Analysis of partially oriented AA′XX′ N.M.R. spin systems with the aid of sample rotation. The 19F spectrum of cis-difluoroethylene dissolved in a nematic phase

The spectrum of an oriented AA′XX′ spin system can be analysed to give only the parameters δ_AX, J _AA′, T _AA′zz , J _XX′, T _XX′zz and the combinations (J _AX + J _AX′ + 2T _AXzz + 2T _AX′zz ) and (J _AX - J _AX′ + 2T _AXzz - 2T _AX′zz ). By controlled, slow sample rotation it is possible to determine all these parameters separately, and some of their relative signs. Application of this technique to cis-difluoroethylene confirms the signs of the coupling constants determined by Baldeschwieler et al. The dipolar couplings for cis-difluoroethylene are compared with values calculated assuming the geometry as determined from microwave spectroscopy and including the effects of harmonic vibrations.     

Conformational Studies of 1-(2′-Hydroxythiobenzoyl)piperidine and 4-(2′-Hydroxythiobenzoyl)morpholine by High Resolution N.M.R. Spectroscopy

Abstract

The 220 MHz ¹H nmr spectra of the title compounds (1a) and (2a), respectively, at low temperature in CDCl₃ solution are interpreted in terms of two interconverting chair forms with unequal populations (K_e = 1.17, δG° ～70 cals/mole for 1a and K_e = 1.8, δG° ～0.2 kcal/mole for 2a at ?30°C). A strong intramolecular OH…S hydrogen bond in both compounds reduces the number of degrees of freedom of the bulky N-thiobenzoyl substituent, which nearly eclipses the equatorial α-CH₂ hydrogen atoms in both comformations. Steric interactions between the 6′ phenyl proton and the hetero-ring α-CH₂ protons trans to the thiocarbonyl group are different in the two conformations of la and 2a.     

Two Dimensional 1HNMR Studies on 2′5′-Dideoxyadenosylcobalamin

The ¹HNMR spectrum of 2′,5′-dideoxyadenosylcobalamin, a Coenzyme B₁₂(5′-deoxyadenosylcobalamin) analogue, has been assigned by 2D COSY. Its proton coupling constants have also been measured by J-resolved experiment. The comparison between the analogue and Coenzyme B¹² was made.     

The decays of theρ′1 andω′1 mesons

New measurements of the reactione ⁺ e ^– confirm previous evidence for the decay₁ and provide a strong constraint on the mass of the₁. The results from a detailed analysis of these data are compared with those from a corresponding analysis of new data on the reactione ⁺ e ^–. It is shown that in accord with expectation. This identification of a strong₁ decay supports a previous claim that the₁ and theC(1480), observed in the channel, cannot be different manifestations of the same particle.     

In-Medium η′ Mass Reduction

In this talk, we present the reduction of the mass of η′-meson at finite temperature which leads to the enhancement of η′ contributions to the dilepton spectra from relativistic heavy ion collisions. QCD low energy theorem, together with the Witten–Veneziano formula, provides the relation of the η′ mass with gluon condensates.     

Pulsed ESR on the organic ion radical salt: 3,3′-diethyl-4,4′-dimethyl-2,2′-thiazolocyanine-[TCNQ]2

We present firstT _1e ^?1 andT _2e ^?1 measurements on the organic ion radical salt 3,3′-diethyl-4,4′-dimethyl-2,2′-thiazolocyanine-(TCNQ)₂ as function of temperature and of orientation. The electronic spin diffusion constant could be determined directly by the electron spin echo field gradient technique:D (300 K)=0.03±0.02 cm²/sec. Pulsed ESR experiments have — in comparison to conventional cw-ESR — the advantage to monitor viaT _1e ^?1 andT _2e ^?1 the spectral density of dynamical processes at different frequencies. This is shown in a general manner on 3,3′-diethyl-4,4′-dimethyl-2,2′-thiazolocyanine-(TCNQ)₂. Between 300 and 60 K,T _1e ^?1 andT _2e ^?1 are close in amplitude and have a similar temperature dependence. At 60 K their degeneracy is lifted, yielding a quantitative value for the effective spin exchange between localized spinsτ _ex ^?1 sec^?1 and via the absolute value of the relaxation an average distance of the localized centers of about 12 Å. The dynamical data as evaluated above cannot be correlated with the conductivity, clearly indicating that the conduction electrons are a minority, not being monitored by the ESR-experiments.     

