Wax formation in oil pipelines: A critical review

The gelling of waxy crudes and the deposition of wax on the inner walls of subsea crude oil pipelines present a costly problem in the production and transportation of oil. The timely removal of deposited wax is required to address the reduction in flow rate that it causes, as well as to avoid the eventual loss of a pipeline in the event that it becomes completely clogged. In order to understand this problem and address it, significant research has been done on the mechanisms governing wax deposition in pipelines in order to model the process. Furthermore, methods of inhibiting the formation of wax on pipeline walls and of removing accumulated wax have been studied to find the most efficient and cost-effective means of maintaining pipelines prone to wax deposition. This paper seeks to review the current state of research into these areas, highlighting what is so far understood about the mechanisms guiding this wax deposition, and how this knowledge can be applied to modelling and providing solutions to this problem.     

Effects of dynamic load on flow and heat transfer of two-phase boiling water in a horizontal pipe

An experimental investigation was performed to obtain the flow and heat transfer characteristics of single-phase water flow and two-phase pipe boiling water flow under high gravity (Hi-G) in present work. The experiments were conducted on a rotating platform, and boiling two-phase flow state was obtained by means of electric heating. The data were collected specifically in the test section, which was a lucite pipe with inner diameter of 20 mm and length of 400 mm. By changing the parameters, such as rotation speed, inlet temperature, flow rate, and etc., and analyzing the fluid resistance, effective heat and heat transfer coefficient of the experimental data, the effects of dynamic load on the flow and heat transfer characteristics of single phase water and two-phase boiling water flow were investigated and obtained. The two-phase flow patterns under Hi-G condition were obtained with a video camera. The results show that the dynamic load significantly influences the flow characteristic and boiling heat transfer of the two-phase pipe flow. As the direction of the dynamic load and the flow direction are opposite, the greater the dynamic load, the higher the outlet pressure and the flow resistance, and the lower the flow rate, the void fraction, the wall inner surface temperature and the heat transfer capability. Therefore, the dynamic load will block the fluid flow, enhance heat dissipation toward the ambient environment and reduce the heat transfer to the two-phase boiling flow.     

Hysteretic heat transfer study of liquid–liquid two-phase flow in a T-junction microchannel

Liquid–liquid two-phase flow in microchannels is capable of boosting the heat removal rate in cooling processes. Formation of different two-phase flow patterns which affect the heat transfer rate is numerically investigated here in a T-junction containing water-oil flow. For this purpose, the finite element method (FEM) is applied to solve the unsteady two-phase Navier–Stokes equations along with the level set (LS) equation in order to capture the interface between phases. It is shown that the two-phase flow pattern in microchannels depends on the flow initial condition which causes hysteresis effect in two-phase flow. In this study, the hysteresis is observed in flow pattern and consequently in the heat transfer rate. The effect of wall contact angle on the hydrodynamics and heat transfer in the microchannel is investigated to gain useful insight into the hysteresis phenomenon. It is observed that the hysteresis is significant in super-hydrophilic microchannels, while it disappears at the contact angle of 75^°. The effect of water to oil flow rate ratio (Q_wat/Q_oil) on the heat transfer is also studied. The flow rate ratio has a negligible effect on the Nusselt number (Nu) in the dripping regime, while the Nu decreases with an increase of Q_wat/Q_oil in the co-flow regime. The thickness of the oil film, velocity, and temperature distribution are studied in the co-flow regime. It is revealed that the normalized slip velocity reduces at higher values of Q_wat/Q_oil, which causes a reduction in the averaged Nu. In dripping regimes, higher flow rate ratios lead to a more frequent generation of droplet/slugs at a smaller size. The passage of the slugs or droplets increases the local Nu. Larger droplets generated at lower flow rate ratios cause a larger increase in the local Nu than smaller droplets. The temperature and velocity field around the droplets are also illustrated to investigate the heat transfer improvement. The generated vortex at the tip of the oil jet causes an increase in the velocity and Nu on the water side.     

