共查询到20条相似文献,搜索用时 15 毫秒
1.
Christopher Glidewell John N. Low Manuel Melguizo Antonio Quesada 《Acta Crystallographica. Section C, Structural Chemistry》2003,59(5):o240-o243
In the title compound, 2C8H12N+·2C4H3N4O4−·C8H11N, the anions are linked by paired N—H⋯N hydrogen bonds [H⋯N = 2.07 and 2.11 Å, N⋯N = 2.942 (3) and 2.978 (3) Å and N—H⋯N = 173 and 170°] and by paired N—H⋯O hydrogen bonds [H⋯O = 1.98 and 2.05 Å, N⋯O = 2.855 (3) and 2.917 (3) Å, and N—H⋯O = 173 and 167°] into chains of rings. These chains are linked into sheets by further N—H⋯O hydrogen bonds in which all of the donors are provided by the cations [H⋯O = 1.83–2.17 Å, N⋯O = 2.747 (3)–2.965 (3) Å and N—H⋯O = 141–168°]. The neutral amine molecule is pendent from the sheet and is linked to it by a single N—H⋯N hydrogen bond [H⋯N = 2.00 Å, N⋯N = 2.901 (3) Å and N—H⋯N = 175°]. 相似文献
2.
Paloma Arranz Mascars Rafael Cuesta Martos Christopher Glidewell John N. Low 《Acta Crystallographica. Section C, Structural Chemistry》2003,59(6):o326-o328
In the title compound, NH4+·C7H8N5O4−·H2O, the independent components are linked into bilayers by an extensive series of two‐centre N—H⃛O hydrogen bonds [H⃛O = 1.85–1.96 Å, N⃛O = 2.776 (2)–2.840 (2) Å and N—H⃛O = 149–172°], and by asymmetric three‐centre N—H⃛(O)2, O—H⃛(N,O) and O—H⃛(O)2 hydrogen bonds. 相似文献
3.
Rodrigo Abonia Christopher Glidewell John N. Low Manuel Nogueras Jairo Quiroga 《Acta Crystallographica. Section C, Structural Chemistry》2003,59(5):o237-o239
Molecules of the title compound, C14H17N5O4, exhibit a highly polarized molecular–electronic structure. The molecules are linked into sheets by two N—H⋯O hydrogen bonds [H⋯O = 2.03 and 2.02 Å, N⋯O = 2.836 (2) and 2.887 (2) Å, and N—H⋯O = 153 and 168°], augmented by a single C—H⋯O hydrogen bond [H⋯O = 2.47 Å, C⋯O = 3.403 (2) Å and C—H⋯O = 166°]. Pairs of sheets, related by inversion, form bilayers with interdigitated dimethoxybenzyl substituents, weakly linked by a further C—H⋯O interaction [H⋯O = 2.50 Å, C⋯O = 3.350 (2) Å and C—H⋯O = 146°]. 相似文献
4.
Jian Huang Yi‐Zhi Li Gang‐Chun Sun Rong‐Bin Dai Qin‐Xi Li Liu‐Fang Wang Chun‐Gu Xia 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(11):e489-e490
In the title complex, [Cu(C6H4FN2O4)2(H2O)4]·4H2O, the Cu atom is located in the centre of a distorted octahedral geometry. The coordination atoms are six O atoms provided by two carboxylate groups [coordinated in a monodentate mode, with Cu—O = 1.9551 (10) Å] and four water molecules [Cu—O = 1.9241 (13) and 2.5771 (14) Å]. In addition, one intramolecular hydrogen bond and ten intermolecular hydrogen bonds make up a three‐dimensional network. 相似文献
5.
Sunil Chohan Robin G. Pritchard 《Acta Crystallographica. Section C, Structural Chemistry》2003,59(5):m187-m189
In addition to associating into cyclic hydrogen‐bonded dimers [O⋯O = 2.663 (1) and 2.914 (1) Å], each hydrogen peroxide molecule in the title structure, K3[Al(C2O4)3]·1.75H2O2·0.25H2O, hydrogen bonds to a neighbouring oxalate ligand [O⋯O = 2.700 (1) and 2.730 (1) Å] and coordinates to two K+ ions [K⋯O = 2.6620 (9)–2.8380 (7) Å]. 相似文献
6.
Antonio Quesada Antonio Marchal John N. Low Christopher Glidewell 《Acta Crystallographica. Section C, Structural Chemistry》2003,59(3):o102-o104
In the title compound, C14H23N6O2+·HSO4−·H2O, the pyrimidinium ring of the cation adopts a twist‐boat conformation, induced by steric clashes between adjacent ring substituents; the anions and the water molecules are linked by three O—H⃛O hydrogen bonds [H⃛O = 1.70–1.78 Å, O⃛O = 2.548 (2)–2.761 (2) Å and O—H⃛O = 161–168°] into chains of edge‐fused R(12) rings, which are linked into sheets by the cations, via three N—H⃛O hydrogen bonds [H⃛O = 1.96–2.17 Å, N⃛O = 2.820 (2)–2.935 (2) Å and N—H⃛O = 145–173°]. 相似文献
7.
