The effect of boron nitride on the rheology and processing of polyolefins

The influence of a new processing additive (fine particles of boron nitride) on the rheology and processability of polyolefins is studied. The equipment used includes an Instron capillary rheometer equipped with capillary and special annular dies (Nokia Maillefer wire coating crosshead) and two rheometers, namely a parallel-plate and a sliding-plate rheometer. Several types of boron nitride powders, varying in average particle size and distribution and in morphology are tested at various concentration levels. The additive with the smallest average particle size and free of agglomeration was found to have the greatest influence on the processability (melt fracture performance) of the polyolefins tested. Specifically, it was found that boron nitride not only eliminates surface melt fracture but also postpones the critical shear rate for the onset of gross melt fracture to significantly higher values, depending on the additive concentration, surface energy, and morphology. A flow visualization technique was used to visualize the polymer flow at the entrance of a transparent capillary die in order to determine the mechanism by which boron nitride eliminates gross melt fracture. Received: 18 January 2000 Accepted: 15 June 2000     

Revisiting shock waves in metals

We cast Wallace's theory of thermoplastic flow in conservative form. We point out the difference between our formulation, which accounts for contact with an external energy reservoir, and previous formulations of thermoplastic flow. The theory is exploited to show that the experiments of Johnson and Barker on 6062-T6 Al can be interpreted as a weak shock wave that splits into an infinite sequence of “infinitesimal”, shocks, caused by increasing plasticity, leading to the observed smooth temporal velocity profile (a dispersed wave). We predict that overdriven shock waves in metals will split as well. We also re-examine the need for invoking a heat dissipation mechanism for overdriven shocks. It is briefly pointed out that our approach of casting the theory of thermoplastic flow in divergence form can be generalized easily to account for heat release in energetic solids. Received 25 March 1996 / Accepted 20 August 1996     

Unsteady oblique shock waves

A spatially and temporally local analysis is provided for unsteady, oblique shock waves, in which the flow is assumed to be two-dimensional or axisymmetric. Three unsteady parameters, in a laboratory frame, are viewed as the known independent variables. These are the upstream Mach number, the shock Mach number, and the angle of the shock relative to the instantaneous upstream velocity. Other steady and unsteady parameters, such as the velocity turn angles and downstream Mach numbers, are evaluated in closed form, in terms of these three quantities. Trends are assessed, and a sensitivity analysis is provided. It is suggested that the theory may find application in converting a shock capturing algorithm, at an early time during the computational process, into a shock fitting algorithm. Received 30 April 1999 / Accepted 29 November 1999     

A molecular mechanics study on size-dependent elastic properties of single-walled boron nitride nanotubes

We present an analytical study for the elastic properties of single-walled boron nitride nanotubes via a molecular mechanics model. Closed-form expressions for Young's modulus, Poisson's ratio and surface shear modulus are derived as functions of the nanotube diameter. The results are helix angle sensitive and comparable to those from ab initio calculations. This work is a first effort to establish analytical model of molecular mechanics for composite nanotubes and reveals the dissimilarities between size-dependent elastic properties of carbon and boron nitride nanotubes.     

Mechanism of gross melt fracture elimination in the extrusion of polyethylenes in the presence of boron nitride

The mechanism by which the addition of a small amount of boron nitride into a polyethylene eliminates gross melt fracture is elucidated. Simple elongational viscosity measurements at high rates revealed that the presence of boron nitride decreases the extensional viscosity of polyethylenes. The extensional rates at which these effects are present were found to be about the same with those at which gross melt fracture is obtained (calculated from Cogswells analysis). Thus, it can be argued that the well dispersed boron nitride particles decrease extensional stresses that are responsible for gross melt fracture and/or their presence dissipate the release of energy resulting from isolated rupture or slip planes within the melt originating at the entrance to the capillary.     

