Optical characterization in Pb(Zr1?xTix)1?yNbyO3 ferroelectric ceramic system

In this work, visible photoluminescence was observed at room temperature in a sintered Pb(Zr_1-xTi_x)_1-y Nb_yO₃\mathrm{Pb}(\mathrm{Zr}_{1-x}\mathrm{Ti}_{x})_{1-y} \mathrm{Nb}_{y}\mathrm{O}_{3} perovskite-type structure system, doped with Nb using the next excitation bands 325, 373 and 457 nm. The intensity and energy of such emissions have been studied by changing the Nb concentration (0<y<0.01) and the Ti content (x), with x=0.20,0.40,0.53,0.60 and 0.80, on both sides of the morphotropic phase boundary (MPB) zone. The principal bands become visible at energies of 1.73, 2.56 and 3.35 eV. The results reveal the role of the Nb⁵⁺ ion substitutions by Zr⁴⁺ or Ti⁴⁺ ions and the symmetry presented in the rhombohedral or tetragonal side of the MPB. Raman spectra which are similar for compositions: 20/80, 40/60 and 53/47 (tetragonal phases) show nine bands, centered around 137, 194, 269, 331, 434, 550, 612, 712 and 750 cm⁻¹. The spectra for samples 60/40 and 80/20, rhombohedral phase, show significant differences, only six bands appear, centered around 124, 209, 234, 330, 549 and 682 cm⁻¹. In addition, optical absorption spectroscopy, structural and micro-structural measurements were carried out by using Uv-vis spectroscopy, X-ray diffraction and scanning electron microscopy techniques, respectively. The experimental results of band gap energy, e.g., in our samples are in accordance with the findings by J. Baedi et al. in the calculations of band structure, energy gap and density of states for different phases of Pb(Zr_1−x Ti _x )O₃ using density functional theory (DFT).     

Electrical conductivity and magnetic properties of La1 ? xCaxMn1 ? yFeyO3 ceramic samples (x = 0.67, y = 0, 0.05)

The temperature dependences of the magnetic susceptibility χ(T) and the electrical resistivity ρ(T) of ceramic samples of La_{1 − x} Ca _x MnO₃ with x = 0.67 (LCMO) and La_{1 − x} Ca _x Mn_{1 − y} Fe _y O₃ with x = 0.67 and y = 0.05 (LCMFO) are investigated in magnetic fields B = 50–10⁵ G and the temperature range T = 4.2–400 K. Both samples undergo a transition from the paramagnetic state to a state with charge (orbital) ordering (CO) at temperatures T _CO ≈ 272 K for LCMO and T _CO ≈ 222 K for LCMFO. The behavior of the paramagnetic phase in the temperature range 320–400 K for LCMO and 260–400 K for LCMFO is described by the Curie-Weiss law with effective Bohr magneton numbers p _eff = 4.83 μ_B (LCMO) and 4.77 μ_B (LCMFO), respectively. The disagreement between the observed positive Weiss temperatures (θ ≈ 175 K (LCMO) and θ ≈ 134 K (LCMFO)) and negative Weiss temperatures required for the antiferromagnetic ground state can be explained by the phase separation and transition to the charge-ordered state. The magnetic irreversibility for T < T _CO is accounted for by the existence of a mixture of the ferromagnetic and antiferromagnetic phases, as well as the cluster glass phase. At low temperatures, doping with iron enhances the frustration of the system, which manifests itself in a more regular behavior of the decay rate of the remanent magnetization with time. The temperature dependence of the electrical resistivity in the range of the charge-ordered phase conforms to the variable-range hopping model. The behavior of the electrical resistivity is governed by the complex structure of the density of localized states near the Fermi level, which includes a soft Coulomb gap Δ = 0.464 eV for LCMO and 0.446 eV for LCMFO. It is established that the ratio between the localization radii of charge carriers a for LCMFO and a _und for LCMO is a/a _und = 0.88. Original Russian Text ? V.S. Zakhvalinskiĭ, R. Laiho, T.S. Orlova, A.V. Khokhulin, 2008, published in Fizika Tverdogo Tela, 2008, Vol. 50, No. 1, pp. 61–68.     

