Generalized Preisach model of hysteresis — theory and experiment

A new approach to the Preisach hysteresis model is presented. Special attention is focused on the analytical expression of the model function. -Fe₂O₃ natural sample is used to demonstrate the model, and the latest findings in the problem of the stability of the Preisach diagram are discussed.     

Two-photon absorption and two-photon induced absorption of liquid toluene at 347.15 nm

Pump pulse transmission and time-delayed probe pulse transmission measurements through liquid toluene were performed with linear and circular polarized second harmonic pulses of a mode-locked ruby laser system. Two-photon absorption and two-photon induced absorption are observed. The induced absorption anisotropy is investigated. A theory of two-photon absorption in isotropic media is presented. The two-photon absorption cross-section components, the effective excited-state absorption cross-section, the absorption anisotropy relaxation time and the excited singlet-state relaxation time are determined.     

Surface electronic structure of Ge(001)2 × 1: experiment and theory

Detailed studies of the surface electronic structure of Ge(001)2 × 1 have been performed with angle-resolved photoemission. Five surface structures are identified in the spectra and their initial-energy dispersions E(k_∥) are presented along the [010] direction. Employing the local density approximation and Green's functions, the surface band structure along this direction has been calculated self-consistently for an asymmetric dimer model of the 2 × 1-reconstructed surface. Four of the five experimental surface structures are identified with calculated surface states or resonances, i.e. the dangling-bond state and two different back-bond resonances. Excellent agreement is obtained between the experimental and theoretical dispersions for these surface electronic bands.     

Improved non-empirical absorption potential for electron scattering at intermediate and high energies: 30–10000 eV

The non-empirical model proposed by Staszewka et al. in 1983 for the imaginary part of the electron scattering optical potential is revised, improving the treatment used for the e⁻ −e⁻ dispersion. New cross-section calculations employing the revised potential are in agreement with available experimental data for elastic and inelastic processes.     

Optical spectra of triglycine sulfate crystals in the range of 7–33 eV and its changes at phase transition

Pseudo-dielectric functions ?ε₁(E)? and ?ε₂(E)? of triglycine sulfate (TGS) crystal have been obtained in the range of 7–33 eV for different temperatures close to ferroelectric phase transition by spectral ellipsometry using the synchrotron radiation source BESSY II. These dielectric functions ε₁(E) and ε₂(E) have also been calculated from first principles using CASTEP CAmbridge Serial Total Energy Package code together with the band structure and density of electronic states of the crystal. Experimental and theoretical dielectric functions agree satisfactorily. A characteristic decrease of temperature dependences of the dielectric losses tgδ(T) and related values just below the phase transition temperature T _c have been found and discussed.     

Lifetimes of rovibrational levels of the long-range I′ 1Πg state of H2 and D2: experiment and theory

The lifetimes of the lowest lying rovibrational levels of the outer well I′ ¹Π_g state of molecular hydrogen were measured for both H₂ and D₂. The measurements were made by direct observation of the time-dependent decay of the fluorescence. The observed lifetimes depend on isotopomer and increase with vibrational excitation. The predominant decay route for these levels is fluorescence. Previously published ab initio lifetimes calculated for these states, which accounted for non-adiabatic interactions [J. Chem. Phys. 92, 7461 (1990)], are in good agreement with experiment for H₂ but are too long by four or five orders of magnitude for D₂. We present new ab initio results at the adiabatic level for the fluorescence lifetimes. The current results are in reasonable agreement with the experimental lifetimes for both H₂ and D₂. We explain the isotopomer and vibrational dependence of the lifetimes and discuss the neglected interactions and decay pathways.     

Estimate of the fraction of primary photons in the cosmic-ray flux at energies ∼1017 eV from the EAS-MSU experiment data

We reanalyze archival EAS-MSU data in order to search for events with an anomalously low content of muons with energies E _μ > 10 GeV in extensive air showers with the number of particles N _e ? 2 × 10⁷. We confirm the first evidence for a nonzero flux of primary cosmic gamma rays at energies E ～ 10¹⁷ eV. The estimated fraction of primary gamma rays in the flux of cosmic particles with energies E ? 5.4 × 10¹⁶ eV is ε_γ = (0.43 _?0.11 ^+0.12 )%, which corresponds to the intensity I _γ = (1.2 _?0.3 ^+0.4 ) × 10^?16 cm^?2 s^?1 sr^?1. The study of arrival directions does not favor any particular mechanism of the origin of the photon-like events.     

