Rotation-vibration analysis of the Coriolis-coupled ν5g, ν6g, ν8g and ν9 bands of H2CCO

Medium resolution infrared grating spectra of gaseous ketene, H₂CCO were recorded between 1000 and 400 cm^?1, both at instrument temperature (40°C) and with cooling (?40°C). Interferometric Fourier spectra were also measured at ?70°C with resolution 0.22 cm^?1 between 450 and 330 cm^?1. The K structure of the fundamentals ν₅, ν₆, ν₈, and ν₉ was assigned. These fundamentals are coupled by a-axis Coriolis interactions. These couplings were analysed on the symmetric top basis for setting up the perturbation matrix and by utilizing the K-dependent Coriolis shifts of levels. A preliminary analysis of the Coriolis intensity anomalies was also undertaken.Band center values from combination differences are $\text{ν}{}_5{}^0\text{= 587.30 (27)}$ and $\text{ν}{}_6{}^0\text{= 528.36 (39)}\text{cm}{}^{\mathrm{?1}}$. Synthetic spectra indicate the band origins of ν₈ and ν₉ to be close to 977.8 and 439.0 cm^?1, respectively. Estimates of Coriolis coupling constants obtained from synthetic spectra are $\text{ζ}{}_{58}{}^{\mathrm{a}}\text{= + 0.33 (5)}$, $\text{ζ}{}_{68}{}^{\mathrm{a}}\text{= + 0.714 (20)}$, $\text{ζ}{}_{59}{}^{\mathrm{a}}\text{= ? 0.774 (20)}$, and $\text{ζ}{}_{69}{}^{\mathrm{a}}\text{= ? 0.30 (2)}$. Approximate ratios of unperturbed vibrational transition moments obtained from spectral simulations are $\text{M}{}_8{}^0\text{:±iM}{}_5{}^0\text{:±iM}{}_6{}^0\text{:M}{}_9{}^0\text{≈ +2:?9:+10:+0.5}$.     

Vibrational spectra and force constants of symmetric tops: High resolution spectra of monoisotopic H3SiCl in the 2200-cm−1 region and rovibrational analysis of the ν1 and ν4 fundamentals

The gas phase infrared spectra of monoisotopic H₃Si³⁵Cl and H₃Si³⁷Cl have been studied in the $\text{ν}{}_1\text{ν}{}_4$ region near 2200 cm^?1 with a resolution of 0.012 and 0.04 cm^?1, respectively, and rotational fine structure for ΔJ = ±1 branches has been resolved. In addition, some information on ν₃ + ν₄ of H₃Si³⁵Cl near 2750 cm^?1 has been obtained. ν₁ and ν₄ are weakly coupled by Coriolis x, y resonance, $\text{B}\text{Ω}{}_{14}\text{ζ}{}_{14}\text{～ 2 × 10}{}^{\mathrm{?3}}\text{cm}{}^{\mathrm{?1}}$, only the upper states K′ = 2, l = 0 and K′ = 1, l = ?1 being substantially affected. Local perturbation due to rotational l(±1, ±1)-type resonance with ν₃ + ν₅⁺¹ + ν₆⁺¹ and ν₃ + ν₅⁺¹ + ν₆^?1 is revealed in the ΔK = +1 and ?1 branches, respectively. From a fit of the experimental line positions, standard deviations of 1.4 and 3.8 × 10^?3 cm^?1, respectively, to a model with five interacting levels conventional excited state parameters and interaction constants have been obtained. In $\text{H}{}_3\text{Si}{}^{35}\text{Cl}\text{H}{}_3\text{Si}{}^{37}\text{Cl}$ the fundamentals are ν₁, $\text{2201.94380(15)}\text{2201.9345(7)}$ and ν₄, $\text{2209.63862(8)}\text{2209.6254(2)}\text{cm}{}^{\mathrm{?1}}$, respectively. Q branches of the “hot” band (ν₃ + ν₄) ? ν₃ and of ν₄ of the ²⁹Si and ³⁰Si species have been detected.     

