E.P.R. evidence for the structuring effect of alcohol in water

A computational scheme for frequency-dependent polarizabilities of open-shell systems by coupled Hartree-Fock perturbation theory is presented. It allows the simultaneous approximate prediction of the involved electronic transition energies and can trivially be extended to imaginary values of the frequency. As a simple application, the dipole polarizability and some related properties of Li atoms are evaluated, the agreement with previous estimates being excellent.     

FREE VIBRATION OF LAMINATED SPHERICAL PANELS WITH RANDOM MATERIAL PROPERTIES

Randomness in the material properties is inherent in all engineering materials. Composites exhibit a greater scatter compared to conventional materials because of the larger number of parameters associated with its fabrication and manufacturing. For accurate prediction of its behavior, the composite material properties have been modelled as random variables in the present study. Higher order shear deformation theory including rotatory inertia effects has been employed in developing the system equations and first order perturbation technique has been adopted for the solution. An approach has been presented for obtaining the analytical solution for generalized eigenvalue problem associated with free vibrations. Mean and variance of the natural frequency have been obtained for cross-ply spherical laminates projected in rectangular plan form with different boundary conditions.     

Invariant exchange perturbation theory for multicenter systems and its application to the calculation of magnetic chains in manganites

The formalism of exchange perturbation theory is presented with regard to the general principles of constructing an antisymmetric vector with the use of the Young diagrams and tableaux in which the coordinate and spin parts are not separated. The form of the energy and wave function corrections coincides with earlier obtained expressions, which are reduced in the present paper to a simpler form of a symmetry-adapted perturbation operator, which preserves all intercenter exchange contributions. The exchange perturbation theory (EPT) formalism itself is presented in the standard form of invariant perturbation theory that takes into account intercenter electron permutations between overlapping nonorthogonal states. As an example of application of the formalism of invariant perturbation theory, we consider the magnetic properties of perovskite manganites La_1/3Ca_2/3MnO₃ that are associated with the charge and spin ordering in magnetic chains of manganese. We try to interpret the experimental results obtained from the study of the effect of doping the above alloys by the model of superexchange interaction in manganite chains that is constructed on the basis of the exchange perturbation theory (EPT) formalism. The model proposed makes it possible to carry out a quantitative analysis of the effect of substitution of manganese atoms by doping elements with different electron configurations on the electronic structure and short-range order in a magnetic chain of manganites.     

Perturbation theory in the Federbush model: Induced interaction terms

We study elastic scattering and production amplitudes in a theory of two massive spinor fields in two space-time dimensions with a current-pseudocurrent interaction (the Federbush model). In contrast to a claim in the recent literature, the results of perturbation theory in the lowest non-trivial orders are consistent with the explicit solution, although massive-Thirring-coupling counter terms must be introduced in order to reproduce the vanishing particle-antiparticle amplitudes of the exact solution.     

Extension of the local curvature approximation to third order and improved tilt invariance

The second-order local curvature approximation (LCA2) is a theory of rough surface scattering that reproduces fundamental low and high frequency limits in a tilted frame of reference. Although the existing LCA2 model provides agreement with the first order small perturbation method up to the first order in surface tilt, results reported in this paper produce a new formulation of the model that achieves consistency with perturbation theory to first order in surface height and arbitrary order in surface tilt. In addition, extension of the modified LCA to third order is presented, and allows the theory to match the second-order small perturbation method to arbitrary order in surface tilt. Crucial to the development of the theory are a set of identities involving relationships among the small perturbation method (i.e. low frequency) and Kirchhoff approximation (i.e. high frequency) kernels; a set of new identities obtained in our derivations is also presented. Sample results involving 3D electromagnetic scattering from penetrable rough surfaces, as well as 2D scattering from Dirichlet sinusoidal gratings, are provided to compare the new results with the existing LCA2 model and with other rough surface scattering theories.     

Collision of optical solitons with Kerr law nonlinearity

The intra-channel collision of optical solitons, with Kerr law nonlinearity, is studied by the aid of quasi-particle theory. The perturbation terms considered in this paper are all of Hamiltonian type. It is shown that the soliton–soliton interaction can be suppressed in the presence of these perturbations, namely, the self-steepening, the third-order dispersion, the fourth-order dispersion and the frequency separation between the soliton carrier and the gain-center frequency. The prediction of quasi-particle theory are fully confirmed by direct numerical simulations.     

