Interaction between Taylor bubbles rising in stagnant non-Newtonian fluids

The interaction between Taylor bubbles rising in stagnant non-Newtonian solutions was studied. Aqueous solutions of carboxymethylcellulose (CMC) and polyacrylamide (PAA) polymers were used to study the effect of different rheological properties: shear viscosity and viscoelasticity. The solutions studied covered a range of Reynolds numbers between 10 and 714, and Deborah numbers up to 14. The study was performed with pairs of Taylor bubbles rising in a vertical column (0.032 m internal diameter) filled with stagnant liquid. The velocities of the leading and trailing bubbles were measured by sets of laser diodes/photocells placed along the column. The velocity of the trailing bubble was analysed together with the liquid velocity profile in the wake of a single rising bubble (Particle Image Velocimetry data obtained from the literature). For the less concentrated CMC solutions, with moderate shear viscosity and low viscoelasticity, the interaction between Taylor bubbles was similar to that found in Newtonian fluids. For the most concentrated CMC solution, which has high shear viscosity and moderate viscoelasticity, a negative wake forms behind the Taylor bubbles, inhibiting coalescence since the bubbles maintain a minimum distance of about 1D between them. For the PAA solutions, with moderate shear viscosity but higher viscoelasticity than the CMC solutions, longer wake lengths are seen, which are responsible for trailing bubble acceleration at greater distances from the leading bubble. Also in the PAA solutions, the long time needed for the fluid to recover its initial shear viscosity after the passage of the first bubble makes the fluid less resistant to the trailing bubble flow. Hence, the trailing bubble can travel at a higher velocity than the leading bubble, even at distances above 90D.     

Turbulent flow of mildly elastic fluids through rotating straight circular tubes

The turbulent flow of mildly elastic drag reducing fluids through a straight tube rotating around an axis perpendicular to its own is analysed using boundary layer approximations. The momentum integral approach is used and the governing equations have been solved numerically using the Runge-Kutta-Merson method. The influence of the Deborah number on the velocity distribution and the boundary layer thickness has been exemplified through the analysis. NCL Communication No. 3354.     

Flow visualization of the elastic Taylor-Couette instability in Boger fluids

Flow visualization is performed on an elastically-dominated instability in several similar Boger fluids in Taylor-Couette flow. The onset and evolution of secondary flow are observed over a range of shear rates using reflective mica platelet seeding. Sequences of ambiently and sheet-illuminated images were digitally processed. Rotation of the inner cylinder was ramped from rest to its final value over a time on the order of a polymer relaxation time. Dilute solutions of high molecular weight polyisobutylene in oligomeric polybutene manifest a flow transition at a Deborah number, De _s = _s 1.5 with a Taylor number of 0.00022 in a cell with dimensionless gap ratio = 0.0963. At this transition, simple azimuthal shearing is replaced by steady, roughly square, axisymmetric counter-rotating vortices grossly similar to the well-known Taylor vortex flow that is observed at De _s = 0, Ta = 3612. At De _s = 3.75, Ta = 0.0014, an axisymmetric oscillatory secondary flow develops initially but is replaced by the steady vortices. At De _s = 7.5, Ta = 0.0054, the oscillatory and vortex flow coexist and possess an irregular cellular cross-section. A wide span of growth rates is observed: the ratio of onset to polymer relaxation time ranges from 170000 at De _s = 1.5 to O(10) at De _s > 5. The role of inertia was explored through changing the solvent viscosity. A transition similar to the one that occurs at De _s = 3.75, Ta = 0.0014, from the base azimuthal shearing flow to axisymmetric vortices, was also observed with a much lower viscosity fluid at De _s = 3.3, Ta = 74.     

