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1.
I. A. Sukhina R. P. Mamedova M. A. Agzamova M. I. Isaev 《Chemistry of Natural Compounds》2007,43(2):159-161
The two trisdesmoside cycloartane glycosides astragaloside VII and cyclotrisectoside were isolated from Astragalus dissectus (Leguminosae) and identified. The latter was 20R,25-epoxy-24S-cycloartan-3β,6α,16β,24-tetraol 3-O-β-D-xylopyranoside-6,24-di-O-β-D-glucopyranoside and was a new natural compound.
Presented at the Sixth International Symposium on the Chemistry of Natural Compounds (SCNC, Turkey, Ankara, 28–29 June 2005).
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Translated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 132–134, March–April, 2007. 相似文献
2.
The structure of the new cycloartane glycoside cyclomacroside D, which was isolated from Astragalus macropus Bunge (Leguminosae) and is 24R-cycloartan-1α,3β,7β,24,25-pentaol 3-O-α-L-rhamnopyranoside–24-O-β-D-xylopyranoside, was proved.
Presented at the 7th International Symposium on the Chemistry of Natural Compounds (SCNC, Tashkent, Uzbekistan, October 16–18,
2007).
Translated from Khimiya Prirodnykh Soedinenii, No. 1, pp. 48–50, January–February, 2009. 相似文献
3.
Ten pure compounds, three of which were identified as β-sitosterol, β-sitosterol β-D-glucopyranoside, and D-3-O-methyl-chiro-inositol, were isolated from roots of Astragalus macropus Bunge (Leguminosae). The structure of the new cycloartane triterpenoid cyclomacrogenin B was established as 24R-cycloartan-1α,3β,7β,24,25-pentaol.
Translated from Khimiya Prirodnykh Soedinenii, No. 5, pp. 502–504, September-October, 2008. Original article submitted May
26, 2008. 相似文献
4.
The new cycloartane glycoside cycloorbicoside D, which has the structure 23ξ,24ξ-cycloartan-3β6α,16β,23,24,25-hexaol 3-O-β-D-xylopyranoside,
was isolated from the aerial part of Astragalus orbiculatus Ledeb. (Leguminosae).
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Translated from Khimiya Prirodnykh Soedinenii, No. 4, pp. 345–346, July–August, 2005. 相似文献
5.
The lactone 20R-25-norcycloartan-3β,6α,16β-triol-20,24-olide was synthesized from cyclosiversigenin.
Presented at the 1st International Symposium on Edible Plant Resources and the Bioactive Ingredients, Xinjiang, China, July
25–27, 2008.
Translated from Khimiya Prirodnykh Soedinenii, No. 3, pp. 324–327, May–June, 2009. 相似文献
6.
M. D. Alaniya N. Sh. Kavtaradze R. Faure L. Debrauwer 《Chemistry of Natural Compounds》2008,44(3):324-326
The structure of a new cycloartane glycoside isolated from leaves of Astragalus caucasicus Pall. (Leguminosae) was elucidated using chemical transformations and spectral data. Cycloascauloside B is 20R, 25-epoxy-24S-cycloartan-3β,6α,16β,24-tetraol 3-O-[α-L-rhamnopyranosyl-(1å2)]-β-D-glucopyranoside. 相似文献
7.
Cycloadsurgenin, 20R,24 S-epoxycycloartan-6α,25-diol-3,16-dione, was partially synthesized in four steps from cyclosieversigenin. Side products with the structures 17E,24S-cycloart-17-en-6α,24,25-triol-3,16-dione and 17Z,24 S-cycloart-17-en-6α,24,25-triol-3,16-dione were obtained in addition to the desired product.
Presented at the 1st International Symposim on Edible Plant Resources and the Bioactive Ingredients, Xinjiang, China, July
25–27, 2008.
Translated from Khimiya Prirodnykh Soedinenii, No. 6, pp. 591–595, November–December, 2008. 相似文献
8.
V. I. Grishkovets I. I. Dovgii V. V. Kachala A. S. Shashkov 《Chemistry of Natural Compounds》2005,41(4):436-441
Structures of 13 new acetylated triterpene glycosides from leaves of Cussonia paniculata (Araliaceae) were established as
28-O-(2-O-acetyl- and 3-O-acetyl-α-L-rhamnopyranosyl)-(1→4)-O-β-D-glucopyranosyl-(1→6)-O-β -D-glucopyranosides of 23-hydroxybetulinic
acid (1a and 1b) and hederagenin (2a and 2b), 3-O-α-L-arabinopyranosyl-28-O-(2-O-acetyl- and 3-O-acetyl-a-L-rhamnopyranosyl)-(1→ 4)-O-β-D-glucopyranosyl-(1→6)-O-β-D-glycopyranosides
of oleanic (3a and 3b) and ursolic (3c and 3d) acids, 3-O-α-L-arabinopyranosyl-28-O-(4-O-acetyl-, 2-O-acetyl-, and 3-O-acetyl-α-L-rhamnopyranosyl)-(1→4)-O-β-D-glucopyranosyl-(1→
6)-O-β-D-glucopyranosides of hederagenin (4, d5a and 5b), and 3-O-β-D-glucopyranosyl-(1→2)-O-α-L-arabinopyranosyl-28-O-(2-O-acetyl- and 3-O-acetyl-α-L-rhamnopyranosyl)-(1→4)-O-β-D-glucopyranosyl-(1→6)-O-β-D-
glucopyranosides of oleanic acid (6a and 6b). The structures of the compounds were established using chemical methods and NMR spectroscopy.
