香荆芥酚的荧光光谱和吸收光谱研究

研究了中药活性成分香荆芥酚(Carvacrol)的荧光光谱和吸收光谱,依据光谱数据测量了香荆芥酚的电离常数和荧光量子产率.在pH＜2.0时,香荆芥酚的荧光随溶液pH增大而增强;在pH2.0～8.0范围内,香荆芥酚有稳定的强荧光,最大激发波长为278 nm,最大发射波长为306 nm; pH＞8.0时荧光强度随pH的增大...     

等离子体X射线吸收谱及发射谱研究

 报道计算高温高密等离子体吸收谱和发射谱（光学薄）的理论方法；该方法基于相对论原子理论，可以计算任何单元素以及多元素等离子体的谱分辨X射线吸收谱和发射谱（光学薄）；应用了量子亏损理论，可以减少计算量。利用该方法计算金等离子体LTE吸收谱，计算结果与实验符合良好。本文还对金等离子体LTE的光学薄发射谱进行了研究, 这将有利于对实验进行进一步的诊断分析。该理论计算方法还可提供等离子体内各电离度能级布居等重要物理参数。因此经“标准实验”检验的该理论计算方法将是提供ICF“精密”物理辐射参数的重要基础。     

Turbulence spectra

The scaling invariance of the Navier-Stokes equations in the limit of infinite Reynolds number is used to derive laws for the inertial range of the turbulence spectrum. Whether the flow is homogeneous or not, the spectrum is chosen to be that given by a well-chosen biorthogonal decomposition. If the flow is hoogeneous, this spectrum coincides with the classical Fourier (energy) spectrum which exhibits Kolmogorov's k^–5/3 power law if the scaling exponent is assumed to be 1/3. In the more general case where the homogeneity assumption is relaxed, the spectrum is discrete and decays exponentially fast under the assumption that the flow is invariant (in a deterministic or statistical sense) under only one subgroup of the scaling coefficient of one scaling group of the equations (corresponding to one value of the scaling exponent). If the flow is invariant under two subgroups of scaling coefficients and, the spectrum becomes maximal, equal toR ₊. Finally, when a full symmetry, namely an invariance under a whole group, is assumed and the spectrum becomes continuous, the decaying law for the spectral density is derived and found to be independent of the specific value ofh These ideas are then applied to locally self-similar flows with multiple dilation centers (localized in space and time) and multiple scaling exponents, extending the concept of multifractals to space and time.     

Emission spectra and cross-section spectra of neodymium laser glasses

Amplified spontaneous emission spectra and light amplification spectra of some Nd³⁺:glass rods (silicate glass Schott LG680, phosphate glasses Schott LG760 and Hoya LHG5) are measured by pulsed flashlamp excitation. The spontaneous emission distribution, the stimulated emission cross-section spectra and the excited state absorption cross-section spectra are extracted. Excited state absorption prevents laser action around 1320 nm for the⁴F_3/2-⁴L_13/2 transition of Nd³⁺ in the investigated glasses.     

Antiproton annihilation spectra

Recent data on antiproton (antineutron) spectra from hydrogen, deuterium and nuclear targets are discussed. Special emphasis is given to rare or unusual channels and phenomena. Work supported in part by the Air Force Office of Scientific Research, Air Force Systems Command, USAF under grant AF05R87-0246 and U.S. National Science Foundation.     

Staggered ladder spectra

We exactly solve a Fokker-Planck equation by determining its eigenvalues and eigenfunctions: we construct nonlinear second-order differential operators which act as raising and lowering operators, generating ladder spectra for the odd- and even-parity states. The ladders are staggered: the odd-even separation differs from even-odd. The Fokker-Planck equation corresponds, in the limit of weak damping, to a generalized Ornstein-Uhlenbeck process where the random force depends upon position as well as time. The process describes damped stochastic acceleration, and exhibits anomalous diffusion at short times and a stationary non-Maxwellian momentum distribution.     

Synthetic infrared spectra

We have designed, microfabricated, and characterized a diffractive optical element that reproduces the infrared spectrum of HF from 3600 to 4300 cm(-1) . The reflection-mode diffractive optic consists of 4096 lines, each 4.5mum wide, at 16 discrete depths relative to the substrate from 0 to 1.2 mum and was fabricated upon a silicon wafer by anisotropic reactive ion-beam etching in a four-mask-level process. We envisage the use of diffractive optical elements of this type as the basis for a new class of miniaturized, remote chemical sensor systems based on correlation spectroscopy.     

Heterodyne spectra analysis

A complete explanation of heterodyne spectra is given here. The study of the folding effect has been carried out and the properties of heterodyne spectra are detailed. A fitting method using synthetic spectra is developed. Ozone heterodyne spectrum is taken as an example.     

抗癌新药安吖啶的近红外拉曼光谱及近红外表面增强拉曼光谱的研究

采用近红外表面增强拉曼光谱技术对抗癌新药安吖啶的结构进行了研究。     

Electronic spectra of parafluorobromobenzene

The electronic absorption spectrum of parafluorobromobenzene is reported together with its band shape and molecular geometry. The electronic transition is found to be the 2900–2400 Å system and the analysis consistent with other paraheterohalogenated benzenes. The intense bands, including 0–0, are double headed and areB-type in nature.A-type vibronic bands are also observed although less intense than theB-type bands. In all 9 excited states and 5 ground state fundamentals could be assigned.