Structural and electrical investigation of (Ag3AsS3)x(As2S3)1?x superionic glasses

Structural studies of (Ag₃AsS₃) _x (As₂S₃)_1−x chalcogenide superionic glasses in the compositional range x = 0.3–0.9 were performed by scanning electron microscopy. Temperature and compositional dependences of transmission coefficient, electrical conductivity, and activation energy were investigated     

Magnetic phase transitions in Nd1 ? xDyxFe3(BO3)4 ferroborates

The magnetic properties of ferroborate single crystals with substituted compositions Nd_{1 − x} Dy _x Fe₃(BO₃)₄ (x = 0.15, 0.25) with competing exchange Nd-Fe and Dy-Fe interactions are investigated. For each composition, we observed a spontaneous spin-reorientation transition from the easy-axis to the easy-plane state and step anomalies on the magnetization curves for the spin-flop transition induced by a magnetic field B | c. The measured parameters and effects are interpreted using a unified theoretical approach based on the molecular field approximation and on calculations performed in the crystal-field model for the rare-earth ion. The experimental temperature dependences of the initial magnetic susceptibility from T = 2 K to T = 300 K, anomalies on the magnetization curves for B | c in fields up to 1.8 T, and their evolution with temperature, as well as temperature and field dependences of magnetization in fields up to 9 T are described. In the interpretation of experimental data, the crystal-field parameters in trigonal symmetry for the rare-earth subsystem are determined, as well as the parameters of Nd-Fe and Dy-Fe exchange interactions.     

(La0.7Sr0.3MnO3 )m(BiFeO3)n 超晶格结构的导电机理

利用射频磁控溅射的方法在SrTiO₃(001) 基片上制备了(La_0.7Sr_0.3MnO₃)_m(BiFeO₃)_n超晶格结构.对所制备的超晶格结构进行了50—150℃温度范围内的电流-电压测试分析.结果表明,随着BiFeO₃薄膜的厚度减小,温度的升高,(La_0.7Sr_0.3MnO₃)_m(BiFeO₃)_n超晶格结构的电流变大.进一步根据介质导电模型对(La_0.7Sr_0.3MnO₃)_m(BiFeO₃)_n超晶格结构的导电特性做了分析.在温度较低或者电场较弱时,所制备的(La_0.7Sr_0.3MnO₃)_m(BiFeO₃)_n超晶格结构表现为欧姆导电,而在高温,高电场的情况下,其导电行为由空间电荷限制电流机理主导. 关键词： 超晶格薄膜 多铁 空间电荷限制电流     

Study of high-temperature oxygen permeability in Sr1 ? xLaxCo0.8 ? yNbyFe0.2O3 ? z perovskites

The oxygen permeability of ceramic SrCo_{0.8 − y} Fe_0.2Nb _y O_{3 − z} (0 ≤ y ≤ 0.2) and La_0.3Sr_0.7Co_0.6Fe_0.2Nb_0.2O_{3 − z} disc membranes as a function of temperature and oxygen partial pressure was studied. Kinetic analysis was performed based on the experimental data on oxygen permeability as a function of oxygen partial pressure.     

Nd0.67Sr0.33MnOy(y<3.0)中的自旋相关电致电阻效应

用固相反应法制备系列Nd_0.67Sr_0.33MnO_y(y = 3.00—2.80)多晶样品.样品输运性质表现出自旋相关电致电阻特征.对氧含量等于化学计量样品，在测量温度范围内电阻不随负载电流变化，I-V曲线符合线性欧姆定律.对氧含量低于化学计量样品，当高于某一特征温度时，电阻变化符合线性欧姆定律；但低于这一特征温度时，电阻大小与负载电流有关，I-V曲线偏离线 关键词： 钙钛矿结构锰氧化物 电致电阻效应 自旋相关界面输运 氧缺陷     

Ferromagnetic resonance and magnetic microstructure in nanocomposite films of Cox(SiO2)1 ? x and (CoFeB)x(SiO2)1 ? x

This paper reports on the results of the investigation of the relation between the magnetic microstructure and ferromagnetic resonance (FMR) in ferromagnetic metal-insulator composites by using granular alloys (Co₄₁Fe₃₉B₂₀) _x (SiO₂)_{1 − x} and Co _x (SiO₂)_{1 − x} as an example. A comparative analysis of the properties of FMR spectra and parameters of random magnetic anisotropy leads to correlations between these quantities. It has been found that the main mechanism that determines the FMR line width in the films under investigation is the exchange narrowing mechanism.     

