Infrared-radio frequency double resonance observations of pure rotational Q-branch transitions of methane

The $\text{F}{}_2{}^{\mathrm{(2)}}\text{← F}{}_1{}^{\mathrm{(2)}}$ and $\text{F}{}_2{}^{\mathrm{(2)}}\text{← F}{}_1{}^{\mathrm{(1)}}$ transitions of the J = 7 levels of the ground state of CH₄ have been observed by infrared-radio frequency double resonance using the 3.39 μ HeNe laser line. The transition frequencies are 423.02 ± 0.02 MHz and 1246.55 ± 0.02 MHz, respectively. Using these frequencies and the splitting of the E and F₂ levels of the J = 2 state calculated from the molecular beam magnetic resonance spectra of Ozier, the centrifugal distortion constants are derived to be D_t = 132933 ± 10 Hz, H_4t = ? 16.65 ± 0.2 Hz, and H_6t = 10 ± 1 Hz. The J = 15 E⁽¹⁾ → E⁽²⁾ microwave transition is predicted as 14150 ± 9 MHz.     

Observed and calculated interactions between valence states of the NO molecule

No perturbation between two valence states of NO has ever been identified, although many valence-Rydberg and several Rydberg-Rydberg perturbations have been extensively studied. The first valence-valence crossing to be experimentally documented for NO is reported here and occurs between the ¹⁵N¹⁸O B²Π (v = 18) and B′²Δ (v = 1) levels. No level shifts larger than the detection limit of 0.1 cm^?1 are observed at the crossings near $\text{J = 6.5 [B}{}^2\text{Π}\text{(F}{}_1\text{) ～ B′}{}^2\text{Δ}\text{(F}{}_2\text{)]}$ and $\text{J = 12.5 [B}{}^2\text{Π}\text{(F}{}_1\text{) ～ B′}{}^2\text{Δ}\text{(F}{}_1\text{)]}$; two crossings involving higher rotational levels could not be examined. Semi-empirical calculations of spin-orbit and Coriolis perturbation matrix elements indicate that although the electronic part of the $\text{B}{}^2\text{Π}\text{～ B′}{}^2\text{Δ}$ interaction is large, a small vibrational factor renders the ¹⁵N¹⁸O B (v = 18) ? B′ (v = 1) perturbation unobservable. Semi-empirical estimates are given for all perturbation matrix elements of the operators $\text{Σ}{}_{\mathrm{i}}\text{a}\text{?}{}_{\mathrm{i}}\text{l}{}_{\mathrm{i}}\text{·s}{}_{\mathrm{i}}$ and $\text{B(L}{}_{\mathrm{\pm }}\text{S}{}_{\mathrm{?}}\text{? J}{}_{\mathrm{\pm }}\text{L}{}_{\mathrm{?}}\text{)}$ which connect states belonging to the configurations $\text{(σ2p)}{}^2\text{(π2p)}{}^4\text{(π}{}^1\text{2p)}$, $\text{(σ2p)(π2p)}{}^4\text{(π}{}^1\text{2p)}{}^2$, and $\text{(σ2p)}{}^2\text{(π2p)}{}^3\text{(π}{}^1\text{2p)}{}^2$.     

Study of the three-proton three-neutron-hole nucleus 208At

Levels in ²⁰⁸At were populated in the ²⁰⁹Bi(α, 5n) reaction, and the subsequent radiation was studied using γ-spectroscopic methods including γ-ray excitation function and angular distribution, γγ(t) coincidence and γt measurements, as well as measurements of conversion electrons. The excited spectrum of ²⁰⁸At is found to consist of two almost disconnected parts which are proposed to originate from seniority-three proton and neutron cascades. Two isometric states are observed. A $\text{T}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{= 45 ± 2}\text{ns}$ state at 1090 keV is proposed to have the main configuration and J^π = 10^?. A high-spin isomer with $\text{T}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{= 1.5 ± 0.2 μs at 2276}\text{keV}$ is assigned to be the state. Shell-model arguments are used to assign configurations to most of the observed levels. Transition rates are discussed.     

