Gamma-ray spectroscopy of short-lived fission products using the recoil separator “Lohengrin”

γ-spectra and half-lives of⁹⁰Br,⁹⁵Rb,⁹⁶Rb,⁹⁶Sr,⁹⁶Y,¹³²Sb and¹³²Sn have been measured using the unslowed fission fragment separator “Lohengrin”. Preliminary decay schemes for⁹⁰Kr,⁹⁵Sr,⁹⁶Sr and⁹⁶Y are given.     

Total beta-decay energies of heavy fission products

TheQ _β-value of^144,145Ba,^144,145,147La,^145,147,148Ce and¹⁴⁸Pr has been measured using mass-separated sources produced at the on-line mass separator LOHENGRIN. The experimental values are compared with mass formula predictions.     

β-decay phenomenology of nuclear fission products

Two data sets representing the two principal experimental techniques used to study the β-decay of short-lived fission fragments are analyzed. The average endpoint and electron energies for nuclei with similar Q-values are the same within statistical accuracy in the two sets. However, the spread of the endpoints is considerably larger in the data set based on integral γ-energies (ANR set) compared with the set based on standard γ-spectroscopy (ENDF set). The averaged β-strength function for the ANR set follows a “universal” trend, decreasing monotonically and rapidly with increasing β-endpoint energy. On the other hand, the β-strength function in the ENDF set is less steep, and at higher excitation energy it is considerably smaller than in the ANR set. These differences imply a systematic bias in one of these two data sets.     

Correlation between fractional independent yields and neutron-to-proton ratio of fission products in low energy fission

Fractional independent yields of fission products in the thermal neutron-induced fission of²³³U,²³⁵U,²³⁹Pu,²⁴¹Pu and in the spontaneous fission of²⁵²Cf have been correlated with the neutron-to-proton ratio of the fission products. The yields of the products from a fissioning system, when plotted as a function of neutron-to-proton (N/Z) ratio of fission preducts, fall on two Gaussian distribution corresponding to light and heavy fission products. The centroids of the distribution or the most probable value of neutron-to-proton ratio is found to be very close to theN/Z of the fissioning nucleus. From the most probable value ofN/Z the various parameters of charge distribution e.g. most probable massA _p, most probable chargeZ _p, the mass dispersionσ _Aand the charge dispersionσ _Zhave been obtained and are in good agreement with the experimental values ofA _pandZ _p.     

Experimental beta-decay energies of short-lived light fission products

The beta-decay energy of 20 nuclides in the mass region 88≦A≦102 has been measured using the on-line mass separator LOHENGRIN. The experimental values obtained are compared with theoretical predictions of different mass formulae.     

Isomeric yield ratios of fission products in the system of 24 MeV proton-induced fission of238U

Isomeric yield ratios of 30 fission products in 24 MeV proton-induced fission of²³⁸U were measured by the use of the ion-guide isotope separator on-line. The obtained isomeric yield ratios were converted to the angular momenta of primary fission fragments based on the statistical model. The deduced angular momenta were examined from various aspects. It is found that in general the angular momentum continuously increases with the fragment mass number including the region of symmetric mass division. However, there are some exceptions. For Sn isotopes the deduced angular momenta are quite small due to the spherical shape of the nuclear shell configuration. It is also concluded from the consideration of the charge distribution that the angular momentum of fission product scatters considerably within the narrow range of mass division. The dependence of the angular momentum on the available energy of fragments at scission point indicates that the individual fragment possesses a characteristic deformation at scission and/or the deduced angular momentum is seriously affected by the particle excitation after scission.     

A method for calculating specific activity of fission products

An algorithm is described for determination of specific activity of any member of a linear decay chain. The algorithm permits calculation of the activity of fission products for all three possible accumulation modes: 1) coexistence, i.e., irradiation time in a reactor; 2) delay after preceding coexistence; 3) delay after instantaneous fission. In comparison with previous studies in this area the proposed method is more suitable for use with computers, both from the point of view of calculating input parameters and accuracy, as well as in convenience of programming.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 9, pp. 32–34, September, 1972.     