Heat transfer to air–water annular flow in a horizontal pipe

Two-phase air–water flow and heat transfer in a 25 mm internal diameter horizontal pipe were investigated experimentally. The water superficial velocity varied from 24.2 m/s to 41.5 m/s and the air superficial velocity varied from 0.02 m/s to 0.09 m/s. The aim of the study was to determine the heat transfer coefficient and its connection to flow pattern and liquid film thickness. The flow patterns were visualized using a high speed video camera, and the film thickness was measured by the conductive tomography technique. The heat transfer coefficient was calculated from the temperature measurements using the infrared thermography method. It was found that the heat transfer coefficient at the bottom of the pipe is up to three times higher than that at the top, and becomes more uniform around the pipe for higher air flow-rates. Correlations on local and average Nusselt number were obtained and compared to results reported in the literature. The behavior of local heat transfer coefficient was analyzed and the role of film thickness and flow pattern was clarified.     

航空发动机轴承腔中油滴运动与沉积的特性分析

本文在获得轴承腔中气相介质流场的基础上,采用Lagrangian方法建立油滴在气相介质流场中运动的分析模型,通过瞬时步进法数值模拟油滴的运动过程,获得了油滴直径和旋转轴转速对油滴运动过程中的速度和轨迹影响的规律.基于获得的油滴与腔壁碰撞前的运动状态,以及结合油滴与腔壁的碰撞模型,实现了油滴直径和旋转轴转速对碰撞后油滴沉积率和动量转移率影响规律的分析.结果表明:油滴直径和旋转轴转速对油滴速度及轨迹,以及油滴沉积率及动量转移率都有很大影响,而且前者的影响更为明显.与国外同等条件下的试验结果对比表明,本文提出的油滴运动与沉积特性分析方法具有较好的可靠性和精度.碰撞前后油滴运动状态和沉积率及动量转移率的计算,为下一步油膜厚度和速度的计算,继而为轴承腔润滑设计和换热分析提供了初始条件.     

Entropy generation analysis of fully developed laminar forced convection in a helical tube with uniform wall temperature

In the present study, fully developed laminar flow and heat transfer in a helically coiled tube with uniform wall temperature have been investigated analytically. Expressions involving relevant variables for entropy generation rate contributed to heat transfer and friction loss, and total entropy generation rate have been derived. The effect of various flow and coil parameters like Reynolds number, curvature ratio, coil pitch, etc. on the entropy generation rate has been studied for two fluids- air and water. The results of the present study have been compared to the corresponding entropy generation values of straight pipe. Investigating the results, some optimum values for Reynolds number have been proposed and compared with the optimum Reynolds numbers of laminar flow inside a coiled tube subjected to constant heat flux boundary condition.     

Turbulent heat transfer characteristics of water flow in a rotating pipe

Large-Eddy-Simulation of turbulent heat transfer for water flow in rotating pipe is performed, for various rotation ratios (0 ≤ N ≤ 14). The value of the Reynolds number, based on the bulk velocity and pipe diameter, is Re = 5,500. The aim of this study is to examine the effect of the rotating pipe on the turbulent heat transfer for water flow, as well as the reliability of the LES approach for predicting turbulent heat transfer in water flow. Some predictions for the case of non-rotating pipe are compared to the available results of literature for validation. To depict the influence of the rotation ratio on turbulent heat transfer, many statistical quantities are analyzed (distributions of mean temperature, rms of fluctuating temperature, turbulent heat fluxes, higher-order statistics). Some contours of instantaneous temperature fluctuations are examined.     

Preventing snow accumulating upon inclined substrates using falling water film

This paper has concerned preventing snow accumulating upon inclined substrates using falling water film. A cluster of physical models for a gas–water–snow system was developed and solved with a control-volume finite-difference procedure. The effects of various parameters on heat transfer and water film temperature decrease were investigated. The results revealed that it is feasible to use falling water film to prevent snow accumulation upon inclined substrates as long as the suitable initial film flow rate and temperature are adopted. It was clarified that among the influential factors of water film temperature decrease, the snowfall intensity, initial water film thickness and the substrate inclination play an important role. The intensity of the film temperature decrease mainly depends on the snowfall intensity and the initial heat capacity of the water film flow, which is a function of temperature and mass flow rate. An intensive heat transfer occurs in a very thin layer near the free surface of the water film. The numerical results were correlated in terms of effective Nusselt number, and Reynolds, Prandtl and Gukhman numbers. The maximum deviation of the numerical data from the correlation is approximately 15.6%, which only causes an uncertainty less than 3% in the simple prediction. Received on 26 April 1999     

Heat transfer measurements and correlations for air–water flow of different flow patterns in a horizontal pipe

