Temperature measurement by single-shot dual-line CARS in low-pressure flows

A CARS method, adapted for diagnostics in low-pressure unsteady flows is described. The technique employs two narrow-band dye lasers and a single-frequency pump laser. Single-shot rotational temperature is obtained from the ratio of the intensities of two isolated Q lines. Temperature-measurement accuracy is discussed. The advantage of referencing the CARS signals from the flow in a cell filled with the same gas is shown. Demonstrative experiments are performed using N₂ at pressures of 10²–10³ Pa.     

Multi-color CARS for hydrogen-fueled scramjet applications

An approach to CARS, with considerable potential as a diagnostic for advanced airbreathing propulsion devices, is described and demonstrated. The technique is capable of providing simultaneous measurements of the major constitutents in H₂/air combustion. The method employs both broadband and narrowband Stokes beams to generate CARS via two, two-color and two, three-color wave mixing processes. Temperature and concentration information are simultaneously available from N₂, H₂, and H₂O. This permits the disappearance of fuel and appearance of product to be monitored. An analysis of the technique's capabilities and future improvements are discussed.     

Two-dimensional measurements of velocity using two rotating gratings

A two-dimensional vector velocimeter is proposed on the basis of the time-varying spatial filtering method using a rotating disk with two transmission gratings. The filtering characteristics of the spatial filter used in the velocimeter were studied theoretically. A preliminary experiment was performed to measure the velocity vector of a rotating random pattern. The experimental results show the usefulness of the present velocimeter for measurements of the velocity.     

Investigation of flame structure and burning behaviour in an IC engine simulator by 2D-LIF of OH radicals

Turbulent combustion of propane/air mixtures in an internal combustion engine simulator has been studied by 2D-LIF of OH radicals formed in the combustion process. A laser light sheet of thickness 75 m at 308 nm was used for excitation of OH and the fluorescence imaged onto an image-intensified CCD-camera. From the large number of images recorded, information on the burning behaviour of various flame structures could be obtained. In particular, flame extinction was clearly observed for lean (=1.5) mixtures.     

A novel method of DNA transfection by laser microbeam cell surgery

A new technique is presented to incorporate exogeneous gene materials (DNA) into cells with a microbeam irradiation from an uv pulsed laser. A frequency-multiplied Nd:YAG laser, 355 m wavelength, 5 ns pulse duration, punches a self-healing hole of submicrometer aperture in cell membrane under selected irradiation conditions. It takes a fraction of a second for the aperture to close, long enough to allow the foreign DNA, contained in the medium, to slip into the cell. The method offers a clear advantage over existing methods: increases the success rate of DNA transfection as well as the efficiency of cell modification by orders of magnitude.     

Rotational temperature measurement in high-temperature air using KrF laser-induced O2 fluorescence

Rotational temperature of O₂ has been measured in an atmospheric-air furnace using KrF laser-induced fluorescence. Average measurement errors of 10.7% and 5.1% over a temperature range of 1325–1725K were observed using two- and four-line excitation techniques, respectively. Ground-state depletion was observed for a spectral laser irradiance greater than approximately 7.5×10⁶ W/cm² cm^–1. This technique is suitable for temperature measurements when the O₂ vibrational population is not in thermal equilibrium.     

Ethylene monitoring by differential absorption with a CO2 waveguide laser

In this paper we report on a differential absorption technique using a CO₂ waveguide laser. The method is based on the measurement of the differential absorption between two different frequencies of the same selected CO₂ laser line. The sensitivity of the technique depends strongly on the total pressure and has been estimated to be about a few tens of ppb or better over a 1 km path length in C₂H₄ diluted with air to a total pressure of a few tens of torrs. Its relative simplicity and high sensitivity at low total pressure enable this technique to be applied to gas detection either at high altitude or to local monitoring of a low pressure sample.     

Principles and development of spatial filtering velocimetry

As one of the interesting optical techniques for measurements of the velocity, the spatial-filtering method is treated briefly in this review. The basic theory of the method is examined by analyzing the filtering characteristics of a spatial filter using the power spectral density function. The signal analyses are summarized as one of the techniques used in the spatial filtering method. Various configurations of the spatial filtering velocimeter are classified into typical four groups and outlined according to a variety of spatial filters employed in the velocimeters.     

Simultaneous CH planar laser-induced fluorescence and particle imaging velocimetry in turbulent nonpremixed flames

jet =18600). Here, PLIF images reveal a CH layer of thickness typically <1 mm from flame base to tip. Furthermore, in these permanently blue flames, we observe instantaneous flamefront strain rates – derived from the PIV data – in excess of ±10⁴ s^-1 without flame extinction. Received: 16 October 1997/Revised version: 30 October 1997     

Detection of aromatic pollutants in the environment by using UV-laser-induced fluorescence

Fluorescence spectra, decay times, and detection limits of the 16 US-EPA polycyclic aromatic hydrocarbons (PAH) have been measured and the results are discussed in terms of separability of single PAHs in a multicomponent mixture. The results of a mathematical analysis of a 16-component mixture is presented. Spectra from natural water samples contaminated with gasoline and tar are also presented and the potential and limits of the LIF technique are discussed. Received: 19 March 1998/Revised version: 2 June 1998     

Calibration of OH laser-induced fluorescence temperature measurements using thermally dissociated H2O

A method for the calibration of OH temperature measurements using laser-induced fluorescence is demonstrated. The technique depends on the thermal dissociation of water vapor in a furnace. The calibration was demonstrated for the excitation of theA ^{2 +}( = 3) – ² ( = 0) band with a tunable KrF laser. Consistent discrepancies of 3% between calculated and measured temperatures with a standard deviation of 8 % were observed.     