Coriolis intensity perturbations in the SO2 molecule: Experimental determination of the relative signs of (∂μ∂Qi)

The Coriolis interactions between ν₁ and ν₃, and between ν₂ and ν₃ in SO₂ have been analyzed to obtain the signs of the products $\text{ζ}{}_{3.1}{}^{\mathrm{c}}\text{(}\text{?μ}{}^{\mathrm{a}}\text{?Q}{}_3\text{)(}\text{?μ}{}^{\mathrm{b}}\text{?Q}{}_1\text{)}$ and $\text{ζ}{}_{3.2}{}^{\mathrm{c}}\text{(}\text{?μ}{}^{\mathrm{a}}\text{?Q}{}_3\text{)(}\text{?μ}{}^{\mathrm{b}}\text{?Q}{}_2\text{)}$. It has been found that both of the signs of these products are positive. Then, relative signs of ($\text{?μ}\text{?Q}{}_1$) have been determined using the calculated values of the Coriolis zeta constants for the present definition of the normal coordinates. The obtained sign combination of ($\text{?μ}\text{?Q}{}_{\mathrm{i}}$) is ±(+?+), which agrees with the one predicted by the molecular orbital calculations. Using the sign combination (+?+), the polar tensors of S and O atoms were also calculated.     

The Ã1B2-X̃1A1 two-photon fluorescence excitation spectrum of 1,3-difluorobenzene

The $\text{A}\text{?}{}^1\text{B}{}_2\text{-}\text{X}\text{?}{}^1\text{A}{}_1$ system of 1,3-difluorobenzene has been observed using the technique of two-photon fluorescence excitation obtained with a pulsed dye laser. Calibration was achieved by a combination of the neon optogalvanic spectrum and etalon fringes. In circular, compared to linear, polarization the bands divide into two groups, those which are B₂-A₁ and which retain their intensity with circular polarization, and those which are A₁-A₁ and lose about 60% of their intensity under the same conditions. These two kinds of bands also show characteristic rotational contours. All of the A₁-A₁ bands whose assignments are established obtain their intensity through vibronic interaction in which the vibration ν′₂₅ (ν′₁₄ in the Wilson numbering) mixes the $\text{A}\text{?}$ with, presumably, the $\text{X}\text{?}$ state. There is an important Fermi resonance between the 9¹ and 10¹11¹ levels. Parts of the one-photon absorption spectrum have been photographed to identify sequences associated with the 0₀⁰ band for comparison with those observed in the two-photon spectrum, and to search for bands involving odd quanta of b₂ vibrations, including ν′₂₅ (ν′₁₄); none was found.     

High-resolution infrared spectrum of the ν2 and ν8 bands of CH2D2

A high-resolution infrared spectrum of methane-d₂ has been measured in the C-D stretching band region (2025–2435 cm^?1). Rotational structures of the ν₂ and ν₈ bands have been assigned by use of the ASSIGN-diagram method, and the c-type Coriolis interaction between ν₂ and ν₈ has been analyzed. The band origins, ν₂ = 2203.22 ± 0.01 cm^?1 and ν₈ = 2234.70 ± 0.01 cm^?1, the rotational constants and the centrifugal distortion constants for the two bands, and the Coriolis coupling constant, $\text{∥;ξ}{}_{28}{}^{\mathrm{c}}\text{∥; = 0.182 ± 0.015}\text{cm}{}^{\mathrm{?1}}$, have been determined.     

Simultaneous analysis of the 2ν2, 2ν5, and ν2 + ν5 vibration-rotation bands of CH3Br

Previous studies of the parallel bands 2ν₂ and $\text{2ν}{}_5{}^0$ of CH₃Br by the two first authors have been completed by the analysis of the weaker perpendicular band ν₂ + ν₅, centered near 2745 cm^?1. It is well known that the v₂ = 1 and v₅ = 1 states of methylbromide are linked by an x-y-type Coriolis interaction. Therefore, in the 2500–2900-cm^?1 range, the levels

$\text{(v}{}_2\text{=2), (v}{}_5\text{2, l}{}_5\text{=0), (v}{}_5\text{=2, l}{}_5\text{±2), (v}{}_5\text{=v}{}_2\text{=1, l=5±1)}$

are linked by a similar interaction. Least-squares and prediction programs have been written to treat this kind of problems and they have been satisfactorily applied to both isotopic species, CH₃⁷⁹Br and CH₃⁸¹Br. A localized resonance in the K = 0 subband of ν₂ + ν₅ has been shown to be due to the 3ν₃ + ν₆ band. No evidence for a strong Fermi resonance between ν₁ and $\text{2ν}{}_5{}^0$ has been found.     

