杨氏双缝干涉实验中光谱奇异现象的特性分析

研究了完全相干光和部分相干光分别照射双缝时,杨氏双缝干涉实验中干涉场区的光谱变化现象.根据干涉场中光谱标准矩定义了光谱的相对光谱移动和相对光谱增宽,并利用相对光谱位移和相对光谱增宽分析了光谱奇异现象的特性.研究结果表明,入射光的某些光谱参量（如源光谱宽度Γ0,中心拦截比ε,相对空间相干度Δ0）对相对光谱增宽的影响相当大.结果还表明了光谱标准矩方法是定量研究光在传输中的光谱变化以及光谱奇异现象的有效工具.     

Spectral anomalies in supercontinuum focused waves

The diffraction-induced spectral anomalies in the focal plane of an apertured spherical wave with supercontinuum flat-top power spectrum are investigated. Coherent broadband radiation (also incoherent white light) demonstrates a strong blue shift in the vicinity of the optical axis, and discrete spectral gaps with overall red shift arise out of this central region. Unlike narrow-band light, the spectral switch effect fades away with ultra-broad spectra.     

Anomalous optical transitions in AlInGaN/GaN heterostructures grown by metalorganic chemical vapor deposition

Using temperature-dependent photoluminescence (PL) measurements, we report a comprehensive study on optical transitions in Al_yIn_xGa_1−x−yN epilayer with target composition, x=0.01 and y=0.07 and varying epilayer thickness of 40, 65 and 100 nm. In these quaternary alloys, we have observed an anomalous PL temperature dependence such as an S-shape band-edge PL peak shift and a W-shape spectral broadening with an increase in temperature. With an increase in excitation power density, the emission peak from the AlInGaN epilayers shows a blue shift at 100 K and a substantial red shift at room temperature. This is attributed to the localization of excitons at the band-tail states at low temperature. Compared to 40 and 65 nm thick epilayers, the initial blue shift observed with low excitation power from 100 nm thick AlInGaN epilayer at room temperature is caused by the existence of deeper localized states due to confinement effects arising from higher In and Al incorporation. The subsequent red shift of the PL peak can be attributed by free motion of delocalized carriers that leads to bandgap renormalization by screening. Due to competing effects of exciton and free carrier recombination processes, such behavior of optical transitions leads to two different values of exponent ‘k’ in the fitting of PL emission intensity as a function of excitation power.     

Gain enhancing due to quantum interference effect in an open four-level atomic system with Doppler broadening

The effect of vacuum-induced coherence (VIC) on the gain of lasing without inversion (LWI) is studied in an open four-level atomic system with Doppler broadening for both cases: co- and counter-propagating probe and driving fields. The results show that: (1) in general, for a fixed VIC strength, LWI gain decreases monotonously with the value of the Doppler broadening width increasing. Regardless of the Doppler broadening being obvious or not, the LWI gain much larger than that without VIC always can be gotten by choosing suitable VIC strength, i.e. values of two factors p₁ and p₂ which represent the VIC effect. (2) Varying p₁ or p₂ will produce remarkable different influence on the LWI gain, and the influence is closely related to the value of the Doppler broadening width. (3) In the case of counter-propagating probe and driving fields, when the Doppler broadening is large enough, gain oscillation occurs. For the same value of the Doppler broadening width, the oscillation amplitude increases with increasing values of strength of VIC. (4) The atomic exit and injection rates also can dramatically affect LWI gain. (5) The LWI gain for the co-propagating probe and driving fields is always larger than that for the counter-propagating probe and driving fields. (6) A much larger LWI gain in open system than that in the corresponding closed system can be obtained.     

Laser-excited spectra of Lu2SiO5:Ce scintillator

The emission spectra of Lu₂SiO₅:Ce single crystal under the excitation of 266 nm laser were investigated. The emission spectra of LSO single crystal show no temperature quenching from 20 to 300 K, under the excitation of 266 nm laser with 2 mJ pulse energy. With rising temperature, the Ce1 emission is slightly decreased, while the Ce2 emission is slightly increased. These results show the emissions of Ce1 and Ce2 is not only dependent on the concentration ratio but also influenced by the possible energy transfer processes, including Ce1 to Ce2, intrinsic STHs to Ce2 and the phonon-assisted transfer processes. The spectral thermal broadening and the spectral overlap become evident at high temperature, leading to the enhancement of energy transfer. When the excitation power lowers, the ratio of Ce1 and Ce2 emission increases, and is close to the Xe lamp ultraviolet (UV) excitation, suggesting that the energy transfer from Ce1 center to Ce2 center may be also dependent on the excitation power.     

