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1.
采用浸渍法制备了单一载体(Al2O3、ZrO2、CeO2)和ZrO2、CeO2改性的Al2O3复合载体的Ni催化剂,考察了在甲烷部分氧化制备合成气反应中的催化性能。通过N2-物理吸附、H2程序升温还原、X射线衍射、NH3程序升温脱附和程序升温氧化等技术对催化剂进行了表征。结果表明,在单一载体催化剂中,Ni/Al2O3具有较大的比表面积,其初始反应活性较高,但该催化剂表面易形成大量的积炭而快速失活。Ni/ZrO2和Ni/CeO2催化剂比表面积较小,活性金属Ni在其表面分散性差,催化剂具有较低的CH4转化率。而CeO2和ZrO2改性的Al2O3复合载体催化剂,具有较大的比表面积,反应活性明显高于单一载体催化剂。CeO2-Al2O3复合载体催化剂具有最高的反应活性和较好的反应稳定性。同时表明,含CeO2催化剂反应后表面积炭较少,CeO2的储放氧功能增强了催化剂对O2的活化,提高催化剂活性的同时,可以抑制积炭的生成。  相似文献   

2.
This review paper reports the recent progress concerning the application of nickel–alumina–zirconia based catalysts to the ethanol steam reforming for hydrogen production. Several series of mesoporous nickel–alumina–zirconia based catalysts were prepared by an epoxide-initiated sol–gel method. The first series comprised Ni–Al2O3–ZrO2 xerogel catalysts with diverse Zr/Al molar ratios. Chemical species maintained a well-dispersed state, while catalyst acidity decreased with increasing Zr/Al molar ratio. An optimal amount of Zr (Zr/Al molar ratio of 0.2) was required to achieve the highest hydrogen yield. In the second series, Ni–Al2O3–ZrO2 xerogel catalysts with different Ni content were examined. Reducibility and nickel surface area of the catalysts could be modulated by changing nickel content. Ni–Al2O3–ZrO2 catalyst with 15 wt% of nickel content showed the highest nickel surface area and the best catalytic performance. In the catalysts where copper was introduced as an additive (Cu–Ni–Al2O3–ZrO2), it was found that nickel dispersion, nickel surface area, and ethanol adsorption capacity were enhanced at an appropriate amount of copper introduction, leading to a promising catalytic activity. Ni–Sr–Al2O3–ZrO2 catalysts prepared by changing drying method were tested as well. Textural properties of Ni–Sr–Al2O3–ZrO2 aerogel catalyst produced from supercritical drying were enhanced when compared to those of xerogel catalyst produced from conventional drying. Nickel dispersion and nickel surface area were higher on Ni–Sr–Al2O3–ZrO2 aerogel catalyst, which led to higher hydrogen yield and catalyst stability over Ni–Sr–Al2O3–ZrO2 aerogel catalyst.  相似文献   

3.
A series of MoO3/ZrO2–Al2O3 catalysts was prepared and investigated in the sulfur-resistant methanation aimed at production of synthetic natural gas. Different methods including impregnation, deposition precipitation, and co-precipitation were used for preparing ZrO2–Al2O3 composite supports. These composite supports and their corresponding Mo-based catalysts were investigated in the sulfur-resistant methanation, and characterized by N2 adsorption–desorption, XRD and H2-TPR. The results indicated that adding ZrO2 promoted MoO3dispersion and decreased the interaction between Mo species and support in the MoO3/ZrO2–Al2O3 catalysts. The co-precipitation method was favorable for obtaining smaller ZrO2 particle size and improving textural properties of support, such as better MoO3 dispersion and increased concentration of Mo6+ species in octahedral coordination to oxygen. It was found that the MoO3/ZrO2–Al2O3 catalyst with ZrO2Al2O3 composite support prepared by co-precipitation method exhibited the best catalytic activity. The ZrO2 content in the ZrO2Al2O3 composite support was further optimized. The MoO3/ZrO2–Al2O3 with 15 wt % ZrO2 loading exhibited the highest sulfur-resistant CO methanation activity, and excess ZrO2 reduced the specific surface area and enhanced the interaction between Mo species and support. The N2 adsorption-desorption results indicated that the presence of ZrO2 in excessive amounts decreased the specific surface area since some amounts of ZrO2 form aggregates on the surface of the support. The XRD and H2-TPR results showed that with the increasing ZrO2 content, ZrO2 particle size increased. These led to the formation of coordinated tetrahedrally Mo6+(T) species and crystalline MoO3, and this development was unfavorable for improving the sulfur-resistant methanation performance of MoO3/ZrO2–Al2O3 catalyst.  相似文献   