Abdul Hamid Othman Yang‐Yi Yang Xiao‐Ming Chen Seik Weng Ng 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(8):e318-e319
The three‐coordinate Ag atom in the title compound, [Ag(C7H3N2O6)(C18H15P)2], shows trigonal–planar coordination [P—Ag—P = 147.1 (1)° and ΣAg = 359.0 (3)°]. Adjacent molecules are linked through the O atoms of adjacent nitro groups [Ag?O = 3.205 (3) and 3.302 (4) Å] into a zigzag chain running parallel to the c axis. 相似文献
8.
Jonnes Taylor Gomes Alan Hazell Christine J. McKenzie 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(3):382-383
The title compound, C36H44N6O4+·2Cl?·2ClO4?·0.132H2O, is shown to be protonated at all the pyridine N atoms; the two chloride ions are hydrogen bonded to three pyridine N atoms and to the phenolic O atom of the same cation [Cl?N = 3.045 (2)–3.131 (2) Å and Cl?O = 2.938 (2) Å], and the remaining pyridine N atom is hydrogen bonded to the phenolic O atom [N?O = 2.861 (2) Å]. The mean value of the C—N—C angle of the protonated pyridine rings is 123.4 (1)°, which is significantly larger than that found for unprotonated pyridine rings. 相似文献
9.
Xi‐Rui Zeng Ren‐Geng Xiong Yan Xu Yong‐Jiang Liu Xiao‐Zeng You 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(8):943-944
The title compound, [Zn(C7H8NO3S)2(H2O)4], has an octahedral coordination around the central Zn atom composed of two axial N atoms from the pyridine ligands and four equatorial O atoms of water molecules, forming a monomeric centrosymmetric complex. The two Zn—N bond distances are 2.102 (3) Å, while the four Zn—O bond distances range from 2.114 (2) to 2.167 (2) Å. Packing is determined by hydrogen bonds formed by the water molecules. The sulfonate group does not take part in coordination to the Zn atom. 相似文献
10.
John N. Low Justo Cobo Silvia Cruz Jairo Quiroga Christopher Glidewell 《Acta Crystallographica. Section C, Structural Chemistry》2003,59(12):o666-o668
The title compound, C17H24O4, crystallizes with two independent molecules, both lying across twofold rotation axes in space group Pccn, in a unit cell whose dimensions closely mimic those of a tetragonal cell. Each molecule contains paired O—H⋯O hydrogen bonds [H⋯O = 1.81 and 1.83 Å, O⋯O = 2.640 (2) and 2.642 (2) Å, and O—H⋯O = 168 and 162°]. 相似文献
11.
Christopher Glidewell John N. Low Janet M. S. Skakle James L. Wardell 《Acta Crystallographica. Section C, Structural Chemistry》2004,60(2):o120-o124
Molecules of 2‐(2‐nitrophenylaminocarbonyl)benzoic acid, C14H10N2O5, are linked into centrosymmetric R(8) dimers by a single O—H⋯O hydrogen bond [H⋯O = 1.78 Å, O⋯O = 2.623 (2) Å and O—H⋯O = 178°] and these dimers are linked into sheets by a single aromatic π–π stacking interaction. The isomeric compound 2‐(4‐nitrophenylaminocarbonyl)benzoic acid crystallizes in two polymorphic forms. In the orthorhombic form (space group P212121 with Z′ = 1, crystallized from ethanol), the molecules are linked into sheets of R(22) rings by a combination of one N—H⋯O hydrogen bond [H⋯O = 1.96 Å, N⋯O = 2.833 (3) Å and N—H⋯O = 171°] and one O—H⋯O hydrogen bond [H⋯O = 1.78 Å, O⋯O = 2.614 (3) Å and O—H⋯O = 173°]. In the monoclinic form (space group P21/n with Z′ = 2, crystallized from acetone), the molecules are linked by a combination of two N—H⋯O hydrogen bonds [H⋯O = 2.09 and 2.16 Å, N⋯O = 2.873 (4) and 2.902 (3) Å, and N—H⋯O = 147 and 141°] and two O—H⋯O hydrogen bonds [H⋯O = 1.84 and 1.83 Å, O⋯O = 2.664 (3) and 2.666 (3) Å, and O—H⋯O = 166 and 174°] into sheets of some complexity. These sheets are linked into a three‐dimensional framework by a single C—H⋯O hydrogen bond [H⋯O = 2.45 Å, C⋯O = 3.355 (4) Å and C—H⋯O = 160°]. 相似文献
12.
