Mössbauer effect and discovery of new hexagonal ferrites prepared at 980^\circ C

In the present article, undoped and Codoped Mtype Srhexaferrites have been prepared at low temperatures down to 980 C for the first time by the usual ceramic procedure and sintering technique. On these materials, a CoK Xray diffraction analysis and the room temperature ⁵⁷Fe Mössbauer spectroscopy (MES) were carefully performed. The results obtained are described and interpreted. The mechanism of Co substitution partially in place of iron and the site of its occupancy were proposed and established.     

Monochromatization of synchrotron radiation for nuclear resonant scattering experiments

An introduction to monochromatization of synchrotron radiation in the energy range of 5–30 keV is presented for applications involving nuclear resonant scattering. The relevant relationships of the dynamical theory of Xray diffraction are used to explain basic concepts of monochromatization. These relations are combined with raytracing techniques to design highenergyresolution monochromators. Transmissionoptimized and energyresolutionoptimized designs that achieve high energy resolutions (10⁶)< E/E < 10⁸) are discussed separately. Practical silicon monochromators of both types are presented for a variety of nuclear resonances in this energy range.     

Photostability of Molecules of Aromatic Amines in a Polymeric Matrix

In the temperature range T = 5–295 K, the spectralluminescent properties and curves of thermostimulated luminescence (TSL) of molecules of triphenylamine (TPA), trirtolylamine (TTA), triranisolamine (TAA), and N,N'diphenylbis(3methylphenyl)(1,1'biphenyl)4,4'diamine (TPD) in polystyrene and 4Brpolystyrene matrices have been investigated. It has been found that photoirradiation at room temperature in the region of the lowest electron transition of molecules leads to a decrease in the intensities of the luminescence, photoluminescence, and TSL bands, as well as to the formation of new deep traps for charge carriers. At equal irradiation doses these changes in TPD are noticeably less pronounced than in TPA, TTA, and TAA. The higher photochemical stability of TPD molecules compared to TPA, TTA, and TAA is attributed to the difference in the mechanisms of nonradiative deactivation of the triplet states of molecules.     

Radiative Properties of an SHF Discharge Formed by a Ring‐Type Waveguide‐Slot Radiator

The actual spatial distribution of the intensity of SHF discharge glow in oxygen at different distances from the zone of input of SHF power has been investigated by the method of optical emission spectroscopy with subsequent abelization of the experimentally obtained integral characteristics of the intensity of radiation emitted by the OI ( = 777.7 nm) line. The investigations were carried out in a plasmatron on the basis of a ringtype waveguideslot radiator. The experimental results obtained indicate that the best uniformity of optical radiation over the discharge length is attained in the mode of pressureoptimum gas breakdown. Radial distributions of the radiation intensity are complicated in nature, which can be attributed to the differently pronounced skin effect exerted by a plasma on an electromagnetic wave under different discharge conditions. The results of the present work make it possible to interpret the previously obtained data of technological experiments and can be employed in developing technological processes of SHF plasma processing of materials and in designing SHF plasmatrons.     

Influence of Solvent Polarity and Viscosity on Nonradiative Processes in Oligothiophenes with Intramolecular Charge Transfer

By the methods of luminescence, picosecond spectroscopy, and quantumchemical calculations the mechanisms of electron excitation energy deactivation in some oligothiophenes with intramolecular charge transfer depending on the solvent polarity and viscosity have been investigated. While for 2Npiperidino5(2,2dicyanovinyl)thiophene (PDCVT) the main channel of nonradiative deactivation is the transition to a lower intermediate state with a twisted double bond controlled by the medium viscosity, in the case of (E){2[25piperidino2thienyl]6(trifluoridemethyl)4H4pyranylidene}propanedinitryl (PTFDN) fluorescence quenching is initiated by the solvent polarity. For two other oligothiophenes, 2Npiperidino5cyanothiophene (PCT) and 2Npiperidino5cyanoterthiophene (PCTT), differing in the length of the thiophene chain, we have revealed, along with the effective quenching of fluorescence in shortchain PCT (independent of the solvent polarity and viscosity), an increase in the radiation capacity in PCTT with increasing polarity of the solvent. The possible mechanisms of nonradiative deactivation in the investigated oligothiophenes are discussed.     