4.
Amorphous Ni-Ru-B/ZrO2 catalysts were prepared by chemical reduction method. The effects of Ni-Ru-B loading and Ru/Ni mole ratio on the catalytic performance for selective CO methanation from reformed fuel were studied, and the catalysts were characterized by BET, ICP, XRD and TPD. The results showed that Ru strongly affected the catalytic activity and selectivity by increasing the thermal stability of amorphous structure, promoting the dispersion of the catalyst particle, and intensifying the CO adsorption. For the catalysts with Ru/Ni mole ratio under 0.15, the CO methanation conversion and selectivity increased significantly with the increasing Ru/Ni mole ratio. Among all the catalysts investigated, the 30 wt% Ni-Ru-B loading amorphous Ni61Ru9B30/ZrO2 catalyst with 0.15 Ru/Ni mole ratio presented the best catalytic performance, over which higher than 99.9% of CO conversion was obtained in the temperature range of 230°C~250°C, and the CO2 conversion was kept under the level of 0.9%.  相似文献   

5.
In this paper, the effect of additive Fe on Ni/Al2O3 catalyst for CO2 methanation was studied. A series of bimetallic Ni–Fe catalysts with different Ni/Fe ratios were prepared by impregnation method. For comparison, monometallic Fe‐based and Ni‐based catalysts were also prepared by the same method. The characterization results showed that adding Fe to Ni catalyst on the premise of a low Ni loading(≦12 wt.%) enhanced CO2 methanation performance. However, when the Ni loading reached 12 wt.%, the catalytic activity decreased with the increase of Fe content, but still higher than the corresponding Ni‐based catalyst without Fe. Among them, the 12Ni3Fe catalyst exhibited the highest CO2 conversion of 84.3 % and nearly 100% CH4 selectivity at 50000 ml g‐1 h‐1 and 420 °C. The enhancement effect of adding Fe on CO2 methanation was attributed to the dual effect of suitable electronic environment and increased reducibility generated by Fe species.  相似文献   

6.
The supported Ni-based catalyst is widely used in the methanation process. Nevertheless, the major disadvantages of this catalyst are a poor behavior in the water-gas-shift (WGS) reaction and the deactivation at higher temperatures. A new kind of catalyst, nickel-containing oxides catalyst (NiMgAl), obtained from thermal treatment of hydrotalcite-like compounds (HTlcs) was prepared using the co-precipitation method. The performance of this catalyst was systematically investigated and compared with that of the Ni/Al2O3 catalyst. It was found that the NiMgAl catalyst shows an enhanced methanation activity compared to that of the Ni/Al2O3 catalyst and the former catalyst shows a better performance for the methanation especially at temperature over 550°C. Three NiMgAl catalysts with different nickel content were prepared and tested in the methanation operated at a GHSV of 15000 h?1 and n(H2)/n(CO) of 1.5. The results indicate that with the NiMg8 catalyst a higher activity and stability could be achieved than with the NiMg5 and NiMg6 samples, the effect mainly attributed to a higher extent of Ni dispersion was confirmed by XRD results.  相似文献   

7.
赵娇娇  余运波  韩雪  贺泓 《催化学报》2013,34(7):1407-1417
分别以La2O2CO3, CeO2, ZrO2和Al2O3为载体, 采用浸渍法制备了Ni基重整催化剂, 并以正十二烷模拟车载燃油进行催化重整反应以同时制备小分子碳氢化合物(HCs)和H2, 考察了其在4wt%Ag/Al2O3上选择性催化还原(HC-SCR)氮氧化物(NOx)的性能. 采用N2吸附-脱附、X射线粉末衍射、H2程序升温还原和热重等手段对Ni基催化剂进行了表征. 结果表明, 随着重整催化剂氧化还原性能增强, 产物中H2浓度增加, 可参与SCR反应的HCs含量减少, 从而导致重整-SCR耦合体系上NOx净化活性温度窗口向低温移动, NOx最高转化率降低. Ni/ZrO2+Ag/Al2O3耦合体系中H2/HCs符合SCR反应所需的最优比例, 在柴油车典型排气温度范围内表现出良好的NOx净化能力. 同时, 在Ni/ZrO2+Ag/Al2O3耦合体系上考察了其燃油重整-SCR的活性稳定性. 结果显示, 重整催化剂的耐久性有待进一步提高.  相似文献   