Phonon confinement effect on nanocrystalline LiCoO2 studied with Raman spectroscopy

A systematic investigation on nanocrystalline LiCoO₂ has been carried out using Raman spectroscopy. We synthesized nanocrystalline LiCoO₂ (ca. 20-50 nm) through a combination of rapid thermal annealing at various annealing temperatures and a sol-gel method assisted with a triblock copolymer surfactant. Powder X-ray diffraction measurements revealed the formation of LiCoO₂. The crystallite size of LiCoO₂ from the Scherrer equation strongly depended on the annealing temperature. The crystallite size was confirmed by SEM and TEM measurements. Raman shifts of the A_1g and E_g modes for nanocrystalline LiCoO₂ exhibited a broadening and a frequency shift according to the crystallite size. While the frequency shift could be ascribed to a structural strain at the surface, the broadening was due to the phonon confinement effect produced by narrow crystal boundaries.     

Size-dependent photo-induced shift of the first exciton band in CdTe quantum dots in glass prepared by a two-stage heat-treatment process

CdTe nanocrystals were grown from commercially available RG850 Schott filter glass by two-step heat-treatment process which almost doubles the particle to matrix volume fraction. A calculation shows that a quantized-state effective mass model in the strong confinement regime might be used to deduce the average radius for the nanocrystals larger than 2 nm in radius from the energetic position of the first exciton peak in optical absorption spectrum. Size-induced shift of ∼360 meV in the first exciton peak position was observed. The steady state photoluminescence spectra exhibit a broad band red shifted relative to the first exciton band, which indicates the existence of shallow trap states. The non-linear optical properties of CdTe nanocrystals were studied by room temperature resonant photoabsorption spectroscopy. The differential absorption spectra had three-lobed structure whose size-dependent evolution was explained by bleaching of the absorption, red shift and broadening in the Gaussian absorption band used to fit the first exciton peak. A maximum red shift of 2.32 meV for the average nanocrystal radius of 4.65 nm was estimated by fitting the photomodulation spectra with a combination of first and second derivative Gaussian absorption bands. We presume that the red shift is induced by the electric field of trapped charges in surface states. Internal electric field strengths of 23 and 65 kV/cm were predicted for the average nanocrystal radii of 3.95 and 4.65 nm, respectively, with the help of second-order perturbation theory in the strong confinement limit.     

Temperature dependence of excitonic emission in cubic CdSe thin film

A detailed photoluminescence investigation of the thermal redshift and broadening of the excitonic line of cubic CdSe film grown by molecular beam epitaxy is presented. Free excitonic emission from the cubic CdSe film was observed at low temperature. Temperature-dependent measurement was performed to obtain material parameters related to exciton-phonon interaction by fitting the experimental data to the phenomenological model. The relative contribution of both acoustic and optical phonon to the band gap shrinkage and exciton linewidth broadening are discussed. Exciton binding energy of 16±1.5 meV was determined from the Arrhenius analysis.     

Autler-Townes triplet spectroscopy

We study the effects of quantum interference in the spontaneous emission spectrum of a four-level driven atomic system. We use three strong laser fields to drive the atom and a weak laser field to prepare the initial state of the atom. The atomic system exhibits Autler-Townes triplet in the spectrum. The single Lorentzian peak splits into triplet and their widths are controlled by the relative strengths of the laser fields.     

