Synthesis, Characterization and Properties of Poly（aryl amides） Containing Methoxy Substituted Phthalazinone Moiety

A novel aromatic diamine, 1, 2-dihydro-2-（4-aminophenyl）-4-[3-methoxy-4-（4-aminophenoxy）]-2, 3-phthalazin-l-one （OO-DA） containing aza heterocyclic structure was synthesized from the bisphenol-like monomer in two steps and used for preparing new aromatic polyamides with high inherent viscosity of 0.89-1.03 dL.g^-1. The structures of diamine and polymers obtained were confirmed by MS, PT-IR, WAXD and ^1H-NMR. The synthesized polymers exhibited high glass transition temperature in the range of 281-307℃ and good solubility in polar solvents.     

辛弗林衍生物的合成

以苯甲醚为起始原料,与乙酰氯发生付-克酰基化后脱甲基得到4-羟基苯乙酮,然后与液溴进行α-溴代得到2-溴-1-(4-羟苯基)乙酮,再与叔丁胺进行胺化得到1-(4-羟基苯基)-2-(叔丁基氨基)乙酮,最后用氢硼化钠还原合成目标产物1-(4-羟基苯基)-2-(叔丁基氨基)乙醇,总收率约为42.3%。     

联苯聚醚醚酮酮的合成与性能研究

用亲核取代路线合成了含亚联苯结构的新型聚醚醚酮酮（联苯ＰＥＥＫＫ），并对其基本性能进行了测定。结果表明，联苯ＰＥＥＫＫ的Ｔｍ比聚醚醚酮（ＰＥＥＫ）高７７℃，其Ｔｇ比ＰＥＥＫ的高４１℃，且保持了良好的力学性能，本文还对联苯ＰＥＥＫＫ的晶体结构进行了初步探讨。     

邻羟基α-叠氮苯乙酮衍生物的合成

以邻羟基苯乙酮衍生物为原料,经溴化反应和叠氮化反应合成了一系列邻羟基α-叠氮苯乙酮衍生物,其结构经1H NMR,13C NMR,IR及HR-MS表征.     

Synthesis and Characterization of Poly (ether imide)s Containing Phthalazinone and Isopropyl Moieties

Uses for aromatic polyimides have developed rapidly in recent years due to their outstanding properties1,2. However, their applications have been limited in many fields because aromatic polyimides are normally insoluble and infusible. The poly (ether imide)s (PEI) prepared by the polymerization of bisphenol-A diphthalic anhydride (BPA dianhydride) and m-phenylenediamine (m-PDA) ,developed by General Electric Plastics and marketed under the trade name Ultem 1000, has excellent processabili…     

Synthesis of Novel Poly(aryl ether amide)s Containing the Phthalazinone Moiety

Considerable research has been carried out to develop new condensation polymerscontai- mug heterocyclic units since many of these polymers possess outstandingstrength and moduli and are used predominantly as high temperature-resistant materialsand fibers. Phthalazinone and its derivatives have been known for almost a century'.Recently Hay et ap'3 first reported that phthalazinone and its derivatives were bisphenolIike monomers which can be polymerized with the activated aryl dihalide monomers …     

Synthesis and Characterization of Poly(ether imide)s Containing m-Methyl and Phthalazinone Moieties

Aromatic polyimides are distinguished for their excellent mechanical and thermal properties in many engineering fields1. However, aromatic polyimides are normally insoluble in common organic solvents, which restricts their applications in some fields. Many efforts have been taken to improve their solubility. Introducing bulky side groups and non-coplanar structure into polymers bone chains is a good way to obtain the polymers with excellent mechanical and thermal properties2. In this paper…     

4-AHBA为核的聚芳醚树枝状化合物的合成及其光学性能

合成了三个新的以2-(4-氨基-2-羟基苯基)苯并噻唑(4-AHBA)为核的聚芳醚树枝状化合物(1a～1c),其结构由1H NMR,13C NMR,IR,MS和元素分析表征.研究了1和4-AHBA在氯仿中的紫外吸收光谱和荧光发射光谱,结果表明,1与4-AHBA相比,紫外吸收强度大大提高,且最大吸收波长从349 nm红移...     

含六苯基苯结构单元桨型分子的合成及光致发光特性

以1,3,5-三苯基苯为中心核, 4-乙烯基联苯为桥联结构, 通过Heck偶联反应合成了含六苯基苯结构单元的桨型分子, 对其结构进行了表征; 对桨型分子及其结构单元[包括4-乙烯基联苯、含六苯基苯结构的“臂”及其母体结构1,3,5-三(4-苯乙烯基苯基)苯]在溶液中的光致发光特性的研究结果表明, 桨型分子具有2个发光中心, 最大发射波长在蓝色光范围内分别为397和445 nm.     

