Wetting, mixing, and phase transitions in Langmuir-Gibbs films

Millimolar bulk concentrations of the surfactant cetyltrimethylammonium bromide (CTAB) induce spreading of alkanes, H(CH(2))(n)H (denoted C(n)) 12< or =n< or =21, on the water surface, which is not otherwise wet by these alkanes. The novel Langmuir-Gibbs film (LGF) formed is a liquidlike monolayer comprising both alkanes and CTAB tails. Upon cooling, an ordering transition occurs, yielding a hexagonally packed, quasi-2D crystal. For 11< or =n< or =17 this surface-frozen LGF is a crystalline monolayer. For 18< or =n< or =21 the LGF is a bilayer with a crystalline, pure-alkane, upper monolayer, and a liquidlike lower monolayer. The phase diagram and film structure were determined by x-ray, ellipsometry, and surface tension measurements. A thermodynamic theory accounts quantitatively for the observations.     

A new commensurate phase on the theoretical phase diagram of the [N(CH<Subscript>3</Subscript>)<Subscript>4</Subscript>]<Subscript>2</Subscript>CuCl<Subscript>4</Subscript> crystal

A theoretical phase diagram of the [N(CH₃)₄]₂CuCl₄ crystal with a new commensurate phase characterized by a dimensionless wavenumber q = 2/5 is constructed on a plane specified by two coefficients of the thermodynamic potential. This diagram is used as the basis for the construction of a theoretical pressure-temperature (P-T) phase diagram. The theoretical P-T phase diagram thus obtained is compared with the experimental P-T phase diagram.     

Structural Lifshitz point in the quasi d = 1 magnetostrictive XY model

We obtain, within a framework in which the crystalline degrees of freedom (assumed essentially three-dimensional) are adiabatically treated and the magnetic degrees of freedom are exactly (approximately) treated in the disordered (ordered) phase (s), the peculiar phase diagram of the d = 1 first-neighbour spin-$\text{1}\text{2}$ magnetostrictive XY model in the presence of a magnetic field along the Z-axis. The structural instability wavevector continuously varies along the (2nd order) critical line. This variation presents two non-trivial points: one of them corresponds, in the phase diagram, to a Lifshitz point, where the uniform and dimerized phases converge with a (complex) modulated one; the other one presents characteristics which, to the best of our knowledge, have never been observed.     

Spin freezing and magnetic inhomogeneities in bilayer manganites

We have performed a muon spin rotation study on polycrystalline samples of electron-doped layered manganites, La2-2xSr1+2xMn2O7 (0.4< or =x<1), in order to investigate the local magnetic structure and spin dynamics. Our results provide evidence for phase separation into A-type antiferromagnetic and charge-ordered phases for x=0.52 and spin freezing at low temperatures (T<100 K) for 0.52< or =x<0.75. A new phase diagram which includes this spin-freezing region is proposed.     

Magnetic,electrical and structural properties of some ternary and quaternary spinels with chromium

Spinel compounds with the general formulas ACr₂X₄ and ACr_2−xB_xX₄ (where A=Cd, Zn, Hg, Ga, Cu; X=S, Se, Te, O; B=Ga, In, Sb), including also substitution of two different cations in the tetrahedral subarray, exhibit different correlations of the magnetic and electrical properties. These properties are correlated with the ionic radii of cations and anions. The solid solutions of the boundary compounds reveal, e.g. correlations of metallic conductivity and a semiconductor–metal phase transition. In some spinel solid solutions the latter phase transition is accompanied by the magnetic phase transitions, i.e. either AF-F or Fi-F. Magnetic and electrical properties and their correlations in different spinel series with chromium are discussed in the frames of the phase diagram of the spinel-type compounds with chromium. Different mechanisms leading to the spin-glass state are discussed and illustrated.     

Metallization and spin crossover in Magnesiowüstite (Mg<Subscript>1 − <Emphasis Type="Italic">x</Emphasis></Subscript>Fe<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>O) at high pressures

The pressure-temperature phase diagram of magnesiowüstite has been constructed using the many-electron LDA+GTB approach. The phase diagram includes a quantum critical point at P _c = 55 GPa and has a symmetrical distribution of high-spin and low-spin states. The existence of a metallic state in a narrow temperature range above the critical point is predicted.     

Mott transition, antiferromagnetism, and d-wave superconductivity in two-dimensional organic conductors

We study the Mott transition, antiferromagnetism, and superconductivity in layered organic conductors using the cellular dynamical mean-field theory for the frustrated Hubbard model. A d-wave superconducting phase appears between an antiferromagnetic insulator and a metal for t'/t=0.3-0.7 or between a nonmagnetic Mott insulator (spin liquid) and a metal for t'/t>or=0.8, in agreement with experiments on layered organic conductors including kappa-(ET)2Cu2(CN)3. These phases are separated by a strong first-order transition. The phase diagram gives much insight into the mechanism for -wave superconductivity. Two predictions are made.     

