共查询到20条相似文献,搜索用时 31 毫秒
1.
Mohammed Fettouhi 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(11):e495-e496
In the title compound, [Zn(NCS)2(C12H16N3O)2], the ZnII ion has a distorted tetrahedral coordination. It is bonded to two thiocyanate and two pyridyl N atoms. The metal ion and the two thiocyanate ligands lie on a mirror plane with the Zn—Npy and average Zn—NNCS bond distances being 2.036 (2) and 1.931 (4) Å, respectively 相似文献
2.
The title complex, [BaZn(C3H2O4)2(H2O)4]n, is polymeric, due to the connectivity brought about by each malonate dianion bonding to two different ZnII cations and two different BaII cations. The BaII cations, on crystallographic twofold axes, have slightly distorted square‐antiprismic coordination, with Ba—O distances ranging from 2.795 (2) to 2.848 (2) Å. The ZnII cations, which lie on crystallographic centres of symmetry, have distorted octahedral coordination, with Zn—O bonds in the range 2.0364 (19)–2.3248 (18) Å. The water molecules participate in extensive O—H⋯O hydrogen bonding. The structure comprises alternating layers along [100], with one type containing ZnII cations and malonate dianions, while the other is primarily composed of BaII cations and water molecules. 相似文献
3.
Ammasai Karthikeyan Matthias Zeller Packianathan Thomas Muthiah 《Acta Crystallographica. Section C, Structural Chemistry》2016,72(4):337-340
Zinc thiocyanate complexes have been found to be biologically active compounds. Zinc is also an essential element for the normal function of most organisms and is the main constituent in a number of metalloenzyme proteins. Pyrimidine and aminopyrimidine derivatives are biologically very important as they are components of nucleic acids. Thiocyanate ions can bridge metal ions by employing both their N and S atoms for coordination. They can play an important role in assembling different coordination structures and yield an interesting variety of one‐, two‐ and three‐dimensional polymeric metal–thiocyanate supramolecular frameworks. The structure of a new zinc thiocyanate–aminopyrimidine organic–inorganic compound, (C6H9ClN3)2[Zn(NCS)4]·2C6H8ClN3·2H2O, is reported. The asymmetric unit consist of half a tetrathiocyanatozinc(II) dianion, an uncoordinated 4‐amino‐5‐chloro‐2,6‐dimethylpyrimidinium cation, a 4‐amino‐5‐chloro‐2,6‐dimethylpyrimidine molecule and a water molecule. The ZnII atom adopts a distorted tetrahedral coordination geometry and is coordinated by four N atoms from the thiocyanate anions. The ZnII atom is located on a special position (twofold axis of symmetry). The pyrimidinium cation and the pyrimidine molecule are not coordinated to the ZnII atom, but are hydrogen bonded to the uncoordinated water molecules and the metal‐coordinated thiocyanate ligands. The pyrimidine molecules and pyrimidinium cations also form base‐pair‐like structures with an R22(8) ring motif via N—H…N hydrogen bonds. The crystal structure is further stabilized by intermolecular N—H…O, O—H…S, N—H…S and O—H…N hydrogen bonds, by intramolecular N—H…Cl and C—H…Cl hydrogen bonds, and also by π–π stacking interactions. 相似文献
4.
Sladjana B. Novakovi Zoran D. Tomi Violeta Jevtovi Vukadin M. Leovac 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(6):m358-m360
In the title compound, [ZnCl(C2H7N3S)2]Cl, the ZnII ion is five‐coordinated in a distorted trigonal–bipyramidal arrangement, with the hydrazine N atoms located in the apical positions. The structure is stabilized by N—H?Cl hydrogen bonds, which involve both the Cl atoms and all the hydrogen donors, except for one of the two thioamide N atoms. A comparison of the geometry of thiosemicarbazide and S‐methylisothiosemicarbazide complexes with ZnII, CuII and NiII shows the pronounced influence of the hydrogen‐bond network on the coordination geometry of ZnII compounds. 相似文献
5.