Désintégration β− de 30Al

Gamma rays following the β^? decay of ³⁰Al have been investigated with a Ge(Li) detector. The ³⁰A1 sources were produced by fast neutron bombardment of an enriched ³⁰Si sample. Evidence for two previously unreported β^? branches has been deduced. The existence of allowed β^? transitions to J^π = 2⁺and 3⁺ states and to the J^π = 4⁺ level at 5.95 MeV determines $\text{J}{}^{\mathrm{\pi }}\text{= 3}{}^{\mathrm{+}}$ for the ³⁰Al ground state $\text{(T}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{= 3.56 ± 0.02 s)}$. These results are compared to a recent shell-model calculation.     

Spin-parity analysis of the nπ+ system produced in the reaction π+p → π+π+n at 16GeV/c

A spin-parity analysis of the nπ⁺ system produced in the reaction π⁺p → π⁺π⁺n at 16 MeV/c has shown apart from the mass enhancements associated with the known resonances Δ⁺(1238), N¹(1520) and N¹(1688) there is an enhancement peaked at M(nπ⁺) ? 1.35 GeV, ∑0.2 GeV wide. For masses below M(nπ⁺) ? 1.35 GeV this enhancement is predominantly due to $\text{J}{}^{\mathrm{P}}\text{=}\text{1}\text{2}{}^{\mathrm{?}}$ states, predominate. The presence of $\text{J}{}^{\mathrm{P}}\text{=}\text{1}\text{2}{}^{\mathrm{?}}$ states indicates that the rule ΔP = (?1)^ΔJ is strongly violated in the diffractive process N → Nπ, and hence it cannot be considered a specific characteristic of all diffractive processes.     

A determination of the spin of the hypernucleus 12ΛB: (II). A complete analysis

The probability distribution calculated for the decay sequence ${}^{12}{}_{\mathrm{\Lambda }}\text{B(g.s.) →}{}^{12}\text{C}{}^1\text{π}{}^{\mathrm{?}}\text{→ αααπ}{}^{\mathrm{?}}$ passing through the (J^P_N) = (2⁺, 1) intermediate state ¹²C¹ (16.11 MeV) is cast in a symmetrical form and used to calculate the likelihood for $\text{J = 1}\text{relative to}\text{J = 2}\text{for}{}^{12}{}_{\mathrm{\Lambda }}\text{B(g.s.}\text{)}$ on the basis of the 85 examples available for this decay process. This procedure has optimum sensitivity, is free from the uncertainties of the comparisons previously made using only projected angular distributions, and strongly indicates that J^P = 1^? holds for ¹²_ΛB(g.s.). An appendix points out that all the data for the decay sequence passing through the (J^P_N, T) = (1⁺, 0) level of ¹²C¹ is well fitted for J = 1 if the J = 1 → J_n = 1 transition amplitude a_s1 takes a value in the range a_s1/s = 0.08 to 0.09.     

Centrifugal distortion effects in the microwave spectrum of methylene cyanide

The rotational spectrum of methylene cyanide has been measured up to J = 62 and a total of 82 b-type transitions have been obtained. These data have been analyzed with a semirigid rotor Hamiltonian to give accurate rotational and centrifugal distortion constants. The rotational constants are (in MHz) $\text{A}$ = 20882.7537 ≠ 0.017, $\text{B}$ = 2942.3003. ≠ 0.0031, $\text{C}$ = 2616.7225 ≠ 0.0031 The quartic centrifugal distortion constants are (in MHz)

$\text{Δ}{}_{\mathrm{J}}\text{(1.855455 ≠ 0.014) x 10}{}^{\mathrm{?3}}\text{Δ}{}_{\mathrm{JK}}\text{= (?6.79218 ≠ 0.027) x 10}{}^{\mathrm{?2}}$

$\text{Δ}{}_{\mathrm{K}}\text{(8.621628 ≠ 0.013) x 10}{}^{\mathrm{?1}}\text{δ}{}_{\mathrm{J}}\text{= (4.892607 ≠ 0.016) x 10}{}^{\mathrm{?4}}$

$\text{δ}{}_{\mathrm{K}}\text{= (6.7501 ≠ 0.29) x 10}{}^{\mathrm{?3}}$

The uncertainties are twice the standard deviations in the constants obtained from the least squares analysis, and represent approximately 95% confidence limits.     

