Neutral lipids of the seeds of Eremostachys moluccelloides

Summary From the sum of the neutral lipids of the seeds ofE. moluccelloides we have isolated the natural di-and monoglycerides, have determined their structure, and have established that these classes of lipids contain a higher amount of saturated acids in the position than the triglycerides of the seeds.It has also been established that in the hydrolysis of natural diglycerides with the nonspecific lipase of the fungusO. lactis synthetic triglycerides are formed that differ from natural triglycerides by an increased amount of saturated acids.Institute of the Chemistry of Plant Substances, Academy of Sciences of the Uzbek SSR, Tashkent. Microbiology Division of the Academy of Sciences of the Uzbek SSR, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 1, pp. 44–48, January–February, 1978.     

Lipids of the fruit ofAcanthopanax sessiliflorus

In the lipids of the seeds and pericarp of the introduced speciesAcanthopanax sessiliflorus (Rupr. et Maxim.) Seem (familyAraliaceae), 23 classes of compounds have been detected, of which 19 have been identified. Sixteen of the classes have been studied. The lipids of the pericarp contain a more complex set of components than the seeds. Hydroxyacyldiacylglycerides, fatty acid methyl esters, and a complex group of pthalicacidesters have been detected in the familyAraliaceae for the first time. The fatty acid compositions of the seed and pericarp lipids are characterized by a high level of petroselinic acid.Institute of the Chemistry of Plant Substances, Academy of Sciences of the Uzbek SSR, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 6, pp. 760–766, November–December, 1985.     

The seed oil ofNepeta cataria

Summary In a study of the glyceride and fatty-acid compositions of the neutral lipids ofN. cataria seeds the presence of di- and monoglycerides in the lipids has been established. It has been shown that the predominating acid in all the glycerides is the 18:3 acid and the main types of triglycerides are those in which the position is esterified with the 18:2 acid and, to a smaller extent, the 18:3 acid.Natural fatty acid methyl esters have been isolated from a seed oil of a higher plant for the first time.Institute of the Chemistry of Plant Substances, Academy of Sciences of the Uzbek SSR, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 174–176, March–April, 1978.     

Lipids from extracts ofChlorella vulgaris

The composition of ethanolic (I) and gasoline (II) extracts of the cultivated microalgaChlorella vulgaris has been studied. With the aid of CC, TLC, qualitative reactions, GLC, and UVS the following classes of compounds have been detected in them. From the neutral lipids: hydrocarbons, carotenoids, traces of sterols and their esters, fatty acid esters, tri- and diacylglycerols, free fatty acids, and chlorophylls; and from the polar lipids: di- and monogalactosylglycerols, phosphatidylethanolamine, lecithin, phosphatidylinositol, phosphatidylserine, and three sphingosine bases. The polar lipids I and II made up 52.4 and 50.2% of the total, respectively. As compared with extract I, extract II was somewhat enriched with neutral lipids, including provitamins of the A group and vitamins of the F group. In the fatty acids of chlorella, 19 components were detected, the main ones being the 16:0 acid and 18:2 and 18:3 acids.Institute of the Chemistry of Plant Substances, Academy of Sciences of the Uzbek SSR, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 3, pp. 284–288, May–June, 1986.     

Polysaccharides of saponin-bearing plants. II. Isolation and characterization of the polysaccharides ofBiebersteinia multifida

The polysaccharides of the tuberous roots ofBiebersteinia multifida D. C. have been isolated and characterized. The neutral polysaccharide consists of a mixture of three glucans — A, B, and C — with molecular weights of 4100, 2200, and 1100, respectively, formed by D-glucopyran residues linked by bonds.Deceased.Institute of the Chemistry of Plants Substances, Academy of Sciences of the Uzbek SSR, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 6, pp. 755–757, November–December, 1985.     