Investigations involving shock waves generation and shock pressure measurement in direct ablation regime and confined ablation regime

Recent investigations involving shock waves generation and shock pressure measurement in direct ablation regime and confined ablation regime for aluminium, copper, titanium and steel (40C130) materials are reported. Experimental measurements demonstrated that in direct ablation regime the peak pressures typically are less than 10 Pa when the incident laser intensity is about 10 W/cm and the time duration of the applied pressure is roughly equal to the laser pulse duration. It is shown that confinement of the surface with a transparent overlayer provided an effective method of enhancing laser-induced shock waves pressure in the target material with an order of magnitude for same laser intensity. Also, in this second regime, the pressure is applied over a period much longer than the laser-pulse duration. As an application measurements of the hardness of target surface before and after laser irradiation in direct ablation regime and confined ablation regime are given, and it is shown that the maximum value of surface hardness is obtained in confined ablation regime. Received 10 March 2001 / Accepted 13 April 2001     

Attenuation of shock waves propagating in polyurethane foams

Shock wave attenuation in polyurethane foams is investigated experimentally and numerically. This study is a part of research project regarding shock propagation in polyurethane foams with high-porosities = 0.951 ~ 0.977 and low densities of ρc = 27.6 ~55.8 kg/m³. Sixty Millimeter long cylindrical foams with various cell numbers and foam insertion condition were installed in a horizontal shock tube of 50 mm i.d. and 5.4 mm in length. Results of pressure measurements in air/foam combination are compared with CFD simulation solving the one-dimensional Euler equations. In the case of a foam B fixed on shock tube wall, pressures at the shock tube end wall increases relatively slowly comparing to non-fixed foam, free to move and a foam A fixed on shock tube wall. This implies that elastic inertia hardly contributes to pressure build up. Pressures behind a foam C fixed on shock tube wall decrease indicating that shock wave is degenerated into compression wave. Dimensionless impulse and attenuation factor decrease as the initial cell number increases. The momentum loss varies depending on cell structure and cell number.     

An experimental and theoretical study of converging polygonal shock waves

An experimental investigation was carried out to explore the possibility of producing converging polygonal shocks in an essentially two-dimensional cavity. Previous calculations by Apazidis and Lesser (1996) suggested that such configurations could be produced by reflecting a cylindrical outgoing shock from a smoothly altered circular boundary, the alteration having n-gonal symmetry. In the experiments the outgoing shock was produced by a spark discharge which yielded shocks in the Mach number range from 1.1 to 1.7 at a radius just prior to the reflection. Polygonal shocks were observed as predicted by using a modified form of geometrical shock dynamics, derived in the above paper. In addition, the modified theory was used to calculate the results of an experiment carried out by Sturtevant and Kulkarny (1976). The results of the numerical calculations were found to be in substantial agreement with both experiments, suggesting that the modifications in geometrical shock dynamics for non-uniform flow ahead of an advancing shock are useful in the case of shock focusing. The experiment also showed that the polygonal shapes were stable in the examined range of shock Mach numbers, a result that may be of importance for a number of practical situations in which shock focusing is present. Received 9 October 2001 / Accepted 7 January 2002 – Published online 11 June 2002     

Detonation and deflagration initiation at the focusing of shock waves in combustible gaseous mixture

Abstract. Detonation and deflagration initiation under focusing conditions in a lean hydrogen-air mixture was experimentally investigated. The experiments were carried out in a shock tube equipped with the laser schlieren system and pressure transducers. Two-dimensional wedges (53° and 90°), semi-cylinder and parabola, were used as the focusing elements. The peculiarities of mild and strong ignition inside the reflector cavity were visualized. A hydrogen-nitrogen mixture was taken for comparison between reactive and inert mixture. It was found that mild ignition inside the reflector cavity can lead to detonation initiation outside the cavity. Schlieren pictures of the process were obtained and the dependence of the distance of detonation initiation on Mach number of the incident shock wave was established. Received 30 August 1999 / Accepted 23 February 2000     