Ground-state properties of 3h 184Ir and 14h 185Ir

The ground-state spectroscopic quadrupole moments of ${}^{184}\text{Ir [J}{}^{\mathrm{\pi }}\text{=(5}{}^{\mathrm{\pm }}\text{);t}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{=3.00]}$ and ${}^{185}\text{Ir (J}{}^{\mathrm{\pi }}\text{=}\text{5}\text{2}{}^{\mathrm{?}}\text{;t}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{= 14}\text{h}\text{)}$ have been determined by nuclear orientation as +2.2(4) b and ?2.03(3) b, respectively. The negative QM of ¹⁸⁵Ir can be explained only by a $\text{J}{}^{\mathrm{\pi }}\text{K=}\text{5}\text{2}{}^{\mathrm{?}}\text{1}\text{2}$ ground-state configuration. The positive QM of ¹⁸⁴Ir implies K ? 4 in contradiction to expectations of K=0, 1 in analogy to ¹⁸⁶Ir.     

“Forbidden” rotational spectra of symmetric-top molecules: PH3 and PD3

A millimeter-wave spectrometer having a sensitivity of 4 × 10^?10 cm^?1 in the 2-mm region has been constructed for observation of extremely weak millimeter-wave spectra of gases. It has been used to measure J → J, K = 0 ← 3 transitions in PH₃ and J → J, K = 0 ← 3 as well as K = ±1 ← ±4 transitions in PD₃. The B₀ and C₀ spectral constants (in MHz) are: for PH₃, B₀ = 133 480.15 ± 0.12 and C₀ = 117 488.85 ± 0.16; for PD₃, B₀ = 69 471.10 ± 0.03 and C₀ = 58 974.37 ± 0.05. The effective ground-state values obtained for the bond angle and bond length are: for PH₃, $\text{r}{}_0\text{(}\text{A}\text{?}\text{) = 1.420}{}_0$ and $\text{α}{}_0\text{(}{}^{\mathrm{o}}\text{) = 93.34}{}_5$; for PD₃, $\text{r}{}_0\text{(}\text{A}\text{?}\text{) = 1.417}{}_6$ and $\text{α}{}_0\text{(}{}^{\mathrm{o}}\text{) = 93.35}{}_9$. The corresponding zero-point-average values were calculated to be: for PH₃, $\text{r}{}_{\mathrm{z}}\text{(}\text{A}\text{?}\text{) = 1.4269}{}_9\text{± 0.0002}$ and $\text{α}{}_{\mathrm{z}}\text{(}{}^{\mathrm{o}}\text{) = 93.228}{}_7$; for PD₃, $\text{r}{}_{\mathrm{z}}\text{(}\text{A}\text{?}\text{) = 1.4226}{}_5\text{± 0.0001}$ and $\text{α}{}_{\mathrm{z}}\text{(}{}^{\mathrm{o}}\text{) = 93.256}{}_7\text{± 0.004}$. For both species, the equilibrium values are $\text{r}{}_{\mathrm{e}}\text{(}\text{A}\text{?}\text{) = 1.4115}{}_9\text{± 0.0006}$ and $\text{α}{}_{\mathrm{e}}\text{(}{}^{\mathrm{o}}\text{) = 93.32}{}_8\text{± 0.02}$.     

Lifetime and g-factor results for the 132− 1985 keV level in 91Nb and the 152− 2288 keV level in 91Zr

Lifetime and g-factor measurements have been made with pulsed beam-γ time-differential techniques using the ⁸⁹Y(α, 2n)⁹¹Nb and ⁸⁸Sr(α, n)⁹¹Zr reactions. A mean lifetime τ = 14.4 ± 0.5 nsec and a g-factor of 1.26 ± 0.04 were obtained for the $\text{13}\text{2}{}^{\mathrm{?}}$ 1985 keV level in ⁹¹Nb and τ = 41.9 ± 1.2 nsec and g = 0.70 ± 0.01 were obtained for the $\text{15}\text{2}{}^{\mathrm{?}}$ 2288 keV level in ⁹¹Zr. These results are compared to theoretical calculations for $\text{(π}\text{g}{}_{\mathrm{<mtext>9</mtext><mtext>2</mtext>}}\text{)}{}^2\text{(π}\text{p}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{)}$ and $\text{(π}\text{g}{}_{\mathrm{<mtext>9</mtext><mtext>2</mtext>}}\text{)(π}\text{p}\text{1}\text{2}\text{)(v}\text{d}{}_{\mathrm{<mtext>5</mtext><mtext>2</mtext>}}\text{)}$ configurations in ⁹¹Nb and ⁹¹Zr, respectively.     