The 280-nm absorption system of benzoyl fluoride

Benzoyl fluoride exhibits a weak, discrete absorption system in the region 290 – 260 nm. Vibrational structure associated with the C₆H₅COF and C₆D₅COF isotopes has been analyzed in detail. The C₆H₅COF and C₆D₅COF origin bands lie at 35 685 and 35 829 cm^?1, respectively. The intensity in the spectrum is principally associated with two progressions, ν′₁₉, the breathing vibration of the benzene ring and ν′₂₄, a COF in-plane bend, and sequence bands involving the COF torsion motion ν₃₆. The $\text{C}{}_6\text{H}{}_5\text{COF}\text{C}{}_6\text{D}{}_5\text{COF}$ν₁₉, ν₂₄, and ν₃₆ vibrational frequencies are respectively 1005/-, $\text{376}\text{357}\text{,}\text{and}\text{57}\text{55}\text{cm}{}^{\mathrm{?1}}$ in the ground state and $\text{950}\text{919}\text{,}\text{348}\text{331}\text{,}\text{and}\text{89}\text{85}\text{cm}{}^{\mathrm{?1}}$ in the excited state. The barriers to rotation of the COF group are estimated from the torsional frequency data to be 1450 and 3450 cm^?1 in the ground and excited electronic states, respectively.     

Strengths and lorentz broadening coefficients for spectral lines in the ν3 and ν2 + ν4 bands of 12CH4 and 13CH4

Line strengths and self- and nitrogen-broadened half-widths were measured for spectral lines in the ν₃ and ν₂ + ν₄ bands of ¹²CH₄ and ¹³CH₄ from 2870–2883 cm^?1 using a tunable diode laser spectrometer. From measurements made over a temperature range from 215 to 297 K, on samples of ¹²CH₄ broadened with N₂, we deduced that the average temperature coefficients n, defined as $\text{b}{}_{\mathrm{<mtext>L</mtext>}}{}^0\text{(T) = b}{}_{\mathrm{<mtext>L</mtext>}}{}^0\text{(T}{}_0\text{)(}\text{T}\text{T}{}_0\text{)}{}^{\mathrm{?n}}$, of the Lorentz broadening coefficients for the ν₃ and ν₂ + ν₄ bands of ¹²CH₄ were 0.97 ± 0.03 and 0.89 ± 0.04, respectively. A smaller increase is observed in line half-width with increasing pressure for E-species lines, for both self- and nitrogen-broadening, than for other symmetry species lines over the range of pressures measured, 70 to 100 Torr.     

Neutral pion production by weak neutral currents in neutrino and antineutrino reactions

A study is presented of single π^o production in neutrino and antineutrino interactions in Gargamelle filled with freon CF₃Br. Limits on the neutral to charged current cross-section ratios $\text{R}{}_{\mathrm{v}}\text{=σ(v}\text{N}\text{→v}\text{N}\text{′π}{}^{\mathrm{o}}\text{)/2 σ(v}\text{N}\text{→ μ}{}^{\mathrm{-}}\text{N}\text{′π}{}^{\mathrm{o}}\text{)}$ and $\text{R}{}_{\mathrm{<mtext>\nu </mtext>}}\text{= σ(}\text{ν}\text{N}\text{→}\text{ν}\text{N}\text{′π}{}^{\mathrm{o}}\text{)/2 σ(}\text{ν}\text{N}\text{→ ω}{}^{\mathrm{+}}\text{N}\text{′π}{}^{\mathrm{o}}\text{)}$ are found to be $\text{0.10 < R}{}_{\mathrm{\nu }}\text{< 0.20}\text{and}\text{0.26 < R}{}_{\mathrm{<mtext>\nu </mtext>}}\text{< 0.44}$ at 68% confidence level.     

The electronic isotope shift in the A2Π-X2Σ+ bands of BeH,BeD and BeT

The 0-0, 1-1, 2-2, and 3-3 bands of the A²Π-X²Σ⁺ transition of the tritiated beryllium monohydride molecule have been observed at 5000 Å in emission using a beryllium hollow-cathode discharge in a He + T₂ mixture. The rotational analysis of these bands yields the following principal molecular constants.

