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1.
Open-cage fullerene derivatives suitable for the encapsulation of a hydrogen molecule 总被引:3,自引:0,他引:3
Iwamatsu S Murata S Andoh Y Minoura M Kobayashi K Mizorogi N Nagase S 《The Journal of organic chemistry》2005,70(12):4820-4825
The encapsulation of molecular hydrogen into an open-cage fullerene having a 16-membered ring orifice has been investigated. It is achieved by the pressurization of H2 at 0.6-13.5 MPa to afford endohedral hydrogen complexes of open-cage fullerenes in up to 83% yield. The efficiency of encapsulation is dominantly dependent on both H2 pressure and temperature. Hydrogen molecules inside the C60 cage are observed in the range of -7.3 to -7.5 ppm in 1H NMR spectra, and the formations of hydrogen complexes are further confirmed by mass spectrometry. The trapped hydrogen is released by heating. The activation energy barriers for this process are determined to be 22-24 kcal/mol. The DSC measurement of the endohedral H2 complex reveals that the escape of H2 from the C60 cage corresponds to an exothermic process, indicating that encapsulated H2 destabilizes the fullerene. 相似文献
2.
Yu Y Xie X Zhang T Liu S Shao Y Gan L Li Y 《The Journal of organic chemistry》2011,76(24):10148-10153
Oxidation of the fullerenediol C(60)(OH)(2)(O)(OAc)(OOtBu)(3) with PhI(OAc)(2) yields the open-cage fullerene derivative C(60)(O)(2)(O)(OAc)(OOtBu)(3)2 with an 11-membered orifice. Compound 2 reacts with aniline to form a new open-cage derivative with a 14-membered orifice, which yields an 18-membered open-cage fullerene derivative upon addition of another molecule of aniline. Two different types of aniline derivatives with either electron-donating or electron-withdrawing substituents can be added sequentially, affording an unsymmetrical moiety in the open-cage structure. Reduction potentials of the 18-membered open-cage fullerene derivatives can be fine-tuned by changing the substituents on the aniline. The results provide new insights about the mechanism of open-cage reactions of fullerene-mixed peroxide. 相似文献
3.
Matsuo Y Isobe H Tanaka T Murata Y Murata M Komatsu K Nakamura E 《Journal of the American Chemical Society》2005,127(49):17148-17149
Regioselective multi-addition reaction of organocopper and amine compounds onto dihydrogen-encapsulated [60]fullerene, H2@C60, produced a variety of organic and organometallic derivatives of H2@C60. The X-ray crystallographic analysis of dihydrogen-encapsulated bucky ferrocene, Fe(H2@C60Ph5)C5H5, showed the presence of the dihydrogen molecule located almost in the center but slightly away from the ferrocene moiety. The 1H NMR chemical shift values for the encapsulated molecular hydrogen indicated that these values are susceptible to the magnetic environment of the inside as well as the outside of the fullerene cage. 相似文献
4.
Chuang SC Murata Y Murata M Komatsu K 《Chemical communications (Cambridge, England)》2007,(17):1751-1753
A methodology to entrap He inside an open-cage fullerene by immediate reduction of the size of an orifice was developed, and the effects of encapsulated He and H(2) on the chemical shift of a proton directly attached to the outer fullerene sphere were revealed. 相似文献
5.
A thermal reaction of fullerene C(60) with 4,6-dimethyl-1,2,3-triazine (4) in o-dichlorobenzene gave azacyclohexadiene-fused fullerene derivative 5, by the reaction with intermediate azete 11, and then, after flash chromatography over SiO(2), open-cage fullerene derivative 6 having an eight-membered ring orifice on the C(60) cage. Compound 6 is assumed to be formed via addition of diradical intermediate 13 to C(60). Compound 6 underwent a further photochemical reaction with singlet oxygen with the cleavage of one of the double bonds at the rim of the orifice to afford triketone derivative 8 having a 12-membered ring orifice. 相似文献
6.
In the field of open-cage fullerenes, there was a lack of a universal standard that could correlate and quantify the orifice size of open-cage fullerenes. One cannot compare the relative orifice size by simple comparison of the number of atoms that composes the orifice. We present a general term for easy estimation of relative orifice size by defining an index for open-cage fullerenes. We estimated the corresponding effective areas A(area) for orifices of open-cage fullerenes by matching calculated activation energies Ea(calcd) for hydrogen release from open-cage fullerenes (B3LYP/6-31G**//B3LYP/3-21G) to the computed energies required for a hydrogen molecule passing through a cyclo[n]carbon ring. Then we define an index K(orifice) based on experimental hydrogen release rate, where K(orifice) = ln k/k degrees (k is rate constant of hydrogen-release rate of any open-cage fullerenes taken for comparison at 160 degrees C; k degrees is the hydrogen release rate from H2@4a taken as the standard compound). We synthesized several open-cage fullerenes and studied kinetics of a set of H2-encapsulated open-cage fullerenes to evaluate their K values. A correlation of the index K(orifice) with the effective areas A(area) showed a good linear fit (r2 = 0.972) that demonstrated a good interplay between experiment and theory. This allows one to estimate K(orifice) index and/or relative rate k of hydrogen release through computing activation energy Ea(calcd) for a designed open-cage fullerene. 相似文献
7.