Synthesis of 1,7-Bis(4-hydroxyphenyl)-3-hydroxy-1,3-heptadien-5-one

l,7-Bis(4-hydroxyphenyl)-3-hydroxy-1,3-heptadien-5-oneIIwagfirstlyisolatedfromtheseedsofAIPiniablepharocalyxK.Schum.(Zingiberaceae)asanoveldiarylheptanoid.Meanwhile,l,7-his(4-hydroxyphenyl)-3-hydroxy-l,3,6-heptatTien-5-one2,aknowndiarylheptanoid,wasisolatedaswell.Therecentpublication'reportedthatIstronglyinhibitedtheaggregationofplateletinducedbycollagen,arachidonicacidandadenosinediphosphate.AdditionalresearchZprovedthat2couldactasaninhibitoroftheHIV-1integrase.Byourfindings,thesynthesi…     

含二氦杂萘酮结构全芳香杂环聚合物的研究进展

高性能高分子材料在高温下仍保持优异的综合性能,是航空航天、电子电气、高速轨道交通等重要高技术领域不可或缺的材料。在不牺牲耐热性能的前提下改善高性能聚合物的加工性能一直是国内外研究的热点。含二氮杂萘酮结构高性能聚合物是高性能高分子材料的新成员。本文主要综述了含二氮杂萘酮结构的聚芳醚（包括聚芳醚砜酮系列、聚芳醚腈砜酮系列、...     

主链含酞和芴结构的无定形聚芳醚酮的合成

通过共聚改性在酚酞聚芳醚酮(PEK-C)的主链上引入含芴侧基,制备了一系列主链含酞和芴结构的线性高分子量无定形聚芳醚酮无规共聚物.通过傅里叶红外光谱(FTIR)、核磁共振谱(1H,13C NMR)等手段确定了共聚物结构.凝胶渗透色谱(GPC)数据表明,共聚物的Mn>6.0×104,Mw>1.0×105,PDI(Mw/Mn)范围在1.6~1.7之间.X射线衍射(XRD)数据表明共聚物系无定形结构,差示扫描量热法(DSC)和热重分析(TGA)测试表明聚合物具有良好的耐热性;初始热分解温度高于467℃;700℃时残炭率大于58.9%;共聚物呈现单一的玻璃化转变温度(Tg>243℃).当酚酞与双酚芴摩尔比在3∶7~5∶5范围时,共聚物的弹性模量和断裂伸长率显著提高,可分别达到3.1 GPa和58%,是酚酞聚芳醚酮的1.4倍和8.3倍.这类含酞和芴侧基的无定形聚芳醚酮保持了在氯仿、二氯甲烷、四氢呋喃(THF)和甲基吡咯烷酮(NMP)等极性非质子溶剂中良好的溶解性能,并显著提高了聚合物的力学性能和热性能.     

Synthesis and Characterization of New 1-Methyl-4-(Methylamino)Piperidine and Decahydroquinoline Platinum(II) Complexes Containing Disubstituted Sulfide as a Leaving Group

A series of cationic platinum(II) complexes of the type [Pt(mmap)R'R"S)Cl](NO₃) and [Pt(dhq)₂(R'R"S)Cl]-(NO₃) (where mmap=1-methyl-4-(methylamino)piperidine; dhq=decahydroquinoline; and R'R"S=dimethylsulfide, diethylsulfide, diisopropylsulfide, diphenylsulfide, dibenzylsulfide, methylphenylsulfide or methyl-p-tolylsulfide) has been synthesized and characterized by elemental analysis, infrared, ¹H and ¹⁹⁵Pt nuclear magnetic resonance spectroscopic techniques.     

Synthesis and Properties of Novel Aromatic Copolyamides Containing Phthalazinone Moiety

A series of novel aromatic copolyamides were synthesized by the direct polycondensation of 2‐(4‐carboxyphenyl)‐4‐[4‐(4‐carboxyphenoxyl)phenyl]‐phthalazinone (1), terephthalic acid (TPA), and four commercial diamines. The inherent viscosities of the polyamides were between 0.79～1.56 dL/g. Introduction of the non‐coplanar phthalazinone segments into the main chains remarkably decreased the crystallinity and improved the solubility of the copolyamides. When the percentage of 1 in the diacid monomers was above 50%, the copolymers were soluble in aprotic polar solvents, such as N‐methyl‐pyrrolidinone and N,N‐dimethylacetamide. The copolyamides showed high thermal properties associated with the glass transition temperatures in the range of 276～337°C and 10% wt loss temperatures in nitrogen over 496°C. Some polymer films cast from NMP solution had tensile strengths up to 123.4 MPa, initial moduli up to 2.10 GPa, and elongation at break values up to 9.6%.     

