外电场作用下Si_2O分子的激发特性

主要对2种Si2O分子异构体的激发特性进行研究,由计算结果可知,外电场对Si2O分子的激发能,振子强度,跃迁偶极矩及吸收光谱有着显著的影响.无外电场时三角型Si2O(C2v,1A1)分子在可见光区无吸收谱,外电场作用下其在可见光区(407.18—526.93nm)有比较弱的吸收谱.直线型Si-Si-O(C∞v,3Σ-)分子在有无外电场作用时在蓝光和紫光区均有一定的吸收谱,其中比较难得的是在蓝色光区(478.88—488.59nm)呈现较强的吸收谱.     

Optical properties of ZnO and Al2O3 implanted with silver ions

ZnO and Al₂O₃ samples implanted with 30-keV silver ions with fluences in the interval (0.25–1.00) × 10¹⁷ ions/cm² are studied by the method of optical photometry in the visible part of the spectrum. The optical transmission spectra of the implanted samples exhibit a selective band associated with surface plasmon resonance absorption of silver nanoparticles. The intensity of this band nonmonotonically depends on the implantation fluence. The silver ion depth distribution in the samples is calculated. It is shown that the non-monotonicity observed in experiments is due to an increase in the substrate sputtering ratio with increasing implantation fluence. It is found that vacuum thermal annealing of the implanted Al₂O₃ layers up to 700°C causes a considerable narrowing of the plasmon absorption bandwidth without a tangible change in its intensity. At higher annealing temperatures, the plasmon absorption band broadens and its intensity drops. Annealing of the ZnO films under such conditions causes their complete vaporization.     

Exciton-phonon interaction in Y2O3 and Sc2O3 thin films

An investigation is made of the fundamental absorption edge of Y₂O₃ thin films. Based on its temperature dependence the exciton-phonon interaction is studied, which makes it possible to interpret the absorption edge as the absorption of self-localized excitons. A number of parameters of the energy spectrum of the investigated films are determined. I. Franko State University, 50, Dragomanov St., L'vov, 290005, Ukraine. Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 66, No. 1, pp. 132–134, January–February, 1999.     

CF3CDCl2分子红外多光子光热吸收谱

本文报道用铂丝光热吸收池作为探测器得到了CF₃CDCI₂的红外多光子吸收谱。并发现在线性吸收谱中944cm^-1处的吸收峰在多光子吸收谱中分裂为947cm^-1和927cm^-1两个吸收峰。这一现象与科里奥利力和非谐性引起的简正振动的耦合作用有关。这样,在用CF₃CDCI₂/CF₃CHCI₂体系分离氘同位素时,可以根据这一新结果选择更合适的激发波长。实验还发现在线性吸收谱中986cm^-1处的吸收峰在多光子吸收谱中出现约6cm^-2的红移。这种红移现象起源于分子振动能级的非谐性。 关键词：     

Resonant two-photon absorption in the Cr2O3 antiferromagnet

Two-photon absorption (TPA) spectra of the Cr₂O₃ model antiferromagnet have been studied for two polarization configurations at energies ranging from 2.5 to 3.55 eV. Several strong TPA peaks with the maximum coefficient β ～ 0.08 cm/MW are observed in the 2.7–3.1-eV range characterized by the ⁴ A ₂(F) → ⁴ T ₁(F) d-d one-photon transition of the Cr³⁺ ion. An analysis of the results obtained suggests that the general form of the TPA spectrum in this range is primarily determined by the resonance at the ² E(G) and ² T ₁(G) intermediate levels. At energies above 3.44 eV, the TPA coefficient sharply increases up to β ～ 0.1 cm/MW due to transitions between the valence and conduction bands.     

Optical absorption of copper metaborate CuB2O4

High-quality single crystals of copper metaborate CuB₂O₄ with a volume exceeding 1 cm³ are grown. The optical absorption spectra of these crystals are recorded for the first time owing to their sufficiently large size. The spectra exhibit a broad transmission window in the visible region and an intense absorption peak around ～2.0 eV, which is already split into two bands at room temperature. A weak anisotropy is revealed in unpolarized light upon light beam propagation along the a and c axes. The spectra are compared with the absorption spectrum of CuGeO₃.     

Spectroscopic properties of the Pr3+ ion in TeO2-WO3-PbO-La2O3 and TeO2-WO3-PbO-Lu2O3 glasses

The goal of this work was to investigate the spectroscopic properties of Pr³⁺ ions, embedded in two different tellurite glass matrices, TeO₂-WO₃-PbO-La₂O₃ and TeO₂-WO₃-PbO-Lu₂O₃. The absorption and fluorescence spectra have been recorded and analyzed in terms of the Judd-Ofelt theory along with the luminescence decay of the ³P₀ and ¹D₂ levels of the Pr³⁺ ion. The spectroscopic studies were completed with ellipsometric measurements providing the dispersion relation of the refractive index of the investigated glasses.     