On the motion of long bubbles in vertical tubes

Potential flow theory has been applied to study the shape and speed of an infinitely long bubble rising through flowing liquid in a vertical tube. In particular, the combined effects of surface tension and externally forced liquid motion are examined. An analytical formula for the bubble rise velocity in stagnant liquid is proposed, and shown to be in good agreement with experimental data for all values of surface tension. Numerical solutions for the bubble velocity in upward flowing liquid are obtained for laminar and turbulent velocity profiles. Approximate expressions for the bubble velocity, where the effects of liquid motion and surface tension are incorporated through the Reynolds and inverse Eötwos, are proposed and compared with experimental data. The predicted changes in bubble shape have, to a large extent, been confirmed through comparisons with photographic evidence for a wide range of parameters.     

An experimental investigation of the motion of long bubbles in inclined tubes

The relative motion of single long air bubbles suspended in a constant liquid flow in inclined tubes has been studied experimentally. Specially designed instrumentation, based on the difference in refractive properties of air and liquid with respect to infrared light, has been constructed and applied to measure bubble propagation rates.A series of experiments were performed to determine the effect of tube inclination on bubble motion with liquid Reynolds and Froude numbers, and tube diameter as the most important parameters.Particular aspects of the flow are described theoretically, and model predictions were found to compare well with observations. A correlation of bubble and average liquid velocities, based on a least squares fit to the data is suggested. Comparisons with other relevant models and data are also presented.     

Chaining of weakly interacting particles suspended in viscoelastic fluids

An asymptotic theory based on multipole expansions is presented for multiparticle interactions in unbounded, weakly viscoelastic, creeping flows. The theory accounts for non-Newtonian sphere–sphere interactions that are of order O(De(a/R)²)$\text{O}(De{(a/R)}^2)$, where De is the Deborah number, a the sphere radius and R is the sphere–sphere separation. Analytic expressions are derived for the non-Newtonian correction to the multisphere mobility matrix for non-neutrally buoyant sedimenting spheres, and for neutrally buoyant spheres suspended in a shear flow. It is shown that these expressions give rise to particle chaining in simulations of interacting spherical particles.     

Effects of bubble size on heat transfer enhancement by sub-millimeter bubbles for laminar natural convection along a vertical plate

Injection of sub-millimeter bubbles is considered a promising technique for enhancing natural convection heat transfer for liquids. So far, we have experimentally investigated heat transfer characteristics of laminar natural convection flows with sub-millimeter bubbles. However, the effects of the bubble size on the heat transfer have not yet been understood. The purpose of this study is to clarify the effects of the bubble size on the heat transfer enhancement for the laminar natural convection of water along a vertical heated plate with uniform heat flux. Temperature and velocity measurements, in which thermocouples and a particle tracking velocimetry technique are, respectively used, are conducted to investigate heat transfer and flow characteristics for different bubble sizes. Moreover, two-dimensional numerical simulations are performed to comprehensively understand the effects of bubble injection on the flow near the heated plate. The result shows that the ratio of the heat transfer coefficient with sub-millimeter-bubble injection to that without injection ranges from 1.3 to 2.2. The result also shows that for a constant bubble flow rate, the heat transfer coefficient ratio increases with a decrease in the mean bubble diameter. It is expected from our estimation based on both experimental data and simulation results that this increase results from an increase in the advection effect due to bubbles.     

The motion of rigid particles in viscoelastic fluids

In this paper, we study the motion of a rigid particle in a viscoelastic fluid under the assumption of negligible inertial effects (based on particle dimensions). Concentrating solely upon situations where no change of orientation or position of the particle is possible in a Newtonian solvent, it suffices to consider the low Weissenberg number limit. By employing the concept of a second-order-fluid, the theoretical predictions for a single particle in an essentially unbounded domain correlate quite well with experimental results. As soon as interaction effects (particle—particle and particle—wall, respectively) are included in the theory, all predictions are at odds with the observations.     