A theoretical investigation of wedged capacitive strip-grating output couplers for optically pumped terahertz lasers

The output power for terahertz lasers influenced drastically by slight changes in the transmittance of the output coupler for a certain terahertz frequency has been discussed in the paper. Therefore it is necessary to design an output coupler whose transmittance does not rapidly modulate with frequency. To obtain the flat and accurate transmittance spectrum in a narrow wavenumber interval (say 3 cm⁻¹), a wedged output coupler is proposed. This conclusion has been revealed after analyzing the disadvantages of two types of capacitive strip-grating output couplers, and theoretically studying its transmission properties. The theoretical results show that the coupler can not only provide flat and accurate transmittance spectrum and thus effectively suppress the etalon effects occurring frequently in previous experiments but also thoroughly eliminate the transmittance sensitivity to the slight shift of substrate thickness. Moreover, the wedged substrate of the improved output coupler can be used repeatedly in the process of adjusting the strip-grating parameters to meet various transmittance requirements for optically pumped terahertz lasers.     

Optimization of supercontinuum generation in photonic crystal fibers for pulse compression

A theoretical study of super generation in photonic crystal fiber and its application to pulse compression is presented. The evolution of the spectrum can be divided into three stages: initial broadening below a certain threshold propagation distance, dramatic broadening to a supercontinuum at a threshold distance, and, finally, saturation of the spectral width on propagation. It is found that the group delay and group-delay dispersion of the supercontinum are sensitive to the input pulse peak power after further propagation at the third stage. Fluctuations from the input pulse are amplified and translated into fluctuations and time shift of the compressed pulses. There exists an optimum compressed distance at which compressed pulses with negligible fluctuation and time shift can be obtained.     

Kinetic theory of radiation in non-equilibrium relativistic plasmas

Many-particle QED is applied to kinetic theory of radiative processes in many-component plasmas with relativistic electrons and non-relativistic heavy particles. Within the framework of non-equilibrium Green’s function technique, transport and mass-shell equations for fluctuations of the electromagnetic field are obtained. We show that the transverse field correlation functions can be decomposed into sharply peaked (non-Lorentzian) parts that describe resonant (propagating) photons and off-shell parts corresponding to virtual photons in plasmas. Analogous decompositions are found for the longitudinal field correlation functions and the correlation functions of relativistic electrons. As a novel result a kinetic equation for the resonant photons with a finite spectral width is derived. The off-shell parts of the particle and field correlation functions are shown to be essential to calculate the local radiating power in relativistic plasmas and recover the results of vacuum QED. The influence of plasma effects and collisional broadening of the relativistic quasiparticle spectral function on radiative processes is discussed.     

Photoluminescence studies in sol-gel derived Zno films

The photoluminescence (PL) properties of high quality ZnO thin films grown on Si (1 0 0) substrates using spin coating technique are investigated as a function of temperature in the range 10-300 K. The PL spectra shows dominant donor bound excitonic emission along with free exciton related emission in the UV region. The corresponding activation energy of thermal quenching is found to be . The parameters that describe the temperature dependent red shift of the band-edge transition energy are evaluated using different models. The broadening of the PL peak due to increase in temperature is mainly attributed to the exciton-LO phonon coupling.     

Focus shaping of cylindrically polarized vortex beams by a high numerical-aperture lens

The focus-shaping technique of a cylindrically polarized vortex beam by a high numerical-aperture lens is reported. Such a polarized vortex beam is decomposed into radial and azimuthal polarization. It is shown that the total intensity distribution in the focal region is dependent not only on the numerical-aperture maximal angle and the polarization rotation angle but also on the topological charge. By choosing the proper combination of parameters, the adjustably confined flat-topped focus and focal hole can be obtained. The focus-shaping technique may find wide applications, such as optical tweezers, laser printing and material processing.     

Pressure broadening measurement of submillimeter-wave lines of O3

The pressure broadening coefficients and their temperature dependences for two submillimeter-wave transitions of ozone, one being monitored with Odin and the other to be monitored with JEM/SMILES and EOS-MLS, have been determined by using a BWO based submillimeter-wave spectrometer. The measurements have also been extended to one of the symmetric isotopic species, ¹⁶O¹⁸O¹⁶O. The isotopic species is observed in natural abundance and as a consequence the temperature dependence is not determined due to weak signal intensity. The pressure broadening parameters are determined with better than 1% accuracy, while the temperature dependence exponents are obtained within 1.5-3% accuracy for the normal species transitions.     