3Cu(IO3)2·2H2O晶体的电子结构研究

本文测定了3Cu(IO₃)₂·2H₂O球晶的电子吸收光谱,吸收峰位于9140cm^-1和15250cm^-1。首次观察到了高达6110cm^-1的低对称晶场分裂。吸收曲线经Gauss分解可得到八个Gauss型吸收峰,分别位于8590,10690,10870,12190,13500,14510,15330和16500cm^-1。测量其EPR谱可得g=2.141±0 关键词：     

Er3+单掺及Er3+/Yb3+共掺SiO2-Al2O3-La2O3玻璃光谱性质研究

研究了单掺Er³⁺及Er³⁺/Yb³⁺共掺SiO₂-Al₂O₃-La₂O₃玻璃的光谱性质随稀土离子浓度变化规律,应用McCumber理论计算了玻璃在1.53 μm的发射截面及积分吸收截面.结果表明:在Er³⁺离子掺杂浓度相同时,玻璃在980 nm吸收截面与Yb³⁺掺杂浓度成反比;当样品中Yb³⁺离子掺杂浓度为3.94×10²⁰ cm^-3时,玻璃在1.53 μm的吸收截面和发射截面最大,在1.40～1.60 μm积分吸收截面也最大;Er³⁺/Yb³⁺共掺SiO₂-Al₂O₃-La₂O₃玻璃在1.53 μm的荧光半高宽随Er³⁺掺杂浓度升高而增加,当Er³⁺离子掺杂浓度为2.41×10²⁰ cm^-3时,玻璃的荧光半高宽(FWHM)达到52.5 nm.     

Physical and optical properties of Li2O-MgO-B2O3 doped with Dy3+

The study on the optical properties of alkali borate glasses doped with rare earths is an interesting area of research. Dysporosium doped lithium magnesium borate glasses were prepared by melt-quenching technique with dysporosium concentration varying from 0.3 to 1.0 mol %. Physical and optical properties of Lithium Magnesium Borate doped with different concentration of Dy³⁺ were observed based on its physical parameters, emission spectra and absorption spectra. The absorption spectra of this study exhibits eight absorption bands with hypersensitive peak at 1260 nm (⁶ H _9/2). Two emitted spectra transitions were also observed at ⁴ F _9/2 → ⁶ H _15/2, ⁴ F _9/2 → ⁶ H _13/2. Lastly, important physical parameters for each concentration of dopant such as density, ions concentration, polaron radius, inter-nuclear distance, refractive index, oscillator strength and other parameters were determined.     

Radiative electron-attachment spectra of O3 and SO2

Several aspects of radiative electron-attachment processes are discussed and the corresponding photon energy spectra computed for O₃ and SO₂. In both cases the vibrational stretching mode is significantly excited. The calculated electron attachment spectrum of SO₂ is compared with the laser photo-detachment spectrum of SO₂ ^-. The computed electron affinities and changes in geometry between natural and negative ion are in good agreement with the experimental data.     

The visible absorption spectrum of S2O

The visible absorption spectrum of S₂O vapor has been studied by spectrographic and laser optoacoustic techniques. Magnetic rotation spectroscopy was used to establish the triplet-singlet nature of the transition. Vibrational analysis gave ν′₁ = 1089, ν′₂ = 505, and ν′₃ = 332 cm⁻¹.     

Bulk phonon modes of YBa2Cu3O7 from infrared absorption at 300-30K

The infrared absorption spectrum of polycrystalline samples of YBa₂Cu₃O₇ is reported in the temperature range of 300-30K Four phonon modes are observed at 436, 488, 579 and 622 cm^-1 which have not been observed yet by reflectance spectroscopy indicating that the microscopic properties of the surface are different from the bulk. A comparison between our infrared data and the Raman scattering data in the literature suggests that two “gerade” modes at 436 and 579 cm^-1 are strongly coupled with the underlying electronic transition, becoming infrared active.     

Energy transfer between Eu3+ ions in a lattice with two different crystallographic sites: Y2O3:Eu3+, Gd2O3:Eu3+ and Eu2O3

The Eu³⁺ ion occupies two different crystallographic sites in (Y_1−xEu_x)₂O₃ and (Gd_1−xEu_x)₂O₃, with site symmetry S₆ and C₂. Energy transfer over more than 7 Å occurs from Eu³⁺ (S₆) ions to Eu³⁺ (C₂) ions. This is shown to be a direct one-phonon assisted process, in combination with a one-site resonant two-phonon assisted process at higher temperatures. For x = 1 there is energy migration over the Eu³⁺ (C₂) sublattice to quenching impurities. The presence of cooperative absorption points to superexchange interaction between the Eu³⁺ ions.     