$\text{A}{}^2\text{Π:}\text{B}{}_{\mathrm{e}}\text{= 4.192}\text{cm}{}^{\mathrm{?1}}\text{; r}{}_{\mathrm{e}}\text{= 1.333}\text{A}\text{?}$

$\text{X}{}^2\text{Σ:}\text{B}{}_{\mathrm{e}}\text{= 4.142}\text{cm}{}^{\mathrm{?1}}\text{; r}{}_{\mathrm{e}}\text{= 1.341}\text{A}\text{?}$

$\text{ω}{}_{\mathrm{e}}\text{′ ? ω}{}_{\mathrm{e}}\text{″ = 16.36}\text{cm}{}^{\mathrm{?1}}\text{; ω}{}_{\mathrm{e}}\text{′X}{}_{\mathrm{e}}\text{′ ? ω}{}_{\mathrm{e}}\text{″X}{}_{\mathrm{e}}\text{″ = 0.84}\text{cm}{}^{\mathrm{?1}}$

From the pure electronic energy difference (E_Π - E_Σ)_BeT = 20 037.91 ± 1.5 cm^?1 and the corresponding previously known values for BeH and BeD, the following electronic isotope shifts are derived

$\text{ΔE}{}_{\mathrm{e}}{}^{\mathrm{i}}\text{(}\text{BeH}\text{?}\text{BeT}\text{) = ?4.7 ≠ 1.5}\text{cm}{}^1\text{, ΔE}{}_{\mathrm{e}}{}^{\mathrm{i}}\text{(}\text{BeH}\text{?}\text{BeT}\text{) = ?1.8 ≠ 1.5}\text{cm}{}^1$

and related to the theoretical approach given by Bunker to the problem of the breakdown of the Born-Oppenheimer approximation.     

Limitation on scalar neutrino masses from Tau decay

The apparent absence of the decay $\text{τ →}\text{ν}{}_{\mathrm{\tau }}\text{ν}{}_{\mathrm{?}}{}^1\text{?,}\text{where}\text{? =}\text{e or}\text{μ}\text{and}\text{ν}{}_{\mathrm{i}}$ is the spin-zero supersymmetric partner of ν_i, implies that the $\text{ν}{}_{\mathrm{i}}$ masses are sufficiently large that the decay is suppressed (assuming the supersymmetric partners exist). We give the resulting limits, which depend on the mass of the W? (the supersymmetric partner of the W) which mediates the decay, and on whether one or both $\text{ν}$ is massive. These are the only experimental limits on $\text{ν}$ masses.     

The two-photon excitation spectrum of fluorobenzene vapor

The two-photon excitation spectrum of fluorobenzene vapor has been recorded in the region of the $\text{A}\text{?}{}^1\text{B}{}_2\text{←}\text{X}\text{?}{}^1\text{A}{}_1$ transition. The spectrum shows considerable rovibronic structure with the bulk of the intensity lying in the subsystem induced by the ν₁₄(b₂) vibration. Two types of rovibronic contours, arising from ΔK_a = ±1 and from ΔK_a = 0, ±2 transitions, are identified. Major features in these contours are assigned by comparison with synthetic spectra, calculated using known upper and lower state rotational constants. The intensity distribution among the various bands in progressions of the totally symmetric vibrations is considerably different from that in the one-photon absorption spectrum, and the possible reasons for this are discussed.     

The giant Gamow-Teller resonance states

The mean energy of the giant Gamow-Teller resonance state (GTS) is studied, which is defined by the non-energy-weighted and the linearly energy-weighted sum of the strengths for Σ^A_i = 1^τi?σⁱ? Using Bohr and Mottelson's hamiltonian with the ξl· σ force, the difference between the mean energies of GTS and the isobaric analog state (IAS) is expressed as$\text{E}{}_{\mathrm{GTS}}\text{?E}{}_{\mathrm{IAS}}\text{,≈ 2〈π¦Σ}{}^{\mathrm{A}}{}_{\mathrm{i}}\text{=1ξ}{}_{\mathrm{i}}\text{l}{}_{\mathrm{i}}\text{· σ}{}_{\mathrm{i}}\text{¦π〉/ (3T}{}_0\text{-4(k}{}_{\mathrm{\tau }}\text{?k}{}_{\mathrm{\sigma \tau }}\text{) T}{}_0$. The observed energy systematics is well explained by k_τ?k_{στ≈ 4/A MeV}. The relationship between the mean energies and the excitation energies of the collective states in the random phase approximation for charge-exchange excitations is discussed in a simple model. From the excitation energy systematics of GTS, the values of k_στ and the Migdal parameter g′ are estimated to be about $\text{k}{}_{\mathrm{\sigma \tau }}\text{=}\text{(16–24)}\text{A}\text{MeV and}\text{g′ = 0.49–0.72}$, respectively.     

