Hyperfine fields in erbium metal

The hyperfine Splitting of the 80.6-keVγ transition in Er¹⁶⁶ has been measured in erbium metal between 4.2 °K and 40 °K using the Mössbauer effect. There is evidence for a unique magnetic field and electric fieldgradient at all nuclei in erbium metal. The magnetic field decreases from (7.55±0.20)·10⁶ Oe at 4.2 °K to (6.10±0.40)·10⁶ Oe at 40 °K. Extrapolation to 0 °K yieldsH (0 °K)=(7.60±0.20)·10⁶ Oe. The quadrupole interaction energy for the 80.6-keV state iseQ V _Z′Z′/4=(0.95±0.20)·10^?6 eV at 4.2 °K. These results are discussed and compared with other measurements.     

Mößbauereffekt in Eisenstilben und FeCl2·H2O

Using Mößbauer effect measurements in the temperature range between 3 °K and 310 °K the magnetic fields at the nucleus in iron-stilbene, FeCl₂·H₂O and FeCl₃ are determined to beH _T=0=(250±10) kOe, (252±18) kOe and (468±10) kOe; a Néel-temperature ofT _N=(23±1) °K is measured for iron-stilbene. The electric quadrupole splittings atT=0 °K for iron-stilbene and FeCl₂ ·H ₂ O, ΔE=(+2.52±0.02) mm/sec and (+2.50±0.05) mm/sec, yield electric field gradients at the iron nucleus ofq _z=+9.7·10¹⁷ V/cm² and +9.6·10¹⁷ V/cm², whereq _z⊥H; Debyetemperatures of θ=162 °K and 188 °K are obtained. The energy of the excited 3d-electron levels in iron-stilbene is estimated to Δ₁=309 cm^?1 and Δ₂=618cm^?1 as deduced from the temperature dependence ofΔE. In contrast to the suggestion ofEuler andWillstaedt bivalence of the iron in ironstilbene is found; its composition is shown to be 4(FeCl₂ ·H ₂O)·stilbene.     

Magnetisches Moment und Quadrupolmoment des 8,42 keV-Zustandes von Tm169 aus der Hyperfeinstrukturaufspaltung in Tm-Metall

The hyperfine transition from the 8·42 kev level to the groundstate of Tm¹⁶⁹ was investigated using the Mössbauer-Effect in Tm-metal in the temperature range between 5° K and 60° K. Well resolved hyperfine spectra were found between 5° K and 25° K indicating an internal magnetic field of about 7×10⁶ Oe and a large electric fieldgradient. The ratio of the magnetic moments of the 8·42 keV rotational state to the groundstateμ _a /μ _g =?2·33±0·04 was deduced from these measurements. The magnetic moment of the groundstate and the quadrupole moment of the 8·42 kev level were deduced from calculated internal fields. These data were analyzed in terms of the “Unified Nuclear Model” and the results compared with other known magnetic moments andM-1-transition probabilities in theK=1/2 rotational band of Tm¹⁶⁹. The complicated hyperfine spectra obtained above 25° K reveal the influence of complex magnetic ordering on the internal fields in Tm-metal.     

Measurement of intensities of multiplets in the 2ν3-band of methane at low temperatures

The integrated intensities of the multiplets P(1)–P(10), R(0)–R(9), and of the Q-branch in the 2ν₃-band of ¹²CH₄ have been measured at 102°K, 152°K, 202°K, 251°K, and 300°K. Comparison of our data with theoretical line strengths confirms, at all of the temperatures mentioned, the intensity anomalies observed by Margolis⁽⁵⁾ for lines in this band. The integrated intensity of the 2ν₃-band is found to be S_v = (1·76±-0·04)(300/T (°K)) cm^?2 atm^?1.     

Nb3Sn正常-超导转变时的比热反常

在16.0°K—20.3°K之间测量了Nb₃Sn样品的热容量。Nb₃Sn在临界温度附近的比热跳跃值ΔC=2.21(±5％)焦耳/克分子·度。样品的临界温度T_c=17.88°K,转变宽度ΔT_c≈0.2°K。ΔC值利用热力学关系式确定了Nb₃Sn在0°K时的热力学临界场H₀=5300奥斯特。利用本文的结果和文献上关于热膨胀系数的跳跃值Δα及?T/?P值验证了热力学关系式。扼要地描述了比热测量装置.     