Spectral‐Luminescence and Generation Properties of 1‐Aza‐2‐Methyl‐6‐Aminopyrene and of Its Protolytic Forms

Spectral manifestations of protolytic forms of 1aza2methyl6aminopyrene in ethanol and aqueous solutions are investigated. The ionization constants of the protolytic forms are determined. The generation properties and photostability of a neutral molecule and a cation in excitation by an excimer XeCl laser are studied.     

An ARC Facility for Studying Carbon Plasma and Obtaining Low‐Dimensional Carbon Structures

An experimental DUF2000 facility for spectroscopic investigations of a reducedpressure carbon arc and also for production of lowdimensional carbon structures (fullerenes, nanotubes, etc.) is described.     

Spectral Analysis of a Hardening Medium Based on I‐20A Oil

Chemical conversions occurring in a hardening medium based on I20A mineral oil through its servicelife are investigated by spectroscopy methods in the IR, visible, and UV regions and by luminescence, massspectroscopy, and elemental analysis methods. The possible reasons leading to deterioration of its cooling properties are established. IR spectroscopic techniques of quantitative determination of the content of compounds in a hardening medium that negatively and positively influence its cooling ability are suggested.     

Spectroscopy of Redox Phototransformations of Porphyrins in Frozen Solutions (Review)

The results of spectral investigations of photochemical transformations of porphyrins and phthalocyanins in frozen solutions have been systematized and critically considered. We investigated the processes responsible for the formation of the products of the primary stages in phototransformations of porphyrins, that is, cations and anions of porphyrins formed in phototransfer of the electron. Photosensitized destruction of the molecules of a frozen matrix with removal of the H atom and its addition to porphyrin leads to the formation of a porphyrin monohydroderivative. In frozen acid media, protonated forms of porphyrins are similar in their photochemical properties to metalloporphyrins: they detach and add electrons, form mono and dihydroderivatives. The process of formation and the properties of the ionicmolecular complexes of Znporphyrin with anions of pyridine, quinoline, and phenazine and also of complexes of the ion–ion type of Znporphyrin anions with pyridine anions have been considered. Owing to the intracomplex charge phototransfer, these formations possess high photochemical activity, which made it possible to use them for solving problems in the field of holeburning spectroscopy.     

Radiative Losses of Plasma on Interaction of Ultrashort Laser Pulses with Matter

Radiative losses of plasma produced by ultrashort laser pulses near the surface of solid targets were studied by the methods of highresolution xray spectroscopy and using the numerical simulation of gasdynamics and radiation processes. The experiments were carried out at the NEODIM laser facility in the Central Research Institute for Machine Building. The flux density was as high as 10¹⁷ W/cm² when the radiation was focussed onto the surface of solid targets from Al and Cu. The timeintegrated discrete spectra of plasma of the multiply charged ions were recorded in the soft xray band from 0.8 to 3.0 keV. The experimental spectra were compared with the results of numerical calculations within the framework of the model, which considered both hydrodynamic and radiationcollisional processes. The association of the radiation dynamics of the individual groups of lines with the spatial and temporal dynamics of the laser torch was revealed. Such an association permits one to judge the nonstationary processes in the expanding plasma even by the spectra integrated over time. From comparison of the experimental results and model calculations, it follows that the line emission of a relatively narrow (in the charge number) group of ions constitutes the major portion of radiation losses.     

Microwave Photonic Signal Down‐Conversion Using a Novel Two‐Frequency Bragg Grating Based Brillouin Fiber Laser

A simple technique using a novel twofrequency Bragg grating based Brillouin fiber laser to downconvert high frequency microwave photonic signals is presented. The mechanism of the Brillouin fiber laser and the principle of this technique for microwave photonic signal downconversion are analyzed. The 12GHz microwave photonic signals are experimentally downconverted to 1.13GHz IF signal with the technique.     

