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1.
Asl? Gök?. ?smail K?rba?lar Hasan Uslu H. Ghanadzadeh Gilani 《Fluid Phase Equilibria》2011,303(1):71-75
Liquid-liquid equilibrium (LLE) data of the solubility (binodal) curves and tie-line end compositions were examined for mixtures of {(water (1) + butyric acid (2) + diethyl succinate or diethyl glutarate or diethyl adipate (3)} at 298.2 K and 101.3 ± 0.7 kPa. The relative mutual solubility of butyric acid is higher in the diethyl succinate or diethyl glutarate or diethyl adipate layers than water layers. The consistency of the experimental tie-lines was determined through the Othmer-Tobias correlation equation. The LLE data were correlated with NRTL model, indicating the reliability of the NRTL equations for these ternary systems. The best results were achieved with the NRTL equation, using non-randomness parameter (α = 0.3) for the correlation. Distribution coefficients and separation factors were measured to evaluate the extracting capability of the solvents. 相似文献
2.
Liquid–liquid equilibrium (LLE) data for the quaternary systems of [water + acetic acid + mixed solvent (dipropyl ether + diisopropyl ether)] were measured at 298.2 K and atmospheric pressure, using various compositions of mixed solvent. Binodal curves and tie-lines for the quaternary systems have been determined in order to investigate the effect of solvent mixture, dipropyl ether (DPE) and diisopropyl ether (IPE), on extracting acetic acid from aqueous solution. A comparison of the extracting capabilities of the mixed solvents was made with respect to distribution coefficients, separation factors, and solvent free selectivity bases. Reliability of the data was confirmed by using the Othmer–Tobias and Hand plots. The tie-lines were also correlated using the UNIFAC model. The average root-mean-square deviations between the observed and calculated mass fractions for the studied systems were in the range of 10–14%. 相似文献
3.
The binodal (solubility) curves and tie line data for ternary systems of (water + propionic acid + dichloromethane) at 91.3 kPa and T = (277.15, 284.15, and 294.15) K are reported. The binodal curve results were determined by cloud point measurements method. A simple titration method has been used for determining of the concentration of propionic acid in the both liquid phases at equilibrium. The results obtained were successfully correlated with the UNIQUAC activity coefficient model. The deviations between experimental and calculated compositions in both phases for the ternary system using this model are reported. The partition coefficients of propionic acid and the selectivity factor of dichloromethane for extracting of propionic acid from water were calculated and are reported. The phase diagrams for the ternary system studied including both the experimental and correlated tie lines are presented. 相似文献
4.
?. ?smail K?rba?lar Selin ?ahin Mehmet Bilgin 《The Journal of chemical thermodynamics》2006,38(12):1503-1509
(Liquid + liquid) equilibrium (LLE) data of the solubility (binodal) curves and tie-line end composition were examined for mixtures of {water (1) + propionic acid (2) + octanol or nonanol or decanol or dodecanol (3)} at T = 298.15 K and 101.3 ± 0.7 kPa. The reliability of the experimental tie-line data was confirmed by using the Othmer-Tobias correlation. The LLE data of the ternary systems were predicted by UNIFAC method. Distribution coefficients and separation factors were evaluated for the immiscibility region. 相似文献
5.
Emilio J. González Begoña GonzálezNoelia Calvar Ángeles Domínguez 《Fluid Phase Equilibria》2011,305(2):227-232
The aim of this work is to determine if the ionic liquid 1-ethyl-3-methylimidazolium ethylsulfate is a good solvent for the separation of xylenes and hexane by liquid extraction. With this purpose, liquid-liquid equilibrium (LLE) data for the ternary systems {hexane + o-xylene, or m-xylene, or p-xylene + 1-ethyl-3-methylimidazolium ethylsulfate} were determined at T = 298.15 K and atmospheric pressure. Selectivity and solute distribution ratio, derived from the experimental equilibrium data, were calculated and used to determine if this ionic liquid can be used as a potential solvent for the extraction of xylenes from their mixtures with hexane. The experimental LLE data for the ternary systems were correlated using the NRTL and UNIQUAC models. 相似文献
6.