Yi‐Zhi Li Min Wang Liu‐Fang Wang Chun‐Gu Xia 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(10):e445-e446
The title complex, [Mn(C5H4NCO2)2(C5H4NCOOH)]OH, consists of a cation and a hydroxide ion. The Mn atom is coordinated by three N atoms and three O atoms from three pyridinecarboxylate ligands, and has a distorted octahedral geometry, with Mn—N distances ranging from 2.157 (1) to 2.233 (1) Å and Mn—O distances from 1.910 (1) to 1.927 (4) Å. One ligand is protonated as the acid form. This forms one of two independent hydrogen bonds, to the anion. 相似文献
13.
In catena‐poly[[(di‐2‐pyridylamine‐κ2N,N′)silver(I)]‐μ‐nicotinato‐κ2N:O], [Ag(C6H4NO2)(C10H9N3)]n, the AgI atom is tetracoordinated by two N atoms from the di‐2‐pyridylamine (BPA) ligand [Ag—N = 2.3785 (18) and 2.3298 (18) Å] and by one N atom and one carboxylate O atom from nicotinate ligands [Ag—N = 2.2827 (15) Å and Ag—O = 2.3636 (14) Å]. Bridging by nicotinate N and O atoms generates a polymeric chain structure, which extends along [100]. The carboxyl O atom not bonded to the Ag atom takes part in an intrachain C—H⋯O hydrogen bond, further stabilizing the chain. Pairs of chains are linked by N—H⋯O hydrogen bonds to generate ribbons. There are no π–π interactions in this complex. In catena‐poly[[(di‐2‐pyridylamine‐κ2N,N′)silver(I)]‐μ‐2,6‐dihydroxybenzoato‐κ2O1:O2], [Ag(C7H5O4)(C10H9N3)]n, the AgI atom has a distorted tetrahedral coordination, with three strong bonds to two pyridine N atoms from the BPA ligand [Ag—N = 2.286 (5) and 2.320 (5) Å] and to one carboxylate O atom from the 2,6‐dihydroxybenzoate ligand [Ag—O = 2.222 (4) Å]; the fourth, weaker, Ag‐atom coordination is to one of the phenol O atoms [Ag⋯O = 2.703 (4) Å] of an adjacent moiety, and this interaction generates a polymeric chain along [100]. Pairs of chains are linked about inversion centers by N—H⋯O hydrogen bonds to form ribbons, within which there are π–π interactions. The ribbons are linked about inversion centers by pairs of C—H⋯O hydrogen bonds and additional π–π interactions between inversion‐related pairs of 2,6‐dihydroxybenzoate ligands to generate a three‐dimensional network. 相似文献
14.
Sheng‐Li Li Anwar Usman Ibrahim A. Razak Hoong‐Kun Fun Jie‐Ying Wu Yu‐Peng Tian Min‐Hua Jiang Zu‐Yao Chen 《Acta Crystallographica. Section C, Structural Chemistry》2003,59(5):m181-m183
In the title compound, [Ni(CH5N3S)2(H2O)2](C4H3O4)2·2H2O, the Ni atom lies on a center of symmetry and is coordinated by N and S atoms from two thiosemicarbazide ligands and the O atoms of two water molecules in a distorted octahedral geometry. In the asymmetric unit, the three components are linked together by one O—H⋯O and two N—H⋯O hydrogen bonds. The packing is built from molecular ribbons parallel to the b direction, stabilized by intramolecular hydrogen bonds, and by one N—H⋯S and two N—H⋯O intermolecular hydrogen bonds. The ribbons are further connected into columns by N—H⋯O interactions and then into a three‐dimensional network by three O—H⋯O hydrogen bonds. 相似文献
15.
Jan Janczak Ynara Marina Idemori 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(11):m549-m550
The title compound, [Mg(C32H16N8)(H2O)], crystallizes with two MgPc(H2O) molecules (Pc is phthalocyaninate) in the asymmetric unit. The geometries of the two molecules are very similar, with the Mg atoms each 4+1‐coordinated by four isoindole N atoms at the base and by the O atom of the water molecule. The Mg atoms are displaced by 0.447 (1) and 0.468 (1) Å from the basal coordination planes towards the water O atoms. O—H?N hydrogen bonds form dimers stacked along the b axis in a herring‐bone fashion. 相似文献
16.