Segregation of Components as a Result of High‐Power Laser Irradiation of Heterogeneous Condensed Media

The effects of periodic segregation of components in metastable (supercooled or supersaturated) binary alloys in the course of kinetic phase transformations as a result of laser irradiation of heterogeneous systems were studied analytically. Nonlinear processes of temporal and spatial selforganization of concentrationrelated structures were simulated using (i) a selfconsistent system of timedependent twodimensional equations for the distribution function for the sizes and spatial coordinates of the newphase particles and (ii) balance equations for the temperature and concentration of dissolved components; the latter equations account for nonlinearity of the particlesource function, sinks, for dependences of the phasetransition temperature on the surface curvature of particles and on the concentration of components, and for diffusive motion of particles in space. The domain of existence for the instabilities under consideration and the characteristics of the formed crystallizationrelated periodic structures are determined. It is established that nanoclusters formed during supersaturation of crystallizing material may play an important role in generation of selfoscillatory crystallization modes. Hydrodynamic aspects of liquidphase concentrationrelated stratification in heterogeneous systems based on immiscible components are considered.     

Quantum Theory of Self‐Phase Modulation of Ultrashort Light Pulses in a Medium with Inertial Electronic Nonlinearity

We develop a systematic quantum theory of formation of ultrashort light pulses in a squeezed state at selfphase modulation. The response time of the electronic Kerr nonlinearity of the medium is accounted for and the dispersion of linear properties of the medium is described in first approximation. The theory uses the approach based on the momentum operator for the electric field. The response function of the nonlinearity is contained in the interaction operator. The results obtained are valid when the pulse duration is far greater than the nonlinear response time and the carrier pulse frequency is offresonance. It is established that the instantaneous spectral distribution depends quasistatically on the pulse form. In the general case, the spectral distribution of the quadraturesqueezed component is defined by both the response time of the nonlinearity and the magnitude of the nonlinear phase addition. It is also shown that the frequency at which suppression of quantum fluctuations is greatest can be controlled by adjusting the phase of the initial coherent light pulse. It is found that, by registering the quadraturesqueezed pulse using a balanced homodyne detector, the squeezing effect can be efficiently measured if the timedependent phase of the heterodyne pulse obeys a specific dependence defined by the pulse form. The spectral photonnumber distribution of the quadraturesqueezed pulse is studied, and the photon antibunching effect is found for the photon number in a limited spectral band.     

Increase in the Gain of a Laser with Autoinjection of Priming Radiation in the Formation of Giant Pulses

Optical schemes of lasers that ensure the formation of giant pulses from narrowband, freeoscillation priming radiation with a change in the Qfactor and simultaneous increase in the gain coefficient and in the coefficient of filling a resonator with an active substance are developed. The results of experimental investigations of the parameters of singlepulse radiation of ruby lasers with electrooptical switching of a linear composite resonator are given.     

Resonance Selective Excitation of Terahertz Plasma Waves in a Semiconductor Quantum Well Using Two-Color Laser Radiation

A new method of coherent resonance excitation of plasma instability in a 2D quantum well driven by twocolor laser radiation due to photoinduced generation of electron–hole pairs is proposed. It is shown that under the resonance condition, where the frequency and wavenumber of the beat wave obey the 2D plasmon dispersion relation, a spacecharge wave is excited efficiently. A selfconsistent treatment of the problem is presented and the smallsignal response of the 2D system in the THz frequency region is found. This new method provides the selective resonance excitation of plasmons, tuning of their frequency, and efficient control of plasma wave parameters crucial for THz semiconductor technology.     

