Etude Cristallographique Et Magnetique De Fe2GeS4 Structures Magnetiques A 85 Et 4,2°K

Fe₂GeS₄ crystallizes in the orthorhombic space group Pnma; the cell parameters are: $\text{a = 12,467}\text{A}\text{?}$, $\text{b = 7,213}\text{A}\text{?}$, $\text{c = 5,902}\text{A}\text{?}$; the crystal structure is isotype with olivine.A magnetic study by the extraction method shows that Fe₂GeS₄ is paramagnetic until 108°K, then antiferromagnetic until 69°K and finally antiferro- and ferrimagnetic at lower temperatures.Neutron diffraction reveals the magnetic structures at 85 and 4,2°K and explains the anisotropy transition at 69°K.     

Oscillation and CP violation in the “horizontal” superweak gauge scheme

A model, in a framework with CP violation processes and K°- $\text{K}$°, D° -$\text{D}$°, … mixing, caused by “Horizontal” gauge interactions, is considered.     

The accommodation of trivalent gold in Silver Chloride

Gold-doped silver chloride annealed in a chlorine atmosphere at 300°C is shown to contain precipitates of AgAuCl₄, a compound not previously reported. The substance melts at 265 ± 2°C and has a monoclinic unit cell with $\text{a = 11.124 ± 0.008}\text{A}\text{?}$, $\text{b = 4.105 ± 0.002}\text{A}\text{?}$, $\text{c = 6.539 ± 0.006}\text{A}\text{?}$ and β = 93.11 ± 0.05°. Its optical absorption spectrum is discussed and the method of precipitate formation in silver chloride is described in terms of an internal oxidation type of process.     

Near 90° scattering in the channels K̄°p → π+Λ°, K̄°p → π+Σ° and KL°p → KS°p from 1.0 to 7.5 GeV/c

Differential cross sections for center of mass scattering angles near 90° are presented for the reactions $\text{K}\text{?}\text{°}\text{p}\text{→ π}{}^{\mathrm{+}}\text{Λ°}$, $\text{K}\text{?}\text{°}\text{p}\text{→ π}{}^{\mathrm{+}}\text{Σ°}$ and K_L°p → K_S°p in the momentum interval 1.0 to 7.5 GeV/c. The energy dependences of these cross sections are found to be equally well described by the parameterization: $\text{(}\text{d}\text{σ}\text{d}\text{Ω}\text{)}{}_{\mathrm{90°}}\text{∞ s}{}^{\mathrm{?2}}$ or $\text{(}\text{d}\text{σ}\text{d}\text{Ω}\text{)}{}_{\mathrm{90°}}\text{∞}\text{exp}\text{(? bp}{}_{\mathrm{\perp }}\text{)}$.     

Effect of Bragg-Williams disorder on reconstructed polar surfaces of tetrahedrally coordinated compound semiconductors by optically simulated leed patterns

Laser generated optical diffraction patterns obtained from two-dimensional model gratings have been used to simulate the surface reconstructions observed by LEED with the polar surfaces of tetrahedrally coordinated compound semiconductors. The 2 × 2 and $\text{4}\text{3}\text{× 4}\text{3}\text{?30°}$ reconstructions conform ideally with the $\text{1}\text{4}$-monolayer criterion dictated by bonding ionicity [Nosker, Mark and Levine, Surface Science 19 (1970) 291] while the 3 × 3, $\text{3}\text{×}\text{3}\text{?30°}$ and $\text{19}\text{×}\text{19}\text{?23.4°}$ reconstructions do not. It is shown that the introduction of Bragg-Williams disorder that preserves long-range order into the latter structures does permit the achievement of conformity with the $\text{1}\text{4}$-monolayer criterion without altering the symmetry of the diffraction pattern. Specifically the intensities of the fractional order beams are reduced relative to those of the integral order beams. Thus all the observed reconstruction LEED patterns can be consistent with the $\text{1}\text{4}$-monolayer criterion, provided account is taken of the insensitivity of LEED to surface defect structure.     

