Photochemical sensitization and magnetic field effect on aerosol particle formation from a gaseous mixture of glyoxal and acrolein

Under light irradiation at 435.8 nm with a medium pressure mercury lamp, pure acrolein (AC) vapour does not produce any deposits, but a gaseous mixture of glyoxal (GLY) and AC produced sedimentary aerosol particles. The nucleation process of the aerosol particles was investigated by measuring He-Ne laser light intensity scattered by the aerosol particles as formed under light irradiation at 435.8 nm. From the dependence of the scattered light intensity on the partial pressure of GLY, it was found that electronically excited GLY in the nπ? state initiated chemical reactions with AC leading to nucleation of the aerosol particles. Magnetic field effects on the nucleation process were measured for a gaseous mixture of GLY and AC. With the application of a magnetic field of 5.3 kG, the nucleation reaction was accelerated, and the convection of the gaseous mixture was changed due to greater heat release during nucleation reaction between GLY and AC. The magnetic field effect on the gaseous mixture is discussed based on the photochemical behaviour of GLY.     

Excitation wavelength dependence and magnetic field effect on aerosol particle formation from a gaseous mixture of carbon disulphide and glyoxal

Upon excitation of carbon disulphide (CS₂) molecules under UV light irradiation at 313?nm a gaseous mixture of CS₂ and glyoxal deposited sedimentary aerosol particles only. The nucleation process of the aerosol particles was investigated by measuring the He–Ne laser light intensity scattered by the aerosol particles formed under light irradiation at 313?nm, and the chemical structure of the sedimentary particles was analysed by measuring the FT-IR and X-ray photoelectron spectra. On application of a magnetic field of up to 5?T, the nucleation process was decelerated and the chemical species originating from CS₂ were less abundant. The results were compared with those obtained under visible light irradiation at 435.8?nm reported previously. Chemical reactions between CS₂ and glyoxal molecules, which were responsive to the magnetic field, are discussed briefly.     

Doppler-free high resolution spectroscopy of carbon disulphide and the effects of a magnetic field

A single-mode autoscan laser spectrometer operating in the ultraviolet in combination with a collimated molecular beam was used to measure high resolution fluorescence excitation spectra of the CS₂ V ¹B₂ ← X ¹Σ⁺ _g transition under collision-free conditions, and the effects of a magnetic field were measured. Rotational and vibrational levels were fully resolved, and Zeeman splittings were observed in many of the perturbed lines. The Zeeman interaction was observed to induce new perturbation, which induces new transitions, level splitting, and energy shift. When the magnetic field strength was changed, the magnitude of the interaction, which was observed in the absence of a magnetic field, changed dramatically depending on the energy shifts of the Zeeman components. It is shown that the V ¹B₂(¹Δ_u) state is mixed with the B₂(³A₂) component by first-order spin-orbit interaction, and through the mixed component, the Zeeman interaction between the V ¹B₂(¹Δ_u) and ³A₂(³Δ_u) states is induced. Large Zeeman splittings were observed for most of the background lines of weak intensity, and this demonstrates that the background levels are levels of the ³A₂(³Δ_u) state. The fluorescence decays of single Zeeman components were observed to be single exponential. The lifetimes of the perturbing ³A₂(³Δ_u) levels were determined by deperturbation analysis. Triplet-triplet ³A₂(³Δ_u) → ³B₂(³Σ⁺ _u) emission was confirmed. It was demonstrated that the quenching of the V ¹B₂ → X ¹Σ⁺ _g fluorescence by a magnetic field was caused by mixing of the ³A₂ state with the V ¹B₂ state and the resulting increase of triplet-triplet emission. In a time-dependent picture, the intersystem crossing from the ¹B₂(¹Δ_u) and ³A₂(³Δ_u) states is enhanced by the magnetic field.     

The thermal conductivity of the gaseous mixture CH3CN-Ar in a magnetic field

Experimental results are reported for the magnetic field influence on the thermal conductivity of CH₃CN-Ar gas mixtures at various compositions for T = 300 K. The observed field dependence is analyzed in terms of the contributions from the W[J]⁽²⁾ and WJ polarizations.     