Nuclear magnetic moment of the 9.7 h 12− isomer 196mAu

The magnetic hyperfine splitting v_M=|gμ_NB_HF/h| of ^196mAu (j^π=12^?; configuration ¦(π$\text{11}\text{2}$($\text{v}\text{13}\text{2}{}^{\mathrm{+}}\text{)〉}{}_{12}{}^{\mathrm{?}}$; $\text{T}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{= 9.7}\text{h}\text{)}$ as dilute impurity in Ni has been determined with nuclear magnetic resonance on oriented nuclei as 96.0(2) MHz. With the known hyperfine field B_HF = ?264.4(3.9) kG corrected for hyperfine anomalies the g-factor and magnetic moment of ^196mAu are deduced to be |g| = 0.476(7) and |μ| = 5.72(8) μ_N. Taking into account the known magnetic properties of $\text{π}\text{1}\text{2}{}^{\mathrm{?}}$ and $\text{v}\text{13}\text{2}{}^{\mathrm{+}}$ isomeric states in the neighbouring odd Pt, Au and Hg nuclei the structure of the 12^? state is discussed.     

Microwave measurements and calculations of quadrupole coupling effects in CH3I and CD3I

The transitions J = 1 ← 0, K = 0; J = 2 ← 1, K = 0; and J = 2 ← 1, K = 1 of CH₃I and CD₃I were measured using a Stark-modulated microwave spectrometer. Iodine quadrupole coupling strengths were analyzed to determine variations with deuterium substitution on the methyl group and variations with centrifugal distortion. Quadrupole coupling strengths were described by the expression $\text{eQq}{}_0\text{+ aJ(J + 1) + bK}{}^2\text{+}\text{cK}{}^4\text{J(J + 1)}$. Explicit expressions are given for a, b, and c for a symmetric top in terms of molecular parameters. For CH₃I eQq₀ = ?1934.11 ± 0.02 MHz and for CD₃I eQq₀ = ?1928.95 ± 0.04 MHz. Rotational constants obtained are B(CH₃I) = 7501.274 ± 0.002 MHz and B(CD₃I) = 6040.298 ± 0.007 MHz. The observed fractional change in halogen quadrupole coupling of 0.0027 is related to previous results for methyl chloride and methyl bromide.     

Multiplicity distributions and double-scattering effects in π−d interactions at 360 GeV/c

Double-scattering effects are studied in π^?d interactions at 360 GeV/c. The partial cross sections $\text{σ}{}_{\mathrm{<mtext>N</mtext>}}\text{(π}{}^{\mathrm{?}}\text{d}\text{), σ}{}_{\mathrm{<mtext>N</mtext>}}\text{(“π}{}^{\mathrm{?}}\text{p}\text{”)}\text{and}\text{σ}{}_{\mathrm{<mtext>N</mtext>}}\text{(“π}{}^{\mathrm{?}}\text{n}\text{”)}$ are presented. The double-scattering probability per πd collision is found to be $\text{? = 0.15 ± 0.02}$. We have extracted the partial cross section X_N of the double-scattering plus interference contributions, and find that X_N obeys KNO scaling. The data are compared with various theoretical predictions.     