Heterogeneous Chemiluminescence of Crystal Phosphors on X‐Ray or UV Irradiation

Using a highvacuum assembly with molecular beams and setups with an implemented atom probe, we investigated atomic and molecular adsorption luminescence of the oxides CaOBi and MgO in O and O₂ beams and also radicalrecombination luminescence excited by H and O atoms in ZnS and in ZnS,CdS samples activated with silver, copper, and the rareearth element Tm. It is established that exposure to UV light and xray radiation of the CaOBi, MgO, and ZnSTm samples, where the mechanism of direct excitation of heterogeneous chemiluminescence (HCL) is realized, does not influence the characteristics of the heterogeneous chemiluminescence, whereas similar exposure of the ZnS,CdSCu,Al and ZnS,CdSAg samples and of selfactivated ZnS, in which the excitation of heterogeneous chemiluminescence is due to the ionization of the lattice, leads to an increase in the intensity of heterogeneous chemiluminescence up to five orders of magnitude. The mechanisms of the phenomenon are considered.     

Manifestation of Extracoordination in the Resonance Raman Spectra of Water‐Soluble Cation Co‐Porphyrins

Resonance Raman spectra (RRS) of Co(II) and Co(III)5,10,15,20tetrakis(4Nmethylpyridinium)porphyrin ((Co^II(TmpyP4), and Co^III(TMPyP4)) in aqueous solutions at different pH as well as in organic solvents (methanol, ethanol, DMSO, DMF) are obtained. The increased sensitivity of the oscillation frequencies ₂, ₄, ₈, and ₆ — the markers of the oxidation state of a metal — to the nature of an axial ligand has been revealed. For Co^III(TmpyP4), the shifts of the indicated frequencies in extracoordination have turned out to be twofold larger than those for Co^II(TmpyP4). The spectral effects observed are related to different electron influence of the extraligands on the system of the porphyrin ring. In the case of Co(III)porphyrin, interaction of the d orbitals of the metal and the e _g ^*orbitals of the macrocycle is more efficient since its ionic radius is smaller than for the Co(II)complex. For Co^III(TmpyP4), a linear correlation between the oscillation frequencies ₂, ₄, ₈, and ₆ and the experimental Gutmann parameters characterizing the electronacceptor properties of solvents is found.     

Formation Dynamics of Absorbing Layers in a Two‐Stage Atomizer

An experimental spatialresolution facility for recording the formation dynamics of absorbing layers in a twostage atomizer is described. An optical scheme with a convergent raying beam in the atomizer zone and a hollow cathode as a radiation source is considered. The dynamics of the absorptivity signal at evaporation of Rb, NaCl, and a standard sample CASS2 has been investigated under different operating conditions of the atomizer. It is shown that the proposed evaporation–condensation–atomization regime considerably lowers the spatial gradients of absorptivity and the level of nonselective absorption in recording the atomic absorption signal.     

Poloidal Magnetic Field Measurements in a Reversed Field Pinch Plasma by a Far‐Infrared Polarimeter

A multichannel farinfrared (FIR) polarimeter has been installed in RFX, a Reversed Field Pinch (RFP) plasma experiment, to measure the poloidal magnetic field profile. The polarimeter uses a CH₃OH FIR laser operating at =118.8 m. Faraday rotation measurements on five of six parallel diagnostic chords are used in preliminary investigations of poloidal field profiles. The experimental results are generally found in good agreement with the &p model predictions. The choice of the profile of = ₀ j·B/B² is discussed. For the reconstruction of the magnetic field profiles a numerical filamentary current equilibrium code is described, where polarimetric data are included as constraints. An alternative method based on the bestfit of a threeparameter profile to the polarimetric data is also reported. Both methods provide reliable reconstructions of the plasma magnetic field and the results indicate the existence in RFX of hollow profiles.     

Mechanism of Intramolecular Transfer of a Proton and an Electron in an Excited State of 4′‐Amine Derivatives of 3‐Hydroxyflavone

The intramolecular transfer of a proton in 4amine derivatives of 3hydroxyflavone was investigated in binary solvents, which are a mixture of polar and nonpolar liquids. The dependence of the efficiency of the intramolecular transfer of a proton in an excited state on the frequency of the exciting light has been revealed, which is due to the spectral inhomogeneity of the molecules of fluorophors in binary solvents. A scheme of the processes of intramolecular transfer of a proton and an electron in 4amine derivatives of 3hydroxyflavone is suggested.