Temperature dependence of the electric field gradient in Er metal

The method of perturbed angular distributions was used to measure the temperature dependence of the electric field gradient in Er single crystal for 98 KT156 K. The I=11^– isomer in Er¹⁵⁴) was used as a probe. ₀ increases monotonically for 98 KT259 K and then decreases. A possible cause for this effect may be short range interactions between the f electrons above the Neel point.Visitor from the Weizmann Institute, Rehovoth, Israel.     

Temperature dependence of electric field gradient in TbCoO3

The temperature dependence of the electric field gradient (efg) in TbCoO₃ perovskite was measured by perturbed angular correlation (PAC) technique using ¹¹¹Cd and¹⁸¹Ta nuclear probes. The radioactive parent nuclei ¹¹¹In and ¹⁸¹Hf were introduced into the compound through a chemical process during sample preparation. The electric quadrupole interactions at ¹¹¹Cd show two different sites, assigned to probe substituting Tb and Co atoms. The temperature dependence of quadrupole frequencies show sharp discontinuities which have been interpreted as thermally activated spin state transitions from low-spin ground state configuration to the intermediate-spin state and from intermediate-spin to high-spin state of Co^3?+? ion. For ¹⁸¹Ta only one interaction was observed, which was assigned to probe at Co site. Indication of a Jahn–Teller distortion, which stabilizes the intermediate-spin state with orbital ordering, is also pointed out. No magnetic order was observed till 77 K.     

Temperature dependence of the electric field gradient of Cd in Hg

We have measured the quadrupole interaction of ¹⁰⁷Cd$\text{Hg}$ as a function of temperature. The relatively large temperature variation observed is consistent with the assumption of lattice vibrations as the main source for the temperature dependence of the electric field gradient.     

Temperature dependence of the electric field gradient of Hg in Bi

The temperature dependence of the nuclear quadrupole interaction of the¹⁸⁸Hg(12⁺) isomer in a Bi host has been measured by the TDPAD technique. Assuming that the T^3/2 law is valid for this system a fit at the high temperature region yields _Q(T=0)=132(6) MHz and B=7.2(6)×10^–5K^–3/2. The EFG of HgBi and the temperature dependence strength follow the general trend of other probes in Bi.Supported in part by the MINERVA Foundation, Munich, Germany and the Israeli Academy of Science, Jerusalem, Israel.Incumbent of the Arye Dissentshik Career Development Chair.Incumbent of the Ruth Epstein Recu Career Development Chair.     

Temperature dependence of the electric field gradient in CdSe and HfO2

The time differential perturbed angular correlation technique was applied to study the electric field gradient in the semiconductor CdSe and the insulator HfO₂ at different temperatures. Whereas the semiconductor CdSe shows an increasing quadrupole coupling constant with increasing temperature, the insulator HfO₂ exhibits no temperature dependence of the electric field gradient over the whole temperature range investigated.     

Temperature dependence of the surface electric field gradient for indium metal

The electric field gradient at indium surfaces was studied with¹¹¹In PAC-probes as a function of temperature. The surface field gradient was determined to be temperature independent up to 100 K and the fraction of¹¹¹In surface sites shows a pronounced annealing behaviour between 150 K and 250 K.     

Temperature dependence of the electric field gradient for111Cd in antimony

For the temperature dependence of the electric field gradient of¹¹¹Cd in the semimetal antimony the well knownT ^3/2 relationship is valid over a wide temperature range. The slope parameterB differs from that for^{121, 123}Sb in antimony by a factor of about 2.3.     

Temperature dependence of the electric field gradient in AgIn2 intermetallic compound

The temperature dependence of the electric field gradient in the AgIn₂ intermetallic compound was measured using the TDPAC technique. From 80 K up to 415 K a linear dependence was found. Below 80 K a change in this behaviour was observed. This and previous results are interpreted as related to optical-phonon modes in intermetallic compounds.     

