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1.
Li Zhang Lang Liu Guan-Cheng Xu Dian-Zeng Jia 《Journal of chemical crystallography》2008,38(11):837-843
Abstract
N-(1,3-Diphenyl-4-benzal-5-pyrazolone)-salicylidene hydrazone(H2L
1
) and its zinc complex Zn(HL
1
)2 · 2CH3OH (1) have been synthesized and characterized by elemental analyses, IR spectra, thermal analyses and single-crystal X-ray diffraction
studies. The X-ray diffraction analyses of the complex Zn(HL
1
)2 · 2CH3OH (1) and the known compound Zn4(L
2
)4 (2) (H2L
2
= N-(1,3-diphenyl-4-phenylethylene-5-pyrazolone)-salicylidene hydrazone) show that different acyl groups in position 4 of pyrazolones
may lead to the different coordination mode of the ligands and distinctive structures of the same central metal Zn(II) complexes,
of which 1 is a mononuclear complex while 2 is a tetranuclear complex. Meanwhile, two Zn(II) complexes have different thermal stabilities and fluorescence properties.
Graphical Abstract
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2.
Abstract These complexes have been characterized by X-ray crystallography, spectroscopic, and cyclic voltammetry. In 1, the copper(II) ion has a distorted square-pyramidal geometry with three nitrogen atoms of the dpa ligand and two oxygen
atoms of the nitrate anions. The crystal structure of 2 shows that the copper(II) ions are bridged by tp anion to form a dinuclear complex, in which each copper(II) ion exhibits
a distorted square-pyramid with three nitrogen atoms of the dpa ligand, water molecule, and the oxygen atom of the bridging
tp ligand. Cyclic voltammetric data indicate that 1 undergoes irreversible one-electron oxidation to the CuIII and reversible one-electron reduction to the CuI, while 2 gives one reversible oxidation and two reversible and irreversible reduced processes. The electronic spectra and redox potentials
of the complexes are influenced significantly by the anionic ligands.
Graphical Abstract The reaction of [Cu(dpa)Cl2] with K(NO3)2 and Na2tp yields mononuclear and dinuclear copper(II) complexes [Cu(dpa)(NO3)2] (1) and [Cu2(dpa)2(H2O)2(μ-tp)](tp)·6H2O (2) (dpa = di-(2-picolyl)amine, tp = terephthalate).
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