8.
The Ni/Mo/SBA-15 catalyst was modified by La2O3 in order to improve its thermal stability and carbon deposition resistance during the CO2 reforming of methane to syngas. The catalytic performance, thermal stability, structure, dispersion of nickel and carbon deposition of the modified and unmodified catalysts were comparatively investigated by many characterization techniques such as N2 adsorption, H2-TPR, CO2-TPD, XRD, FT-IR and SEM. It was found that the major role of La2O3 additive was to improve the pore structure and inhibit carbon deposition on the catalyst surface. The La2O3 modified Ni/Mo/SBA-15 catalyst possessed a mesoporous structure and high surface area. The high surface area of the La2O3 modified catalysts resulted in strong interaction between Ni and Mo-La, which improved the dispersion of Ni, and retarded the sintering of Ni during the CO2 reforming process. The reaction evaluation results also showed that the La2O3 modified Ni/Mo/SBA-15 catalysts exhibited high stability.  相似文献   

9.
Our groups studies on Cu/ZnO-based catalysts for methanol synthesis via hydrogenation of CO2 and for the water-gas shift reaction are reviewed. Effects of ZnO contained in supported Cu-based catalysts on their activities for several reactions were investigated. The addition of ZnO to Cu-based catalyst supported on Al2O3, ZrO2 or SiO2 improved its specific activity for methanol synthesis and the reverse water-gas shift reaction, but did not improve its specific activity for methanol steam reforming and the water-gas shift reaction. Methanol synthesis from CO2 and H2 over Cu/ZnO-based catalysts was extensively studied under a joint research project between National Institute for Resources and Environment (NIRE; one of the former research institutes reorganized to AIST) and Research Institute of Innovative Technology for the Earth (RITE). It was suggested that methanol should be produced via the hydrogenation of CO2, but not via the hydrogenation of CO, and that H2O produced along with methanol should greatly suppress methanol synthesis. The Cu/ZnO-based multicomponent catalysts such as Cu/ZnO/ZrO2/Al2O3 and Cu/ZnO/ZrO2/Al2O3/Ga2O3 were highly active for methanol synthesis from CO2 and H2. The addition of a small amount of colloidal silica to the multicomponent catalysts greatly improved their long-term stability during methanol synthesis from CO2 and H2. The purity of the crude methanol produced in a bench plant was 99.9 wt% and higher than that of the crude methanol from a commercial methanol synthesis from syngas. The water-gas shift reaction over Cu/ZnO-based catalysts was also studied. The activity of Cu/ZnO/ZrO2/Al2O3 catalyst for the water-gas shift reaction at 523 K was less affected by the pre-treatments such as calcination and treatment in H2 at high temperatures than that of the Cu/ZnO/Al2O3 catalyst. Accordingly, the Cu/ZnO/ZrO2/Al2O3 catalyst was considered to be more suitable for practical use for the water-gas shift reaction. The Cu/ZnO/ZrO2/Al2O3 catalyst was also highly active for the water-gas shift reaction at 673 K. Furthermore, a two-stage reaction system composed of the first reaction zone for the water-gas shift reaction at 673 K and the second reaction zone for the reaction at 523 K was found to be more efficient than a one-stage reaction system. The addition of a small amount of colloidal silica to a Cu/ZnO-based catalyst greatly improved its long-term stability in the water-gas shift reaction in a similar manner as in methanol synthesis from CO2 and H2.  相似文献   

10.
Two series of Co and Ni based catalysts supported over commercial (ZrO2, CeO2, and Al2O3) nano supports were investigated for dry reforming of methane. The catalytic activity of both Co and Ni based catalysts were assessed at different reaction temperatures ranging from 500—800 °C; however, for stability the time on stream experiments were conducted at 700 °C for 6 h. Various techniques such as N2 adsorption‐desorption isotherm, temperature‐programmed reduction (H2‐TPR), temperature‐programmed desorption (CO2‐TPD), temperature‐programmed oxidation (TPO), X‐ray diffraction (XRD), thermogravimetric analysis (TGA) were applied for characterization of fresh and spent catalysts. The catalytic activity and stability tests clearly showed that the performance of catalyst is strongly dependent on type of active metal and support. Furthermore, active metal particle size and Lewis basicity are key factors which have significant influence on catalytic performance. The results indicated that Ni supported over nano ZrO2 exhibited highest activity among all tested catalysts due to its unique properties including thermal stability and reducibility. The minimum carbon deposition and thus relatively stable performance was observed in case of Co‐Al catalyst, since this catalyst has shown highest Lewis basicity.  相似文献   