Hyperfine structure of CH3OH

Hyperfine structure of the (0, 0, 1) - (1, 0, 1) transition of methanol has been investigated by beam absorption and of the (J, 1, 3?) → (J, 1, 3+) transitions for J = 2, 3, and 6 by beam-maser spectroscopy. The best-fit results for the spin-rotation and spin-spin coupling constants $\text{C}{}_{\mathrm{JK\tau \pm }}{}^{\mathrm{(i)}}$ and $\text{D}{}_{\mathrm{JK\tau \pm }}{}^{\mathrm{(i)}}$, respectively, are in kHz¹: $\text{C}{}_{101}{}^{\mathrm{(1)}}\text{= 2.4(10)}$, $\text{C}{}_{101}{}^{\mathrm{(2)}}\text{= ?0.6(10)}$, $\text{D}{}_{101}{}^{\mathrm{(1)}}\text{= ?13.8(9)}$, $\text{D}{}_{101}{}^{\mathrm{(2)}}\text{= 7.0(9)}$, $\text{C}{}_{\mathrm{213?}}{}^{\mathrm{(1)}}\text{= ?5.0(10)}$, $\text{C}{}_{\mathrm{213?}}{}^{\mathrm{(2)}}\text{= ?5.5(10)}$ and ($\text{C}{}_{\mathrm{J13?}}{}^{\mathrm{(2)}}\text{- C}{}_{\mathrm{J13+}}{}^{\mathrm{(2)}}\text{) = 0.98(9)}$.     

Lifetimes and g-factors of the 6− and 7− isomers in 66Ga and 68Ga

The 6^? and 7^? isomeric states in ⁶⁶Ga and ⁶⁸Ga at 1440.9 and 1229.6 keV, respectively, have been populated with the (¹³C, 2np) and (¹⁵N, n2p) reactions on natural Fe. The half-lives of these states have been measured to be $\text{T}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{(6}{}^{\mathrm{?}}\text{,}{}^{66}\text{Ga}\text{) = 57.3 ± 1.2}\text{ns}$ and $\text{T}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{(7}{}^{\mathrm{?}}\text{,}{}^{68}\text{Ga}\text{) = 64 ± 2}\text{ns}$. Using previous data on the hyperfine field of Ga in Fe, the g-factors of these states have been determined by means of the TDPAD method. The results are $\text{g(6}{}^{\mathrm{?}}\text{,}{}^{66}\text{Ga}\text{) = 0.129 ± 0.003}$ and $\text{g(7}{}^{\mathrm{?}}\text{,}{}^{68}\text{Ga}\text{) = 0.105 ± 0.003}$. These values are in very good agreement with the independent particle model if one assumes the and configurations and uses the empirical proton and neutron g-factors from odd-A neighboring nuclei instead of the Schmidt values. The large disagreements with experiment when Schmidt values are used show that core polarization effects are important in these nuclei.     

Inclusive π electroproduction in the deep inelastic region

Using 20.5 GeV electrons on protons, we measured inclusive π⁰'s (of transverse momentum, p_T, from 0 to 1.4 GeV/c) produced by virtual photons of energy, ν, from 4 to 16.5 GeV and four-momentum squared, q², from ?1.8 to ?8.5 (GeV/c)². Comparing with charged pion data, we find , supporting the quark model. Photon knockout of a quark is favored as the interpretation of these data because of scaling in z = E_π/ν and similarity in z-dependence of other pion production data. Consistent with this interpretation are the dependence of 〈p_T〉 on q², the azimuthal dependence, and fits to the constituent interchange model. We also observe a possible p_T^?4 dependence at large |q²| over a limited p_T range.     

Temperature and pressure dependence of the elastic property of GeS2 glass

The sound velocities in GeS₂ glass have been measured by means of ultrasonic interferometry as a function of temperature or pressure up to 1.8 kbar. The bulk modulus K_s = 117.6 kbar and shear modulus G = 60.60 kbar were obtained for GeS₂ glass at 15°C and 1 atm. The temperature derivatives of both sound velocities and elastic moduli are negative :

$\text{(}\text{?ν}{}_1\text{?T}\text{)}$

_p =

$\text{?1.54 × 10}{}^{\mathrm{?4}}\text{km}\text{sec}$

°C,

$\text{(}\text{?ν}{}_1\text{?T}\text{)}$

_p =

$\text{?1.27× 10}{}^{\mathrm{?4}}\text{km}\text{sec}$

°C and

$\text{(}\text{?K}{}_{\mathrm{s}}\text{?T}\text{)}$

_p =

$\text{?1.27 × 10}{}^{\mathrm{?2}}\text{kbar}\text{°C}$

,

$\text{(}\text{?G}\text{?T}\text{)}$

_p = ?1.23 × 10^?2 kbar/°C,

$\text{(}\text{?Y}\text{?T}\text{)}$

_p = ?2.93 × 10^?2 their pressure derivatives are positive:

$\text{(}\text{?ν}{}_1\text{?P}\text{)}$

_T = 4.43× 10^?2km/kbar,

$\text{(}\text{?ν}{}_1\text{?P}\text{)}$

_T =

$\text{0.633 × 10}{}^{\mathrm{?2}}\text{km}\text{kbar}$

and (?K_s?P0)_T=6.81,

$\text{(}\text{?G}\text{?P)}{}_{\mathrm{T}}$

= 1.03, (?Y?T_T= 3.57. The Grüneisen parameter, γ_th= 0.298, and the second Grüneisen parameter, δ_s = 3.27, have also been calculated from these data. The elastic behavior of GeS₂ glass has proved to be normal despite the structural similarity among the tetrahedrally coordinated SiO₂, GeO₂ and GeS₂ glasses.     

Observation of interference between Iu=12 and Iu=32 baryon exchange amplitudes in 4 GeV/c backward inelastic scattering

Interference between the $\text{I}{}_{\mathrm{<mtext>u</mtext>}}\text{=}\text{1}\text{2}$ and $\text{I}{}_{\mathrm{<mtext>u</mtext>}}\text{=}\text{3}\text{2}$ baryon exchange amplitudes is observed in the reaction π^?p → pπ^?π⁰, with the proton produced forward with $\text{cos}\text{θ}{}_{\mathrm{p}}{}^1\text{>0.8}$. The Dalitz plot shows that the reaction is dominated by the quasi two body final states ρ^?p(δ exchange) and $\text{N}{}^{10}\text{(1670)π}{}^0\text{(}\text{N exchange}\text{)}$, with δ(1238), N¹(1520) and higher mass N¹'s also produced. The relative phase between the ρ and the N¹(1670) production amplitudes is measured to be 135° ± 10° and is compared with the Regge pole signature factor phase predictions.     

The 85Rb(p,d)84Rb reaction

The spectrum seen in single neutron pickup leading to the doubly odd nucleus ⁸⁴Rb is remarkably clean, with only five levels populated by l = 4 and six by l = 1 transitions. A simple 2J+1 weighting for the l = 4 data, combined with previous information on ⁸⁴Rb, allowed the J^π = 2^?–7^? states of the ($\text{v}\text{g}{}_{\mathrm{<mtext>9</mtext><mtext>2</mtext>}}{}^{\mathrm{?3}}\text{? π}\text{f}{}_{\mathrm{<mtext>5</mtext><mtext>2</mtext>}}{}^{\mathrm{?3}}$) multiplet to be identified. These data are used to determine the two-hole $\text{π}\text{f}{}_{\mathrm{<mtext>5</mtext><mtext>2</mtext>}}{}^{\mathrm{?1}}\text{-v}\text{g}{}_{\mathrm{<mtext>9</mtext><mtext>2</mtext>}}{}^{\mathrm{?}}$ interaction matrix elements.     

Critical spin relaxation in GdCl3

In the critical region of the insulating, uniaxial ferromagnet GdCl₃ the real part of the uniform susceptibility χ(q = 0, ω; T) has been measured by means of a frequency counting method in the ranges $\text{1.7 MHz ?}\text{ω}\text{2π}\text{? 720 MHz, 0.003 ? (}\text{T}\text{T}{}_{\mathrm{c}}\text{? 1 ≡ ?) ? 0.5}$. Parallel to the easy direction at all temperatures, χ′(ω) has a lorentzian shape, its amplitude being equal to the static susceptibility, χ_T. The half-widths τ^?1 exhibit s critical slowing down: above ?_c = 0.03 they are proportional to χ^?1_T, while at ?_c a change-over to $\text{τ}{}^{\mathrm{?1}}\text{∝ χ}{}^{\mathrm{<mtext>?</mtext><mtext>1</mtext><mtext>2</mtext>}}{}_{\mathrm{T}}$ occurs, the origin of which is uncertain.