Elektronen-Spin-Resonanz an (La1??xGdyCex)Al2

In the EPR of (La_1––x Gd _y Ce _x )Al₂ a bottleneck in the relaxation of the conduction electrons to the lattice is present at sufficiently high Gd-concentrations. The bottleneck can be broken by decreasing the Gd-concentration or by adding Cerium as a spin-flip-scatterer.g-factor and line broadening are measured for (La_1–y Gd _y )Al₂ and (La_1––x Gd _y Ce _x )Al₂ as a function of temperature and Gd- and Ce-concentrations. The Cerium induced relaxationsrate _eL (Ce) increases linearly with Ce-concentration up tox0.025. This corresponds to the fact, well known by measurements of the Kondo anomalies, that Cerium impurities show no significant interaction up to rather high concentrations.     

Ferromagnetic resonance, magnetic properties, and resistivity of (CoFeZr)x(Al2O3)1 ? x/Si multilayer nanostructures

Comparative investigations of static magnetic properties, magnetoresistance, and ferromagnetic resonance data of multilayer nanostructures consisting of CoFeZr-Al₂O₃ composite magnetic layers and amorphous silicon semiconductor spacers were performed in a layer thickness range below 5 nm. The influence of layer dimension parameters and chemical peculiarities of silicon on the inner structure and type of magnetic interactions in nanostructures with 35 and 46 at % magnetic phase composite layers is discussed.     

Magnetic anisotropy and magnetoelectric properties of Tb1 ? xErxFe3(BO3)4 ferroborates

Magnetic and magnetoelectric properties of ferroborate single crystals with complex composition (Tb_{1 − x} Er _x Fe₃(BO₃)₄, x = 0, 0.75) and with competing exchange Tb-Fe and Er-Fe interactions are investigated. Jumps in electric polarization, magnetostriction, and magnetization are observed as a result of spin-flop transitions, as well as a considerable decrease in the critical field upon an increase in the Er concentration, in a field H _c parallel to the c axis. The observed behavior of phase-transition fields is analyzed and explained using a simple model taking into account anisotropy in g factors and exchange splitting of funda-mental doublets of the easy-axis Tb³⁺ ion and easy-plane Er³⁺ ion. It is established that magnetoelectric and magnetostriction anomalies under spin-flop transitions are mainly controlled by the Tb subsystem. The Tb subsystem makes a nonmonotonic contribution ΔP _a (H _a , T) to polarization along the a axis: the value of ΔP _a reverses its sign and increases with temperature due to the contribution from the excited states of the Tb³⁺ ion. Original Russian Text ? A.K. Zvezdin, A.M. Kadomtseva, Yu.F. Popov, G.P. Vorob’ev, A.P. Pyatakov, V.Yu. Ivanov, A.M. Kuz’menko, A.A. Mukhin, L.N. Bezmaternykh, I.A. Gudim, 2009, published in Zhurnal éksperimental’noĭ i Teoreticheskoĭ Fiziki, 2009, Vol. 136, No. 1, pp. 80–86.     