233Pa(2nth, f ) cross-section determination using a fission track technique

The νp process is a primary nucleosynthesis process which occurs in core-collapse supernovae. An essential role in this process is being played by electron antineutrinos. They generate, by absorption on protons, a supply of neutrons which, by (n, p) reactions, allow to overcome waiting point nuclei with rather long beta-decay and proton-capture lifetimes. The synthesis of heavy elements by the νp process depends sensitively on the $\bar \nu _e$ luminosity and spectrum. As has been shown recently, the latter are affected by collective neutrino flavor oscillations which can swap the $\bar \nu _e$ and $\bar \nu _{\mu ,\tau }$ spectra above a certain split energy. Assuming such a swap scenario, we have studied the impact of collective neutrino flavor oscillations on the νp-process nucleosynthesis. Our results show that the production of light p-nuclei up to mass number A = 108 is very sensitive to collective neutrino oscillations.     

基于反相位脉冲技术的生物组织谐波成像研究

理论及实验研究了反相位脉冲技术在生物组织二次谐波成像中的应用。结合有限振幅声波的非线性传播理论,从理论上证明了反相位脉冲技术可有效抑制基波信号,同时二次谐波信号增强两倍,轴向及径向声场的实验测量结果基波被抑制30~50dB,二次谐波提高6dB,与理论相符。建立了相应的成像系统,对若干生物离体组织进行了基于反相位脉冲相位技术的二次谐波成像,并与常规的基波及二次谐波图像对比,进一步证明了该技术能有效提高图像的对比度和清晰度。     

利用CARS方法研究超短脉冲激光的脉冲宽度

在理论上提出了利用两光束CARS/CSRS方法测量超短脉冲激光的三阶相关函数。实验上在几种样品中测量了CARS/CSRS的时间特性,得到了泵浦光脉冲,SCDL输出光脉冲以及受激喇曼散射光脉冲的宽度。     

Identification of the unknown transformation products derived from lincomycin using LC-HRMS technique

In this paper, a comprehensive study of the fate of an antibiotic, lincomycin, in the aquatic environment is presented. High-resolution mass spectrometry was employed to assess the evolution of the process over time. Formation of intermediate compounds was followed by high performance liquid chromatography-high resolution mass spectrometry (LC-HRMS); accurate mass-to-charge ratios of parent ions were reported with inaccuracy below 1 mmu, which guarantee the correct assignment of their molecular formula in all cases, while their MS(2) and MS(3) spectra showed several structural-diagnostic ions that allowed to characterize the different transformation products (TPs) and to discriminate the isobaric species. The simulation of phototransformation occurring in the aquatic environment and the identification of biotic and abiotic TPs of the pharmaceutical compound were carried out in different experimental conditions: dark experiments, homogeneous photolysis and heterogeneous photocatalysis using titanium dioxide, in order to recreate conditions similar to those found in the environment. Twenty-one main species were identified afterwards lincomycin transformation. Several isomeric species were formed and characterized by analyzing MS and MS(n) spectra and by comparison with parent molecule fragmentation pathways. The major transformation process for lincomycin is hydroxylation either at N-alkyl side chain or at the pyrrolidine moiety. In addition, oxidation/reduction, demethylation or cleavage of pyranose ring occurs. Based on this information and additional assessment of profiles over time of formation/disappearance of each species, it was possible to recognize the transformation pathways followed by the drug.     

Investigation of ion dynamics in a Penning trap using a pulse-probe technique

We demonstrate a pulse-probe method for measuring the ion-cloud rotation frequency in a Penning trap. We show that it is useful over a range of parameters not accessible to the photon correlation method of Dholakia et al. [1]. In particular, the pulse-probe method works for larger clouds than the photon-correlation method. We show that the pulse-probe method measures the space-charge-shifted frequency and gives us the optical pumping times within clouds. Furthermore, we show that, for Mg⁺ ions, it is capable of measuring much higher degrees of space-charge shift than the photon-correlation method. Improvements to the method may enable its use in measuring diffusion rates for ions in clouds.     