Triterpene glycosides of silphium perfoliatum. V. The structure of silphioside A

From the epigeal part ofSilphium perfoliatum L. we have isolated glycoside F, identified as oleanolic acid 3-0--D-glucopyranosiduronic acid and a new triterpene glycoside — silphioside A — for which the structure of oleanolic acid 28-0--D-glucopyranoside 3-0-(methyl -D-glucopyranosiduronate) has been established.Pyatigorsk Pharmaceutical Institute, and Institute of the Chemistry of Plant Substances, Academy of Sciences of the Uzbek SSR, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 1, pp. 63–66, January–February, 1986.     

Glutamate receptor blockers from venoms of the spiders Argiope lobata and Araneus tartaricus

The presence of glutamate receptor blockers with molecular masses below 1000 Da and pI9 has been detected in the venoms of the spidersArgiope lobata andAraneus tartaricus.Institute of Physiology, Academy of Sciences of the Uzbek SSR, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 4, pp. 532–537, July–August, 1990.     

Alkaloids of the leaves of Cocculus laurifolius the structure of coclafine

Cocculine, isoboldine, norisoboldine, and a new erythrinan alkaloid, coclafine, for which the structure and absolute configuration of 3S,5R-3,15-dihydroxyerythrin-1(6)-ene have been established, have been isolated from the leaves ofCocculus laurifolius DC.Institute of Chemistry of Plant Substances, Academy of Sciences of the Uzbek SSR, Tashkent. Tashkent Agricultural Institute. Translated from Khimiya Prirodnykh Soedinenii, No. 1, pp. 84–86, January–February, 1991.     

Group composition of the neutral lipids in the oil of the fruit ofHippophaë rhamnoides

The composition of the neutral lipids of the fruit flesh and seeds of two forms of sea buckthorn have been determined. The presence of more than 20 groups of lipids has been shown. The two oils differed in the amounts and compositions of their carotenoids and acyl glycerols and the amounts of alcohols, free fatty acids, and esters.Institute of the Chemistry of Plant Substances, Academy of Sciences of the Uzbek SSR, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 3, pp. 300–305, May–June, 1984.     

Post-infection changes in lipids of the roots of a cotton plant variety moderately resistant to Verticillium dahliae

A comparative study has been made of the lipid composition of healthy roots of the cotton plant of the Tashkent-1 variety (I) and of the corresponding plants infected withVerticillium dahliae Kleb. (II) grown under field conditions. The action of the factors of infection stress and seasonal and climatic conditions change the lipid metabolism. In lipids (I) and (II) seven classes of neutral lipids (NLs), three classes of glycolipids, and six classes of phospholipids (PLs) were identified and their fatty acid compositions were determined. It was established that in (II) there was a smaller amount of total lipids, NLs, and PLs, and an increased level of polyphenolic pigments, but the level of gossypol pigments with free aldehyde groups was unchanged. In the NLs of (II), as compared with (I), there were more triacylglycerols, sterols, triterpenols, and squalene. Complex changes were observed in the fatty acid composition of the acyl-containing lipids.Institute of the Chemistry of Plant Substances, Uzbek SSR Academy of Sciences, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 1, pp. 59–63, January–February, 1989.     

Isolation and antibiotic properties of cis-hexadeca-4,7,10,13-tetraenoic acid from the algaScenedesmus obliquus UA-2-6

Summary By the method of checking antibiotic activity, conditions have been selected for the isolation of cis-hexadeca-4,7,10,13-tetraenoic acid from the fatty-acid fractions of the lipids ofScenedesmus obliquus UA-2-6. Its structure has been confirmed and it has been established that this acid possesses a broad spectrum of antibiotic action.Institute of Microbiology, Academy of Sciences of the Uzbek SSR, Tashkent. Institute of the Chemistry of Plant Substances, Academy of Sciences of the Uzbek SSR, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 3, pp. 379–385, May–June, 1978.     