Structure, phase transitions, 55Mn NMR, and magnetoresistive properties of La0.6Sr0.2Mn1.2 ? yCryO3 ± δ

The structure and properties of lanthanum strontium manganite perovskites La_0.6Sr_0.2Mn_{1.2 − y} Cr _y O_{3 ± δ} (y = 0–0.3) sintered at 1430°C have been studied by X-ray, resistive, and magnetic (χ_ac and ⁵⁵Mn NMR) methods. The parameter of the rhombohedrally distorted (R $ \bar 3 $ \bar 3 c) perovskite structure decreases with increasing y. The real perovskite structure contains point (anion and cation vacancies) and cluster-type nanostructure defects. The analysis of asymmetrically broadened ⁵⁵Mn NMR spectra has confirmed the high-frequency electron-hole exchange Mn³⁺ ↔ Mn⁴⁺ and local inhomogeneity of their surrounding by other ions and point and cluster-type defects. An increase in the Cr content leads to an increase in the resistivity and the magnetoresistive effect and a decrease in the metal-semiconductor and ferromagnetic-paramagnetic phase transition temperatures (T _ms and T _c ) due to the distortion of the exchange interactions Mn³⁺ ↔ Mn⁴⁺ by chromium ions, vacancies, and clusters. Introduction of Cr decreases the ferromagnetic component and increases the activation energy. The magnetoresistive effect near T _ms and T _c is caused by scattering of charge carriers from intercrystallite nanostructure inhomogeneities of the lattice, and the low-temperature effect is associated with the tunneling on mesostructural intercrystallite boundaries.     

Synthesis and characterization of ZnxHg1?xSeyS1?y quantum dots

This article describes the synthesis of highly water-soluble Zn _x Hg_1−x Se _y S_1−y quantum dots (QDs) in aqueous solution through a simple photo-assisted reaction between ZnSe QDs and mercury(I) nitrate dihydrate [Hg₂(NO₃)₂·2H₂O]. In order to deduce the optimal synthesis conditions, we varied several parameters, including the concentrations of mercaptosuccinic acid (MSA) and Hg₂(NO₃)₂·2H₂O, the illumination time, and the reaction temperature. When irradiated at temperatures below 80 °C, the ZnSe QDs reacted with the S²⁻ ions formed rapidly from MSA and the Hg²⁺ ions formed from Hg₂ ²⁺ ions to form Zn _x Hg_1−x Se _y S_1−y QDs through a process of photo-etching and surface combination. Under different conditions, we prepared a series of Zn _x Hg_1−x Se _y S_1−y QDs that emit fluorescence at the maximum wavelengths ranging from 405 to 760 nm. Inductively coupled plasma-mass spectrometry and transmission electron microscopy/energy dispersive spectrometry revealed that the content of Hg in the Zn _x Hg_1−x Se _y S_1−y QDs was greater when the synthesis was conducted at higher temperature. The Zn_0.88Hg_0.12Se_0.44S_0.56 QDs exhibit improved photostability than crude ZnSe QDs and possess long lifetimes (τ₁ ~ 38 ns and τ₂ ~ 158 ns).     

Magnetic and ferroelectric properties of exchange-frustrated multiferroics (Ni1 ? xTx)3V2O8 (T = Co, Mn, Zn)

The effect of the substitution of Co²⁺, Mn²⁺, and Zn²⁺ ions for Ni²⁺ ions on the magnetic, dielectric, and ferroelectric properties of vanadate single crystals (Ni_{1 − x} T _x )₃V₂O₈ has been analyzed. It has been found that the low-level (x ≤ 0.1) substitution of both magnetic and nonmagnetic ions stabilizes the ferroelectric state with a cycloidal magnetic structure. The existence region of this state is expanded to low temperatures down to 3 K for Zn²⁺ and below 1.8 K for Co²⁺ and Mn²⁺ owing to the suppression of a low-temperature weak ferromagnetic phase. At the same time, the ferroelectric phase disappears completely at large concentrations of Co and Mn. The effect of magnetic fields on the magnetic and ferroelectric states has been analyzed. It has been shown that the magnetic field along the c axis suppresses the ferroelectric state, whereas the magnetization along the antiferromagnetism axis (a axis) induces the reentrant phase transition from a paraelectric weak ferromagnetic structure to a ferroelectric structure. The corresponding H-T phase diagrams have been drawn.     