Liquid-liquid equilibrium data for mixtures of (ethylene carbonate + benzene + cyclohexane) at temperatures 303.15 and 313.15 K and (ethylene carbonate + BTX + cyclohexane) at temperature 313.15 K are reported, where the BTX is benzene, toluene and m-xylene. The compositions of liquid phases at equilibrium were determined by gas liquid chromatography. The selectivity factors and partition coefficients of ethylene carbonate for the extraction of benzene, toluene and m-xylene from (ethylene carbonate + BTX + cyclohexane) are calculated and presented. The obtained results are compared with the selectivity factors and partition coefficients of ethylene carbonate for the extraction of benzene from (ethylene carbonate + benzene + cyclohexane). The liquid-liquid equilibrium data were correlated with the UNIQUAC and NRTL activity coefficient models. The phase diagrams for the studied mixtures are presented and the correlated tie line results have been compared with the experimental data. The comparisons indicate the applicability of the UNIQUAC and NRTL activity coefficients model for liquid-liquid equilibrium calculations of the studied mixtures. The tie line data of the studied mixtures also were correlated using the Hand method. 相似文献
7.
This study demonstrates the course of solubility and (liquid + liquid) equilibrium (LLE) for the system (cyclohexane + 1-butanol + 2,2,2-trifluoroethanol) at temperatures of (288.15, 298.15, and 308.15) K and pressure 101.3 kPa. The titration method was used to assess solubility (binodal) curves, while a direct analytical method to acquire tie lines.The consistency of the binodal curves and phase diagrams data were well calculated by Hand and Othmer–Tobias empirical equations. The NRTL and UNIQUAC thermodynamic models gave accurate tie-line values for the systems. Plait-point, distribution coefficient, solvent selectivity, and NRTL and UNIQUAC binary interaction parameters were obtained.The immiscibility region of the system decreases significantly with increasing temperature. The results present an overview of the high efficiency of liquid extraction using 2,2,2-trifluoroethanol as solvent to yield pure cyclohexane from its 1-butanol azeotrope mixture at ambient temperatures. 相似文献
8.
This work reports liquid–liquid equilibrium (LLE) results for the ternary systems {cyclooctane + benzene + 1-ethyl-3-methylpyridinium ethylsulfate}, {cyclooctane + toluene + 1-ethyl-3-methylpyridinium ethylsulfate}, and {cyclooctane + ethylbenzene + 1-ethyl-3-methylpyridinium ethylsulfate} at T = 298.15 K and under atmospheric pressure. The selectivity, percent removal of aromatic, and distribution coefficient ratio, derived from the tie-line data, were calculated to determine if this ionic liquid is a good solvent for the extraction of aromatics from cyclooctane. The phase diagrams for the ternary systems are shown, and the tie-lines correlated with the NRTL model have been compared with the experimental data. The consistency of the experimental LLE data was ascertained using the Othmer–Tobias and Hand equations. No data for mixtures presented here have been found in the literature. 相似文献
9.
In this paper, we present the results of our study of the phase equilibria for two quaternary systems: water + 1-propanol/2-propanol + potassium chloride (KCl) + cesium chloride (CsCl) at 298.1 ± 0.1 K. We also produced the binodal curves and tie-lines at different KCl/CsCl mass-fraction ratios, and produced integrated phase diagrams for the quaternary systems. We also discuss the solvation abilities of KCl and CsCl, and the effect of the polarity of the organic solvent on the liquid–liquid equilibrium. We compared the experimental tie-lines derived for the quaternary systems with values predicated by modifying the Eisen–Joffe equation. The model produced satisfactory results. 相似文献
10.
Liquid–liquid equilibrium (LLE) data of the solubility (binodal) curves and tie-line end compositions were examined for mixtures of {(water (1) + levulinic acid (2) + dimethyl succinate or dimethyl glutarate or dimethyl adipate (3)} at 298.15 K and 101.3 ± 0.7 kPa. The reliability of the experimental tie-line data was confirmed by using the Othmer–Tobias correlation. The LLE data of the ternary systems were predicted by UNIFAC method. The LLE data were correlated fairly well with UNIQUAC and NRTL models, indicating the reliability of the UNIQUAC and NRTL equations for these ternary systems. The best results were achieved with the NRTL equation, using non-randomness parameter (α = 0.3) for the correlation. Distribution coefficients and separation factors were measured to evaluate the extracting capability of the solvents. 相似文献
11.