高阶贝塞尔脉冲光束通过色散光阑透镜的传输特性

研究了高阶贝塞尔脉冲光束通过色散光阑透镜的光谱和时间空间特性.结果表明:脉冲光束在几何焦面上会出现光谱开关,透镜色散使产生光谱开关的临界位置向z轴移动;透镜一阶色散使几何焦面上峰值光强减小,并使脉冲波形产生显著时间移动和展宽,而二阶和高阶色散的影响较小.此外,光束阶数n和空间参量α也会影响横向光强分布.     

Optical absorption of 1,3-diphenyl-1H-Pyrazolo[3,4-b]quinoline and its derivatives

Paper deals with the experimental investigations and quantum chemical calculations of the absorption spectra of newly synthesized 1,3-diphenyl-1H-Pyrazolo[3,4-b]quinoline and its 6-Vinyl, 6-N,N-Diphenyl, 6-Methyl, 6-Fluoro, 6-Bromo, and 6-Chloro derivatives. The calculations are performed by means of the semiempirical quantum chemical methods AM1 or PM3 combined with: (a) equilibrium molecular conformation (EMC) in vacuo; (b) the molecular conformation model considering a dynamical rotation of phenyl rings only (T = 300 K); and (c) the most general model of the conformational molecular dynamics (MD) at T = 300 K. It is shown that the phenyl dynamics appears to be not important in the spectral position of absorption thresholds as well as in a broadening of most absorbtion bands. On the other hand, the MD simulations reproduce a broadening of the absorbtion spectra as well as the electron-vibronic coupling leading to a red-shift of absorption bands with increasing of temperature. The conformational MD model in combination with the quantum chemical AM1 method gives in most cases the best agreement with the experimental data, namely in the sense of spectral positions and width of the absorption bands including first oscillators (absorption thresholds).     

Transmittance of partially coherent cosh-Gaussian, cos-Gaussian and annular beams in turbulence

Average relative power transmittance is evaluated, by incorporating atmospheric turbulence, for partially coherent cosh-Gaussian, cos-Gaussian, Gaussian and annular beams. For all the collimated versions of these beams, against the increasing propagation length, there is a typical trend of the decrease in the relative average power transmittance with incremental drop being much less for partially coherent cos-Gaussian beams. The change in the transmittance versus the propagation length will be similar to the corresponding collimated cases, when these beams are focused at a certain focal length. Also partially coherent beams are less sensitive to propagation length changes, except for cos-Gaussian case. Partially coherent cosh-Gaussian beams exhibit a drop in the transmittance as the displacement parameter of the beam is made larger, whereas this trend is just the opposite for partially coherent cos-Gaussian beams. When examined versus the source size, for all the four types of beams, the transmittance has a similar behavior, i.e., it becomes high at small source sizes, falling with increasing source size, and following a dip, it starts to rise, eventually approaching the plane wave limit of unity. The occurrence of the dip coincides with the smallest source size for cosh-Gaussian, with the largest for cos-Gaussian, and about the same source size for Gaussian and annular beams. In general, the average relative power transmittance of coherent beam is affected much more than the partially coherent beams against the variations in source properties.     

Inverse photoemission spectroscopy of the unoccupied electronic structure of Na/Cu(110)

The unoccupied electronic states of Na thin films on a Cu(110) substrate have been measured by inverse photoemission spectroscopy (IPES). The IPES spectrum provides the intensity of the unoccupied states, which decreases with increasing Na coverage at off-normal incidence of the electron beam. The IPES spectra at 17 and 19 eV incident electron energies show a shift towards the Fermi level with increasing Na coverage for the peak at ∼7.8 eV.     

Radiation properties of sources inside an opal structure modified by changing the incident angle of pump light

In this paper we discuss the strong incident angle dependence of the modification of emission in an opal structure. We study the emission with oblique incidence and find that we can control the emission properties, such as emission intensity and spectral width, just by changing the incident angle of pump light. Calculations with varying incident angles show that the band gap of the structure blue shifts with the increase of incident angle and the emission power of embedded sources is strongly determined by this gap change. In addition, the photonic band gap determines the emission spectrum. With the incident angle increasing, the width of emission spectrum increases first and then decreases.