On viscoelastic effects in non-Newtonian steady flows through porous media

This paper presents a mathematical model for describing approximately the viscoelastic effects in non-Newtonian steady flows through a porous medium. The rheological behaviour of power law fluids is considered in the Maxwell model of elastic behaviour of the fluids. The equations governing the steady flow through porous media are derived and an analytical solution of these equations in the case of a simple flow system is obtained. The conditions for which the viscoelastic effects may become observable from the pressure distribution measurements are shown and expressed in terms of some dimensionless groups. These have been found to be relevant in the evaluation of viscoelastic effects in the steady flow through porous media.     

Computation of flow of viscoelastic fluids by parameter differentiation

A technique combining the features of parameter differentiation and finite differences is presented to compute the flow of viscoelastic fluids. Two flow problems are considered: (i) three-dimensional flow near a stagnation point and (ii) axisymmetric flow due to stretching of a sheet. Both flows are characterized by a boundary value problem in which the order of the differential equation exceeds the number of boundary conditions. The exact numerical solutions are obtained using the technique described in the paper. Also, the first-order perturbation solutions (in terms of the viscoelastic fluid parameter) are derived. A comparison of the results shows that the perturbation method is inadequate in predicting some of the vital characteristic features of the flows, which can possibly be revealed only by the exact numerical solution.     

Detecting instabilities in flows of viscoelastic fluids

There is a growing interest in developing numerical tools to investigate the onset of physical instabilities observed in experiments involving viscoelastic flows, which is a difficult and challenging task as the simulations are very sensitive to numerical instabilities. Following a recent linear stability analysis carried out in order to better understand qualitatively the origin of numerical instabilities occurring in the simulation of flows viscoelastic fluids, the present paper considers a possible extension for more complex flows. This promising method could be applied to track instabilities in complex (i.e. essentially non‐parallel) flows. In addition, results related to transient growth mechanism indicate that it might be responsible for the development of numerical instabilities in the simulation of viscoelastic fluids. Copyright © 2003 John Wiley & Sons, Ltd.     

Flow of viscoelastic fluids through a porous channel—I

The flow of viscoelastic fluids through a porous channel with one impermeable wall is computed. The flow is characterized by a boundary value problem in which the order of the differential equation exceeds the number of boundary conditions. Three solutions are developed: (i) an exact numerical solution, (ii) a perturbation solution for small R, the cross-flow Reynold's number and (iii) an asymptotic solution for large R. The results from exact numerical integration reveal that the solutions for a non-Newtonian fluid are possible only up to a critical value of the viscoelastic fluid parameter, which decreases with an increase in R. It is further demonstrated that the perturbation solution gives acceptable results only if the viscoelastic fluid parameter is also small. Two more related problems are considered: fluid dynamics of a long porous slider, and injection of fluid through one side of a long vertical porous channel. For both the problems, exact numerical and other solutions are derived and appropriate conclusions drawn.     

Transient behavior of Boger fluids under extended shear flow in a cone-and-plate rheometer

Three different dilute solutions of high molecular weight polymers in viscous, binary solvents were used in experiments performed in a cone-and-plate rheometer. The solutions all fall into the class of fluids referred to as Boger fluids and were previously used in studies of viscoelastic Taylor-Couette instabilities. Under prolonged shearing in the cone-and-plate geometry, these fluids all exhibited a decrease of the first normal stress growth function N₁⁺(t) from an initial plateau value to a second, lower plateau value. This behavior has been previously observed, but is here reported for widely used polyisobutylene-based Boger fluids for the first time. As in earlier studies (Magda JJ, Lee C-S, Muller SJ, Larson RG (1993) Macromolecules 26:1696–1706; MacDonald M, Muller SJ (1997) J Rheol Acta 36:97–109), the time at which this decrease occurs (the decay time) is much longer than the polymer molecules relaxation time. Here, we focus on three issues: 1) the time-temperature superposition of the first normal stress growth function N₁⁺(t), including the decay time and the value of the second plateau, 2) the sample recovery time required to reproduce the initial plateau value of N₁⁺ and the decay time, and 3) the relationship between the time scales for this decay of normal stresses and the onset of viscous heating induced instabilities in the Taylor-Couette geometry. Our results suggest that shear-induced conformational changes, possibly coupled to viscous heating of the sample, may be responsible for the decrease in the first normal stress growth function during prolonged shearing.     