Temperature dependence of the electric field gradient in the AgIn2 intermetallic compound

The temperature dependence of the electric field gradient in the AgIn₂ intermetallic compound was measured using the TDPA correlation technique. From 80 K up to 415 K the electric field gradient follows a linear temperature dependence. Below 80 K a change in this behaviour is observed.Work supported in part by FINEP and CNPq.     

Temperature dependence of the electric field gradient of204Pb in hexagonal Tl

The temperature dependence of the nuclear quadrupole interaction of²⁰⁴Pb(4⁺) isomer in hexagonal Tl host has been investigated by the TDPAD technique. It is the first reported EFG which does not respect the T^3/2 law fors-p metals. The chosen approach is the independent treatment of the ionic contribution and of the electronic contribution in the approximation of the additivity of the two contributions, avoiding any assumption of a direct temperature dependence for the total EFG.     

Temperature dependence of the electric field gradient at Ta nuclei in hafnium pyrovanadate

The electric field gradient EFG in hafnium pyrovanadate has been measured at Hf sites at different temperatures with the time-differential perturbed angular correlation method. The results obtained show the existence of a phase transition around 110°C.     

Temperature dependence of the Isomer Shift and electric field gradient of181Ta in Re-metal

The 6.2-keV Mössbauer transition of¹⁸¹Ta was used to study both the Isomer-Shift (IS) and the quadrupole interaction in Re-single crystal host in the temperature range of 77 K to 517 K. Spectra were obtained for the¹⁸¹W diffused into Re-single crystal source using a single line Ta-metal absorber. The temperature change for the IS, δS/δT, is 55(1)×10^?4 mm/s·deg, which is of the order of ?24 times the second-order Doppler shift. The temperature change of the electric field gradient follows the T^3/2 relation. The relative smaller change of the EFG with respect to the IS change with temperature, reflects the strong role of the change of the s-electron density (s-d electron transfer) with temperature over other parameters.     

Grain size dependence of the electric field gradient

Precise measurements of the electric field gradient (EFG) with the perturbed angular correlation method (PAC) in Cd and Zn show significant differences between single-crystalline and poly-crystalline samples. These differences (up to four percent at low temperatures) decrease with increasing temperature and vanish at about 2 60 K. In all samples the lowest EFG values are obtained for single crystals. In poly-crystalline samples the EFG as well as the width of the EFG distribution increase with decreasing grain size. This effect is also observed in semiconducting ZnO.This work was supported financially by the Bundesministerium für Forschung und Technologie.     

Temperature dependence of the electric field gradient in GaN measured with the PAC-probe 181Hf

A radial inhomogeneous magnetic field produced by counter-propagating currents in anti-Helmholtz configuration coils has been superimposed to a Penning trap. The confinement properties of electrons in such a trap have been studied experimentally. Without the radial B-field we find a number of operating conditions where instabilities occur, arising from higher order contributions to the quadrupolar trapping field. When we apply the radial field the trap properties remain essentially unchanged until the strength of this field at the boundary of the electron cloud is of the same order as the homogeneous Penning field. Then a sudden breakdown in the confinement appears. The experiments have been performed in low magnetic fields. The equations of motions of the trapped particles can be cast in a dimensionless form and our results can be considered as independent of the field strength. Contribution was presented at the TCP06, Vancouver Island, 2006.     

Probe atom dependence of the electric field gradient in bismuth

The electric field gradient of T1 in Bi has been determined with the PAD method. The observed value follows the general trend of sp-probe atoms in the group V semimetals in accordance with a covalent bond picture.     

Temperature dependence studies of the electric field gradient at cadmium impurities in heavy rare earth metals

Several of the rare earth metals (Gd, Tb, Dy, Ho and Er) containing¹¹¹Cd impurities have been studied by the method of time differential perturbed angular correlations (TDPAC) to study electric field gradients. Experiments have been made over a temperature range in which no magnetic interactions are expected. We have observed general correlation patterns whose shapes are temperature dependent. We suggest this provides evidence of a reversible temperature dependent strain or distortion near the impurity atom.Supported in part by the US Energy and Research Development Administration under grant #E(11-1)-2184.