中学化学教学中达成情感态度与价值观目标的途径

诠释了中学化学学科中情感态度与价值观目标,提出了创设智慧的课堂教学、开展丰富的课后拓展和实施多元的学业评价是中学化学教学中达成情感态度与价值观目标的重要途径。     

我国中学化学课程中情感态度与价值观目标内涵的历史演变

情感态度与价值观目标在本次新课程改革中得到前所未有的重视。通过对我国历次化学课程标准或教学大纲中情感态度与价值观目标的历史梳理,分析出其变化的特征,以便帮助教师正确认识情感态度与价值观目标的内涵。     

"情感态度与价值观"目标在中学化学教学中落实的建议

"情感态度与价值观"教学目标是新课程提出的三维教学目标之一.分析了目前中学化学教学中对"情感态度与价值观"目标实施所存在的一些问题,提出了"情感态度与价值观"目标落实策略的建议.     

科学渗透情感态度与价值观目标

正确理解初中化学教学中的“情感态度与价值观”目标,必须把握其内容、特点以及与学科德育目标的联系和区别;全面达成情感态度与价值观目标,必须优化教学过程并准确设计、科学渗透课时情感态度与价值观目标。     

中学化学情感态度价值观教学目标实施的影响因素分析

情感态度价值观教学目标是新课程提出的三维教学目标之一。本文通过质的研究方法,分析出影响中学化学教学中情感态度价值观教学目标实施的因素,并提出一些促进中学化学情感态度价值观教学目标有效落实的策略。     

手持技术和模型发现教学模式在“酸雨的形成”教学中的应用

以高中化学教材内容“酸雨的形成”为例,以手持技术实验为辅助手段,以酸雨的形成为原型构建系统模型,通过对模型的分析、拟合得出酸雨形成及影响因素的理论框架,实现知识与技能、过程与方法、情感态度与价值观的全而提升,有效地达到提高学生科学素养的目的。     

化学教学设计中三维目标设计与叙写的问题与对策

针对化学教学设计中三维教学目标的设计与叙写的突出问题,从理论与实践层面进行了分析,并提出了解决问题的对策：（1）过程与方法是学生学习的过程和方法,不能设计成教师教学的过程与方法;过程与方法既是实现教学目标的手段,又是学生学习的目标,是相互关联的,不能割裂,陈述时要选择适宜的动词和恰当的行为结果。（2）情感态度是心理倾向,价值观是情感发展的结果,情感态度与价值观是生命发展的心理需求。在教学设计中教师要注重发掘教学内容中情感态度价值观素材,并明确目标达成方式。（3）三维目标是一个整体,不能割裂;整合目标,才能从整体上把握三维目标;自觉践行,才能逐步提高设计能力。     

用活动表现评价深化学生对分子和原子概念的认识

活动表现评价是通过学生在一个真实的活动情境中的行为表现,对学生在知识、技能、过程、方法、情感、态度及价值观等方面的水平做出评判的评价方法。在“分子和原子”教学过程中,依据教学目标运用实验探究、模型分析或图示表达等多种活动表现评价方法,深化学生对分子原子概念的认识。     

"中和滴定"的教学设计

基于全新的教学方式实施"中和滴定"教学,引领同学从探索中去获取相关知识与技能,具体落实"知识与技能、过程与方法、情感态度与价值观"的课程目标。     

高中化学教学中情感态度与价值观目标落实情况的调查

通过调查分析了当前高中化学教学中情感态度与价值观目标的教学现状：包括教师的理解和认识,落实的途径和方法等。     

二氧化碳和丙烯直接合成甲基丙烯酸的NiPMo/TiO2催化剂的研究

用溶胶-凝胶法以磷钼酸(MPA)的镍盐溶液水解钛酸四丁酯制备了NiPMo/TiO2催化剂.使用ICP、 XRD、 TG-DTA、 IR、 TPD-MS和微反应技术研究了催化剂的化学组成、热稳定性、化学吸附性质和催化反应性能.杂多钼酸盐与TiO2通过O2-在TiO2表面发生了键合.在623 K下,杂多阴离子仍保持原有的Keggin结构.CO2在Lewis酸位Ni(Ⅱ)和Lewis碱位Ni-O-Mo的桥氧协同作用下生成CO2卧式吸附态Ni(Ⅱ)←O-(CO)←(O--Ni).丙烯有多种吸附态在催化剂上吸附.在563 K、 1 MPa和空速1500 h-1的反应条件下,丙烯的摩尔转化率为3.2%,产物MAA选择性为95%.     