On the fully developed tube flow of a class of non-linear viscoelastic fluids

The fully developed pipe flow of a class of non-linear viscoelastic fluids is investigated. Analytical expressions are derived for the stress components, the friction factor and the velocity field. The friction factor which depends on the Deborah and Reynolds numbers is substantially smaller than the corresponding value for the Newtonian flow field with implications concerning the volume flow rate. We show that non-affine models in the class of constitutive equations considered such as Johnson-Segalman and some versions of the Phan-Thien-Tanner models are not representative of physically realistic flow fields for all Deborah numbers. For a fixed value of the slippage factor they predict physically admissible flow fields only for a limited range of Deborah numbers smaller than a critical Deborah number. The latter is a function of the slippage.     

A note on start-up and large amplitude oscillatory shear flow of multimode viscoelastic fluids

Start up of plane Couette flow and large amplitude oscillatory shear flow of single and multimode Maxwell fluids as well as Oldroyd-B fluids have been analyzed by analytical or semi-analytical procedures. The result of our analysis indicates that if a single or a multimode Maxwell fluid has a relaxation time comparable or smaller than the rate of change of force imparted on the fluid, then the fluid response is not singular as Elasticity Number (E ). However, if this is not the case, as E , perturbations of single and multimode Maxwell fluids give rise to highly oscillatory velocity and stress fields. Hence, their behavior is singular in this limit. Moreover, we have observed that transients in velocity and stresses that are caused by propagation of shear waves in Maxwell fluids are damped much more quickly in the presence of faster and faster relaxing modes. In addition, we have shown that the Oldroyd-B model gives rise to results quantitatively similar to multimode Maxwell fluids at times larger than the fastest relaxation time of the multimode Maxwell fluid. This suggests that the effect of fast relaxing modes is equivalent to viscous effects at times larger than the fastest relaxation time of the fluid. Moreover, the analysis of shear wave propagation in multimode Maxwell fluids clearly show that the dynamics of wave propagation are governed by an effective relaxation and viscosity spectra. Finally, no quasi-periodic or chaotic flows were observed as a result of interaction of shear waves in large amplitude oscillatory shear flows for any combination of frequency and amplitudes.     

On the flow resistance of viscoelastic fluids through packed beds

Analytical solutions are obtained for the free surface cell model of packed beds using a third order fluid. Second order perturbed results indicate a substantial increase in resistance to the flow of a viscoelastic fluid through a packed bed. This predicted increase is in good agreement with experimental findings.     

Break-up of a Newtonian drop in a viscoelastic matrix under simple shear flow

The effect of matrix elasticity on the break-up of an isolated Newtonian drop under step shear flow is herein presented. Constant-viscosity, elastic polymer solutions (Boger fluids) were used as matrix phase. Newtonian silicon oils were used as drop phase. Three viscosity ratios were explored (drop/matrix), i.e. 2, 0.6 and 0.04. Following the theoretical analysis of Greco [Greco F (2002) J Non-Newtonian Fluid Mech 107:111–131], the role of elasticity on drop fluid dynamics was quantified according to the value of the parameter p=/_em, where is a constitutive relaxation time of the matrix fluid and _em is the emulsion time. Different fluids were prepared in order to have p ranging from 0.1 to 10. At all the viscosity ratios explored, break-up was hindered by matrix elasticity. The start-up transient of drop deformation, at high, but sub-critical capillary numbers, showed an overshoot, during which the drop enhanced its orientation toward the flow direction. Both phenomena increase if the p parameter increases. Finally, the non-dimensional pinch-off length and break-up time were also found to increase with p.This paper was presented at the first Annual European Rheology Conference (AERC) held in Guimarães, Portugal, September 11-13, 2003.     