Unusual nucleation and growth of γ′ iron nitride upon nitriding Fe–4.75 at.% Al alloy

The influence of substitutionally dissolved Al in ferritic Fe–4.75 at.% Al alloy on the nucleation and growth of γ′ iron nitride (Fe₄N_{1? x} ) was investigated upon nitriding in NH₃/H₂ gas mixtures. The nitrided specimens were characterised employing optical microscopy, scanning electron microscopy, transmission electron microscopy, electron probe microanalysis and X-ray diffraction. As compared to the nitriding of pure ferrite (α-Fe), where a layer of γ′ develops at the surface, upon nitriding ferritic Fe–4.75 at.% Al an unusual morphology of γ′ plates develops at the surface, which plates deeply penetrate the substrate. In the diffusion zone, nano-sized precipitates of γ′ and of metastable, cubic (NaCl-type) AlN occur, having, with the ferrite matrix, a Nishiyama–Wassermann orientation relationship and a Bain orientation relationship, respectively. The γ′ plates contain a high density of stacking faults and fine ε iron nitride (Fe₂N_{1? z} ) precipitates, although the formation of ε iron nitride is not expected for the employed nitriding parameters. On the basis of dedicated nitriding experiments it is shown that the unusual microstructural development is a consequence of the negligible solubility of Al in γ′ and the obstructed precipitation of the thermodynamically stable, hexagonal (wurtzite-type) AlN in ferrite.     

Morse 势中矩阵元Xνν′、Pνν′的计算

矩阵元ＸＶＶ’和ＰＶＶ’在有关量子力学问题中有相关重要的应用，本文利用广义拉盖尔多项式的正交性和分部积分的方法，推导Ｍｏｒｓｅ势中ＸＶＶ’、ＰＶＶ’的计算公式。     

1,1′-和1,2′-二萘甲酮结构的光谱分析

本文用红外光谱仪 (FTIR)、紫外分光光度计 (UV)对在无水AlCl3 存在下萘与草酰氯反应合成的1 ,1′ 和 1 ,2′ 二萘甲酮的结构进行了研究。结果表明 ,1 ,1′ 和 1 ,2′ 二萘甲酮结构 (对称性 )上的差别表现出FTIR、UV光谱图上的明显不同。     

f.c.c./f.c.c.LUCS的电子结构

在只计入最近邻间相互作用的紧束缚近似下,计算了由两种面心立方金属组成的多层超薄共格结构(LUCS)的电子能谱和态密度。 关键词：     

Chin. Phys. B Vol. 21. No. 6 （2012） 066301

[BO4]^-1＋4SIO2 → [BSi4O1o]^-1 ＋ 02, 2BaC03＋SiO2→Ba2SiO4＋2C02. The relatively higher temperature that is suffi-cient to melt the mixture was chosen to be 1100 ℃. 510 ℃ was determined as the annealing temperature to exclude stress and air bubbles.     

К ТЕОРИИ СПОНТАННОЙ Н АМАГНИЧЕННОСТИ ТОНК ИХ СЛОЕВ. I. ЧАСТЬ

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J.J.汤姆孙

J·J·汤姆孙是英国著名的物理学家,曾因气体导电的实验研究和发现电子,获1906年的诺贝尔物理学奖.他是原子物理学的主要奠基人之一,又是一位伟大的教育家,是研究生制的创立者,是现代科研中心——卡文迪什实验室的第三任卡文迪什教授. J·J.汤姆孙于1856年12月18日生于曼彻斯特     

B →πη（′）, η（′）η（′） decays and NLO contributions in the pQCD approach＊

By employing the perturbative QCD （pQCD） factorization approach, we calculate the full leading and the partial next-to-leading order （NLO） contributions to the seven B →πη（′） and η（′）η（′） decays. For B^＋→ π＋η（′） decays, the pQCD predictions for their decay rates agree very well with the data after the inclusion of the small NLO contributions. For neutral decays, the pQCD predictions are also consistent with the experimental upper limits and can be tested by the LHC experiments. The measured value of dir .Acp^dir（π＋η）= 19±7% can also be accommodated by the pQCD approach.     

′2004中国平板显示学术会议

“′2 0 0 4中国平板显示学术会议”定于 2 0 0 4年 1 0月在上海召开。本次会议的主题为 :“新视野———平板显示” ,会议将云集国内外一流专家 ,力争办成全国最大规模和最高水平的平板显示技术交流大会。会议期间将邀请国际著名显示技术专家、学者演讲并进行技术交流 ,同时举办新产品、新技术展示。 主办单位 :国家和上海市有关行业协会、学会 ; 承办单位 :上海广电股份有限公司欢迎国内外从事平板显示相关行业的科研、工程技术、产品开发、技术推广以及教学的同仁踊跃投稿并参加大会。征文范围 :′2 0 0 4中国平板显示学术会议覆盖显示科…     

P.W.J.M鲍曼斯逝世

著名光谱化学专家P.w.J.M鲍曼斯于2008年10月26 日逝世,享年76岁. 鲍曼斯1932年生予荷兰,于阿姆斯特丹大学化学物理系毕业.1961年获博士学位.1961～1968年间在阿姆斯特丹大学任教,从事原子光谱分析,发射光谱光源激发机理的研究.1966年出版专集:"Theory of Spectrochemical Excitation"1968年他进入Eindhoven的Philips研究实验室,曾任该实验室主任研究员