Nonideal effects behind reflected shock waves in a high-pressure shock tube

Abstract. Shock tubes often experience temperature and pressure nonuniformities behind the reflected shock wave that cannot be neglected in chemical kinetics experiments. Because of increased viscous effects, smaller tube diameters, and nonideal shock formation, the reflected-shock nonidealities tend to be greater in higher-pressure shock tubes. Since the increase in test temperature () is the most significant parameter for chemical kinetics, experiments were performed to characterize in the Stanford High Pressure Shock Tube using infrared emission from a known amount of CO in argon. From the measured change in vibrationally equilibrated CO emission with time, the corresponding ddt (or for a known time interval) of the mixture was inferred assuming an isentropic relationship between post-shock temperature and pressure changes. For a range of representative conditions in argon (24–530 atm, 1275–1900 K), the test temperature 2 cm from the endwall increased 3–8 K after 100 s and 15–40 K after 500 s, depending on the initial conditions. Separate pressure measurements using a shielded piezoelectric transducer confirmed the isentropic assumption. An analytical model of the reflected-shock gas dynamics was also developed, and the calculated 's agree well with those obtained from experiment. The analytical model was used to estimate the effects of temperature and pressure nonuniformities on typical chemical kinetics measurements. When the kinetics are fast (s), the temperature increase is typically negligible, although some correction is suggested for kinetics experiments lasting longer than 500 s. The temperature increase, however, has a negligible impact on the measured laser absorption profiles of OH (306 nm) and CH (216 nm), validating the use of a constant absorption coefficient. Infrared emission experiments are more sensitive to temperature and density changes, so nonuniformities should be taken into account when interpreting ir-emission data. Received 25 April 2000 / Accepted 8 September 2000     

Experimental and computational studies focusing processes of shock waves reflected from parabolic reflectors

This paper describes experimental and numerical studies of the focusing process of shock waves reflected from various shapes of a parabolic reflector. The effect of incident shock strength on the focusing process was also investigated. Experiments were carried out in a conventional shock tube and a test gas was air for incident shock Mach numbers ranging from 1.1 to 2.0. In the experiments, the process of shock focusing was visualized by schlieren method. Numerical simulations were conducted for incident shock Mach numbers up to 3.0 by solving the two-dimensional unsteady Euler equations. The numerical results were compared with experiment for various parabolic reflector shapes and for various incident shock Mach numbers. Based on the experimental and computational results, the pattern of shock focusing and shock focusing mechanism are discussed.This article was processed using Springer-Verlag T_EX Shock Waves macro package 1.0 and the AMS fonts, developed by the American Mathematical Society.     

Experimental investigation of the interaction of shock waves with textiles

Experimental studies have been performed to investigate the pressure amplification experienced behind a textile when exposed to a shock wave. Three textiles with different masses and air permeabilities were studied. Mach numbers for tests varied between 1.23 and 1.55. The distance between the back wall and the textile was varied between 3 and 15 mm. It was found that in most cases the presence of the textile led to a pressure amplification at the back wall. This amplification was dependent on the textile, Mach number and distance from the back wall. The processes causing the pressure amplification were identified by analysing pressure traces and contact shadowgraphs. It was found that when the incident wave impinges on the textile, a part is reflected upstream and a part is transmitted through the textile. The transmitted portion reflects back and forth in the gap between the textile and the back wall leading to a back wall pressure trace with a stepped profile. In addition, the textile moves towards the back wall causing compression waves to propagate towards the back wall. The combination of the stepped profile and the compression waves cause the pressure amplification. The contribution of each mechanism depends on the textile properties. Approximate wave diagrams have been constructed. Tests involving multiple layers of textiles are also discussed. Received 17 October 2000 / Accepted 2 February 2001     

Propagation of converging and diverging shock waves under isothermal condition

In this article the flows of perfect gas behind converging and diverging strong shock waves under isothermal condition in the cases of spherical and cylindrical symmetry are examined. A diverging shock wave is formed by energy supply according to a power law. These waves propagate in a uniform medium at rest and all conservation laws hold at the fronts of these shock waves. It was established that in the case of converging waves for any value of the ratios of specific heats the solution of the problem under consideration exists and is unique. When the problem has more than one solution. In the case of diverging shock waves the solution exists and is unique for any from the interval and any value of power in the energy input law. Received 4 August 1996 / Accepted 28 May 1996     

Experimental studies of ignition and transition to detonation induced by the reflection and diffraction of shock waves