Semiconductor-metal transition in doped (CH)x: Thermoelectric power

Thermoelectric power studies of polyacetylene have been carried out as a function of dopant concentration and temperature. The thermopower of pure trans-(CH)_x is large $\text{(S =}\text{+850 μ V}\text{°K}\text{)}$ and positive consistent with p-type material. With iodine doping, (CHI_y)_x, the thermopower remains positive over the full range of concentration 0 < y < 0.22. The semiconductor-metal transition is clearly observed at n_c ? 3 mole %; S falls dramatically from $\text{S =}\text{+850 μ V}\text{°K}$ at y = 0.003 to $\text{S =}\text{+30 μ V}\text{°K}$ at y = 0.03. At higher concentrations, S remains nearly constant saturating at $\text{+18 μ V}\text{°K}$ in the heavily doped metallic polymer. Temperature dependences are consistent with metallic behavior at the highest dopant concentrations and hopping transport in the undoped and lightly doped polymer.     

The change of conductivity of erbium films caused by the sorption of hydrogen and oxygen

Films of erbium were evaporated onto the inside wall of a pyrex glass reaction vessel at 1O^?9 torr. Their mean thickness (200–600 Å) was deduced from their mass and geometrical area. Estimates of their surface areas were made from the physical adsorption of krypton at 78 °K (BET method) giving a mean specific surface area of 71 m^?2 g^?1. The number of surface sites was calculated from a relationship given by Brennan et al.¹⁾. The sorption of hydrogen and oxygen was studied separately, by measuring the changes in the electrical resistance of the films as a function of the amount of pure gas admitted to the reaction vessel in measured doses ～ 10¹⁸ atoms per dose. The experiments were repeated at 295 °K, 200 °K, 130–140 °K for both gases (measurements at 78 °K were not reproducible, probably because of a magnetic phase change). Hydrogen at 295 °K [as reported²⁾] caused an initial increase ΔR in the original resistance R to a maximum $\text{ΔR}\text{R}$ ～ 20 %, which was followed by a decrease to $\text{ΔR}\text{R}\text{= 0}$ and then to $\text{ΔR}\text{R}\text{< 0.}$ A similar pattern of resistance changes was observed at 200°K and 130–140°K with smaller changes of $\text{ΔR}\text{R}$, i.e. 16 % and 8 % respectively, but no significant differance in surface (θ) and bulk atomic ratios at which the maxima occurred, e.g. $\text{ΔR}\text{R}$ was a maximum for 1.6?θ?1.9.     

Characterization of LiFeCl4 and AgFeCl4 ionic conductors

LiFeCl₄ and AgFeCl₄ are obtained by direct reaction between LiCl or AgCl and FeCl₃ at 300°C and 400°C respectively. Both compounds are monoclinic with $\text{a = 7.02 (1)}\text{A}\text{?}$, $\text{b = 6.33 (1)}\text{A}\text{?}$, $\text{c = 12.72 (4)}\text{A}\text{?}$, β = 92° (30') for LiFeCl₄ and $\text{a = 10.60 (5)}\text{A}\text{?}$, $\text{b = 6.30 (5)}\text{A}\text{?}$, $\text{c = 12.34 (10)}\text{A}\text{?}$, β = 106° (1) for AgFeCl₄.LiFeCl₄ is clearly isotypic of LiAlCl₄. Magnetic measurements characterize in both cases Fe³⁺ ions in a high spin tetrahedral situation. LiFeCl₄ becomes antiferromagnetic at low temperature (T_N?10 K). AgFeCl₄ reveals a more complex situation. On contrary to the silver derivative, LiFeCl₄ is a good ionic conductor with activation energy of 0.78 eV in the solid state below 105°C, and a sharp increase in the lithium mobility at this temperature.     

Rotational spectrum of sulfuryl bromide fluoride

The rotational spectra of SO₂⁷⁹BrF and SO₂⁸¹BrF have been obtained between 18 and 40 GHz. Both molecules are near-prolate symmetric rotors with a and b-type dipole components. A least-squares fit of the observed moments of inertia obtained by correcting for the bromine quadrupole interaction yields $\text{r}\text{(SBr) = 2.155 ± 0.006}\text{A}\text{?}$ and ? FSBr=100.6°±1.5° structural parameters when $\text{r}\text{(SO) = 1.407}\text{A}\text{?}$, $\text{r}\text{(SF) = 1.56}\text{A}\text{?}$, and ? OSO=123.7° are assumed.     