[60]Fullerene mixed peroxide C(60) (OH)(Cl)(OOtBu) reacts with PhMe(2)SiH/B(C(6)F(5))(3) to give oxahomofullerene. Mechanistic investigation indicates that the hydroxyl group in the central pentagon ring is essential to convert the tert-butylperoxo group into a ketal moiety. Migration of the silyl group and transformation of the siloxy group into a phenyl group are observed in the deprotection of the fullerene bound siloxy group. A 12-membered open-cage fullerendione was obtained through oxidation of a [6,6]-fullerendiol. This orifice could be closed to form ketal/hemiketal moieties by BF(3)-catalyzed reaction with methanol. All of the new fullerene derivatives were characterized by spectroscopic data, and structure of the open-cage fullerendione was also confirmed by single-crystal X-ray analysis. 相似文献
8.
Whitener KE Frunzi M Iwamatsu S Murata S Cross RJ Saunders M 《Journal of the American Chemical Society》2008,130(42):13996-13999
We put ammonia into an open-cage fullerene with a 20-membered ring ( 1) as the orifice and examined the properties of the complex using NMR and MALDI-TOF mass spectroscopy. The proton NMR shows a broad resonance corresponding to endohedral NH 3 at delta H = -12.3 ppm relative to TMS. This resonance was seen to narrow when a (14)N decoupling frequency was applied. MALDI spectroscopy confirmed the presence of both 1 ( m/ z = 1172) and 1 + NH 3 ( m/ z = 1189), and integrated intensities of MALDI peak trains and NMR resonances indicate an incorporation fraction of 35-50% under our experimental conditions. NMR observations showed a diminished incorporation fraction after 6 months of storage at -10 degrees C, which indicates that ammonia slowly escapes from the open-cage fullerene. 相似文献
9.
Murata Y Maeda S Murata M Komatsu K 《Journal of the American Chemical Society》2008,130(21):6702-6703
An open-cage C70 derivative having a 13-membered ring opening (2) was synthesized by a three-step reaction; thermal reaction of C70 with a pyridazine derivative, oxidative cleavage of the CC double bond, and insertion of a sulfur atom to the opening. The structure of 2 was determined by X-ray analysis. One H2 molecule was introduced into 2 to give H2@2 in 97% yield. Furthermore, two H2 molecules were encapsulated in 2 in 3% yield. The positional exchange of two H2 molecules inside 2 was clearly observed by the dynamic low-temperature NMR measurements. 相似文献
10.
Two novel open-cage fullerene derivatives bearing a 12-membered-ring orifice on the fullerene cage have been isolated. Removal of the N-MEM protective group leads to the first open-cage [60]fullerene derivative without organic addends on the rim of the orifice. [structure: see text] 相似文献
11.
López-Gejo J Martí AA Ruzzi M Jockusch S Komatsu K Tanabe F Murata Y Turro NJ 《Journal of the American Chemical Society》2007,129(47):14554-14555
The quenching rate constants of singlet oxygen by C60, H2@C60, D2@C6o, H2, and D2 in solution were measured. The presence of a hydrogen (H2@C60) or deuterium (D2@C60) molecule inside the fullerene did not produce any observable effect based on triplet lifetime or EPR measurements. However, a remarkable effect was found for the 1O2 quenching by C60, H2@C60, D2@C6o, H2, and D2. Singlet oxygen was generated by photosensitization or by thermal decomposition of naphthalene endoperoxide derivatives. Comparison of the rate constants for quenching of 1O2 by H2@C60 and D2@C60 demonstrates a significant vibrational interaction between oxygen and H2 inside the fullerene. The quenching rate constant for H2 is 1 order of magnitude higher than that of D2, in agreement with the results observed for the quenching of 1O2 with H2@C60 or D2@C60. 相似文献
12.
Roubelakis MM Vougioukalakis GC Orfanopoulos M 《The Journal of organic chemistry》2007,72(17):6526-6533
A novel open-cage [60]fullerene derivative, having two sulfur atoms on the rim of its 13-membered-ring orifice, has been isolated and characterized. Extensive studies on the N-MEM group reactivity of this as well as other previously reported open-cage [60]fullerene derivatives led to several new open-cage [60]fullerene adducts. 相似文献
13.
100% encapsulation of a hydrogen molecule into an open-cage fullerene derivative and gas-phase generation of H2@C60 总被引:1,自引:0,他引:1
By applying high-pressure H2 to a new fullerene derivative, C63NO2SPh2Py (1), having a 13-membered-ring orifice, 100% incorporation of a H2 molecule into the fullerene cage has been achieved for the first time. This result substantiates the theoretical calculations indicating that the energy barrier required for H2 insertion through an orifice in 1 is considerably lower than that for the previously reported derivative with the largest orifice among open-cage fullerenes synthesized thus far. Upon matrix-assisted laser desorption/ionization mass spectroscopy, the removal of organic addends from the fullerene derivative 1 encapsulating H2 and restoration of the pristine C60 cage, which retains approximately one-third of incorporated H2, have been observed. 相似文献
14.
