共查询到19条相似文献,搜索用时 93 毫秒
1.
2.
清洁及氧修饰Cu(100)表面上水煤气变换反应的能量学 总被引:1,自引:0,他引:1
分别以清洁及氧修饰Cu(100)表面作为金属态铜和部分氧化态铜的表面模拟,用键级守恒Morse势法研究了两种表面上水煤气变换(WGS)反应的能量学。计算结果表明:清洁Cu(100)表面上,WGS反应有可能同时按表面氧化还原和甲酸根两种机理进行;表面氧化还原机理中,COs主要由OHs(而不是Os)氧化为CO2s。与清洁铜表面相比,Cu(100)p(2×2)O表面上WGS反应中活化能最大的基元步骤H2 相似文献
3.
用角分辨XPS(Angle-resolvedXPS)研究研究了HS(CH2)10COOH(I)HS(CH2)3OC6H4N=NC6H4(CH2)7CH3(II)和HS(CH2)6HS(Ⅲ)3种分子在Au膜表面制备的自组装单分子层,得出了(I)中S原子,(Ⅱ)中S,N原子距膜表面的垂直距离,并结合构象分析确定了分子的取向和倾角,对分子(Ⅲ)则得出分子在紫外光照射下氧化反应的选择性,发现氧化主要在底层 相似文献
4.
5.
铝粉对己烷与氧混合物快速反应发射光谱的影响 总被引:1,自引:1,他引:0
观察高温激波管中己烷与氧气在不同摩尔比下加入不同粒度铝粉前后的快速反应发射光谱。整个光辐射范围从400nm一直延伸到探测上限830nm。对几种较重要反应产物的辐射时间变化进行了研究,发现铝粉的加入提高了己烷的反应特性,确定了几种反应产物光辐射出现的可能顺序为:C2、CH、CH2O、CHO、OH、H2O、CO2,并对己烷快速反应点火机理进行了初步分析。 相似文献
6.
采用激波管技术、光电探测技术及高速数据采集系统研究氮气对CH3NO2+O2快速反应的抑制作用,通过探测CH3O、CH的辐射强度随氮气加入量的变化关系,分析氮气抑制反应进行的微观机制,得出了氮气抑制CH3NO2+O2快速反应的主要过程是通过基元反应N2+O→N2O消毁掉自由原子O,从而使自由基OH、CH的产量大为减少,支链反应不能继续进行下去,阻碍爆轰反应的实现。 相似文献
7.
La—Ce—Mn系钙钛矿型催化剂性能研究 总被引:5,自引:0,他引:5
采用共沉淀法制得了Ce^4+,部分取代La^3+的La1-xCexMnO3钙钛矿型催化剂,实验结果表明,随Ce^4+取代量x的增大,La1-xCexMnO3催化剂越易被还原,其还原活化逐渐降低,对于CO,CH4氧化的反应其活性有一最大值,CO反应x的0.4,CH4反应x为0.2,这是由于随x值的增大,催化剂晶格缺陷增多,晶格氧的化学势增大,以及CeO2杂质相的协同作用的结果,在CO氧化和用H2还原 相似文献
8.
用TPSR,TPD,CTPR和ITD在线分析技术,初步考察了HZSM-5负载型金属氧化物催化剂上甲酸乙酯氧化偶联表面反应性能,以及催化剂表面对氧的吸附能力,对CO吸附和反应性能,同时,通过XPS,EPR和CO-IR,CO2-IR等物理方法,对甲酸乙酯氧化偶联催化剂的表面组成,表面酸碱性及在不同温度下CO和CO2在催化剂表面吸附态的变化,进行了初步的探索,研究结果初步揭示,不同载体,不同金属氧化组成 相似文献
9.
10.
11.
A. N. Golovanov A. S. Yakimov A. A. Abramovskikh Ya. R. Sukov 《Thermophysics and Aeromechanics》2008,15(4):651-662
Based on a mathematical model of a porous reacting medium the statement and mathematical solution are presented for a problem
of the peat smoldering rise as a result of the effect of a lower seat of fire. It is found that at moderate temperatures T ≤ 750 K the firing and smoldering of the initial reagent are determined by the intensity of the external burning seat as
well as by the processes of the peat drying, pyrolysis, and the oxidation reaction of the coked fixed bed.
The work was financially supported by the Program of the Federal Agency for Education (Grant No. P 042242). 相似文献
12.
飞火是开放空间中大尺度火灾非连续性蔓延的主要形式。本文通过不同热流下的木质飞火颗粒自由燃烧实验,揭示不同燃烧状态飞火颗粒的结构变形、质量损失及温度分布的变化规律。研究表明,颗粒结构变形受材料化学反应机制和热机械力作用共同影响;颗粒燃烧反应易造成热解气体的内部积聚,以致内压激增、诱发喷射或喷溅细小颗粒的现象;阴燃过程颗粒表面温度变化较小但持续时间很长,明火状态的颗粒持续高温并且温度与质量变化剧烈。 相似文献
13.