Triterpene glycosides and their genins fromThalictrum foetidum. II. The structure of cyclofoetigenin A

A glycoside isolated from the epigeal parts ofThalictrum foetidum (Ranunculaceae) has yielded a new genin — cyclofoetigenin A, the structure of which has been established on the basis of chemical transformations and spectral characteristics as 24S-cycloartane-3,16,25,25-tetraol.Irkutsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR. Institute of the Chemistry of Plant Substances, Academy of Sciences of the Uzbek SSR, Tashkent Translated from Khimiya Prirodnykh Soedinenii, No. 3, pp. 370–375, May–June, 1985.     

Metabolites of the pathogenic fungusVerticillium dahliae. IV. Influence of the source of carbon on the lipid composition of the fungusVerticillium dahliae

Summary The compositions of the neutral lipids and the fatty-acid compositions ofVerticillium dahliae Kleb. grown in a fermenter with various sources of carbon-containing nutriment have been studied. It has been shown that the capacity of the fungus for synthesizing lipids and the quantitative and qualitative compositions of the neutral lipids and the fatty acids change according to the source of carbon-containing nutriment. Under the conditions of growth of the fungus in a fermenter, in some cases the formation of linolenic acid and of saturated iso acids is observed.It has been established that whenV. dahliae is grown on sucrose, the neutral lipids of the fungus include a chlorine-containing compound. The chlorine in the initial oil has been determined quantitatively.V. I. Lenin Tashkent State University. Institute of the Chemistry of Plant Substances, Academy of Sciences of the Uzbek SSR, Tashkent. All-Union Scientific-Research Institute of Agricultural Microbiology, Leningrad. Translated from Khimiya Prirodnykh Soedinenii, No. 1, pp. 22–26, January–February, 1977.     

Lipid complex of the kernels of seeds of cotton plants of the wilt-resistant variety 175-F

The amount, qualitative and class compositions, and total fatty acid composition of the free, bound, and strongly bound lipids of kernels of the seeds of cotton plant of variety 175-F have been determined, and with the aid of enzymatic hydrolysis the strongly bound lipids have been isolated from the cottonseed kernels in the native form. It has been established that more than half the weight of the lipids comprises neutral varieties and the remainder are polar components. The lipids of the more stable lipid-protein complexes possess a higher degree of saturation.Institute of Chemistry of Plant Substances, Academy of Sciences of the Uzbek SSR, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 3, pp. 314–318, May–June, 1991.     

Triterpene glycosides of Astragalus and of their genins. X. Cyclogalegigenin from Astragalus galegiformis

The flowers of the plantAstragalus galegiformis L. have yielded a new isoprenoid — cyclogalegigenin — the structure of which has been established on the basis of chemical transformations and spectral characteristics as 20R,24S-epoxycycloartane-3,6,16,25-tetraol.I. G. Kutateladze Institute of Pharmacochemistry, Academy of Sciences of the Georgian SSR, Tbilisi. Institute of the Chemistry of Plant Substances, Academy of Sciences of the Uzbek SSR, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 3, pp. 332–339, May–June, 1983.     

Phospholipase A2 from the venom of the spider Eresus niger

A phospholipase A₂ with a molecular mass of 12–14 kDa has been isolated from the venom of the spiderEresus niger by three-stage column chromatography. Asparagine has been identified as the N-terminal amino acid.Institute of Physiology, Academy of Sciences of the Uzbek SSR, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 4, pp. 557–560, July–August, 1991.     

Obtusifolin — A new coumarin from roots of Haplophyllum obtusifolium

From the neutral fraction of a methanolic extract of the roots ofHaplophyllum obtusifolium Ledeb. (family Rutaceae) have been isolated the lignan diphyllin, the alkaloids skimmianine and -fagarine, and a new coumarin with mp 179–180°C the structure of which has been established as 3-(,-dimethylallyl)-7-methoxy-8(3-methylbuta-1,3-diethyl)coumarin.Institute of Chemistry of Plant Substances, Uzbek SSR Academy of Sciences, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 187–189, March–April, 1988.