Electrical and magnetic properties of [(CoFeZr)x(Al2O3)1 ? x/(α-SiH)]n multilayer structures

The concentration dependences of the electrical resistivity and complex permeability of [“(Co₄₅Fe₄₅Zr₁₀) _x (Al₂O₃)_{100 − x} ”/“α-Si: H”] _n multilayer structures and (Co₄₅Fe₄₅Zr₁₀) _x (Al₂O₃)_{100 − x} composites have been studied. It has been established that introduction of a semiconductor interlayer into the (Co₄₅Fe₄₅Zr₁₀) _x (Al₂O₃)_{100 − x} composites substantially decreases the electrical resistivity of [“(Co₄₅Fe₄₅Zr₁₀) _x (Al₂O₃)_{100 − x} ”/“α-Si: H”] _n multilayer structures. The concentration dependences of the real and imaginary parts of the complex permeability of the [“(Co₄₅Fe₄₅Zr₁₀) _x (Al₂O₃)_{100 − x} ”/“α-Si: H”] _n nanomultilayer structures substantially differ from those of the (Co₄₅Fe₄₅Zr₁₀) _x (Al₂O₃)_{100 − x} composites. The real part of the complex permeability of the [“(Co₄₅Fe₄₅Zr₁₀) _x (Al₂O₃)_{100 − x} ”/“α-Si: H”] _n nanomultilayer structures follows the curve with a minimum near the percolation threshold of the composite, and the imaginary part smoothly decreases as the ferromagnetic phase concentration increases. The results obtained are explained by the increase in the bifurcation temperature due to the conduction electrons of the semiconductor interlayer, which favor magnetic ordering of ferromagnetic grains.     

Optical properties of (In2Se3)1–x·(CuIn5Se8)x solid solutions

Single crystals of In₂Se₃ and CuIn₅Se₈ compounds and (In₂Se₃)_1–x·(CuIn₅Se₈)_x solid solutions have been grown from the melt using the Bridgman method and their composition and structure determined. It is shown that the crystals have n-type conductivity. Their transmission spectra were studied in the self-absorption edge region at 80 and 295 K. Based on the spectral measurements, the band gap width (E_g) was determined and the band gap concentration dependences were plotted. It is found that E_g varies with the x composition nonlinearly. Using the dielectric model of Van Vechten–Bergstresser and the Hill–Richardson pseudo potential model, E_g(x) was calculated theoretically.     

Dielectric tunability and conduction mechanisms of?nanostructured (Pb1?xSrx)TiO3 thin films

The effect of nanosize grains to enhance dielectric tunability in chemically prepared (Pb_1−x Sr _x )TiO₃ (PST) (x=0.1 to 0.5) thin films has been observed. The grain size is evaluated from X-ray diffraction patterns and atomic force microscopy. The average grain size lies in the range of 80–23 nm with varying Sr content. The nanosize grains in the PST films control the dielectric behavior up to the higher frequency region and exhibit large tunability with low loss factor at room temperature. The current–voltage characteristics show a large tunability as electron transport takes place within a highly resistive Fermi gap.     

(La0.7Sr0.3MnO3)m(BiFeO3)n超晶格间隔的La0.7Sr0.3MnO3三明治结构制备及表征

采用射频磁控溅射的方法在SrTiO₃（001） 基片上制备了（La_0.7Sr_0.3MnO₃）_m（BiFeO₃）_n超晶格间隔的La_0.7Sr_0.3MnO₃三明治结构.X射线衍射分析证明（La_0.7Sr_0.3MnO_{关键词： 超晶格薄膜 电诱导效应 隧道效应}     

Profile of the refractive index distribution over the depth of (HfO2)x(Al2O3)1 ? x films

Capabilities of the method of laser null ellipsometry for the study of optical parameters of thin films of multicomponent alloys are demonstrated. Films of alloys (HfO₂) _x (Al₂O₃)_{1 − x} on single-crystal silicon are obtained by the chemical vapor deposition with the use of the following volatile compounds: hafnium dipivaloylmethanate (IV) and aluminum acetylacetonate (III). The selection of initial sets for their optical parameters is justified. The selected model is shown to correspond to experimental data. In films deposited from the mixture of precursors, the refractive index increases from a substrate to a film surface. Due to the separation of sources, films described by a single-layer model were deposited. This fact is indicative of the homogeneous distribution of components over the film thickness.