Heat transfer coefficients were measured and new correlations were developed for two-phase, two-component (air and water) heat transfer in a horizontal pipe for different flow patterns. Flow patterns were observed in a transparent circular pipe using an air–water mixture. Visual identification of the flow patterns was supplemented with photographic data, and the results were plotted on the flow regime map proposed by Taitel and Dukler and agreed quite well with each other. A two-phase heat transfer experimental setup was built for this study and a total of 150 two-phase heat transfer data with different flow patterns were obtained under a uniform wall heat flux boundary condition. For these data, the superficial Reynolds number ranged from 640 to 35,500 for the liquid and from 540 to 21,200 for the gas. Our previously developed robust two-phase heat transfer correlation for a vertical pipe with modified constants predicted the horizontal pipe air–water heat transfer experimental data with very good accuracy. Overall the proposed correlations predicted the data with a mean deviation of 1.0% and an rms deviation of 12%.     

An inertial two-phase model of wax transport in a pipeline during pigging operations

Pig in pipelines performs operations for cleaning the pipe interior and internal inspection. In the past few years many 1D models have been developed to simulate the process because of their reduced computational cost; however, they rely on simplifications which are not always valid. In this paper, the results of a three-dimensional (3D) numerical investigation of the interaction between a waxy-oil and a dynamic sealing pig in a pipeline are presented. The results are obtained at a reduced computational cost by using a moving frame of reference, and an “injection” boundary condition for the wax deposited on the wall. The effect of the temperature and the wax particles’ size has been investigated. The 3D results show the structure assumed by the debris field in front of the pig. In particular, a lubrication region at the bottom of the pipe, whose dimensions are temperature dependent, is shown. This information cannot be deduced from 1D modeling. The influence of the oil on the mixture viscosity and the internal bed dynamics are discussed. This work provides insights into the interaction between the debris field in front of the pig and pipeline hydraulics.     

Direct contact heat transfer between two immiscible liquids flowing in a horizontal concentric annulus

Direct contact heat transfer between water and a heat transfer oil was investigated under non-boiling conditions in co-current turbulent flow through a horizontal concentric annulus. The ratio of the inner pipe diameter to the outer pipe diameter (aspect ratio) κ = 0.730−0.816; total liquid velocity (mixture velocity) V_T = 0.42−1.1 m/s; inlet oil temperature T_oi = 38−94°C; oil volume fraction in the flowing mixture φ_o = 0.25−0.75 were varied and their effects on the overall volumetric heat transfer coefficient U_v were determined at constant interfacial tension of 48 dynes/cm.

It was found that, in each concentric pipe set, the overall volumetric heat transfer coefficient increased with increasing dispersed phase volume fraction at each constant mixture velocity and reached a maximum at around φ_o = φ_w ≈ 0.5. The maximum U_v values increased with increasing total liquid velocity and decreasing aspect ratio of the annulus. The volumetric heat transfer coefficient was also found to increase with increasing inlet oil temperature and increasing total liquid velocity but to decrease with length along the test section keeping all other parameters constant. Empirical expressions for the volumetric heat transfer coefficient were obtained within the ranges of the experimental parameters.     

Direct contact heat transfer from an immiscible liquid jet

Temperature distribution and transfer of heat in a vertical, immiscible, liquid jet in direct contact with a liquid matrix are analyzed. A theoretical model for plug and parabolic flow is adopted from the literature, the treatment of a special V-shaped velocity distribution expected in the experiment and suitable for reactor application is calculated. Two common surface conditions, i.e. constant heat flux or constant temperature are considered. An experiment was performed in which a high Prandtl number fluid (oil) formed the jet and a low Prandtl number fluid (water) formed the matrix. The experimental results fall within theoretical results obtained for a V-type velocity distribution and plug flow. It was determined that the heat transfer characteristics of a direct contact jet flow in most cases have definite advantages over those of flow in a pipe beyond the obvious advantage of removal of the pipe wall's thermal resistance. These advantages result from the more flat velocity distribution encountered in jet flow as compared to a corresponding Laminar pipe flow. The likeliness of having a particular flow shape is discussed. Advantages of a central wire, leading to the V-type flow, are the enhancement of heat transfer and the stabilisation of the jet for any desired length. The jet flow is laminar.     