11.
The correlation between phase structures and surface acidity of Al2O3 supports calcined at different temperatures and the catalytic performance of Ni/Al2O3 catalysts in the production of synthetic natural gas (SNG) via CO methanation was systematically investigated. A series of 10 wt% NiO/Al2O3 catalysts were prepared by the conventional impregnation method, and the phase structures and surface acidity of Al2O3 supports were adjusted by calcining the commercial γ-Al2O3 at different temperatures (600–1200 °C). CO methanation reaction was carried out in the temperature range of 300–600 °C at different weight hourly space velocities (WHSV = 30000 and 120000 mL·g?1·h?1) and pressures (0.1 and 3.0 MPa). It was found that high calcination temperature not only led to the growth in Ni particle size, but also weakened the interaction between Ni nanoparticles and Al2O3 supports due to the rapid decrease of the specific surface area and acidity of Al2O3 supports. Interestingly, Ni catalysts supported on Al2O3 calcined at 1200 °C (Ni/Al2O3-1200) exhibited the best catalytic activity for CO methanation under different reaction conditions. Lifetime reaction tests also indicated that Ni/Al2O3-1200 was the most active and stable catalyst compared with the other three catalysts, whose supports were calcined at lower temperatures (600, 800 and 1000 °C). These findings would therefore be helpful to develop Ni/Al2O3 methanation catalyst for SNG production.  相似文献   

12.
The preparation of synthesis gas from carbon dioxide reforming of methane (CDR) has attracted increasing attention. The present review mainly focuses on CDR to produce synthesis gas over Ni/MOx/Al2O3 (X = La, Mg, Ca) catalysts. From the examination of various supported nickel catalysts, the promotional effects of La2O3, MgO, and CaO have been found. The addition of promoters to Al2O3-supported nickel catalysts enhances the catalytic activity as well as stability. The catalytic performance is strongly dependent on the loading amount of promoters. For example, the highest CH4 and CO2 conversion were obtained when the ratios of metal M to Al were in the range of 0.04–0.06. In the case of Ni/La2O3/Al2O3 catalyst, the highest CH4 conversion (96%) and CO2 conversion (97%) was achieved with the catalyst (La/Al = 0.05 (atom/atom)). For Ni/CaO/Al2O3 catalyst, the catalyst with Ca/Al = 0.04 (atom/atom) exhibited the highest CH4 conversion (91%) and CO2 conversion (92%) among the catalysts with various CaO content. Also, Ni/MgO/Al2O3 catalyst with Mg/Al = 0.06 (atom/atom) showed the highest CH4 conversion (89%) and CO2 conversion (90%) among the catalysts with various Mg/Al ratios. Thus it is most likely that the optimal ratios of M to Al for the highest activities of the catalysts are related to the highly dispersed metal species. In addition, the improved catalytic performance of Al2O3-supported nickel catalysts promoted with metal oxides is due to the strong interaction between Ni and metal oxide, the stabilization of metal oxide on Al2O3 and the basic property of metal oxide to prevent carbon formation.  相似文献   

13.
CH4与CO2干重整反应对于环境保护和天然气资源的合理利用具有重要意义。SiO2和Al2O3是适用于甲烷干重整反应的两种典型的催化剂载体。为了阐明这两种载体对催化剂性能的影响,本研究采用等体积浸渍法制备了Ni/Al2O3和Ni/SiO2催化剂,并利用BET、TEM、H2-TPR、XRD、TG和Raman等技术对还原和反应后的催化剂进行了表征。结果表明,由于载体的性质不同,Ni基催化剂在甲烷干重整中的催化性能也不同。Ni/SiO2催化剂的初始活性较高,但由于其金属-载体相互作用较弱,催化稳定性较差,在800℃下反应15h其催化活性急剧下降;较弱的金属-载体相互作用使得Ni/SiO2催化剂上的Ni颗粒较大,有利于积炭前驱物种的生成,导致催化剂快速失活。而对于Ni/Al2O3催化剂,金属-载体相互作用较强,Ni颗粒较小,但由于Ni与Al2O3生成了NiAlxOy物种,有效活性位减少,其催化活性相对较低,但催化稳定性较好,干重整反应进行50h其活性保持稳定;Ni与Al2O3之间较强的相互作用有利于形成小且稳定的Ni粒子,能减少积炭,因而具有优异的催化稳定性。  相似文献   