Cork taint is a musty off-flavour in wines mainly caused by 2,4,6-trichloroanisole, but other haloanisoles can contribute. In this work, a method for the extraction of 2,4,6-trichloroanisole, 2,4,6-tribromoanisole and 2,6-dichloroanisole has been developed. The procedure involves the extraction of the haloanisoles from cork by pressurised liquid extraction and the analysis of the extracts by both GC-μECD and GC-MS-MS. A central composite design was used to investigate the dependence of the recoveries of the analytes on the temperature, percentage pentane-diethyl ether ratio and the extraction time. Experimental data were then processed by using the multiple regression analysis in order to calculate a mathematical model representing the relationship between factors and responses and to determine the best experimental conditions for PLE method. These conditions corresponded to a temperature of 176 °C, an extraction time between 2.8 and 4 min and an 80:20 pentane:diethyl ether ratio. 相似文献
12.
Mehmet Bilgin 《The Journal of chemical thermodynamics》2006,38(12):1634-1639
(Liquid + liquid) equilibrium (LLE) data for the ternary system of (water + butyric acid + oleyl alcohol) at T = (298.15, 308.15, and 318.15) K are reported. Complete phase diagrams were obtained by determining solubility and the tie-line data. The reliability of the experimental tie lines was confirmed by using Othmer-Tobias correlation. The UNIFAC method was used to predict the phase equilibrium data. The phase diagrams for the ternary mixtures including both the experimental and correlated tie lines are presented. Distribution coefficients and separation factors were evaluated for the immiscibility region. A comparison of the solvent extracting capability was made with respect to distribution coefficients, separation factors, and solvent-free selectivity bases for T = (298.15, 308.15, and 318.15) K. It is concluded that oleyl alcohol may serve as an adequate solvent to extract butyric acid from its dilute aqueous solutions. 相似文献
13.
Fariborz Momenbeik Mostafa Roosta Ali Akbar Nikoukar 《Journal of chromatography. A》2010,1217(24):3770-3773
An environmentally benign and simple method has been proposed for separation and determination of fat-soluble vitamins using isocratic microemulsion liquid chromatography. Optimization of parameters affecting the separation selectivity and efficiency including surfactant concentration, percent of cosurfactant (1-butanol), and percent of organic oily solvent (diethyl ether), temperature and pH were performed simultaneously using genetic algorithm method. A new software package, MLR-GA, was developed for this purpose. The results indicated that 73.6 mM sodium dodecyl sulfate, 13.64% (v/v) 1-butanol, 0.48% (v/v) diethyl ether, column temperature of 32.5 °C and 0.02 M phosphate buffer of pH 6.99 are the best conditions for separation of fat-soluble vitamins. At the optimized conditions, the calibration plots for the vitamins were obtained and detection limits (1.06–3.69 μg mL−1), accuracy (recoveries > 94.3), precision (RSD < 3.96) and linearity (0.01–10 mg mL−1) were estimated. Finally, the amount of vitamins in multivitamin syrup and a sample of fish oil capsule were determined. The results showed a good agreement with those reported by manufactures. 相似文献
14.
Juan Han Cuilan Yu Yun Wang Xueqiao Xie Yongsheng Yan Guowu Yin Weixing Guan 《Fluid Phase Equilibria》2010
Binodal curves of the aqueous 1-butyl-3-methylimidazolium tetrafluoroborate ([Bmim]BF4) + sodium citrate (Na3C6H5O7), [Bmim]BF4 + sodium tartrate (Na2C4H4O6) and [Bmim]BF4 + sodium acetate (NaC2H3O2) systems have been determined experimentally at 298.15 K. The Merchuk equation was used to correlate the binodal data. The effective excluded volume (EEV) values obtained from the binodal model for these three systems were determined. The binodal curves and EEV both indicate that the salting-out abilities of the three salts follow the order: Na3C6H5O7 > Na2C4H4O6 > NaC2H3O2. The liquid–liquid equilibrium (LLE) data were obtained by density determination and binodal curves correlation of these systems. Othmer–Tobias and Bancraft, and Setschenow equations were used for the correlation of the tie-line data. Good agreement was obtained with the experimental tie-line data with both models. 相似文献
15.