Cavity correlation and bridge functions at high density and near the critical point: a test of second-order Percus–Yevick theory

ABSTRACT

Cavity correlation functions, pair correlation functions, and bridge functions for the Lennard-Jones fluid are calculated from first Percus–Yevick (PY) theory and second-order Percus– Yevick (PY2) theory, molecular dynamics, and grand canonical Monte Carlo techniques. We find that the PY2 theory is significantly more accurate than the PY theory, especially at high density and near the critical point. The pair correlation function near the critical point has the expected slowly decaying long-range behaviour. However, we do not observe any long-range behaviour in the bridge function for the state points near the critical point we have simulated. However, we do note that the bridge function, which is usually negative near r = 0, becomes positive as r → 0. This behaviour is seen for the bridge functions computed from both PY2 and molecular dynamics, but not from PY.     

High–pressure electrical conductivity and Raman spectroscopy of chalcanthite

Abstract

The phase transitions and dehydration of chalcanthite were investigated by electrical conductivity and Raman spectroscopy at 1.0–24.0?GPa and 293–673?K in a diamond anvil cell. At ambient temperature, two secondary phase transitions were observed according to discontinuous changes in the slope of Raman shifts, full width at half maximum and electrical conductivities at ～7.3 and ～10.3?GPa. The dehydration temperatures were determined by the splitting of Raman peaks and changes in electrical conductivity as ～350 and ～500?K at respective ～3.0 and ～6.0?GPa. A positive relationship for chalcanthite between dehydration temperature and pressure is established.     

Resonant scattering of He-atoms from missing-row reconstructed Pt(110)1 × 2: comparison of theory and experiment

Close coupled channels calculations concerning the angular dependence of the specular beam were performed on the basis of the He/Pt(110)1 × 2 interaction potential, which we previously derived by analyzing a large number of He-diffraction intensities. The excellent agreement with experimental data obtained for several wavelengths confirms the reliability of the potential form and depth and allows proper assignment of resonant scattering features and thus secure determination of the bound state levels.     

Clock hypothesis of relativity theory,maximal acceleration,and Mössbauer spectroscopy

Results obtained several years ago using the high-resolution 93.3 keV Mössbauer resonance in ⁶⁷ZnO and β^′-brass have been reanalyzed with the notion that the clock hypothesis of Special Relativity Theory is not sufficient, but that a maximal acceleration a_m exists and that an acceleration a contributes to the temperature dependence of the center shift by a term ±(1/2)(a/a_m)². The significance of the sign of this term is discussed in detail. For both substances a lower limit of a_m>1.5?10²¹m/s ² is inferred which is more than two orders of magnitude larger than - and thus excludes - the value a_m=1?10¹⁹m/s ² suggested by ⁵⁷Fe rotor experiments.     

Single-electron charge transfer in collisions of CF 2 ++ with Ar and Ne at collision energies 3–5 eV

Non-dissociative, single-electron charge transfer processes between the dication CF ₂ ⁺⁺ and Ar and Ne were investigated in crossed beam scattering experiments at collision energies of 3.0 and 4.55eV (c.m.). The reaction with Ar produces CF ₂ ⁺ in its ground state and, to a smaller extent, in the excited CF ₂ ⁺ (²_u) state. The reaction with Ne occurs only with an excited state of CF ₂ ⁺⁺ lying about 4.4 eV above the ground state and present in a small amount in the reactant dication beam; its molecular product is CF ₂ ⁺ in the ground state.     

On the limits of quantum theory: Contextuality and the quantum–classical cut

This paper is based on four assumptions: 1. Physical reality is made of linearly behaving components combined in non-linear ways. 2. Higher level behaviour emerges from this lower level structure. 3. The way the lower level elements behaves depends on the context in which they are embedded. 4. Quantum theory applies to the lower level entities. An implication is that higher level effective laws, based on the outcomes of non-linear combinations of lower level linear interactions, will generically not be unitary; hence the applicability of quantum theory at higher levels is strictly limited. This leads to the view that both state vector preparation and the quantum measurement process are crucially based on top-down causal effects, and helps provide criteria for the Heisenberg cut that challenge some views on Schrödinger’s cat.     

Time-domain terahertz and infrared spectroscopy of BaTiO3–PVDF nanocomposites

Several composites of BaTiO₃ nanoparticles obtained by mechanosynthesis embedded into a PVDF matrix were studied using time-domain THz and FTIR spectroscopies and microwave measurements with the split-post-resonator technique. No indication of the ferroelectric phase transition could be seen in the temperature dependence of the effective dielectric response, in agreement with expectations based on various effective medium models. The effective soft-mode frequency is strongly shifted up and smeared. No conclusion on the size effect of ferroelectricity can be drawn from the effective dielectric response.