Analysis of the (ν1 + ν2) and (ν2 + ν3) combination bands of ozone

The fine structures of the (ν₁ + ν₂) and (ν₂ + ν₃) combination bands of ozone in the 5.7-μm region have been recorded and analyzed. The two vibrational states are coupled through Coriolis and second-order distortion terms. The interaction has been treated by the numerical diagonalization of the secular determinant for the two coupled states. With the centrifugal distortion parameters fixed to the ground state values, the following constants have been obtained: ν₁ + ν₂ = 1796.26₆, A₁₁₀ = 3.610₄, B₁₁₀ = 0.4414₅, $\text{C}{}^1{}_{110}\text{= 0.3902}{}_9$, ν₂ + ν₃ = 1726.52₆, A₀₁₁ = 3.553₇, B₀₁₁ = 0.4398₂, $\text{C}{}^1{}_{011}\text{= 0.3884}{}_4$, Y₁₃ = ?0.46₆, and X₁₃ = ?0.01₀ cm^?1. In addition, the following anharmonic constants have been obtained: x₁₂ = ?7.82₁ and x₂₃ = ?16.49₄ cm^?1. The value of the dipole moment ratio, $\text{R =}\text{〈011|μ}{}_{\mathrm{z}}\text{|0〉}\text{〈110|μ}{}_{\mathrm{x}}\text{|0〉}$, is 1.30 ± 0.10.     

The A′(3Π2) state of ICl

Although $\text{A′(}{}^3\text{Π}{}_2\text{) ← X(}{}^1\text{Σ}{}^{\mathrm{+}}\text{)}$ is forbidden in near case c molecules the A′ ← X transition can be efficiently accomplished by the three-step sequence $\text{A′(}{}^3\text{Π}{}_2\text{) ← D′(2) ← A(}{}^3\text{Π}{}_1\text{) ← X(}{}^1\text{Σ}{}^{\mathrm{+}}\text{)}$. Transitions to a range of levels of A′, v_A′ = 2–38, have been recorded by this means, using J-selective polarization-labeling spectroscopy. Principal constants of the A′ state of I³⁵Cl are T_e = 12682.05, ω_e = 224.57, ω_eχ_e = 1.882, ω_ey_e = ?0.0107, B_e = 0.08653, and α_e = 0.000675 cm^?1. The A′ state is therefore similar in its physical characteristics to two other (relatively) deep states, $\text{A(}{}^3\text{Π}{}_1\text{)}$ and $\text{B(}{}^3\text{Π}{}_0\text{+)}$, of the 2431 configuration.     

Analysis of the Raman spectrum of SF6

The Raman active fundamentals ν₁(A1g), ν₂(Eg), ν₅(F2g), and the overtone 2ν₆ of SF₆ have been investigated with a higher resolution and the band origins were estimated to be: ν₁ = 774.53 cm^?1, ν₂ = 643.35 cm^?1, ν₅ = 523.5 cm^?1, and 2ν₆ = 693.8 cm^?1. Raman and infrared data have been combined for estimation of several anharmonicity constants. The ν₆ fundamental frequency is calculated as 347.0 cm^?1. From the analysis of the ν₂ Raman band, the following rotational constants of both the ground and upper states have been calculated:

$\text{B}{}_0\text{= 0.09111 ± 0.00005}\text{cm}{}^{\mathrm{?1}}\text{; D}{}_0\text{= (0.16±0.08)10}{}^{\mathrm{?7}}\text{cm}{}^{\mathrm{?1}}$

;

$\text{B}{}_2\text{= 0.09116 ± 0.00005}\text{cm}{}^{\mathrm{?1}}\text{; D}{}_2\text{= (0.18±0.04)10}{}^{\mathrm{?7}}\text{cm}{}^{\mathrm{?1}}$

.     

Infrared spectrum of acetonitrile: Analysis of Coriolis resonance

The Coriolis resonance between ν₄ and ν₇ in CH₃CN and between ν₁ and ν₅, ν₃ and ν₆, and ν₄ and ν₇ in CD₃CN has been analyzed, applying the technique developed by DiLauro and Mills, to obtain the signs of [$\text{ζ}{}_{\mathrm{r,sa}}{}^{\mathrm{y}}\text{(}\text{?p}\text{?Q}{}_{\mathrm{r}}\text{)(}\text{?p}\text{?Q}{}_{\mathrm{sa}}\text{)}$] and the ratio of $\text{?μ}\text{?Q}{}_{\mathrm{r}}$ to $\text{?μ}\text{?Q}{}_{\mathrm{s}}$ for the interacting pairs in CD₃CN. For (ν₄, ν₇) in both CH₃CN and CD₃CN, the sign of [$\text{ζ}{}_{\mathrm{r,sa}}{}^{\mathrm{y}}\text{(}\text{?p}\text{?Q}{}_{\mathrm{r}}\text{)(}\text{?p}\text{?Q}{}_{\mathrm{sa}}\text{)}$] is found to be negative as it is also for (ν₁, ν₅) in CD₃CN. For (ν₃, ν₆) the sign of this interaction term is found to be positive. For a given definition of normal coordinates the signs of these interaction terms give the relative signs of $\text{?p}\text{?Q}{}_{\mathrm{r}}$ and $\text{?p}\text{?Q}{}_{\mathrm{sa}}$; our study also gives approximate values for the corresponding ratio [$\text{(}\text{?p}\text{?Q}{}_{\mathrm{r}}\text{)}\text{(}\text{?p}\text{?Q}{}_{\mathrm{sa}}\text{)}$]     