Study into thermal stresses due to turbulent flow in pipes

Flow through pipes with heat transfer finds wide applications in industry. The thermal stresses, which develop in the pipe limit the heat transfer rate in pipe flow. In the present study, a turbulent flow in thick pipe with external heating is considered. The flow and temperature fields in a pipe and in the fluid are predicted using a numerical scheme; which employs a control volume approach. A k- model is introduced to account for the turbulence. The thermal stresses developed in the pipe due to heat transfer are predicted. The simulations are repeated for different pipe materials and fluids. It is found that the temperature gradient in the pipe changes rapidly in the vicinity of the solid-fluid interface. This change is not affected considerably by the Reynolds number. The effective stress developed at mid-plane of the pipe is independent of the Reynolds number; however, the pipe material affects the effective stress considerably.     

Multiphase flow model developed for simulating gas hydrate transport in horizontal pipe

The hydrate formation or dissociation in deep subsea flow lines is a challenging problem in oil and gas transport systems. The study of multiphase flows is complex while necessary due to the phase changes (i.e., liquid, solid, and gas) that occur with increasing the temperature and decreasing the pressure. A one-dimensional multiphase flow model coupled with a transient hydrate kinetic model is developed to study the characteristics of the multiphase flows for the hydrates formed by the phase changes in the pipes. The multiphase flow model is derived from a multi-fluid model, while has been widely used in modelling multiphase flows. The heat convection between the fluid and the ambient through the pipe wall is considered in the energy balance equation. The developed multiphase flow model is used to simulate the procedure of the hydrate transport. The results show that the formation of the hydrates can cause hold-up oscillations of water and gas.     

Flow and heat transfer characteristics of drag reducing surfactant solution in a helically coiled pipe

The reduction characteristic of turbulent drag and heat transfer of drag reduction surfactant solution flowing in a helically coiled pipe were experimentally investigated. The drag reduction surfactant used in the present study was the amine oxide type nonionic surfactant of oleyldihydroxyethylamineoxide (ODEAO, C₂₂H₄₅NO₃=371). The zwitterion surfactant of cetyldimethylaminoaciticacidbetaine (CDMB, C₂₀H₄₁NO₂=327) was added by 10% to the ODEAO solution in order to avoid the chemical degradation of ODEAO by ionic impurities in a test tape water. The experiments of flow drag and heat transfer reduction were carried out in the helically coiled pipe of coil to pipe diameter ratio of 37.5 and the helically coiled pipe length to pipe diameter of 1180.5 (pipe diameter of 14.4 mm) at various concentrations, temperatures and flow velocities of the ODEAO surfactant solution. The ODEAO solution showed a non-Newtonian behavior at high concentration of the ODEAO. From the experimental results, it was observed that the friction factor of the ODEAO surfactant solution flowing through the coiled pipe was decreased to a great extent in comparison with water as a Newtonian fluid in the turbulent flow region. Heat transfer measurements for water and the ODEAO solution were performed in both laminar and turbulent flow regions under the uniform heat flux boundary condition. The heat transfer coefficients for the ODEAO solution flow were the same as water flow in the laminar region. On the other hand, heat transfer reduction of the ODEAO solution flow was remarkedly reduced as compared with that of the water flow in the turbulent flow region.     

Experimental on the liquid cooling system with thermoelectric for personal computer

In the present experimental investigation, the liquid cooling in the micro channel fin heat sink with and without thermoelectric for central processor unit (CPU) of personal computer. The micro channel heat sinks with two different channel height are fabricated from the aluminum with the length, the width and the base thickness of 28, 40, 2?mm respectively. The de-ionized water is used as coolant. Effects of channel height, coolant flow rate, and run condition of PC on the CPU temperature are considered. The liquid cooling in micro-rectangular fin heat sink with thermoelectric is compared with the other cooling techniques. The thermoelectric has a significant effect on the CPU cooling of PC. The experiments are performed at no load and full load conditions within 60?min after steady state, which the mass flow rate are 0.023, 0.017 and 0.01?kg/s. The results heat transfer rate increase with increasing coolant flow rate and higher channel. When comparing with the other cooling system, cooling system with thermoelectric gives the highest efficiency. However, thermoelectric has the high or low heat transfer rate from heat rejected and cooling capacity conditions.     