Characterisation of the reduction properties of La0.5Sr0.5Fe0.5Co0.5O3

We report here on the characterisation by temperature programmed reduction, ⁵⁷Fe Mössbauer spectroscopy and X-ray absorption spectroscopy of the phases resulting from treatment of the perovskite-related material La_0.5Sr_0.5Fe_0.5Co_0.5O₃ in a flowing 90% hydrogen/10% nitrogen atmosphere. The results show that treatment of La_0.5Sr_0.5Fe_0.5Co_0.5O₃ (which contains approximately 50% Fe⁴⁺ and 50% Fe³⁺) in the flowing 90% hydrogen/10% nitrogen atmosphere at 600°C does not result in the reduction of any of the constituent elements of the material and that the perovskite structure is still retained. The Mössbauer spectrum recorded following heating in the gaseous reducing environment at 1,000°C shows the presence of metallic iron, an Fe³⁺-containing phase with parameters compatible with the presence of SrLaFeO₄ which has a K₂NiF₄-type structure, and a paramagnetic Fe³⁺ phase. The X-ray absorption spectroscopy results show the presence of metallic cobalt. The Mössbauer spectrum recorded following heating at 1,200°C continues to show the Fe³⁺-containing components plus a larger contribution from metallic iron. The X-ray absorption spectroscopy results show the presence of metallic cobalt, SrLaFeO₄, La₂O₃ and SrO.     

Experimental study of laser-induced thermal ignition in O2/O3 mixtures

O₂/O₃ mixtures are ignited by absorption of laser pulses of a TEA CO₂ laser along the axis of a cylindrical cell. The dependence of the radial propagation of the O₃ decomposition, detected by uv absorption of the ozone, on laser fluence and on O₃ concentration is investigated. Oscillations of the signals are identified to be the first radial acoustic mode of the cell. For mixtures of 0.35 bar and 0.70 bar total pressure and O₃ percentages within 20–50%, the ignition limit is in the order of 0.1–0.2 J/cm³ (absorbed energy density). These values are in reasonable agreement with the results of the corresponding numerical simulations.     

Determination of the D2O Content in Water by Infrared Spectrometry

A method for determining deuterium oxide content in the concentration range of 1 to 100% with a precision of 1 to 0.1 percentage unit is described. Measurements were made with a glass cell 0.6 mm thick using the infrared spectrum region from 4000 to 4400 cm^?1. It was found that glass windows can be also used for absorption cells in the range between 2300 and 3800 cm^?1 in which very intense OD and OH bands appear.     

V centers in single crystal Al2O3

From optical and thermal bleaching experiments it is concluded that the 400 nm absorption band which appears in Al₂O₃ after γ-irradiation is a composite V band. One of its components is attributed to the V^-_OH center which also is responsible for a localized vibrational band at 3316 cm^-11 analogous to the one observed for the V_OH center in MgO. The irradiation also results in electron trapping at Cr³⁺ impurity ions to produce a band at 227 nm. Annealing at 170°C destroys the V^-_OH center by releasing holes which convert the Cr²⁺ to Cr³⁺ with an attendant thermoluminescence.     

Excited states dynamics of Er3+ in Sc2O3 ceramic

The spectral characteristics of Er³⁺ in Sc₂O₃ transparent ceramics are presented. The Er³⁺ visible spectra in the ceramics, prepared by solid-state synthesis, show only lines that could be assigned to C₂ sites. The Stark energy levels, cross-sections and emission kinetics of levels involved in the green upconversion emission under infrared excitation in the 800 nm range were determined. The green upconversion emission (²H_11/2, ⁴S_3/2)→⁴I_15/2 characteristics under excitation with a pulsed Ti:sapphire laser in (⁴I_15/2→⁴I_9/2) absorption were analyzed. The emission kinetics reveal a competition of two-step (⁴I_15/2→⁴I_9/2)+(⁴I_9/2→²H_9/2) excited state absorption (ESA) and (⁴I_11/2, ⁴I_15/2)→(⁴I_11/2, ⁴F_7/2) energy transfer upconversion (ETU) processes function on the excitation wavelength.     

Synthesis, characterization, optical absorption, luminescence and defect centres in Er3+ and Yb3+ co-doped MgAl2O4 phosphors

The Er³⁺–Yb³⁺ co-doped MgAl₂O₄ phosphor powders have been prepared by the combustion method. The phosphor powders are well characterized by X-ray diffraction (XRD) and energy dispersive (EDX) techniques. The absorption spectrum of Er³⁺/Er³⁺–Yb³⁺ doped/co-doped phosphor powder has been recorded in the UV–Vis–NIR region of the electro-magnetic spectrum. The evidence for indirect pumping under 980 nm excitation of Er³⁺ from Yb³⁺ was observed in the MgAl₂O₄ matrix material. Electron spin resonance (ESR) studies were carried out to identify the defect centres responsible for the thermally stimulated luminescence (TSL) process in MgAl₂O₄:Er³⁺ phosphor. Three defect centres were identified in irradiated phosphor by ESR measurements which were carried out at room temperature and these were assigned to an O^? ion and F⁺ centres. O^? ion (hole centre) appears to correlate with the low temperature TSL peak at 210 °C and one of the F⁺ centres (electron centre) is related to the high temperature peak at 460 °C.