Synthesis of Gingerenone C and 5-Hydroxy-1-(4'-hydroxy- 3'-methoxyphenyl)-7-(4"-hydroxyphenyl)-3-heptanone

The two diarylheptanoids (E)-1-(4'-hydroxy-3'-methoxyphenyl)-7-(4"-hydroxyphenyl) hept-4-en-3-one 1 (Gingerenone C) and (±)-5-hydroxy-1-(4'-hydroxy-3'-methoxyphenyl)-7-(4"-hydroxyphenyl)-3-heptanone 2 were synthesized from vanillin 3 and 4-hydroxybenzaldehyde 9.     

二种氧氮杂环戊二烯类化合物的合成及其光性能研究

本文合成了对-(2-苯基-1,3,4,-噁二唑基-5)-(5’-苯基噁唑基-2’)苯和对-(2-苯基-1,3,4-噁二唑基-5)-(2’-苯基q罨唑基-5’)苯二类共12种化合物,测试了它们的紫外、荧光、红外光谱和激光转换效率.     

含氟偶氮苯光响应性聚合物的合成及性能

以1,2,3,4,5-五氟苯胺为原料, FeSO-4?7H2O负载的KMnO4为氧化剂, 制得全氟代偶氮苯, 在KOH作用下醇解, 进行丙烯酰化反应, 得到光响应性的功能单体4-甲基丙烯酰氧基九氟偶氮苯, 用GC-MS, 元素分析及NMR等方法对功能单体进行表征, 并研究了其光异构化性能. 以4-甲基丙烯酰氧基九氟偶氮苯(MANFAB)为功能单体, 与十字交联剂三羟甲基丙烷三甲基丙烯酸酯(TRIM)在自由基引发下合成了光响应性的三维交联聚合物, 并研究了其光响应性质.     

1-(2-羟基苯基)-3-苯基-1,3-丙二酮及其铕(Ⅲ)配合物的合成和发光研究

以邻羟基苯乙酮和苯甲酰氯为原料, 经过酯化反应、 Fries重排合成了1-（2-羟基苯基）-3-苯基-1,3-丙二酮（HPPPD）及其与铕（Ⅲ）的配合物, 并通过IR, 热重-差热分析和^1H-NMR谱对其进行了表征. 研究了酚羟基的引入对稀土配合物发光性能的影响. 结果表明该配体与铕（Ⅲ）形成的配合物发出很强的铕（Ⅲ）的特征荧光, 并且以邻菲罗啉为第二配体的三元配合物的荧光强度明显高于二元配合物. 但是, 配体HPPPD与铽（Ⅲ）、钐（Ⅲ）和镝（Ⅲ）等形成的配合物, 无论是二元的, 还是三元的发光均很弱. 这是由于该配体的能级与不同稀土离子能级匹配程度的差别所致.     

新有机试剂4-(2-苯并噻唑偶氮)焦棓酚的合成、性能和分析应用

本文以2-氨基苯并噻唑为原料,经重氮化后与焦棓酚偶联合成了4-(2-苯并噻唑偶氮)焦棓酚,用乙醇重结晶精制。并用元素分析、波谱等鉴定了结构。测定了其离解常数和质子化常数。研究了该试剂的一般性质、多配位显色反应,发现其与Mo(Ⅵ)、W(Ⅵ)、Ti(Ⅳ)等的显色反应在CTMAB和CPB等阳离子表面活性剂存在下有高的灵敏度。     

Synthesis, Crystal Structure and Fluorescent Properties of 1-（4-（Dimethylamino）benzylidene）- 4-（naphthalen- 1-yl） Thiosemicarbazide

1 INTRODUCTION Recently, for the fluorescent properties, Schiff base has been more and more important and widely studied in density optical memories, nonlinear op- tics (NLO), organic light-emitting diodes (OLED), polymer LED and electrogenerated chemilumines- cence (ECL)[1~5]. Thiosemicarbazones are a kind of Schiff bases with thiourea and good ligands easily chelating with transition metal ions. Although they have been studied extensively for a long time due to their chemical and b…