Transition De Phase Metamagnetique Du Bromure Ferreux

In a magnetic field parallel to the magnetization axis of an antiferromagnetic Fe Br₂ single crystal, a caracteristic metamagnetic behaviour is observed. The transition from an antiferromagnetic phase to a paramagnetic phase is studied by help of magnetization measurements in a steady field (H < 60 kOe). The measurement precision has allowed a detailed study of the magnetization isotherms, caracteristic of a first order magnetization phase transition (T < T_c = 4, 7 K) and of a second order phase transition (T_c < T < T_N = 14, 2 K).We have observed an original phase diagram. In a certain temperature and field range, the ordered phase is stable on the high temperature side of the transition point. Some theoretical studies in an Ising model, or in the hypothesis of a strong magnetoelastic coupling forecast the existence of such a magnetic phase diagram.At present, we proceed to a theoretical study, in a molecular field approximation, of the magnetic phase diagram of compounds similar to Fe Br₂ where we take into account the relative values of parameters J₁, J₂ and D associated with ferromagnetic and antiferromagnetic interactions and crystalline anisotropy.     

Charge Stripes Due to Electron Correlations in the Two-Dimensional Spinless Falicov—Kimball Model

We calculate the restricted phase diagram for the Falicov–Kimball model on a two-dimensional square lattice. We consider the limit where the average conduction electron density is equal to the average localized electron density, which is the limit related to the S _z =0 states of the Hubbard model. After considering over 20,000 different candidate phases (with a unit cell of 16 sites or less) and their thermodynamic mixtures, we find only about 100 stable phases in the ground-state phase diagram, where the ground state is usually the phase separated mixture of two or three stable phases, that often have different electron densities than in the Maxwell-constructed mixture. We analyze these phases to describe where stripe phases occur and relate these discoveries (were appropriate) to the physics behind stripe formation in the Hubbard model.     

The quantum compass chain in a transverse magnetic field

We study the magnetic behaviors of a spin-1/2 quantum compass chain (QCC) in a transverse magnetic field, by means of the analytical spinless fermion approach and numerical Lanczos method. In the absence of the magnetic field, the phase diagram is divided into four gapped regions. To determine what happens by applying a transverse magnetic field, using the spinless fermion approach, critical fields are obtained as a function of exchanges. Our analytical results show, the field-induced effects depend on in which one of the four regions the system is. In two regions of the phase diagram, the Ising-type phase transition happens in a finite field. In another region, we have identified two quantum phase transitions (QPT)s in the ground state magnetic phase diagram. These quantum phase transitions belong to the universality class of the commensurate-incommensurate phase transition. We also present a detailed numerical analysis of the low energy spectrum and the ground state magnetic phase diagram. In particular, we show that the intermediate state (h _c1 < h < h _c2) is gapful, describing the spin-flop phase.     

55Mn NMR investigation of electronic phase separation in La1-xCaxMnO3 for 0.2 < or = x < or = 0.5

55Mn NMR line shape measurements in La1-xCaxMnO3 for 0.20< or =x< or =0.50 provide experimental evidence about the existence of two distinct regions in the T-x magnetic phase diagram, where the homogeneous ferromagnetic (FM) metallic state is separated into FM metallic and FM insulating regions. These results are in agreement with recent theoretical predictions, which reveal a novel electronic phase separation in two FM states, providing orbital ordering and Jahn-Teller phonons are taken into consideration.     

The influence of magnetoelastic interaction on structural phase transitions in cubic ferromagnetics

In the framework of the Landau theory of phase transitions, the influence of the magnetoelastic interaction on structural transitions in cubic ferromagnetics with a positive first magnetic anisotropy constant is analyzed. It is shown that structural transitions are not accompanied by a reorientation of magnetization in this case. The phase diagrams of such ferromagnetics either contain a termination point of the structural transition or a critical point in which the first-order transition is replaced by a second-order one. Magnetoelastic interaction also leads to the appearance of an interval of the ferromagnetic parameters in which a coupled first-order structural-magnetic transition exists. The phase T?x diagram for Heusler Ni_2+x Mn_1?x Ga alloys is calculated, which is in good agreement with the experimental phase diagram of these alloys.     

Zero and finite temperature phase diagram of the spinless fermion model in infinite dimensions

The phase diagram of the model of spinless fermions with repulsive nearest neighbour interaction is calculated analytically on a hypercubic lattice in infinite dimensions (d → ∞). In spite of its simplicity the model displays a rich phase diagram depending on the doping δ, the interaction U and the temperature T. The system can be in the homogeneous phase (HOM), the nonsegregated AB charge density wave (AB-CDW), the AB phase separation region (PS-AB/HOM; coexistence of AB-CDW and HOM), the incommensurate phase (IP) or the IP phase separation region (PS-AB/IP; coexistence of AB-CDW and IP). We identify three important values of the interaction U_IPL = 0.572 < U_IPH = 1.914 < U_IP/PS = 4.212 which distinguish four intervals of U. These imply four different types of phase diagrams. In all the three phase diagrams with U below U_IP/PS the IP appears. We propose a new general ansatz for the order parameter of this phase. A competition between the IP, the PS-AB/IP and the PS-AB/HOM is found. The relevance of our findings for the phase scenario of the Hubbard model is shown.     