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Translated from Khimiya Prirodnykh Soedinenii, No. 4, pp. 351–356, July–August, 2005. 相似文献
9.
Galactomannan of molecular weight 472 kDa was isolated from Astragalus danicus Retz. (Fabaceae) seeds and consisted of galactose and mannose units in a 1:1.40 molar ratio. The main chain of the macromolecule
was constructed of 1,4-β-D-mannopyranose units, 71% of which were substituted at C-6 by single α-D-galactopyranose units.
Translated from Khimiya Prirodnykh Soedinenii, No. 3, pp. 255257, May-June, 2009. 相似文献
10.
11.
D. A. Panov V. I. Grishkovets V. V. Kachala A. S. Shashkov 《Chemistry of Natural Compounds》2005,41(3):322-325
The known hederagenin 3-O-β-D-glucopyranosyl-(1→4)-O-β-D-xylopyranosyl-(1→ 3)-O-α-L-rhamnopyranosyl-(1→2)-O-α-L-arabinopyranoside (sapindoside C) and its 28-O-α-L-rhamnopyranosyl-(1→4)-β-D-glucopyranosyl-(1→6)-O-β-D-glucopyranosyl and 28-O-α-L-rhamnopyranosyl-(1→4)-O-6-O-acetyl-β-D-glucopyranosyl-(1→6)-O-β-D-glucopyranosyl esters, new triterpene glycosides, were isolated from leaves of Kalopanax septemlobum var. maximowiczii introduced to Crimea. The structures of these compounds were established using chemical methods and two-dimensional NMR spectroscopy.__________Translated from Khimiya Prirodnykh Soedinenii, No. 3, pp. 260–262, May–June, 2005. 相似文献
12.
The structure of the novel cycloartane triterpene glycoside cyclomacroside A, which was isolated from Astragalus macropus Bunge (Leguminosae) roots, was determined as 3-O-α-L-rhamnopyranoside-24,25-isopropylidenedioxy-24R-cylcoartan-1α,3β,7β-triol. 相似文献
13.
V. I. Lutskii A. S. Gromova E. A. Khamidullina N. L. Owen 《Chemistry of Natural Compounds》2005,41(2):117-140
Structures and chemical and spectral properties of triterpenoids isolated from plants of the Thalictrum genus were systematized for the first time. Features of 13C NMR spectra of cycloartane triterpenoids were discussed. Data for the biological activities of certain cycloartane and oleanane triterpenoids were given.__________Translated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 97–114, March–April, 2005. 相似文献
14.
15.
The structure of a new cycloartane-type triterpene glycoside, cyclomacroside E, which was isolated from roots of Astragalus macropus Bunge (Leguminosae), was established as 3-O-α-L-rhamnopyranoside,24-O[(β-D-xylopyranosyl)(1→2)-β-D-xylopyranoside]-24R-cycloartan-1α,3β,7β,24,25-pentaol. 相似文献
16.
17.
The new triterpene glycoside cycloorbicoside C was isolated from the aerial parts of Astragalus orbiculatus Ledeb. (Leguminosae) and was identified as (23R,24S)-16,23;16,24-diepoxycycloartan-3,25-diol 3-O--D-xylopyranoside 25-O--D-glucopyranoside. 相似文献
18.
The structure of galactomannans isolated from seeds of G. delavayi and G. aquatica was studied by 1H and 13C NMR spectroscopy. It was found that the galactomannans consisted mainly of β-1-4-bound mannopyranoses, a part of which was substituted on the C-6 hydroxyl by terminal units of α-galactopyranose.__________Translated from Khimiya Prirodnykh Soedinenii, No. 1, pp. 12–13, January–February, 2005. 相似文献
19.
The structure of a new triterpenoid, secomacrogenin B, which was isolated from Astragalus macropus Bunge (Leguminosae) roots
and is 24R-9,10-seco-cycloartan-1(10),9(11)-dien-3β,7β,24,25-tetraol, was elucidated. 相似文献
20.
G. I. Kovylyaeva G. A. Bakaleinik I. Yu. Strobykina V. I. Gubskaya R. R. Sharipova V. A. Al’fonsov V. E. Kataev A. G. Tolstikov 《Chemistry of Natural Compounds》2007,43(1):81-85
A new laboratory method for isolating the glycosides stevioside and rebaudiosides A and C from leaves of Stevia rebaudiana was proposed. According to HPLC, the glycoside contents in plants grown in Russia (Voronezh Oblast’) and Ukraine (Crimea)
were 5–6% (stevioside) and 0.3–1.3% (rebaudiosides A and C).
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Translated from Khimiya Prirodnykh Soedinenii, No. 1, pp. 68–71, January–February, 2007 相似文献