This paper presents results from a program of experimental studies of ignition induced by the interaction of an initially planar shock wave with an obstacle in its path. With the aid of pressure measurements, spark schlieren photography and smoked foil techniques it is shown how, given favourable initial conditions, the two-dimensional multiple shock reflection and diffraction can promote ignition and transition to detonation in reactive gaseous mixtures. Comparison of the results with those of a non-reactive gas distinguishes the gas dynamic and chemical processes involved, and experimentally determined detonation cell sizes are compared with values predicted using chemical kinetic rate data. The systems investigated were argon, air, propane-air, propane-oxygen-argon and ethylene-oxygen-argon. Received: 3 December 1998 / Accepted: 27 October 1999     

Evolution of shock waves and the primary vortex loop discharged from a square cross-sectional tube

In this paper, a numerical and experimental investigation of the evolution of a transmitting shock wave and its associated primary vortex loop, which are discharged from the open end of a square cross-sectional tube, is described. The experiments were conducted in the square tube connected to a diaphragmless shock tube and the flowfield was visualized from the axial direction with diffusive holographic interferometry. The numerical simulations were carried out by solving the three-dimensional Euler equations with a dispersion-controlled scheme. The numerical results were displayed in the form of interferograms to compare them with experimental interferograms. Good agreement between the numerical and experimental results was obtained. More detailed numerical calculations were carried out, from which the three-dimensional transition of the shock wave configuration from an initial planar to a spherical shape and the development of the primary vortex loop from a square shaped to a three-dimensional structure were clearly observed and interpreted. Received 29 January 1998 / Accepted 22 May 1998     

Measurement of shock waves velocity in the air plasma of capacitively coupled RF discharge

The velocity of shock wave propagation in the air plasma of stationary capacitively coupled RF discharge at different gas pressure and charged particles concentration has been measured. It is shown, that the velocity of the shock wave increases at the increase of the concentration. Measurement results are brought to the universal dependence. Received 17 August 1998 / Accepted 10 December 1999     

Numerical investigation of the propagation of shock waves in rigid porous materials: flow field behavior and parametric study

A numerical parametric study of the flow field which develops when a planar shock wave impinge on a rigid porous material is presented. This study complements an earlier study (Levy et al. 1996a) where the values of some dominating parameters were estimated and the dependence of the resulting flow field on these values was not checked. Received 22 April 1996 / Accepted 5 January 1997     

A computational study of shock speeds in high-performance shock tubes

This paper describes U2DE, a finite-volume code that numerically solves the Euler equations. The code was used to perform multi-dimensional simulations of the gradual opening of a primary diaphragm in a shock tube. From the simulations, the speed of the developing shock wave was recorded and compared with other estimates. The ability of U2DE to compute shock speed was confirmed by comparing numerical results with the analytic solution for an ideal shock tube. For high initial pressure ratios across the diaphragm, previous experiments have shown that the measured shock speed can exceed the shock speed predicted by one-dimensional models. The shock speeds computed with the present multi-dimensional simulation were higher than those estimated by previous one-dimensional models and, thus, were closer to the experimental measurements. This indicates that multi-dimensional flow effects were partly responsible for the relatively high shock speeds measured in the experiments. Received 15 November 1996 / Accepted 3 February 1997     

Global modelling of heat release during initiation and propagation of detonation and deflagration waves in methane-air-particle systems

In the present paper the direct initiation of a self supporting detonation and propagation of a low-speed combustion in methane-air-coal particles mixtures are solved. For particles, a heterogeneous regime of combustion is used, for methane one overall chemical reaction is taken into account: CH + 2O = CO + 2HO. The heat release rate is assumed to be defined as a delay time based on the well-known thermal theory of Frank-Kamenetsky (1967). The proposed model allows one to investigate the influence inert particles or coal dust on the explosion limits of methane-air mixtures. It is shown that the addition of a limited quantity of particles leads to detonation stability. In low speed combustion problems this method allows one to get a good correlation between theoretical and experimental velocities of steady flame propagation in carbon-hydrogen gaseous mixtures. Coal dust influence on gasdynamics of a methane-air mixture combustion is investigated in an unsteady problem by using of the global modelling. It is shown that limited coal dust concentration increases the flame wave intensity in lean methane-air mixtures in contrast to inert particles. In stoichiometric gas mixtures, sand and coal dusts decrease a flame velocity. Far from the ignition point flame, the velocity is largely defined by the dust mass concentration and not by the size of particles. Received 5 July 1997 / Accepted 13 July 1998