Internal friction of deformed zinc single crystals

Zinc single crystals with the side in a (0001) basal plane were elongated and the internal friction measurements were carried out as a function of temperature in the mode of a flexural vibration. Two relaxation peaks were observed to appear: one at around 500°K and the other at about 570°K. Each activation energy was obtained 0.70±0.08eV and 1.01±0.06eV, respectively, by the peak shift method. The experimental results were discussed in terms of dislocations in pyramidal slip system {$\text{11}$22} 〈11$\text{2}$3〉 and twinning dislocations in the planes {$\text{1}$012} 〈10$\text{1}$1〉, respectively.     

Observation of the ABC effect in the reaction n+p → d+(mm)0 with A 1.88 GeV/c neutron beam

A significant production of the ABC effect is observed in the free nucleon reaction n+p → d+(mm)°, using a 1.88 GeV/c neutron beam. The complete deuterón momentum spectra produced in this inclusive experiment are measured at 0°, 4.5°, 7.5° and 10.5° (lab). The double differential cross sections $\text{d}{}^2\text{σ/}\text{d}\text{Ω}\text{d}\text{p}$, are compared with the predictions of two exchange models.     

Resistivity of dilute AlMg and AlMn between 0° and 100°C a generalized approach

We have measured the resistivity of $\text{Al}$Mg and $\text{Al}$Mn up to 0.5 at. % impurity concentration between 0° and 100°C. The results for the resistivity for both systems can be analysed within one generalized model in which spinfluctuations as well as changes in the electron-phonon interaction are considered. For $\text{Al}$Mn a calculation of the impurity contribution to d?/dT is attempted. For $\text{Al}$Mg there are indications that the superconducting T_c will increase with Mg concentration.     

The impurity resistivity and resistivity minima in AlCr and AlMn alloys

The impurity resistivity of $\text{Al}$Cr between 1.5 and 50°K was determined with a characteristic temperature for the T² variation θ₁=960±40°K. The behaviour of the resistivity minimum both in $\text{Al}$Cr and $\text{Al}$Mn alloys with impurity concentration provides evidence that a T³ phonon resistivity is found also in aluminium with anomalous impurity resistivity.     

Neutron-proton elastic scattering at 325 MeV

Accurate measurements of the P and D_T parameters in np elastic scattering at 325 MeV resolve a major ambiguity in the phase shift analysis. The mixing parameters $\text{ε}{}_1\text{= 8.4 ± 0.6°}$ and $\text{ε}{}_3\text{= 7.2 ± 0.4°}$ are particularly well determined, and in good agreement with theoretical expectations.     

Nuclear magnetic resonance and relaxation in liquid zinc

Measurements of the Knight shift K and the nuclear spin-lattice relaxation rate $\text{(}\text{1}\text{T}{}_{\mathrm{l}}\text{)}$ of Zn⁶⁷ are reported for liquid Zn. Measurements of K extend from 409°C (supercooled) to 700°C; measurements of $\text{(}\text{1}\text{T}{}_{\mathrm{l}}\text{)}$ cover the range 425 – 620°C. The Knight shift shows a weak positive temperature dependence attributed to thermal expansion. The reciprocal enhancement factor of the Korringa relation K(α) is found to increase with temperature from .77 ± .04 to .82 ± .04 in the range 425 – 620°C. The quadrupolar contribution to the relaxation rate was concluded to be very small with an estimated upper limit given by $\text{(}\text{1}\text{T}{}_{\mathrm{l}}\text{)}{}_{\mathrm{Q}}\text{≤ 15 sec.}{}^{\mathrm{-l}}$     

Low density specific heat measurements of para-hydrogen adsorbed on exfoliated graphite

Heat-capacity measurements of para-hydrogen adsorbed on bare graphite foam for coverages below about the $\text{(}\text{3}\text{×}\text{3}\text{) R30°}$ configuration between 0.0126 and 0.0622 Å^?2 were made as a function of temperature in the range of 5 to 25 K using a quasiadiabatic method. From the data a phase diagram is suggested having three distinct regions: a pure $\text{(}\text{3}\text{×}\text{RCD>3}\text{)R30°}$; phase, a coexistence region between $\text{(}\text{3}\text{×}\text{3}\text{)R30°}$ and fluid and a pure fluid region. A tricritical point seems to exist at $\text{T}{}_{\mathrm{TC}}\text{? 12.4 K and}\text{n}{}_{\mathrm{TC}}\text{? 0.039}\text{A}\text{?}{}^{\mathrm{?2}}$. The critical exponent α = 0.37 ± 0.03 was calculated which, within our experimental measurements, is the theoretical 3-state Potts value of $\text{1}\text{3}$. Considering the adatoms behaving as localized Einstein oscillators, for the 0.0636 Å^?2 density, an average Einstein temperature of 54.4 ± 4.9 K was obtained. Our results are compared with data obtained by other authors.     