Identification of volatile components in yak butter using SAFE, SDE and HS-SPME-GC/MS 总被引:1,自引:0,他引:1
The volatile components of yak butter were isolated by solvent-assisted flavour evaporation (SAFE), simultaneous distillation extraction (SDE; dichloromethane and diethyl ether as solvent, respectively) and headspace solid-phase microextraction (HS-SPME; CAR/PDMS, PDMS/DVB and DVB/CAR/PDMS fibre extraction, respectively) and were analysed by GC/MS. A total of 83 volatile components were identified under six different conditions, including 28 acids, 12 esters, 11 ketones, 10 lactones, 10 alcohols, 4 other compounds, 2 aldehydes, 2 unsaturated aldehydes, 1 furan, 1 sulphur-containing compound, 1 unsaturated alcohol and 1 unsatruated ketone. Among them, 51 were identified by SAFE, 58 by SDE (45 with dichloromethane as solvent and 41 with diethyl ether as solvent) and 40 by HS-SPME (26 with CAR/PDMS; 26 with PDMS/DVB and 32 with DVB/CAR/PDMS). Three pretreatment methods were compared to show that the volatile components obtained using different methods varied greatly, both in terms of categories and in content. Therefore, a multi-pretreatment method should be adopted, together with GC/MS. A total of 25 aroma-active compounds were detected by gas chromatography-olfactometry, among which 20 aroma-active compounds were found by SDE (14 with dichloromethane as solvent and 14 with diethyl ether as solvent) and 17 by SAFE. 相似文献
16.
In this work we use the vapor-sorption equilibrium data to show the degree of solvent upturn in each solvent-polymer system. For this purpose, 23 isothermal data sets for four polymer + solvent binaries, one block copolymer + solvent binary and for the corresponding polymer pairs have been used in the temperature range of 25-70 °C. Solvents studied are benzene, carbon tetrachloride, chloroform and pentane. Homopolymers studied are polyisobutylene, poly(ε-caprolactone), poly(ethylene oxide), n-heptadecane, polystyrene, poly(vinyl chloride), poly(vinyl methyl ether), and n-tetracosane.According to these data sets, solvent weight fraction in the polymer is plotted against solvent-vapor activity that is calculated assuming an ideal gas phase of pure solvent vapor neglecting the vapor pressure of the polymer. We use the Flory-Huggins theory to obtain dimensionless interaction parameter, χ. Also the Zimm-Lundberg clustering theory and non-ideality thermodynamic factor, Γ are used to interpret the equilibrium data. 相似文献
17.
A domino reaction composed of a Knoevenagel condensation combined with a simultaneous catalytic hydrogenation is reported in an ionic liquid solvent under mild conditions (298-363 K and 300 kPa). No interference between the catalysts (Pd/C and amine acetate salt) of the two diverse steps was monitored. The product could be neatly extracted by diethyl ether and the solvent containing the catalysts could be recycled and reused five times without any loss in activity or selectivity. The same methodology in a common organic solvent such as DMA resulted in significant competing parallel hydrogenation of the aldehyde to alcohol. 相似文献
18.