Measurement of integrated intensities of acetylene bands at 3·04, 7·53 and 13·7 μm

Integrated intensities of acetylene bands at 3·04, 7·53 and 13·7 μm have been measured at 300°K using the Wilson-Wells-Penner-Weber technique and a spectral resolution of 0·6 cm^?1. Our best estimates of the intensities are 294 ± 6 cm^?2atm^?1 for the 3·04 μ bands, 87 ± 2 cm^?2atm^?1forthe 7·53 μband and 729 ± 28 cm^?2atm^?1 for the 13·7 μ band at 300°K.     

The exciton absorption in deformed germanium

Absorption spectra at 77° K near the direct (κ = 0) exciton transition are reported for deformed and undeformed single-crystal films of n-type Ge oriented on (111); Elliott's theory is applied. The optical width of the forbidden band for this transition is found as E_{g 0} = (0.8821 ±±0.0002) eV, while the exciton binding energy is found as E_ex(0) = = (0.0016±0.0003) eV for undeformed Ge at 77 ° K. The mean temperature coefficient of E_g for κ = 0 in the range 77 °–297 ° K is (dE_g/ /dT)_p =?3.50 · 10^?4 eV/deg. The effects of thermoelastic deformation on the exciton spectrum give (dE_g/dT)_d = (?1.5±0.1) · 10^?4 eV/deg. The half-width σ ≈ 5 · 10^?4 eV of the exciton peak gives the exciton lifetime as gt ≥ 10^?12 sec.     

Crystal field parameters and phase transitions in ErSb

The crystal field levels of the Er ($\text{J =}\text{15}\text{2}$) ion in a single crystal of ErSb have been measured by inelastic neutron scattering. The crystal field parameters obtained by a least squares fit to the spectra at several temperatures are: B₄ = (0·473 ± 0·005) × 10^?2°K and B₆ = (0·59 ± 0·06) × 10^?5°K, which differ considerably from the values o by interpolation from measurements on other compounds. In addition the temperature dependence of the magnetic scattering in the vicinity of the Néel temperature (T_N = 3·55°K) clearly demonstrates that the transition is second order in contrast to the first order behavior suggested by specific heat measurements. Also, any lattice distortion accompanying the magnetic ordering is less than 0.1 per cent, the resolution of the present experiment.     

Mössbauer studies of europium and ytterbium hydrides

Mössbauer absorption spectra were obtained for the 21·6 ke V transition of ¹⁵¹Eu in EuH₂ at various temperatures and for the 84·3 keV transition of ¹⁷⁰Yb in YbH₂ at 4·1°K. The isomer shift of EuH₂ relative to Eu³⁺: Sm₂O₃ is ? 12·1 ± 0·3 mm. sec^?1, and the magnetic hyperfine field equals ? 305 ± 5 kOe at saturation. The Curie temperature is found to be 16·2 ± 0·05°K, and the critical parameters of the transition are D = 1·17 ± 0·02 and β = 0·35 ± 0·01. The magnetic field is perpendicular to the principal axis of the electric field gradient and the values of the quadrupole hyperfine interaction e²qQ₀(3 cos² θ ? 1)/8 is ? 28 ± 4 Mc . sec^?1. A large increase of the resonance area (21%) occurs at the transitio to the ferromagnetic state. The isomer shift of YbH₂ relative to Yb: TmAl₂ is ?0·11 ± 0·01 mm . sec^?1. The value of the quadrupole coupling constant e²qQ_c/4is ? 91·5 ± 2 Mc . sec^?1 and the asymmetry parameter of the electric field gradient equals 0·89 ± 0·05. The data for EuH₂ and YbH₂ is shown to be consistent with the hydridic model for the rare earth hydrides.     

Intensity and half-width measurements in the 1·525 μm band of acetylene

Line intensities at 150°K and 295°K, self-broadened half-widths at 171°K, 200°K, 250°K and 295°K, and hydrogen-broadened half-widths at 171°K, 200°K and 295°K have been measured in the ν₁+v₃ band of C₂H₂ at 1·525 μm. The absolute intensity of the band has been determined independently by employing the Wilson-Wells-Penner-Weber technique. Our best estimate for the absolute intensity of the band is S_v=7·82 ± 0·07 cm^?2 atm^?1 at 295°K. Line intensities calculated using this value of S_v are in good agreement with the measured intensities at the two extreme temperatures of 150°K and 295°K considered in the present study, thereby not suggesting any significant intensity anomalies. Line positions have been measured for the first time for this band for R(29)?P(25).     