Azizolla Beheshti William Clegg Sophie H. Dale Reza Hyvadi 《Acta Crystallographica. Section C, Structural Chemistry》2009,65(8):m314-m316
The title complex, [Zn(C15H22BN6)(C2H3O2)] or (TpMe,Me)Zn(OAc), contains a tripodal tris(pyrazolyl)hydroborate ligand, a monodentate acetate ligand and a ZnII centre in a distorted tetrahedral coordination environment capped on one triangular face by a secondary Zn...O interaction with the second O atom of the acetate ligand. The four‐coordination of ZnII and the essentially monodentate character of the acetate ligand are due to the high steric demands of the ligand set, which prevent chelate formation and five‐coordination and lead to relatively long Zn—O and Zn—N bonds compared with related complexes of ZnII and other metals. 相似文献
6.
Yong Wang Dong‐Xia Zhu Zhong‐Min Su Kui‐Zhan Shao Ya‐Hui Zhao 《Acta Crystallographica. Section C, Structural Chemistry》2008,64(1):m70-m72
The novel title ZnII coordination polymer, poly[bis(μ‐6‐thioxo‐1,6‐dihydropyridine‐3‐carboxylato‐κ2S:O)zinc(II)], [Zn(C6H4NO2S)2]n, consists of two crystallographically independent zinc centers and two 6‐mercaptonicotinate (Hmna−) ligands. Each ZnII atom is four‐coordinated and lies at the center of a distorted tetrahedral ZnS2O2 coordination polyhedron, bridged by four Hmna− ligands to form a two‐dimensional (4,4)‐network. Each Hmna− ion acts as a bridging bidentate ligand, coordinating to two ZnII atoms through the S atom and a carboxyl O atom. The metal centers reside on twofold rotation axes. The coordination mode of the S atoms and N—H...O hydrogen‐bonding interactions between the protonated N atoms and the uncoordinated carboxyl O atoms give the extended structure a wavelike form. 相似文献
7.
Xu‐Cheng Fu Ming‐Tian Li Xiao‐Yan Wang Cheng‐Gang Wang Xiao‐Tao Deng 《Acta Crystallographica. Section C, Structural Chemistry》2006,62(6):m258-m260
The title complex, [CaZn(C3H2O4)2(H2O)4]n, is a two‐dimensional polymer and consists of CaO8 and ZnO6 polyhedra linked together by malonate ligands. The CaII cation, lying on a twofold axis, is coordinated by two water molecules and six malonate O atoms. The ZnII cation, which lies on an inversion center in an octahedral environment, is coordinated by four malonate O atoms in an equatorial arrangement and two water molecules in axial positions. The Zn—O and Ca—O bond lengths are in the ranges 2.0445 (12)–2.1346 (16) and 2.3831 (13)–2.6630 (13) Å, respectively. The structure comprises alternating layers along the [101] plane, the shortest Zn⋯Zn distance being 6.8172 (8) Å. The whole three‐dimensional structure is maintained and stabilized by the presence of hydrogen bonds. 相似文献
8.
Qiang Xu Miao Du Ya‐Mei Guo Xian‐He Bu 《Acta Crystallographica. Section C, Structural Chemistry》2001,57(8):893-894
The title complex, [Zn2(C13H19N2O)2Cl2]·2C3H6O, resides on a crystallographic inversion center. The two ZnII centers bridged by the phenoxo groups are in pentacoordinated distorted square‐pyramidal coordination environments with an intramolecular Zn?Zn distance of 3.175 (3) Å. The mesocyclic ligand takes a boat–chair conformation and an H atom from the 1,5‐diazacyclooctane ring effectively blocks the axial coordination site opposite the Cl ligand to form the ZnN2O2Cl geometry. The crystal structure is stabilized by a N—H?O hydrogen bond between the amino group and an acetone molecule. 相似文献
9.
