to2.35
ⅹ10⁹ T. The variation of spatial distributions of electron probability densities with magnetic field strengths is discussed and competition between Coulomb and magnetic interactions is illustrated.     

GaAs电介质表面对剥离电子通量分布影响的数值研究

利用半经典开轨道理论,研究了GaAs电介质表面对氢负离子在磁场中的光剥离干涉图样的作用,推导并计算了本体系下的光剥离电子流通量,主要研究GaAs电介质表面到离子的距离不同对电子通量的影响。结果表明,电介质表面到离子的距离可以改变电子通量分布中的振荡结构,影响探测平面上形成的干涉图样的分布。因此,可以通过改变电介质表面到离子的距离来调控剥离电子的通量和干涉图样分布。     

Influence of the laser field polarization on the electron impact ionization of hydrogen

The triple differential cross-sections for the ionization of hydrogen by electron impact in the presence of a laser field have been calculated in the coplanar asymmetric geometry by using the first Born approximation and the symmetric geometry by using the Coulomb-Born approximation at an incident electron energy of 250 eV. The variation of the triple differential cross-sections, for fixed values of the angles of scattering and ejection, is studied as a function of the linear polarization of the laser field. The changes are quite amenable to experimental investigation.     

负氢离子源中电子能量沉积三维数值模拟研究

本文理论计算了多峰离子源永磁体, 采用二体碰撞模型(binary collision)处理电子之间的库仑碰撞, 采用空碰撞(null-collision)方法处理电子与氢元素相关粒子, 开发了全三维PIC-MCC模拟算法, 并利用该算法模拟了多峰离子源中电子沉积过程, 分析了多峰磁场对电子的空间和能量分布影响, 结果显示: 电子的非均匀分布起源于高能电子在引出区的B× ▽B漂移.     

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采用Langmuir探针方法对氢等离子体中电子密度和电子能量概率函数随射频功率的变化进行研究,发现电子密度在射频功率增加过程中出现两次跳跃。通过发射光谱法测得氢等离子体Hα、Hβ和Hγ三条谱线强度比值的变化,进一步验证了密度跳跃现象。该现象说明氢等离子体的放电模式发生了从电感耦合到电容耦合再到螺旋波模式的转变。从电子与氢分子的相互作用和Nagoya type Ⅲ型(N-型)天线电场耦合作用两方面解释密度跳跃现象。随着输入功率的增加,电子与氢分子相互作用增强,使电子密度发生跃变;当天线横向电场Ey取最大值,螺旋波轴向波矢kz分别为π/la和3π/la时天线与等离子体耦合最好,分别产生两次密度跳跃。     

Effect of atomic hydrogen adsorption on the transport characteristics of semiconducting carbon nanotubes

The effect of atomic hydrogen adsorption on the conduction and diffusion properties of carbon nanotubes of zigzag type in an external electric field is considered. The model of adsorption of atomic hydrogen on the surface of single-walled carbon nanotubes of zigzag type is based on the single-impurity periodic Anderson model. The theoretical calculation of the diffusion coefficient and electrical conductivity of carbon nanotubes of zigzag type doped with hydrogen atoms is carried out in the relaxation time approximation. It has been revealed that the electrical conductivity and electron diffusion coefficient decrease with increasing concentration of adsorbed hydrogen atoms. It has been shown that the dependence of the electrical conductivity and the diffusion coefficient on the amplitude of the constant electric field at the constant concentration of hydrogen adatoms is nonlinear.     

Adsorption and desorption of hydrogen and ethene on clean Si (111) faces

Workfunction, surface conductivity, field effect mobility and desorbed species have been measured after adsorption of hydrogen and ethene on heated clean silicon (111) faces. Whereas the hydrogen studies mostly show the same drastic changes as with cleaved faces, ethene does not change the electronic parameters except the electron affinity due to the dipole moment of the adlayer. During that treatment desorption of ethene and hydrogen due to decomposition is observed. The results enable a study of hydrogenation of ethene for simultaneous adsorption.     

Magnetic field focusing of hyperfine interaction in hydrogen

We find a new correction to hyperfine splitting in the ground state of hydrogen atom in magnetic field. The physical basis for this effect is the reduction of the size of the electron orbit in magnetic field. As a result, the value of the wavefunction at the origin increases which can be called magnetic focusing. Another magnetic-field-induced effect is the appearance of field dependent tensor forces.     

Positron-impact ionisation of atomic hydrogen in the presence of a bichromatic laser field

The positron impact-ionisation of atomic hydrogen in the presence of a linearly polarised bichromatic field is investigated in the first Born approximation.The field is composed of a fundamental frequency and its second harmonic.The state of positron in the field is described by the Volkov wavefunction,and the continuum state of the ejected electron is described by the Coulomb-Volkov wavefunction.The dressed ground state of target is a first order time-dependent perturbative wavefunction.The triple differential cross sections and their dependencies on laser field parameters are discussed and compared with the results modified by a monochromatic field.Numerical results show that the coherent phase control is significant and the laser-assisted ionisation cross sections caused by positron and electron are different.     

The strong OHO hydrogen bond. How much covalency?

In the strong OHO hydrogen bond of the phosphoric acid–urea 1?:?1 complex the proton shifts gradually with temperature from the donor towards the acceptor atom, passing through the center of the hydrogen bond at around 315?K. The AIM parameters were evaluated for the published neutron structures at different temperatures. The values of the electron density, its Laplacian, and the energy densities at both the critical points between the proton and the oxygen atoms in the OHO hydrogen bond were correlated with the OH and HO distances. Changes in the AIM parameters of the strong hydrogen bond were compared with those of the weak NHO bond in this complex.