Zeeman spectroscopy of the 4 Eu → 2 B 1g phosphorescence of copper porphin in an n-alkane single crystal

The phosphorescence spectrum of the metastable ⁴ E_u state of copper porphin in single crystals of n-octane (C₈) and n-decane (C₁₀) has been studied between 2·3 and 35 K, with and without a magnetic field B. The crystal field splitting between the orbital components observed at 35 K is δ = 30·3 ± 0·3 (C₈), 13·8 ± 0·2 cm^-1 (C₁₀). From the Zeeman shifts we derive the effective orbital angular momentum Λ′ = 0·8 ± 0·2 (C₁₀), the spin-orbit coupling parameter |Z′| = 1·5 ± 1·0 cm^-1 (C₁₀), the spin-spin dipolar interaction parameters D = -0·1 ± 0·2 cm^-1 (C₈, C₁₀) and |E| = 0·31 ± 0·03 cm^-1 (C₈, C₁₀), and the g-factors g _∥ = 2·14 ± 0·04 (C₈, C₁₀) and g _⊥ = 2·00 ± 0·03 (C₈, C₁₀).     

Solid-state2H NMR studies of methyl group dynamics in aspirin and aspirin · β-cyclodextrin

The dynamics of the methyl group in aspirin, and in the inclusion complex aspirin · β-cyclodextrin, have been studied by deuterium nuclear magnetic resonance spectroscopy and relaxation time measurements. The methyl group in aspirin undergoes fast thermally activated rotation about its axis of symmetry within the temperature range studied, 120 ≤T ≤ 295 K, with an activation energy of 4.9±0.05 kJ/mol and a correlation time at 230 K of (2.47±0.3) · 10^?12 s. The motionally averaged electric field gradient tensor, however, remains axially asymmetric because of electronic effects of a neighbouring oxygen atom. In aspirin · β-cyclodextrin the methyl group rotation about its axis of symmetry is less hindered with an activation energy of 2.1 ± 0.7 kJ/mol and a correlation time at 230 K of (2.5 + 0.4) · 10^?12 s. The axis of symmetry undergoes a slow reorientation with a higher activation energy of 21 ±9 kJ/mol and a correlation time at 230 K of (1.7±1.5) · 10^?6 s.     

Initial slope of the critical magnetic field curve of yttrium thorium sesquicarbide

The initial slope of the critical magnetic field curve of yttrium thorium sesquicarbide was observed to be 2.4±0.2 × 10⁴ Oe/K. Assuming no paramagnetic limitation, as was the case for lanthanum sesquicarbide, the zero temperature critical-magnetic field is estimated to be 280 ± 24 kOe.     

Some detailed investigations of optically detected Ē(2 E) →4 A 2 cross relaxation in ruby

Cross relaxation betweenē(² E) and⁴ A ₂ states of Cr³⁺ in ruby at an applied external magnetic field ofH=5336 Oe was measured by monitoring the ¦? 1/2〉_ex→ ¦? 3/2〉_g optical transition in the temperature region of 1.6 to 4.2 °K. The chromium concentration varied from 2.9· 10^?4 to 4 · 10^?6 Cr³⁺/Al³⁺. With a concentration greater than 2 · 10^?5, the light intensity of the observed transition increases when cross relaxation takes place, while below this value it decreases. By measurement of the fluorescent intensity of one transition and simultaneously inducing EPR ground state transitions, we monitored the effect of trapping. Taking the value for trapping from fluorescence decay time measurements, we have used rate equations for calculating the actual change of excited state population when cross relaxation occurs. With this phenomenological model we are able to explain our experimental data. Finally some calculations for the effective spin temperature in theē(² E) state as a function of Cr³⁺ concentration as well as for various applied magnetic fields have been done.     

Heat capacity behaviour of Pu−Fe eutectic alloy (10 a/o Fe) between 15 and 373°K. Evidence for order-disorder and an antiphase structure below room temperature

Low temperature heat capacity studies of Pu?Fe eutectic alloy (10 a/o Fe) have suggested the possibility of order-disorder of atoms and an antiphase structure below room temperature. Slow cooling and temperature cycling below 76°K were required for appearance of the postulated antiphase structure. Fermi surface-Brillouin zone boundary interactions are suggested as an explanation for the low temperature behavior of the eutectic alloy as well as for the resistivity maximum in both Pu₆Fe and α-Pu. The best values for S°(298) and {H°(298)?H°(0)} were judged to be 14·20±0·10 cal mol^?1 K^?1 and 1660±30 cal mol^?1.     