Three-dimensional flow of Newtonian and Boger fluids in square–square contractions

The flow of a Newtonian fluid and a Boger fluid through sudden square–square contractions was investigated experimentally aiming to characterize the flow and provide quantitative data for benchmarking in a complex three-dimensional flow. Visualizations of the flow patterns were undertaken using streak-line photography, detailed velocity field measurements were conducted using particle image velocimetry (PIV) and pressure drop measurements were performed in various geometries with different contraction ratios. For the Newtonian fluid, the experimental results are compared with numerical simulations performed using a finite volume method, and excellent agreement is found for the range of Reynolds number tested (Re₂ ≤ 23). For the viscoelastic case, recirculations are still present upstream of the contraction but we also observe other complex flow patterns that are dependent on contraction ratio (CR) and Deborah number (De₂) for the range of conditions studied: CR = 2.4, 4, 8, 12 and De₂ ≤ 150. For low contraction ratios strong divergent flow is observed upstream of the contraction, whereas for high contraction ratios there is no upstream divergent flow, except in the vicinity of the re-entrant corner where a localized atypical divergent flow is observed. For all contraction ratios studied, at sufficiently high Deborah numbers, strong elastic vortex enhancement upstream of the contraction is observed, which leads to the onset of a periodic complex flow at higher flow rates. The vortices observed under steady flow are not closed, and fluid elasticity was found to modify the flow direction within the recirculations as compared to that found for Newtonian fluids. The entry pressure drop, quantified using a Couette correction, was found to increase with the Deborah number for the higher contraction ratios.     

Estimation of particle dynamics in 2-D fluidized beds using particle tracking velocimetry

The experimental characterization of particle dynamics in fluidized beds is of great importance in fostering an understanding of solid phase motion and its effect on particle properties in granulation processes. Commonly used techniques such as particle image velocimetry rely on the cross-correlation of illumination intensity and averaging procedures. It is not possible to obtain single particle velocities with such techniques. Moreover, the estimated velocities may not accurately represent the local particle velocities in regions with high velocity gradients. Consequently, there is a need for devices and methods that are capable of acquiring individual particle velocities. This paper describes how particle tracking velocimetry can be adapted to dense particulate flows. The approach presented in this paper couples high-speed imaging with an innovative segmentation algorithm for particle detection, and employs the Voronoi method to solve the assignment problem usually encountered in densely seeded flows. Lagrangian particle tracks are obtained as primary information, and these serve as the basis for calculating sophisticated quantities such as the solid-phase flow field, granular temperature, and solid volume fraction. We show that the consistency of individual trajectories is sufficient to recognize collision events.     

Electrohydrodynamic instability of two superposed Walters B´ viscoelastic fluids in relative motion through porous medium

Summary  The electrohydrodynamic Kelvin–Helmholtz instability of the interface between two uniform superposed viscoelastic (B′ model) dielectric fluids streaming through a porous medium is investigated. The considered system is influenced by applied electric fields acting normally to the interface between the two media, at which there are no surface charges present. In the absence of surface tension, perturbations transverse to the direction of streaming are found to be unaffected by either streaming and applied electric fields for the potentially unstable configuration, or streaming only for the potentially stable configuration, as long as perturbations in the direction of streaming are ignored. For perturbations in all other directions, there exists instability for a certain wavenumber range. The instability of this system can be enhanced (increased) by normal electric fields. In the presence of surface tension, it is found also that the normal electric fields have destabilizing effects, and that the surface tension is able to suppress the Kelvin–Helmholtz instability for small wavelength perturbations, and the medium porosity reduces the stability range given in terms of the velocities difference and the electric fields effect. Finally, it is shown that the presence of surface tension enhances the stabilizing effect played by the fluid velocities, and that the kinematic viscoelasticity has a stabilizing as well as a destabilizing effect on the considered system under certain conditions. Graphics have been plotted by giving numerical values to the parameters, to depict the stability characteristics. Received 27 March 2000; accepted for publication 3 May 2001