Lifetime measurements of excited levels in prompt fission products of 252Cf

Lifetimes in the range 10⁻¹¹ to 10⁻⁹ s of prompt γ rays emitted from the fission fragments of ²⁵²Cf were measured using a recoil distance method. A ²⁵²Cf source was deposited on a stretched Ni foil and placed in a plunger device, the recoil direction of the studied fragments being determined by the detection of the complementary fragment. The lifetime was determined by the change in the non-Doppler-shifted peak intensities of prompt γ rays as a function of the source-plunger distance. The 2⁺ → 0⁺ half-life in ¹¹²Pd and 4⁺ → 0⁺ halflives in ^{104, 106}Mo, ^108,110Ru and ¹⁴²Ba were determined for the first time. Several other measurements of longer lived 2⁺ → 0⁺ transitions were repeated as well. The experimental results are discussed within the framework of the rotational and the IBA-2 models.     

Nuclide yields of light fission products from thermal-neutron induced fission of 233U at different kinetic energies

The yields of light fission products from thermal-neutron induced fission of ²³³U are measured as a function of their mass A, their nuclear charge Z, their kinetic energy E and their ionic charge state q at the recoil spectrometer Lohengrin of the Institut Laue-Langevin in Grenoble. The mass yields are determined by intercepting the fragments with an ionization chamber of high energy resolution positioned at the focal plane of the spectrometer. The nuclear charges and their yields are determined with the same ionization chamber by measuring the residual energy of fission products, selected monoenergetically by Lohengrin, behind a passive absorber made of parylene-C. The nuclear charge resolution enabled by this detector device is considerably improved to Z/dZ = 58. The nuclear charge and mass distributions summed over all ionic charge states are listed within the mass range 79 ⩽ A ⩽ 106 at 6 energies: E = 85.34, 90.41, 95.46, 100.50, 105.55 and 110.55 MeV. The energy-integrated nuclear charge and mass yields are also given. The isotonic and isotopic yields are shown. An odd-even effect in the yields is found for the protons as well as for the neutrons at all kinetic energies. The yield weighted total odd-even effect for the protons is found to be (22.1 ± 2.1)%, for the neutrons (5.4 ± 1.7)%. An odd-even effect for the protons in the mean kinetic energy is also observed. The displacement of the mean isobaric nuclear charges from the unchanged charge-density values and the variances of the isobaric nuclear-charge distributions reveal fine structures in their mass dependences.     

Determining isotopic distributions of fission products with a Penning trap

A novel method to determine independent yields in particle-induced fission employing the ion guide technique and ion counting after a Penning trap has been developed. The method takes advantage of the fact that a Penning trap can be used as a precision mass filter, which allows an unambiguous identification of the fission fragments. The method was tested with 25MeV and 50MeV proton-induced fission of ²³⁸U . The data is internally reproducible with an accuracy of a few per cent. A satisfactory agreement was obtained with older ion guide yield measurements in 25MeV proton-induced fission. The results for Rb and Cs yields in 50MeV proton-induced fission agree with previous measurements performed at an isotope separator equipped with a chemically selective ion source.     

Beta spectroscopy of some neutron-rich cerium isotopes in252Cf fission products

The method of cyclic-time optimization has been used, in conjunction with a beta-Kx-ray coincidence technique, to obtain the beta spectrum of some decaying cerium isotopes in the fission products of²⁵²Cf. A Kurie plot of the beta spectrum revealed at least four beta groups. From the relative isotopic yields of Kx-ray the isotopic origin of each group has been determined. The coincidence method used in this study allows the measurement of beta groups feeding excited levels of daughter products with high internal conversion coefficients. The end-point energies and isotopic origin of the measured beta groups were as follows: 2.349(±0.100)MeV,¹⁴⁵Ce; 1.715(±0.103)MeV,¹⁴⁵Ce and¹⁴⁸Ce; 1.267 (±0.103)MeV,¹⁴⁵Ce; 0.748(±0.109) MeV,¹⁴⁶Ce and¹⁴⁸Ce.