14.
采用等体积浸渍法和共沉淀法制备了Ni催化剂,在固定床反应器上考察了Ni负载量、焙烧温度、反应温度等因素对乙二醇低温重整制氢反应活性和选择性的影响。应用X射线衍射、氮物理吸附、H2程序升温还原等技术对负载型Ni催化剂进行了表征。结果表明,共沉淀法制备的Ni/CeO2催化剂具有较小的NiO颗粒与CeO2载体颗粒粒径,催化活性较高。添加少量氧化钴到Ni/CeO2催化剂中可使H2收率达72.6%,EG转化率达93.1%。在CeO2中添加Al2O3能提高负载Ni催化剂的活性,乙二醇转化率达94.0%,H2收率达67.0%;但添加SiO2则使其活性明显变差。  相似文献   

15.
In the current paper, dry (CO2)-reforming of glycerol, a new reforming route, was carried out over alumina (Al2O3)-supported, non-promoted and lanthanum-promoted nickel (Ni) catalysts. Both sets of catalysts were synthesized via a wet co-impregnation procedure. Physicochemical characterization of the catalysts showed that the promoted catalyst possessed smaller metal crystallite size, hence higher metal dispersion compared to the virgin Ni/Al2O3 catalyst. This was also corroborated by the surface images captured by the FESEM analysis. From temperature-programmed calcination analysis, the derivative weight profiles revealed two peaks, which represent a water elimination peak at a temperature range of 373 to 473 K followed by nickel nitrate decomposition from 473 to 573 K. In addition, BET surface area measurements gave 85.0 m2·g−1 for the non-promoted Ni catalyst, whilst the promoted catalysts showed an average of 1% to 6% improvement depending on the La loadings. Significantly, reaction studies at 873 K showed that glycerol dry reforming successfully produced H2. The 2%La-Ni/Al2O3 catalyst, which possessed the largest BET surface area, gave an optimum H2 generation (9.70%) at a glycerol conversion of 24.5%.  相似文献   

16.
In this research,new catalyst with high industrial impact is developed,which can catalyze the conversion of CO2 to methane through methanation reaction.A series of catalysts based on nickel oxide were prepared using wetness impregnation technique and ageing,followed by calcination at 400℃.Rh/Ni(30:70)/Al2O3 catalyst was revealed as the most potential catalyst based on the results of catalytic activity measurement monitored by Fourier Transform Infrared Spectroscopy(FTIR)and Gas Chromatography(GC).The results showed 90.1%CO2 conversion and 70.8% yield at 400℃.  相似文献   

17.
The present work studied the effect of different carbon dioxide (CO2) adsorbents on Ni-based dual-function materials (DFMs) for the development of carbon capture and on-site utilization in a reactor at isothermal condition. The DFMs containing Ni functioning as a methanation catalyst with various CO2 adsorbents (i.e., CaO, MgO, K2CO3, or Na2CO3) were prepared on γ-Al2O3 through sequential impregnation. The result indicated that Ni-Na2CO3/γ-Al2O3 had the highest methanation capacity (i.e., 0.1783 mmol/g) and efficiency (i.e., 71.09%) in the CO2 adsorption–methanation test. The CO2 uptake and the subsequent methanation capacity of the Ni-Na2CO3/γ-Al2O3 increased to more than 24 times and more than 17 times, respectively, compared to Ni/γ-Al2O3. The high methanation capacity was correlated to its highest amount of weak basic sites, substantial CO2 capture capacity and capture/release efficiency, and reactivity to H2 at a lower temperature, supported by CO2-TPD, TGA analyses for adsorption or adsorption–desorption at the isothermal condition, and H2-TPRea, respectively. A continuous cyclic CO2 adsorption–methanation was performed by using the Ni-Na2CO3/γ-Al2O3 and Ni-CaO/γ-Al2O3, showing that the CO2 adsorption capacity was stabilized from third cycle onward, whereas the methanation capacity was stabilized at all cycles, indicating the high stability of the DFMs for both CO2 adsorption and subsequent methanation. This work demonstrated successful synthesis of the Ni-based, low-cost, and stable DFMs with the ability to produce methane via the direct capture of CO2.  相似文献   