Cross-flow heat transfer in fixed bed

Radial flow reactor operated at cross-flow heat transfer is focused for large scale methanol synthesis. The effects of operating conditions including the reactor inlet air temperature, the heating pipe temperature and the air flow rate on the cross-flow heat transfer were investigated and results show that the temperature profile of the area in front of the heating pipe is slightly affected by all the operating conditions. The main area whose temperature profile is influenced is located behind the heating pipe. The heat transfer direction is related to the direction of the flow. In order to obtain the basic parameters for radial flow reactor designing calculation, the dimensionless number group method was used for data fitting of the bed effective thermal conductivity and the wall heat transfer coefficient which were calculated by the mathematical model with the product of Reynolds number and Prandtl number. The comparison of experimental data and calculated values shows that the calculated values fit the experimental data satisfactorily and the formulas can be used for reactor designing calculation.     

水流损失和热补偿共同作用对增强型地热系统(EGS)产能影响的研究

基于青海共和盆地-3705m地热田实测数据,结合流固耦合传热理论并运用Comsol软件,建立了离散型裂隙岩体流体传热模型。考虑水流损失和热补偿共同作用,模拟得到了开采过程中上、下岩层(盖层和垫层)为绝热不渗透、传热不渗透、渗透传热时,储层(上、下岩层和压裂层)温度场的变化特征,分析了产出流量、水流损失、产出温度、产热速率的变化规律。研究结果表明:采热过程中产出流量始终小于注入流量;产出流量增幅速率先增大后减小,最后趋于稳定,前3a产出流量增幅超过总增幅量的3/4;忽略水流损失,将高估产热速率,采热初期甚至达到考虑水流损失时产热速率的3倍以上;考虑水流损失,产热速率呈先快速上升再趋于稳定后逐渐下降的趋势,最优开采时间为3a^11a;研究上、下岩层对产出温度的影响,仅考虑传热,采热寿命延长5.43%,同时考虑渗流传热时,采热寿命延长2.71%;采热前9a,水流损失占主导作用,即流入上、下岩层水流损失对产热速率的影响高于热补偿效应,开采10a后,热补偿效应占主导作用;同时考虑水流损失和热补偿效应得到的产热速率变化规律与实际工程更为符合,建议选择低渗透能力的上、下岩层延长增强型地热系统(EGS)运行时间。     

Heat transfer characteristics of a new helically coiled crimped spiral finned tube heat exchanger

In the present study, the heat transfer characteristics in dry surface conditions of a new type of heat exchanger, namely a helically coiled finned tube heat exchanger, is experimentally investigated. The test section, which is a helically coiled fined tube heat exchanger, consists of a shell and a helical coil unit. The helical coil unit consists of four concentric helically coiled tubes of different diameters. Each tube is constructed by bending straight copper tube into a helical coil. Aluminium crimped spiral fins with thickness of 0.5 mm and outer diameter of 28.25 mm are placed around the tube. The edge of fin at the inner diameter is corrugated. Ambient air is used as a working fluid in the shell side while hot water is used for the tube-side. The test runs are done at air mass flow rates ranging between 0.04 and 0.13 kg/s. The water mass flow rates are between 0.2 and 0.4 kg/s. The water temperatures are between 40 and 50°C. The effects of the inlet conditions of both working fluids flowing through the heat exchanger on the heat transfer coefficients are discussed. The air-side heat transfer coefficient presented in term of the Colburn J factor is proportional to inlet-water temperature and water mass flow rate. The heat exchanger effectiveness tends to increase with increasing water mass flow rate and also slightly increases with increasing inlet water temperature.     

Heat and mass transfer characteristics of a new combined absorber-evaporator exchanger operating near the triple point of water

The present experimental study investigates the controlling mechanism involved in a new combined vertical film-type absorber-evaporator exchanger operating near the condition of the triple point of water. This peculiar exchanger plays the most important role in the VFVPE process that can be utilized in many industrial applications, water pollution prevention, desalination, and purification of chemicals, for example. The method of analogy of the heat and mass transfer near the film surface is used to calculate the interfacial concentration and temperature, and thus determining the heat and mass transfer coefficients. It is shown that the working temperature level has the negligible effect on the characteristics of the mass transfer. The mass transfer coefficients are higher than those obtained in the case of isothermal absorption due to the convective effect arisen from vapor absorption in the falling solution film. The water flow rate in the evaporator side has a minor effect on the performance of this combined exchanger. The overall mean heat transfer coefficient remains nearly constant in the lower range of the solution flow rate of the absorber; however, it would increase with increasing solution flow rate in the higher range. The correlating equations for both the heat and mass transfer coefficients are suggested.