Zhong‐Lu You 《Acta Crystallographica. Section C, Structural Chemistry》2005,61(10):m456-m458
The title complex, [Zn(C13H10BrN2O)Cl]n, is a chloride‐bridged polynuclear zinc(II) compound. Each ZnII ion is five‐coordinated in a square‐pyramidal configuration, with one O and two N atoms of one Schiff base and one bridging Cl atom defining the basal plane, and another bridging Cl atom occupying the apical position. The novelty of the compound lies in the bridging by chlorine of two square‐pyramidal Zn atoms, so that the bridging atom is apical for one Zn ion and basal for the other. This structural arrangement has not been observed before. The linked moieties form polymeric zigzag chains running along the a axis. 相似文献
10.
Alexander J. Blake Lorenzo Tei Claire Wilson Martin Schrder 《Acta Crystallographica. Section C, Structural Chemistry》2003,59(2):m43-m45
The asymmetric unit of {[4,7‐bis(2‐aminoethyl)‐1,4,7‐triazacyclononan‐1‐yl]acetato}zinc(II) triaqua{μ‐[4,7‐bis(2‐aminoethyl)‐1,4,7‐triazacyclononan‐1‐yl]acetato}lithium(I)zinc(II) chloride diperchlorate, [Zn(C12H26N5O2)][LiZn(C12H26N5O2)(H2O)3]Cl(ClO4)2, obtained from the reaction between the lithium salt of 4,7‐bis(2‐aminoethyl)‐1,4,7‐triazacyclononane‐1‐acetate and Zn(ClO4)2, contains two ZnII complexes in which each ZnII ion is six‐coordinated by five N‐atom donors and one O‐atom donor from the ligand. One carboxylate O‐atom donor is not involved in coordination to a ZnII atom, but coordinates to an Li+ ion, the tetrahedral geometry of Li+ being completed by three water molecules. The two complexes are linked via a hydrogen bond between a primary amine N—H group and the carboxylate‐O atom not involved in coordination to a metal. 相似文献
11.
Yaln Elerman Hülya Kara Sabahat
zcan Engin Kendi 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(8):950-951
The crystal structure of the title compound, chloro(1,10‐phenanthroline‐N,N′)(1‐phenyl‐1,3‐butanedionato‐O,O′)copper(II), [CuCl(C10H9O2)(C12H8N2)], has been determined. The CuII ion displays a distorted square‐pyramidal coordination, being linked to the two O atoms of the benzoylacetonate ligand and the two N atoms of the 1,10‐phenanthroline ligand in the basal plane, and the Cl atom in the apical site. TheCu—N, Cu—O and Cu—Cl bond lengths are 2.043 (2)/2.025 (2), 1.914 (2)/1.941 (2) and 2.485 (1) Å, respectively. 相似文献
12.
Peng‐Bin Pan Lei Zhang Zhao‐Ji Li Xin‐Yi Cao Yuan‐Gen Yao 《Acta Crystallographica. Section C, Structural Chemistry》2007,63(6):m270-m272
The title compound, [Zn(C14H8O6S)(H2O)2]n, is the first reported metal complex of the 4,4′‐sulfonyldibenzoate anion. The structure comprises zigzag chains of alternating [Zn(H2O)2]2+ and sulfonyldibenzoate units, the central Zn and S atoms of which lie on crystallographic twofold axes. The ZnII centre occupies a strongly distorted tetrahedral environment [O—Zn—O = 83.30 (7)–136.19 (8)°], coordinated by the two water O atoms [Zn—O = 1.986 (2) Å] and one O atom from each of two carboxylate groups [Zn—O = 1.9942 (19) Å], with much longer contacts to the other O atoms of these carboxylates [Zn—O = 2.528 (2) Å]. Hydrogen bonds between carboxylate O atoms and coordinated water molecules in adjacent chains lead to the formation of a three‐dimensional network structure. 相似文献
13.