The Quantum Consistency of the Ten-Dimensional Heterotic String Effective Action

The finiteness of superstring theory at each order in perturbation theory is considered with respect to the ten-dimensional effective action. The quantum consistency of the ten-dimensional superstring effective action is confirmed with an analysis of the perturbative expansion of the quartic sector. It is found to be compatible with the finiteness of reduced four-dimensional theory.Furthermore, implications for the validity of superstring perturbation theoryat lower energies is considered.     

Divergent perturbation series

Various perturbation series are factorially divergent. The behavior of their high-order terms can be determined by Lipatov’s method, which involves the use of instanton configurations of appropriate functional integrals. When the Lipatov asymptotic form is known and several lowest order terms of the perturbation series are found by direct calculation of diagrams, one can gain insight into the behavior of the remaining terms of the series, which can be resummed to solve various strong-coupling problems in a certain approximation. This approach is demonstrated by determining the Gell-Mann-Low functions in ?⁴ theory, QED, and QCD with arbitrary coupling constants. An overview of the mathematical theory of divergent series is presented, and interpretation of perturbation series is discussed. Explicit derivations of the Lipatov asymptotic form are presented for some basic problems in theoretical physics. A solution is proposed to the problem of renormalon contributions, which hampered progress in this field in the late 1970s. Practical perturbation-series summation schemes are described both for a coupling constant of order unity and in the strong-coupling limit. An interpretation of the Borel integral is given for “non-Borel-summable” series. Higher order corrections to the Lipatov asymptotic form are discussed.     

Extension of the local curvature approximation to third order and improved tilt invariance

The second-order local curvature approximation (LCA2) is a theory of rough surface scattering that reproduces fundamental low and high frequency limits in a tilted frame of reference. Although the existing LCA2 model provides agreement with the first order small perturbation method up to the first order in surface tilt, results reported in this paper produce a new formulation of the model that achieves consistency with perturbation theory to first order in surface height and arbitrary order in surface tilt. In addition, extension of the modified LCA to third order is presented, and allows the theory to match the second-order small perturbation method to arbitrary order in surface tilt. Crucial to the development of the theory are a set of identities involving relationships among the small perturbation method (i.e. low frequency) and Kirchhoff approximation (i.e. high frequency) kernels; a set of new identities obtained in our derivations is also presented. Sample results involving 3D electromagnetic scattering from penetrable rough surfaces, as well as 2D scattering from Dirichlet sinusoidal gratings, are provided to compare the new results with the existing LCA2 model and with other rough surface scattering theories.     

Can perturbation theory of nuclear friction explain the rapid and strong energy damping,found in deeply inelastic heavy ion collisions?

It is shown that the lowest order perturbation theory for the excitation of each single particle state due to the time dependent variation of the combined two centers s.p. potential is a promising candidate to account for most of the energy loss occuring in the deeply inelastic collisions of heavy ions. The linear response theory of nuclear friction is at T=0 a special case of the simpler perturbation theory. Important improvements are presented.     

First-principles calculations of structural stability,elastic, dynamical and thermodynamic properties of SiGe,SiSn, GeSn

A first-principles calculations, based on the norm-conserving pseudopotentials and the density functional theory (DFT) and the density functional perturbation theory (DFPT) as implemented in the ABINIT code, have been performed to investigate the structural stability, elastic, lattice dynamic and thermodynamic properties of the ordered SiGe, SiSn and GeSn cubic alloy in zinc-blende (B3) structure. The calculated lattice parameters and bulk modulus agree with the previous results. The second-order elastic constants have been calculated and other related quantities such as the Young’s modulus, shear modulus, anisotropy factor are also estimated. We also obtain the data of lattice dynamics and the temperature dependent properties currently lacking for SiGe, SiSn and GeSn. Findings are also presented for the temperature-dependent behaviors of some thermodynamic properties such as the internal energy, Helmholtz free energy, entropy and heat capacity.     