Autoassociation du cyclohexanol. II - caracteristiques spectroscopiques des vibrateurs ν(OH) dans les complexes d'autoassociation.

From a thermodynamic model of associated solution, the molar extinction coefficients for the spectroscopically discernable ν(OH) vibrations of associated species of cyclohexanol in isooctane solutions at 25°C and 45°C are obtained. It is found that the molar extinction coefficients for the end hydroxyl group of open species and for the monomer band are very near (57 M^?1 cm^?1 at 25°C). For the hydrogen bonded hydroxyl groups, molar extinction coefficients at 25°C are found to be, in M^?1 cm^?1 units : 93 for the open dimer ($\text{ν}$ = 3515 cm^?1), 90 for the open trimer ($\text{ν}$ = 3440 cm^?1), 126 for the other i-mers ($\text{ν}$ = 3340 cm^?1).     

A study of the (00) LEED beam intensity at normal incidence from CdS(0001), Cu(001), Cu(111), and Ni(111)

A Faraday cage apparatus is used for the measurement of the (00) LEED beam intensity, I₍₀₀₎, and the total secondary emission coefficient, δ(E_k), for angles of incidence from 0° ± 2° to 8° ± 2°, with an energy resolution of ± 0.037 of the incident beam energy, in the energy range 1 to 200 eV. The data are normalized and expressed as a fraction of the incident beam intensity. The basic principle of operation is the separation of the incident and specularly diffracted beams in a uniform magnetic field. Monolayer, or in-plane, resonances associated with the emergence of nonspecular beams, as well as beam threshold minima, are observed in I₍₀₀₎ at normal incidence from clean CdS(0001), Cu(111), and Ni(111). Some major differences are observed in the I₍₀₀₎ profiles for the clean (111) surfaces of nickel and copper. All secondary Bragg peaks, except the 2$\text{2}\text{3}$ order, have greater intensities for Ni(111) in the energy range 50–150 eV, thus indicating that the atomic scattering cross-section for electrons in this energy range is larger for nickel than for copper. For the (111) surface of nickel, the (11) resonance is missing, but the (10) resonance and all $\text{1}\text{3}$ order secondary Bragg peaks between the second and fifth orders are observed. For Cu(111) both the (10) and (11) resonances are observed, but the $\text{1}\text{3}$, $\text{2}\text{3}$, 1$\text{2}\text{3}$, and 3$\text{1}\text{3}$ order secondary Bragg peaks are missing in this energy range. These data indicate that multiple scattering with evanescent intermediate waves, or “shadowing”, is predominate on the (111) surfaces on nickel and copper for energies above 30 eV, and that below 30 eV multiple scattering with propagating intermediate waves is predominate on Cu(111). Correlation of the (00) beam intensity profiles from clean Ni(111) at 0°, 2°, and 6° with the intensity profiles of the (10). (1&#x0304;0), and (11) non-specular beams is nearly one-to-one from 30 eV to 100 eV, thus supporting the dynamical theories of LEED in which peaks in the (00) beam are expected to occur at nearly the same energies as peaks in the non-specular beams.     

Mean lifetimes of excited levels of Ar II. I. Time correlation measurements

Mean Lifetimes of excited levels of Ar II have been measured using the method of time-correlated photons in cascade. The following results were obtained: for 4p⁴S^°_{$\text{3}\text{2}$}, τ = 7·2±0·3ns; for 4p′²F^°_{$\text{7}\text{2}$}, τ = 8·8±0·2 ns; for 4p′²F^°_{$\text{5}\text{2}$}, τ = 8·0±0·2 ns. These results are compared with experimental and theoretical values.     

Proton-proton bremsstrahlung and the 2H(p, 2p)n reaction at 51.8 MeV

Proton-proton bremsstrahlung cross sections were measured at 33°-33° and 8.5°-8.5° with a coplanar symmetric geometry. A comparison between experimental cross sections and theoretical predictions was made. The ²H(p, 2p)n reaction was also investigated at 12.5°–12.5° and 8.5°–8.5°. The cross sections were compared with the values calculated by existing theories.