Alain Bekaert Pascale Lemoine Jean Daniel Brion Bernard Viossat 《Acta Crystallographica. Section C, Structural Chemistry》2005,61(2):m76-m77
The title compound, tris[(R)‐2‐hydroxypropanamide‐κ2O,O′]zinc(II) tetrabromozincate, [Zn(C3H7NO2)3][ZnBr4], contains one monomeric six‐coordinate zinc complex cation and one tetrahedral [ZnBr4]2− anion. Both ZnII atoms lie on threefold axes. Coordination in the cation occurs via the amide and hydroxy O atoms [Zn—O = 2.074 (5) and 2.073 (6) Å] and has a distorted octahedral geometry, with cis‐O—Zn—O angles in the range 76.2 (2)–109.2 (2)°. In the crystal structure, the cations and anions are linked by N—H⋯Br and O—H⋯O hydrogen bonds, generating a three‐dimensional network. 相似文献
14.
Yasunori Muranishi Yue Wang Mamiko Odoko Nobuo Okabe 《Acta Crystallographica. Section C, Structural Chemistry》2005,61(6):m307-m310
In the three title complexes, namely (2,2′‐biquinoline‐κ2N,N′)dichloropalladium(II), [PdCl2(C18H12N2)], (I), and the corresponding copper(II), [CuCl2(C18H12N2)], (II), and zinc(II) complexes, [ZnCl2(C18H12N2)], (III), each metal atom is four‐coordinate and bonded by two N atoms of a 2,2′‐biquinoline molecule and two Cl atoms. The PdII atom has a distorted cis‐square‐planar coordination geometry, whereas the CuII and ZnII atoms both have a distorted tetrahedral geometry. The dihedral angles between the N—M—N and Cl—M—Cl planes are 14.53 (13), 65.42 (15) and 85.19 (9)° for (I), (II) and (III), respectively. The structure of (II) has twofold imposed symmetry. 相似文献
15.
Pascale Lemoine Karima Bendada Bernard Viossat 《Acta Crystallographica. Section C, Structural Chemistry》2004,60(10):m489-m491
The asymmetric unit of the title compound, [Zn(C7H5O3)2(C10H8N2)], contains one monomeric zinc complex. The Zn atom is coordinated to one 2,2′‐bipyridyl ligand via both N atoms and to two salicylate anions (Hsal−) in a bidentate chelating manner involving carboxylate O‐atom coordination. The complex exhibits a distorted octahedral geometry about the ZnII atom, with the `apical' positions occupied by one of the two N atoms of the bipyridyl ligand and an O atom from one Hsal− ligand; the Zn atom is 0.168 (1) Å out of the `basal' plane. Two intramolecular six‐membered hydrogen‐bonded rings are present, generated from interactions between the carboxyl and hydroxyl groups of the salicylate ligands. The crystal packing is governed by weak C—H⋯O and C—H⋯π interactions. 相似文献
16.
Alok K. Mukherjee Chitra Samanta Monika Mukherjee M. Helliwell 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(8):952-954
In the title compound, [Zn(C8H10N3O2)2], the Zn atom displays a highly distorted octahedral coordination involving O and N atoms of two bidentate planar ligands approximately orthogonal to each other; the dihedral angle between the ligand planes is 84.95 (4)°. The ligand molecules show great asymmetry in their bonding to the Zn2+ ion, with Zn—O bond distances ranging between 2.056 (2) and 2.534 (2) Å. The planar phenyl ring and the trigonal–planar geometry about the triazene N atom bonded to the phenyl ring suggest a resonance interaction extending over adjacent atoms. 相似文献
17.