Higher-order approximations for the particle-particle propagator

A new type of approximations for many-body Green's functions proposed recently is applied to the particle-particle (pp) propagator for anN-particle fermion system. The new approach which is referred to as the algebraic diagrammatic construction (ADC) is based on an exact resummation of the perturbation series for the pp-propagator in terms of a simple algebraic form introducing energy-independent effective interaction matrix elements and transition amplitudes. These effective quantities are represented by perturbation expansions and can be determined consistently through a given ordern of perturbation theory by comparing the algebraic form with the diagrammatic perturbation series of the pp-propagator through ordern. By this procedure one obtaines a systematic set of approximation schemes (ADC(n)) that represent infinite partial summations for the pp-propagator being complete throughnth order of perturbation theory. The explicit ADC equations forn=1 and 2 are presented and discussed. Comparison is made with the particle-particle random phase approximation (RPA). It is demonstrated that the second-order ADC scheme constitutes an essential step beyond the RPA which is consistent only through first order.     

Interval analysis of transient temperature field with uncertain-but-bounded parameters

Based on the traditional finite volume method, a new numerical technique is presented for the transient temperature field prediction with interval uncertainties in both the physical parameters and initial/boundary conditions. New stability theory applicable to interval discrete schemes is developed. Interval ranges of the uncertain temperature field can be approximately yielded by two kinds of parameter perturbation methods. Different order Neumann series are adopted to approximate the interval matrix inverse. By comparing the results with traditional Monte Carlo simulation, a numerical example is given to demonstrate the feasibility and effectiveness of the proposed model and methods.     

Adsorption isotherm of a Lennard-Jones nitrogen in a carbon slitlike pore

A density functional perturbation approximation based both on second-order perturbation theory and on the pore average density has been proposed to study the adsorption hysteresis of nitrogen in a carbon slit pore. The main advantage of the present approximation is that it is computationally much simpler than the original density functional approximation based on the second-order perturbation theory of liquids, and can be applied to several model fluids confined in a strong external field in order to study their structural and thermodynamic properties. The calculated adsorption hysteresis for the confined Lennard-Jones nitrogen is in very good agreement with computer simulation, even if its accuracy slightly deteriorates for the desorption branch. The calculated equilibrium particle density distributions also compare well with computer simulations, and are better than those of a density functional theory based on the so-called mean-field approximation.     

The super-heat-kernel expansion and the renormalization of the pion–nucleon interaction

A recently proposed super-heat-kernel technique is applied to heavy baryon chiral perturbation theory. A previous result for the one-loop divergences of the pion–nucleon system to is confirmed, giving at the same time an impressive demonstration of the efficiency of the new method. The cumbersome and tedious calculations of the conventional approach are now reduced to a few simple algebraic manipulations. The present computational scheme is not restricted to chiral perturbation theory, but can easily be applied or extended to any (in general non-renormalizable) theory with boson–fermion interactions. Received: 21 July 1998 / Published online: 5 October 1998     

Radiative corrections to positronium energy levels

A systematic perturbation theory for the computation of positronium energy levels is presented. The proposed method is based on the Bethe-Salpeter equation and a zeroth-order kernel for which exact solutions are known explicitly. The cancellation of ultraviolet divergences arising in the perturbation series is discussed, and new contributions to the ground-state hyperfine splitting of positronium are evaluated up to order α⁶.     

Quadrupolar order in the Heisenberg ferromagnet with the single-ion cubic anisotropy

The ground state properties of S =2 ferromagnets with isotropic Heisenberg exchange (J) and single-ion cubic anisotropy (D) are studied. The perturbation theory for is used to find an effective Hamiltonian up to the fourth order for 1, 2 and 3 dimensions. It is shown that in opposition to the MFA prediction there is the quadrupolar long range order at T = 0 in the non-magnetic state of the system without a quadrupolar type of interaction. The effect is a consequence of the quantum nature of the model. Received: 19 February 1998 / Accepted: 17 March 1998     

The roles of extrinsic periodic information on the stability of stock price

The perturbation expansion for the nonlinear Schrödinger equation with a random potential that was developed in earlier works by some of us is extended to higher orders. As the order is increased a solution that is valid for longer time can be found. In particular it is found that Anderson localization persists in the fifth and sixth orders for times when perturbation theory is valid. The perturbation expansion is asymptotic and for the value of the nonlinearity parameter used, the fifth order is the optimal order of the perturbation theory. There are indications that for the sixth order perturbation theory may not be valid.