Influence of a magnetic field on diffusion and thermal diffusion in gaseous mixtures

The influence of a magnetic field on the transport properties of binary mixtures of a polyatomic and a noble gas is studied theoretically. Using an inverse operator technique, first thermal conductivity and viscosity are treated. Then diffusion and thermal diffusion are discussed in detail, with special emphasis on the composition dependence. A relation connecting the magnitudes of the field effects on thermal conductivity, diffusion, and thermal diffusion is derived. This relation is used to estimate the field effect on diffusion.     

Squeezed states of a particle in magnetic field

For a charged particle in a homogeneous magnetic field, we construct stationary squeezed states which are eigenfunctions of the Hamiltonian and the non-Hermitian operator , and Ŷ being the coordinates of the Larmor circle center and Φ is a complex parameter. In the family of the squeezed states, the quantum uncertainty in the Larmor circle position is minimal. The wave functions of the squeezed states in the coordinate representation are found and their properties are discussed. Besides, for arbitrary gauge of the vector potential we derive the symmetry operators of translations and rotations. Fiz. Tverd. Tela (St. Petersburg) 40, 1405–1412 (August 1998) Published in English in the original Russian journal. Reproduced here with stylistic changes by the Translation Editor.     

Charged particle trajectories in a magnetic field on a curved space-time

In this paper we have studied the motion of charged particles in a dipole magnetic field on the Schwarzscbild background geometry. A detailed analysis has been made in the equatorial plane through the study of the effective potential curves. In the case of positive canonical angular momentum the effective potential has two maxima and two minima giving rise to a well-defined potential well rear the event horizon. This feature of the effective potential categorises the particle orbits into four classes, depending on their energies. (i) Particles, coming from infinity with energy less than the absolute maximum ofV _eff, would scatter away after being turned away by the magnetic field. (ii) Whereas those with energies higher than this would go into the central star seeing no barrier. (iii) Particles initially located within the potential well are naturally trapped, and they execute Larmor motion in bound gyrating orbits. (iv) and those with initial positions corresponding to the extrema ofV _eff follow circular orbits which are stable for non-relativistic particles and unstable for relativistic ones. We have also considered the case of negative canonical angular momentum and found that no trapping in bound orbits occur for this case. In the case when particles are not confined to the equatorial plane we have found that the particles execute oscillatory motion between two mirror points if the magnetic field is sufficiently high, but would continuously fall towards the event horizon otherwise. An erratum to this article is available at .     

Angular distribution of transient radiation from an ultrarelativistic particle in a magnetic field

It is shown that a magnetic field acting on an ultrarelativistic charged particle escaping from a conductor changes the intensity of transient radiation. The angular and frequency distribution of transient radiation in the magnetic field is determined. The possibility of determining the energy of the ultrarelativistic particle from the change in the azimuthal asymmetry of transient radiation emitted by this particle in the magnetic field is discussed.     

Brownian motion of a charged particle in a magnetic field

We develop and numerically illustrate an exact solution of the multivariate, stochastic, differential equations that govern the velocity and position of a charged particle in a plane normal to a uniform, stationary, magnetic field. The equations self-consistently incorporate the Lorentz force into an Ornstein-Uhlenbeck collision model. Properties of the solution in the infinite dissipation limit are explored and the spectral energy density function is found     

Investigation of particle formation and superstructure development in FePt nanoparticles and their effect on magnetic properties

FePt nanoparticles with perpendicular magnetic anisotropy embedded in non-magnetic matrices M (M=Ag, C) have been fabricated by sputtering FePt/M multilayer films onto single crystal MgO [0 0 1] at temperatures above 300 °C. Particles with controlled particle size down to a few nanometers and tailored microstructure and magnetic properties can be obtained by varying the bilayer thicknesses, the substrate temperature, the type of substrate material and the post-annealing conditions. Ordered FePt nanoparticles have also been prepared directly by gas phase condensation techniques (cluster gun).The cluster gun allows a better control of particle size and distribution, and enables an in situ heat treatment of the particles to transform their structure into the desired phase before they are deposited onto the substrate, thus avoiding the undesirable effects of alloying and oxidation.     