Pattiya Krinchampa Kittipong Chainok Siriporn Phengthaisong Sujittra Youngme Filip Kielar Nanthawat Wannarit 《Acta Crystallographica. Section C, Structural Chemistry》2016,72(12):960-965
One of most interesting systems of coordination polymers constructed from the first‐row transition metals is the porous ZnII coordination polymer system, but the numbers of such polymers containing N‐donor linkers are still limited. The title double‐chain‐like ZnII coordination polymer, [Ag2Zn(CN)4(C10H10N2)2]n, presents a one‐dimensional linear coordination polymer structure in which ZnII ions are linked by bridging anionic dicyanidoargentate(I) units along the crystallographic b axis and each ZnII ion is additionally coordinated by a terminal dicyanidoargentate(I) unit and two terminal 1‐benzyl‐1H‐imidazole (BZI) ligands, giving a five‐coordinated ZnII ion. Interestingly, there are strong intermolecular AgI…AgI interactions between terminal and bridging dicyanidoargentate(I) units and C—H…π interactions between the phenyl rings of BZI ligands of adjacent one‐dimensional linear chains, providing a one‐dimensional linear double‐chain‐like structure. The supramolecular three‐dimensional framework is stabilized by C—H…π interactions between the phenyl rings of BZI ligands and by AgI…AgI interactions between adjacent double chains. The photoluminescence properties have been studied. 相似文献
18.
Marcos A. De Brito Adailton J. Bortoluzzi Alessandra Greatti Augusto S. Ceccato Antnio C. Joussef Sueli M. Drechsel 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(10):1188-1190
The binuclear cation of the title compound, [Ni2(C33H29N4O3)(H2O)4]C2H3O2·C3H7NO·0.75H2O, was synthesized as a model for the active site of urease. Two tridentate halves of the symmetrical 2,6‐bis{[(2‐hydroxyphenyl)(2‐pyridylmethyl)amino]methyl}‐4‐methylphenolate (BPPMP3?) ligand are arranged in a meridional fashion around the two NiII ions, with the phenoxo O atom bridging the NiII ions. The cation has an approximate twofold rotation axis running through the C—O bond of the bridging phenolate group. Four water molecules complete the octahedral environment of each NiII ion. 相似文献
19.
Yi‐Hang Wen Jian Zhang Jian‐Kai Cheng Zhao‐Ji Li Ye‐Yan Qin Yao Kang Rui‐Feng Hu Yuan‐Gen Yao 《Acta Crystallographica. Section C, Structural Chemistry》2004,60(6):m248-m249
The crystal structure of the title compound, [Zn(C5H5NS)4](NO3)2, consists of a [Zn(C5H5NS)4]2+ (C5H5NS is pyridinium‐2‐thiolate) cation and two nitrate anions. The central ZnII atom lies at a site with imposed symmetry and is surrounded by four S atoms [Zn—S = 2.3371 (5) Å] from four symmetrical pyridinium‐2‐thiolate ligands in a distorted tetrahedral geometry. There are N—H⋯O hydrogen‐bonding interactions between the pyridinium‐2‐thiolate ligands and nitrate O atoms. In addition, π–π interactions via aromatic N‐containing ligands are discussed. 相似文献
20.
Veysel T. Yilmaz Serkan Guney Omer Andac William T. A. Harrison 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(8):m427-m430
The title complexes [M(sac)2(mpy)2] [sac is saccharinate (C7H4NO3S) and mpy is 2‐pyridylmethanol (C6H7NO)], with M = ZnII and CdII, are isostructural and consist of neutral molecules. The ZnII or CdII cations are octahedrally coordinated by the two neutral mpy and two anionic sac ligands. The mpy ligand acts as a bidentate donor through the amine N and hydroxyl O atoms. The sac ligands exhibit an ambidentate coordination behaviour; one is N‐coordinated and the other is O‐coordinated within the same coordination octahedron. The crystal packing is determined by C—H?O‐type hydrogen bonding, as well as by weak py–py and sac–sac aromatic π–π‐stacking interactions. 相似文献