Second-order Coriolis resonance between ν2 and ν5 of CH3F by microwave spectroscopy

The J = 1 ← 0 and J = 2 ← 1 transitions and the l-doubling transitions of J = 2 – 6 of ¹²CH₃F in the ν₂ and ν₅ states were analyzed by taking into account the Coriolis interaction between the two modes. The molecular constants which are derived are: ν₅ - ν₂, 252 412 ± 112; $\text{B}{}_5{}^1$, 25 611.60 ± 0.40; A_ζ5, ?38 772 ± 116; $\text{B}{}_2{}^1$, 25 432.52 ± 0.33; D, 21 838.4 ± 8.2; $\text{q}{}_5{}^1$, 39.58 ± 0.30 MHz; in addition to a few other minor constants. The present result is completely consistent with the recent Raman data of Escribano, Mills, and Brodersen, J. Mol. Spectrosc.61, 249 (1976). Molecular constants in the ν₃ and ν₆ states have also been obtained: B₃, 25 197.570 ± 0.020; B₆, 25 418.917 ± 0.047; A_ζ6ηJ, ?0.562 ± 0.030; |q₆|, 8.70 ± 0.13 MHz. Errors are 2.5 times the standard deviations.     

The 352 nm emission spectrum of difluorodiazirine

Difluorodiazirine fluoresces strongly in the vapor phase showing an extensive band system from about 352 to 451 nm and with no background continuum. The fluorescence is assigned as $\text{A}\text{?}{}^1\text{B}{}_1\text{(nπ}{}^1\text{)-}\text{X}\text{?}{}^1\text{A}{}_1$ and corresponds to the 352 nm absorption system previously studied.The band system is dominated by a progression in ν₁″, the a₁N = N stretching vibration, with ν₄″, the a₁ CF₂ symmetrical deformation vibration, showing a shorter progression.The 0₀⁰ and most others show type B rotational contours but type C bands, involving ν₅″ (a₂), and probably type A bands, involving ν₇″ (b₁) and perhaps ν₆″ (b₁) are also observed.The extremely low intensity of bands involving ν₃″ (a₁) is surprising but there seems to be no reason to doubt the assignment from infrared and Raman data.There is a strong vibrational perturbation affecting some quite strong bands in a region within about 275 cm^?1 of bands 1_n⁰4₀⁰, where n = 0 – 3. The cause of the perturbation is not known.There is no evidence for the emission spectrum consisting of more than one band system.     

The bending vibration bands ν4 and ν5 of HCCI

The bending vibration bands ν₄ and ν₅ of HCCI were studied. From the observed rotational structure the rotational constant B₀ and the centrifugal distortion constant D₀ were obtained. The results were B₀ = 0.105968(7) cm^?1 and D₀ = 1.96(7) × 10^?8 cm^?1 from ν₄ and B₀ = 0.105948(8) cm^?1 and D₀ = 1.96(11) × 10^?8 cm^?1 from ν₅. The structure of the hot bands 2ν₅(Δ) ← ν₅(Π) and 3ν₅(φ) ← 2ν₅(Δ) was also resolved and hence the values α₅ = ?3.033(8) × 10^?4 cm^?1 and q₅ = 9.3(3) × 10^?5 cm^?1 could be derived. The other most intense hot bands following ν₅ could be explained in terms of the Fermi diads $\text{ν}{}_3\text{2ν}{}_5{}^0$ and $\text{ν}{}_3\text{+}\text{ν}{}_5{}^{\mathrm{\pm 1}}\text{3ν}{}_5{}^{\mathrm{\pm 1}}$. Of the numerous hot bands accompanying ν₄, only those between different excited states of ν₄ could be assigned. Then estimates for α₄ and q₄ were also obtained. In addition, several vibrational constants were derived.