Nanoscopic coexistence of magnetism and superconductivity in YBa2Cu3O6+x detected by muon spin rotation

We performed zero and transverse field muon spin rotation experiments on a large number of YBa2Cu3O6+x samples. We detect the coexistence of antiferromagnetic (AF) short range magnetism with superconductivity below T(f) < or = 10 K in compositions 0.37 < or = x < or = 0.39. Most muons experience local AF fields, even when a SQUID detects a full superconducting volume fraction, which points to a local minimal interference organization of short AF stripes embedded in the superconductor. A detailed phase diagram is produced and the consequences of the minimal interference are discussed.     

Cluster simulations of loop models on two-dimensional lattices

We develop cluster algorithms for a broad class of loop models on two-dimensional lattices, including several standard O(n) loop models at n> or =1. We show that our algorithm has little or no critical slowing-down when 1< or =n< or =2. We use this algorithm to investigate the honeycomb-lattice O(n) loop model, for which we determine several new critical exponents, and a square-lattice O(n) loop model, for which we obtain new information on the phase diagram.     

Phase behavior of symmetric ternary block copolymer-homopolymer blends in thin films and on chemically patterned surfaces

The phase diagram of symmetric ternary blends of diblock copolymers and homopolymers in thin films was determined as a function of increasing volume fraction of homopolymer (phi(H)) and was similar to that for these materials in the bulk. Blends with compositions in the lamellar region of the diagram (phi(H)< or =0.4) could be directed to assemble into ordered lamellar arrays on chemically striped surfaces if the characteristic blend dimension (L(B)) and the period of the stripes (L(S)) were commensurate such that L(S)=L(B)+/-0.10L(B). Blends with compositions in the microemulsion region of the diagram (phi(H) approximately 0.6) assembled into defect-free lamellar phases on patterned surfaces with L(S)> or =L(B), but formed coexisting lamellar (with period L(S)) and homopolymer-rich phases when L(S)相似文献   

What drives pseudogap physics in high-Tc cuprates? A view from the (resistance) bridge

Taking into account the evolution of the in-plane resistivity with temperature and doping, a candidate proposal for the (hole-doped) cuprate phase diagram is constructed. Many features of the phase diagram are viewed as a consequence of an anisotropic interaction that intensifies with decreasing doping from the heavily overdoped side. At a critical doping p_c, that coincides with the development of the normal state pseudogap, the interaction becomes sufficiently strong that all electronic states near the zone boundary are effectively incoherent even at T = 0.     

Low temperature phase diagrams for quantum perturbations of classical spin systems

We consider a quantum spin system with Hamiltonian $$H = H^{(0)} + \lambda V,$$ whereH ⁽⁰⁾ is diagonal in a basis ∣s〉=? _x ∣s _x 〉 which may be labeled by the configurationss={s_x} of a suitable classical spin system on ? ^d , $$H^{(0)} |s\rangle = H^{(0)} (s)|s\rangle .$$ We assume thatH ⁽⁰⁾(s) is a finite range Hamiltonian with finitely many ground states and a suitable Peierls condition for excitation, whileV is a finite range or exponentially decaying quantum perturbation. Mapping thed dimensional quantum system onto aclassical contour system on ad+1 dimensional lattice, we use standard Pirogov-Sinai theory to show that the low temperature phase diagram of the quantum spin system is a small perturbation of the zero temperature phase diagram of the classical HamiltonianH ⁽⁰⁾, provided λ is sufficiently small. Our method can be applied to bosonic systems without substantial change. The extension to fermionic systems will be discussed in a subsequent paper.     

Understanding the insulating phase in colossal magnetoresistance manganites: shortening of the Jahn-Teller long-bond across the phase diagram of La1-xCaxMnO3

The detailed evolution of the magnitude of the local Jahn-Teller (JT) distortion in La(1-x)Ca(x)MnO3 is obtained across the phase diagram for 0< or =x< or =0.5 from high-quality neutron diffraction data using the atomic pair distribution function method. A local JT distortion is observed in the insulating phase for all Ca concentrations studied. However, in contrast with earlier local structure studies, its magnitude is not constant, but decreases continuously with increasing Ca content. This observation is at odds with a simple small-polaron picture for the insulating state.     

Spherical 2 + p spin-glass model: an exactly solvable model for glass to spin-glass transition

We present the full phase diagram of the spherical 2 + p spin-glass model with p > or = 4. The main outcome is the presence of a phase with both properties of full replica symmetry breaking phases of discrete models, e.g., the Sherrington-Kirkpatrick model, and those of one replica symmetry breaking. This phase has a finite complexity which leads to different dynamic and static properties. The phase diagram is rich enough to allow the study of different kinds of glass to spin glass and spin glass to spin glass phase transitions.