Toward new camptothecins. Part 6: Synthesis of crucial ketones and their use in Friedländer reaction

In the context of the preparation of camptothecin and luotonin A analogs, the synthesis of some key keto-precursors and their use in Friedländer condensation are described. This paper also focuses on the stability of these keto intermediates and emphasizes the major differences between indolizinones and pyrroloquinazolinones series. Noteworthy is also the report of some original structures isolated as by-products of some experiments.     

CoFe2O4自形成磁性液体场致结构化对磁化的影响

The Langevin paramagnetic theory can’t describe the relation between magnetization of ferrofluids and applied magnetic field. The structuralization of ferrofluids, which is considered the main influence factor of the magnetization, is regarded. The part of magnetization works is deposited when the structure is forming. This action influences the magnetization of ferrofluids directly or indirectly. On the base of the “compressing” model, the Langevin function that usually describes the magnetization of ferrofluid is modified, and a well-fitted curve is obtained. An equation of the relation between the equivalent volume fraction after being “compressed” and the intensity of magnetic field is discovered, which approximately describes the process of magnetization. The relation between the approximate initial susceptibility and the volume fraction can be obtained from modified formula.     

Highly regioselective Buchwald–Hartwig amination at C-2 of 2,4-dichloropyridine enabling a novel approach to 2,4-bisanilinopyridine (BAPyd) libraries

The highly regioselective Buchwald–Hartwig amination at C-2 of the cheap and readily accessible reagent, 2,4-dichloropyridine with a range of anilines and heterocyclic amines is described. This new methodology is robust and provides a facile access to 4-chloro-N-phenylpyridin-2-amines on 0.25 mol scale. These intermediates undergo a further Buchwald–Hartwig amination at higher temperature to enable rapid exploration of the chemical space at C-4 and to provide a library of 2,4-bisaminopyridines.     

KMnO4-mediated oxidative CN bond cleavage of tertiary amines: Synthesis of amides and sulfonamides

KMnO₄-mediated oxidative CN bond cleavage of tertiary amines producing secondary amine was introduced, which was trapped by electrophiles (acyl chloride and sulfonyl chloride) to form amides and sulfonamides. The reaction could take place at mild condition, tolerating a wide range of function groups and affording products in moderate to excellent yields.     

Chemistry of heterocyclic compounds at the A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, over 50 years (Review)

The review contains a concise historical account and information on the most significant researches undertaken by the staff at the A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences on the Chemistry of Heterocyclic Compounds. Dedicated to Academician of the Russian Academy of Sciences B. A. Trofimov on his 70th jubilee. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 10, pp. 1443–1502, October, 2008.     

Sulfur-directed metal-free and regiospecific methyl C(sp3)–H imidation of thioanisoles

Regiospecific and direct imidation of the methyl C(sp³)–H bond of thioanisoles is realized under mild and metal-free conditions with N-fluorobis(benzenesulfonyl)imide as an oxidant and nitrogen source. Proposed mechanism suggests that thionium ion intermediates and a Pummerer-type reaction are involved. The imidation has advantages such as high step-economy, excellent functionality tolerance, and regiospecificity, giving structurally diverse imidation products.     

Selective syntheses of 2H-1,3-oxazines and 1H-pyrrol-3(2H)-ones via temperature-dependent Rh(II)-carbenoid-mediated 2H-azirine-ring expansion

The Rh(II)-catalyzed reaction of 2-carbonyl-substituted 2H-azirines with ethyl 2-cyano-2-diazoacetate or 2-diazo-3,3,3-trifluoropropionate provides an easy access to 2H-1,3-oxazines and 1H-pyrrol-3(2H)-ones. These compounds can be selectively prepared from the same starting material using temperature as the only varied parameter. The 2-azabuta-1,3-diene intermediate, a common precursor for both heterocyclic products, isomerizes into 2H-1,3-oxazine under kinetic control, while 1H-pyrrol-3(2H)-one is the sole product of the reaction at elevated temperatures. According to DFT-calculations a one-atom oxazine ring contraction involving ring-opening to a 2-azabuta-1,3-diene intermediate, followed by a 1,5- and 1,2-prototropic shift leads to the consecutive formation of imidoylketene and azomethine ylide, which then further undergo cyclization to the pyrrole derivative.     

Synthesis of 1-benzyloxypyrazin-2(1H)-one derivatives

Different approaches for the synthesis of 1-benzyloxypyrazin-2(1H)-one derivatives from simple amino acids have been investigated. A library of 33 precursors for the preparation of N-hydroxy pyrazinones was obtained in moderate to good yields.