Byron Mhaka Ewa Cukrowska Bernadette Tse Sum Bui Olof Ramström Karsten Haupt Hlanganani Tutu Luke Chimuka 《Journal of chromatography. A》2009,1216(40):6796-6801
A selective extraction technique based on the combination of liquid membrane (microporous membrane liquid–liquid extraction) and molecularly imprinted polymers (MIP) was applied to triazines herbicides in food samples. Simazine, atrazine and propazine were extracted from aqueous food samples through the hydrophobic porous membrane that was impregnated with toluene, which also formed part of the acceptor phase. In the acceptor phase, the compounds were re-extracted onto MIP particles. The extraction technique was optimised for the amount of molecularly imprinted polymers particles in the organic acceptor phase, extraction time, and type of organic acceptor solvent and desorption solvent. An extraction time of 90 min and 50 mg of MIP were found to be optimum parameters. Toluene as the acceptor phase was found to give higher triazines binding onto MIP particles compared to hexane and combinations of diethyl ether and hexane. 90% methanol in water was found to be the best desorption solvent compared to acetonitrile, methanol and water. The selectivity of the technique was demonstrated by extracting spiked lettuce and apple extracts where clean chromatograms were obtained compared to liquid membrane extraction alone or to the microporous membrane liquid–liquid extraction – non-imprinted polymer combination. The MIP showed a certain degree of group specificity and the extraction efficiency in lettuce extract was 79% (0.72) for simazine, 98% (1.55) for atrazine and 86% (3.08) for propazine. 相似文献
19.
This work presents a new methodology to quantify ethyl carbamate (EC) in fortified wines. The presented approach combines the microextraction by packed sorbent (MEPS), using a hand-held automated analytical syringe, with one-dimensional gas chromatography coupled with mass spectrometry detection (GC–MS). The performance of different MEPS sorbent materials was tested, namely SIL, C2, C8, C18, and M1. Also, several extraction solvents and the matrix effect were evaluated. Experimental data showed that C8 and dichloromethane were the best sorbent/solvent pair to extract EC. Concerning solvent and sample volumes optimization used in MEPS extraction an experimental design (DoE) was carried out. The best extraction yield was achieved passing 300 μL of sample and 100 μL of dichloromethane. The method validation was performed using a matrix-matched calibration using both sweet and dry fortified wines, to minimize the matrix effect. The proposed methodology presented good linearity (R2 = 0.9999) and high sensitivity, with quite low limits of detection (LOD) and quantification (LOQ), 1.5 μg L−1 and 4.5 μg L−1, respectively. The recoveries varied between 97% and 106%, while the method precision (repeatability and reproducibility) was lower than 7%. The applicability of the methodology was confirmed through the analysis of 16 fortified wines, with values ranging between 7.3 and 206 μg L−1. All chromatograms showed good peak resolution, confirming its selectivity. The developed MEPS/GC–MS methodology arises as an important tool to quantify EC in fortified wines, combining efficiency and effectiveness, with simpler, faster and affordable analytical procedures that provide great sensitivity without using sophisticated and expensive equipment. 相似文献
20.
Yasuhiro Matsuda Yuji Miyazaki Shinji Sugihara Sadahito Aoshima Kazuya Saito Takahiro Sato 《Journal of Polymer Science.Polymer Physics》2005,43(20):2937-2949
Cloud‐point and binodal curves of the LCST type were obtained for aqueous solutions of a thermoresponsive polymer, poly [2‐(2‐ethoxy)ethoxyethyl vinyl ether], poly(EOEOVE). The cloud‐point curve obtained was very flat except in a dilute region, that is the cloud‐point temperature was insensitive to the polymer concentration, resembling the cloud‐point curve for aqueous solutions of poly(N‐isopropylacrylamide). On the other hand, the binodal curve obtained was parabolic, and located within the two‐phase region of the cloud‐point curve. Accompanied with the phase separation, a sharp endothermic peak was observed in a region including the cloud‐point and binodal temperatures. The reciprocal of the osmotic compressibility ?Π/?c obtained by sedimentation equilibrium indicated that water changes from a good to poor solvent for poly(EOEOVE) with increasing temperature. Analyzing the ?Π/?c data by a thermodynamic perturbation theory, we determined the interchain interaction parameters, the hard‐core diameter d and the depth ε of the square‐well potential. Theoretical binodal and endothermic curves calculated by the perturbation theory using the estimated interaction parameters reproduced experimental ones semiquantitatively, but the theoretical binodal disagreed with the experimental flat cloud‐point curve. The disagreement at high concentrations was in the opposite direction to that expected from the sample polydispersity in the molecular weight. © 2005 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 43: 2937–2949, 2005 相似文献