水雾与可燃多孔介质火焰相互作用的实验研究 总被引:2,自引:0,他引:2
采用非传播扩散火焰形式,研究了固体可燃多孔介质中水雾-火焰的相互作用,探讨了床层厚度、多孔介质粒度以及燃料预燃时间对水雾灭火效果的影响。结果表明,随着预燃时间增长,水雾停止后床层内部可能发生闷烧现象,随着燃料粒度的减小,这种闷烧几率反而降低。这表明,固体火焰与水雾的相互作用有其独特之处。 相似文献
14.
A new statement and the numerical solution of the problem of the peat layer firing as a result of the effect of the surface
fire is given on the basis of a mathematical model of a porous reacting medium. The original reagent smoldering at moderate
temperatures (T
1 ≤ 750 K) is found to be determined by the processes of heat and mass exchange with the forest fire source, peat drying and
pyrolysis, reaction of the carbon oxide oxidation, thermophysical characteristics, and the peat height as well as by the thickness
of the water layer under the peat layer. 相似文献
15.
16.
A. Bar-Ilan O.M. Putzeys G. Rein A.C. Fernandez-Pello D.L. Urban 《Proceedings of the Combustion Institute》2005,30(2):2295-2302
Experimental observations are presented of the effect of flow velocity, oxygen concentration, and a thermal radiant flux on the transition from smoldering to flaming in forward smoldering of small samples of polyurethane foam with a gas/solid interface. The experiments are part of a project studying the transition from smoldering to flaming under conditions encountered in spacecraft facilities, i.e., microgravity, low velocity variable oxygen concentration flows. Because the microgravity experiments are planned for the International Space Station, the foam samples had to be limited in size for safety and launch mass reasons. The feasible sample size is too small for smolder to self-propagate because of heat losses to the surroundings. Thus, the smolder propagation and the transition to flaming had to be assisted by reducing heat losses to the surroundings and increasing the oxygen concentration. The experiments are conducted with small parallelepiped samples vertically placed in a wind tunnel. Three of the sample lateral-sides are maintained at elevated temperature, and the fourth side is exposed to an upward flow and a radiant flux. It is found that decreasing the flow velocity and increasing its oxygen concentration, and/or increasing the radiant flux enhances the transition to flaming and reduces the time delay to transition. Limiting external conditions for the transition to flaming are reported for this experimental configuration. The results show that smolder propagation and transition to flaming can occur in relatively small fuel samples if the external conditions are appropriate. The results also indicate that transition to flaming occurs in the char region left behind by the smolder reaction, and it has the characteristics of a gas-phase ignition induced by the smolder reaction, which acts as the source of both gaseous fuel and heat. A simplified energy balance analysis is able to predict the boundaries between the transition/no transition regions. 相似文献
17.
A mathematical model is proposed to show the evolution of temperature, chemical composition and energy release or transfer in slugs, clouds and particulate phase, in a fluidized bed where there are slugs, of a mixture of air and propane, moving up through the particulate phase previously set in the state of incipient fluidization with air. The analysis begins as the slugs are formed at the orifices of the distributor, until they explode inside the bed or emerge at the free surface. The model also makes the analysis of what happens in the gaseous mixture that leaves the free surface of the fluidized bed until the propane is thoroughly burnt. It is essentially built upon a simple quasi-global mechanism for the combustion reaction and the mass and heat transfer equations from the two-phase model of fluidization. The aim was not to propose a new modelling approach, but to combine classical models, one concerning the reaction kinetics and the other the bed hydrodynamic aspects, to obtain a better insight on the events occurring inside a fluidized bed reactor, enhancing the understanding of this type of reactor. Experimental data to balance with the numerical model were obtained through tests on the combustion of commercial propane, in a laboratory scale fluidized bed, using four sand particle sizes: 400–500, 315–400, 250–315 and 200–250 μ m. The mole fractions of CO2, CO and O2 in the flue gases and the temperature of the fluidized bed were measured and compared with the numerical results. 相似文献
18.
19.
This study investigated the characteristics of high-temperature lithium vapor-capturing reaction in a packed bed of calcined kaolin particles. The packed-bed sorption experiments were carried in the a temperature range of 700-900 °C. The high-temperature reaction between LiCl vapor and calcined kaolin sorbent generated lithium aluminum silicate (Li2O·Al2O3·2SiO2). An increase in kaolin bed temperature results in an increase in lithium-capturing rate, but it has no effect on the maximum lithium uptake. The resistance of LiCl vapor diffusion into the pores of calcined kaolin particles was negligible, and the chemical reaction at the kaolin surface controlled the overall sorption reaction rates by up to 60% of metakaolinite conversion. The order of the reaction between metakaolinite and LiCl vapor was determined as 1.94 and its activation energy was estimated as 7.95 kcal/mol according to the Arrhenius relationship. 相似文献