Motion of a charged particle in a uniform rotating magnetic field

The motion of a charged particle in a rotating, uniform magnetic field is investigated. Expressions are obtained for the domains of steady-state motion and for the particle trajectories. The investigation includes a treatment of conditions specifying the particle localization within the bounded space domain.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 12, pp. 7–11, December, 1976.     

Effect of field cooling on magnetic properties of ultrafine CoO/Co particles

In CoO-Ag granular films with small CoO contents, we have observed ultrafine Co particles inside or on the surface of the CoO particles. After field cooling under the external magnetic field of 50 kOe, a sustained magnetization (or vertical) shift and exchange field shift were observed. The magnetization shift and the exchange field shift increased as the cooling field is increased and temperature decreased, in correlation to each other. PACS 75.30.Et; 75.30.Gw; 75.75.+a     

Effect of an electric field on Ps formation in gaseous CO2

Summary The yield of O-Ps has been studied in moderately dense CO₂ with a static electric field applied across the gas. The results are shown to be consistent with recent models of Ps formation which have considered that Ps is formed in molecular gases by both Ore and spur processes.

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Riassunto La produzione di O-Ps è stata studiata in CO₂ moderatamente denso con un campo elettrico statico applicato attorono al gas. Si mostra che i risultati sono consistenti con recenti modelli di formazione di Ps che considerano che Ps sia formato in gas molecolari per mezzo dei processi di Ore e spur.

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Реэюме Исследуется выход O-Ps в умеренно плотном CO₂ в случае статического электрического поля, приложенного к гаэу. Покаэывается, что реэулътаты согласуются с недавними моделями обраэования Ps которые предполагают, что Ps обраэуется в молекулярных гаэах.

     

Discrete accidental symmetry for a particle in a constant magnetic field on a torus

A classical particle in a constant magnetic field undergoes cyclotron motion on a circular orbit. At the quantum level, the fact that all classical orbits are closed gives rise to degeneracies in the spectrum. It is well-known that the spectrum of a charged particle in a constant magnetic field consists of infinitely degenerate Landau levels. Just as for the 1/r and r² potentials, one thus expects some hidden accidental symmetry, in this case with infinite-dimensional representations. Indeed, the position of the center of the cyclotron circle plays the role of a Runge-Lenz vector. After identifying the corresponding accidental symmetry algebra, we re-analyze the system in a finite periodic volume. Interestingly, similar to the quantum mechanical breaking of CP invariance due to the θ-vacuum angle in non-Abelian gauge theories, quantum effects due to two self-adjoint extension parameters θ_x and θ_y explicitly break the continuous translation invariance of the classical theory. This reduces the symmetry to a discrete magnetic translation group and leads to finite degeneracy. Similar to a particle moving on a cone, a particle in a constant magnetic field shows a very peculiar realization of accidental symmetry in quantum mechanics.     

Peierls相变与磁场中碳纳米管的场发射

应用紧束缚模型和WKB方法研究碳纳米管的out-of-plane型Peierls相变,及其对碳纳米管的场发射的影响.结果发现Peierls相变会在室温出现,并使碳纳米管费米面附近出现能隙,导致碳纳米管发生金属—半导体转变,从而抑制碳纳米管的场发射.磁场也会抑制Peierls形变,Peierls相变和磁场相互竞争影响碳纳米管的能带结构,从而影响碳纳米管的场发射. 关键词： 场发射 碳纳米管 Peierls相变     

Effects of a vertical magnetic field on particle confinement in a magnetized plasma torus

The particle confinement in a magnetized plasma torus with superimposed vertical magnetic field is modeled and measured experimentally. The formation of an equilibrium characterized by a parallel plasma current canceling out the grad B and curvature drifts is described using a two-fluid model. Characteristic response frequencies and relaxation rates are calculated. The predictions for the particle confinement time as a function of the vertical magnetic field are verified in a systematic experimental study on the TORPEX device, including the existence of an optimal vertical field and the anticorrelation between confinement time and density.