Die Temperaturabhängigkeit des Bandabstandes von Bleiselenid,gemessen an photoleitenden Schichten

The temperature dependence of spectral distribution of photoconductivity was measured on evaporated polycrystalline layers of lead-selenide in the range from 80 to 300 °K. The method ofBardeen, Blatt andHall was used, to calculate the band gap for direct and indirect transitions. A linear positive temperature coefficient was obtained for both transitions. The values areβ _dir=+(4.5±0.2) · 10^?4 eV/°K andβ _ind=+(3.0±0.2)· 10^?4eV/°K.     

The heat capacity of LaPd3 and PrPd3 at low temperature

Values of γ=0.33±0.01 mJ/K²·g atom and θ_D=176±1 K were found for LaPd₃. PrPd₃ shows magnetic ordering below 0.6 K and a Schottky anomaly whose maximum lies around 1.8 K. The crystalline field at the Pr³⁺ site creates a Γ₃ (doublet) excited state lying 4 K above the Γ₅ (triplet) ground state.     

Static electric quadrupole interaction of Ta- and Hf-ions in barium and lead titanate

The static electric quadrupole interaction of¹⁸¹Ta and¹⁷⁸Hf in polycrystalline barium and lead titanate at the site of titanium has been measured using time differential PAC and the Mössbauer effect. The electric field gradients (EFG) at room temperature at the¹⁸¹Ta nucleus are ¦V _zz¦=(3.6±0.2)·10¹⁷V/cm² in BaTiO₃ and ¦V _zz¦=(14.6±0.6)·10¹⁷ V/cm² in PbTiO₃. The temperature dependence of the quadrupole interaction has been studied giving the following EFG values: ¦V _zz¦=(2.4±0.2)·10¹⁷ V/cm² in the monoclinic and ¦V _zz¦=(1.1±0.3)·10¹⁷ V/cm² in the rhomboedral phase of BaTiO₃, and ¦V _zz¦=(15.7±0.6)·10¹⁷ V/cm² for¹⁸¹Ta/PbTiO ₃ at 77 °K. The EFG of¹⁷⁸Hf in PbTiO₃ has been derived from a Mössbauer effect experiment to beV _zz=+(10.7±0.5)·10¹⁷ V/cm². The results are compared with EFG's calculated in a point charge model and with experimental EFG's measured at⁴⁴Sc and⁵⁷Fe in the same titanates by other authors. Contributions of covalent bonds to the effective EFG's in perovskit crystals are discussed.     

EPR of Fe3+ ion and symmetry of [AIF5·H2O]2? complex ion in (NH4)2AIF5·H2O single crystals

We used the spin-Hamiltonian method for the analysis of the electron paramagnetic resonance (EPR) spectrum of Fe³⁺ as a probe ion in (NH₄)₂AlF₅·H₂O single crystalline basic material. The theoretical expressions for the magnetic field (at which the fine structure transition lines appear) versus the angle between the magnetic field and the axis of symmetry of the magnetic complex are also given. These values were calculated by applying the perturbation theory to the second-order terms. From the experimental results (at 300 K and 9.21 GHz), the spin-Hamiltonian parameters were deduced:D=(668±10)·10⁻⁴ T,E=(−56±10)·10⁻⁴ T,a=(−54±10)·10⁻⁴ T,F=(30±10)·10⁻⁴ T. An isotropic superhyperfine structure was evidenced for the five fluorine ions. The obtained EPR data were used to determine the local symmetry of the Al³⁺ ion. A good agreement with X-ray diffraction measurements was found.     

The electric field gradient at Ta in HfB2

Using the time-differential perturbed-angular correlation technique, we have observed the nuclear electric quadrupole interaction at ¹⁸¹Ta (482 keV) as an impurity in the refractory compound HfB₂. The measured interaction frequency is ν_Q=730±5 MHz which corresponds to an electric field gradient of |eq|=(1·19±0·05)×10¹⁸ V/cm² at room temperature. By considering a second measurement at 4·2°K, which yields the same results as above, and by comparison with available results for Hf in HfB₂, we conclude that the d-electron density of states at the Fermi level is quite small in agreement with trends observed by others.