18.
The screening of commercial nickel catalysts for methanation and a series of nickel catalysts supported on CeO2, γ-Al2O3, and ZrO2 in the reaction of selective CO methanation in the presence of CO2 in hydrogen-containing mixtures (1.5 vol % CO, 20 vol % CO2, 10 vol % H2O, and the balance H2) was performed at the flow rate WHSV = 26000 cm3 (g Cat)−1 h−1. It was found that commercial catalytic systems like NKM-2A and NKM-4A (NIAP-07-02) were insufficiently effective for the selective removal of CO to a level of <100 ppm. The most promising catalyst is 2 wt % Ni/CeO2. This catalyst decreased the concentration of CO from 1.5 vol % to 100 ppm in the presence of 20 vol % CO2 in the temperature range of 280–360°C at a selectivity of >40%, and it retained its activity even after contact with air. The minimum outlet CO concentration of 10 ppm at 80% selectivity on a 2 wt % Ni/CeO2 catalyst was reached at a temperature of 300°C.  相似文献   

19.
The dispersion of nickel catalysts is crucial for the catalytic ability of CO2 methanation, which can be influenced by the fabrication method and the operation process of the catalysts. Therefore, a series of fabrication methods, including ultrasonic, hydrothermal, microwave, and co-precipitation, have been applied to prepare 25Ni-5Er-Al2O3 catalysts. The fabrication method can partially influence the structural and catalytic activity of the nickel aluminate catalysts. Among the catalysts modified by Erbium prepared with various methods, the catalyst fabricated by ultrasonic pathway exhibited better catalytic performance and CH4 selectivity especially, at a temperature (400 ℃). The impact of the temperature of the reaction (200–500 °C) was examined under a stoichiometric precursor ratio of (H2:CO2) = 4: 1, atmospheric pressure, and space velocity (GHSV) of 25000 mL/gcath. The results demonstrate that the ultrasonic method is strongly efficient for fabricating Ni-based catalysts with a high BET surface area of about 190.33 m2g?1. The catalyst composed via the ultrasonic technique has 69.38 % carbon dioxide conversion and 100 % methane selectivity at 400 °C for excellent catalytic performance in CO2 methanation reactions. The fabrication effect can be associated with its high surface area, which is achieved via the hot spot mechanism. Besides, the addition of Erbium promotes the Ni dispersion on the supports and stimulates the positive reaction because of the erbium oxygen vacancies.  相似文献   

20.
Pt‐Co/Al2O2 catalyst has been studied for CO2 reforming of CH4 to synthesis gas. It was found that the catalytic performance of me catalyst was sensitive to calcination temperature. When Co/Al2O3 was calcined at 1473 K prior to adding a small amount of Pt to it, the resulting bimetallic catalyst showed high activity, optimal stability and excellent resistance to carbon deposition, which was more effective to the reaction than Co/Al2O3 and Pt/Al2O3 catalysts. At lower metal loading, catalyst activity decreased in the following order: Pt‐Co/ Al2O3 > Pt/Al2O3 > Co/Al2O3. With 9% Co, the Co/Al2O3 calcined at 923 K was also active for CO2 reforming of CH4, however, its carbon formation was much more fast man that of the Pt‐Co/Al2O3 catalyst. The XRD results indicated that Pt species well dispersed over the bimetallic catalyst. Its high dispersion was related to the presence of CoAl2O4, formed during calcining of Co/Al2O3 at high temperature before Pt addition. Promoted by Pt, Co/Al2O4 in the catalyst could be reduced partially even at 923 K, the temperature of pre‐reduction for the reaction, confirmed by TPR. Based on these results, it was considered that the zerovalent platinum with high dispersion over the catalyst surface and the zerovalent cobalt resulting from Co/Al2O4 reduction are responsible for high activity of the Pt‐Co/Al2O3 catalyst, and the remain Co/Al2O4 is beneficial to suppression of carbon deposition over the catalyst.  相似文献   

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