Yun‐Ling Gao Xiao‐Jun Peng Shi‐Guo Sun Chang‐Neng Chen 《Acta Crystallographica. Section C, Structural Chemistry》2005,61(1):m13-m15
The novel μ‐oxo‐diiron complex [Fe2O(BPHPA)2](ClO4)4 [BPHPA is (6‐hydroxymethyl‐2‐pyridylmethyl)bis(2‐pyridylmethyl)amine, C19H20N4O], contains a binuclear centrosymmetric [Fe2O(BPHPA)2]4+ cation (the bridging O atom lies on an inversion centre) and four perchlorate anions. Each iron ion is coordinated by four N atoms [Fe—N = 2.117 (5)–2.196 (5) Å] and one O atom [Fe—O = 2.052 (5) Å] from a BPHPA ligand, and by one bridging oxo atom [Fe—O = 1.7896 (9) Å], forming a distorted octahedron. There are hydrogen bonds between the hydroxy group and perchlorate O atoms [O—H·O = 2.654 (7) Å]. 相似文献
17.
Brandy H. Courtney Booker W. O. Juma Steven F. Watkins Frank R. Fronczek George G. Stanley 《Acta Crystallographica. Section C, Structural Chemistry》2006,62(5):o268-o270
In the title compound, C2H8N+·C12H11O5P2−, pairs of hydrogen diphenyldiphosphonate anions form dimers across a twofold axis, with two symmetric O⋯H⋯O hydrogen bonds [O⋯O = 2.406 (3) and 2.418 (3) Å]. The 12‐membered ring thus formed has crystallographic 2 and quasi‐222 symmetry. Cations on either side of the ring form N—H⋯O hydrogen bonds to the four extraannular O atoms, with N⋯O distances of 2.765 (2) and 2.748 (3) Å. 相似文献
18.
Yue Pan Kunhao Li Wenhua Bi Jing Li 《Acta Crystallographica. Section C, Structural Chemistry》2008,64(2):o41-o43
The cocrystallization of adamantane‐1,3‐dicarboxylic acid (adc) and 4,4′‐bipyridine (4,4′‐bpy) yields a unique 1:1 cocrystal, C12H16O4·C10H8N2, in the C2/c space group, with half of each molecule in the asymmetric unit. The mid‐point of the central C—C bond of the 4,4′‐bpy molecule rests on a center of inversion, while the adc molecule straddles a twofold rotation axis that passes through two of the adamantyl C atoms. The constituents of this cocrystal are joined by hydrogen bonds, the stronger of which are O—H...N hydrogen bonds [O...N = 2.6801 (17) Å] and the weaker of which are C—H...O hydrogen bonds [C...O = 3.367 (2) Å]. Alternate adc and 4,4′‐bpy molecules engage in these hydrogen bonds to form zigzag chains. In turn, these chains are linked through π–π interactions along the c axis to generate two‐dimensional layers. These layers are neatly packed into a stable crystalline three‐dimensional form via weak C—H...O hydrogen bonds [C...O = 3.2744 (19) Å] and van der Waals attractions. 相似文献
19.
Delphine Firley Bernard Fraisse Fatima Zouhiri Anne Spasojevi‐de Bir Didier Desmaële Jean D'Angelo Nour Eddine Ghermani 《Acta Crystallographica. Section C, Structural Chemistry》2005,61(3):o154-o157
Both 7‐carboxylato‐8‐hydroxy‐2‐methylquinolinium monohydrate, C11H9NO3·H2O, (I), and 7‐carboxy‐8‐hydroxy‐2‐methylquinolinium chloride monohydrate, C11H10NO3+·Cl−·H2O, (II), crystallize in the centrosymmetric P space group. Both compounds display an intramolecular O—H⋯O hydrogen bond involving the hydroxy group; this hydrogen bond is stronger in (I) due to its zwitterionic character [O⋯O = 2.4449 (11) Å in (I) and 2.5881 (12) Å in (II)]. In both crystal structures, the HN+ group participates in the stabilization of the structure via intermolecular hydrogen bonds with water molecules [N⋯O = 2.7450 (12) Å in (I) and 2.8025 (14) Å in (II)]. In compound (II), a hydrogen‐bond network connects the Cl− anion to the carboxylic acid group [Cl⋯O = 2.9641 (11) Å] and to two water molecules [Cl⋯O = 3.1485 (10) and 3.2744 (10) Å]. 相似文献
20.
Christopher Glidewell John N. Low Manuel Melguizo Antonio Quesada 《Acta Crystallographica. Section C, Structural Chemistry》2003,59(4):o202-o204
Molecules of the title compound, C6H9N3O2, are linked by an N—H⃛O hydrogen bond [H⃛O = 2.29 Å, N⃛O = 3.169 (2) Å and N—H⃛O = 173°] and an N—H⃛N hydrogen bond [H⃛N = 2.12 Å, N⃛N = 2.999 (2) Å and N—H⃛N = 175°] into sheets containing centrosymmetric R(8) and R(28) rings; the sheets are reinforced by a single aromatic π–π‐stacking interaction. 相似文献