A thermal liquid-phase reaction of fullerene C(60) with 3-(2-pyridyl)-5,6-diphenyl-1,2,4-triazine afforded aza-open-cage fullerene derivative 5 having an eight-membered-ring orifice on the fullerene cage. Compound 5 was found to undergo oxidative ring-enlargement reactions with singlet oxygen under photo-irradiation to give azadioxo-open-cage fullerene derivatives 9 and 10, which have a 12-membered-ring orifice, in addition to a small amount of azadioxa-open-cage fullerene derivative 11, which has a 10-membered-ring orifice. A thermal reaction of 9 with elemental sulfur in the presence of tetrakis(dimethylamino)ethylene resulted in further ring-enlargement to give azadioxothia-open-cage fullerene derivative 15, which has a 13-membered-ring orifice. The structures of 5 and 15 were determined by X-ray crystallography, while those of 9, 10, and 11 were confirmed by the agreement of observed (13)C NMR spectra with those obtained by DFT-GIAO calculations. These reactions were rationalized based on the results of molecular orbital calculations. Following electrochemical measurements, compounds 9 and 10, which have two carbonyl groups on the rim of the orifice, were found to be more readily reduced than C(60) itself (the first reduction potential was found to be 0.2 V lower than that of C(60)), while the first reduction potentials of other open-cage fullerene derivatives, 5, 11, and 15, were nearly the same as that of C(60). 相似文献
15.
Chuang SC Murata Y Murata M Mori S Maeda S Tanabe F Komatsu K 《Chemical communications (Cambridge, England)》2007,(12):1278-1280
A newly synthesized open-cage fullerene containing selenium in the rim of the 13-membered-ring orifice allows milder conditions for hydrogen insertion, and the rate for hydrogen release is ca. three times faster than its sulfur analogue. 相似文献
16.
Guanglin Huang Shota Hasegawa Dr. Yoshifumi Hashikawa Dr. Yuki Ide Prof. Dr. Takashi Hirose Prof. Dr. Yasujiro Murata 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(2):e202103836
An H2O2 molecule was isolated inside hydroxylated open-cage fullerene derivatives by mixing an H2O2 solution with a precursor molecule followed by reduction of one of carbonyl groups on its orifice. Depending on the reduction site, two structural isomers for H2O2@open-fullerenes were obtained. A high encapsulation ratio of 81 % was attained at low temperature. The structures of the peroxosolvate complexes thus obtained were studied by 1H NMR spectroscopy, X-ray analysis, and DFT calculations, showing strong hydrogen bonding between the encapsulated H2O2 and the hydroxy group located at the center of the orifice. This OH group was found to act as a kinetic stopper, and the formation of the hydrogen bonding caused thermodynamic stabilization of the H2O2 molecule, both of which prevent its escape from the cage. One of the peroxosolvates was isolated by HPLC, affording H2O2@open-fullerene with 100 % encapsulation ratio, likely due to the intramolecular hydrogen-bonding interaction. 相似文献
17.
Vougioukalakis GC Prassides K Campanera JM Heggie MI Orfanopoulos M 《The Journal of organic chemistry》2004,69(13):4524-4526
The addition reaction of the N-MEM-ketolactam derivative of [60]fullerene with phenyl, p-Br-phenyl, and p-MeO-phenyl hydrazines proceeds regioselectively, affording three open-cage fullerene derivatives bearing a 15-membered-ring orifice on the fullerene cage. Both experimental data and theoretical calculations were utilized for the structure determination of the new [60]fullerene adducts. 相似文献
18.
Stanisky CM Cross RJ Saunders M Murata M Murata Y Komatsu K 《Journal of the American Chemical Society》2005,127(1):299-302
(3)He has been inserted into the cavity of an open-cage fullerene derivative close to room temperature, reaching an incorporation fraction of 0.1%. The rate of escape of (3)He from this fullerene was monitored by (3)He NMR to yield the activation barrier and to compare the size of the orifice to those of other open-cage fullerenes. The equilibrium constant was also measured. 相似文献
19.
Roubelakis MM Murata Y Komatsu K Orfanopoulos M 《The Journal of organic chemistry》2007,72(18):7042-7045
The synthesis of 10 new open-cage fullerene derivatives with a 16-membered-ring orifice is being reported. These compounds, derived from the regioselective addition reaction of an aromatic hydrazine or hydrazone to isomeric diketone derivatives of C(60), were isolated in moderate to excellent yields. 相似文献
20.
Solid-state NMR spectroscopy of molecular hydrogen trapped inside an open-cage fullerene 总被引:3,自引:0,他引:3
Carravetta M Murata Y Murata M Heinmaa I Stern R Tontcheva A Samoson A Rubin Y Komatsu K Levitt MH 《Journal of the American Chemical Society》2004,126(13):4092-4093
Solid-state 1H experiments were performed an open-cage fullerene hosting molecular hydrogen. The anisotropy of the molecular hydrogen rotation was studied by double-quantum magic-angle-spinning NMR. The time scale of the molecular hydrogen rotation was estimated by spin-lattice relaxation measurements as a function of temperature. 相似文献