Laboratory and atmospheric ozone measurements by infrared-laser heterodyne detection

A laser-heterodyne spectrometer with a resolution of 5 MHz has been used to record laboratory and atmospheric spectra of ozone in the 10 m region. The necessary parameters to process the atmospheric spectra are defined through the laboratory spectra. The atmospheric ozone concentration versus altitude and the atmospheric CO₂ volume mixing ratio have been obtained.     

Laser scattering by metallic particles in two-phase nozzle flow into a vacuum

For several years the Max-Planck-Institute for Extraterrestrial Physics has performed experiments with artificial barium clouds in space by means of research rockets and satellites in order to investigate electric fields and currents in the ionosphere and in the magnetosphere. The processes which lead to the formation of these artificial clouds were simulated in laboratory in order to optimize the barium vapor yield and to obtain a better insight into the initial phase of the clouds. In these experiments the combustion of excess barium with copper oxide, the two-phase flow of the combustion products through a nozzle and their expansion into a 20 m³ vacuum chamber were investigated in detail. Purpose of this work is to measure through detection techniques of scattered laser light and thermal radiation: 1) the density of small metall particles on the particle jet axis, 2) the particle velocity, 3) the thermal radiation of larger particles, and 4) the position of the Mach disk which limits the free nozzle jet downstream. This work was carried out at the Max-Planck-Institut für extraterrestrische Physik, Garching, Germany.     

Broadband (1000 cm−1) multiplex CARS spectroscopy: Application to polarization sensitive and time-resolved measurements

A multiplex CARS spectrometer based on a cw diode-pumpedQ-switched Nd: YLF laser, a broadband dye-laser and a multichannel spectrum detection system has been constructed. Excellent mode characteristics of the laser beams and high pulse repetition rate (2 kHz) have resulted in good signal-to-noise ratio achieved with a few seconds accumulation time. A 1000 cm^–1 wide spectral range is covered in a single CARS spectrum with an expanded bandwidth of the dye laser. A thin-jet sampling method is used in order to avoid the phase-matching limitation. The efficient spectral intensity normalization by the reference (CCl₄) nonresonant spectrum and subsequent computer fitting have been implemented. The performance of the system is demonstrated by two different experiments. First, the polarization sensitive measurements (PS-CARS) of cyclohexane show its potential for accurate Raman depolarization ratio determination and for detection of weak (overlapped) Raman bands. Second, the transient resonance CARS measurement of the lowest excited triplet state of all-trans retinal indicate its feasibility to time-resolved CARS spectroscopy of fluorescent excited states.     

Dual-broadband CARS temperature measurements in hydrogen-oxygen atmospheric pressure flames

Dual-broadband coherent anti-Stokes Raman scattering (CARS) spectroscopy of the Q₀₁-branch of H₂ has been employed for thermometry in an atmospheric-pressure hydrogen-oxygen flame. The aim was to investigate the applicability of the technique for single-shot temperature evaluation and to analyse the precision of the measurements. The results are presented of temperature and relative H₂ density mapping of the flame in the temperature range of 700-2800 K. The achieved precision of single-shot measurements was 3-5%.     

Simultaneous single-shot imaging of OH and O2 using a two-wavelength excimer laser

A technique is described for simultaneous single-shot imaging of OH and O₂. Laser-induced fluorescence of both molecules is excited by a tunable KrF laser, which is operated simultaneously on two wavelengths. By using two CCD detectors with image intensifiers and suitable filters, separate images of OH and O₂ distributions in H₂/O₂ and hydrocarbon/air flames were obtained.     

CARS measurements of temperature and species concentrations in an IC engine

Temperature measurements alone, and also simultaneous CO₂ concentration and temperature measurements, have been performed inside a fired IC engine. To tackle the two main problems encounted when making measurements in an engine (i.e., cycle-to-cycle variations and beam steering by density gradients), the shot-by-shot referencing technique and the in situ referencing technique using N₂ to determine [CO₂] were used. The temperature is deduced from the broadband N₂ CARS signal and narrow band detection is used for CO₂. A representative example of temperature measurements is given which shows a correlation between temperature and knocking intensity in the burnt gas of a knocking engine. The first simultaneous determinations of temperature and [CO₂] are also reported; so far these are reliable only during the compression stoke.     

Optical measurements of silicon wafer temperature

An optical technique for precise, non-contact, and real time measurement of silicon wafer temperature that uses the polarized reflectivity ratio R_p/R_s is described. The proposed method is based on temperature dependence of the optical functions of silicon. Expected strong temperature sensitivity is obtained near band gap. Simultaneous monitoring of temperature and oxide layer thickness is discussed using measurements at four wavelength 365 nm, 405 nm, 546 nm, and 820 nm.     

The application of single-pulse CARS for temperature measurements in a turbulent stagnation flame

N₂ Q-branch CARS spectra have been recorded and evaluated for temperature determination in a turbulent, premixed CH₄/air stagnation flame with a burner of 40 mm diameter and 22 kW thermal load. Temperature histograms on the flame axis at different distances from the stagnation plate have been measured. Problems of practical applicability are addressed, including those arising from the limited spatial resolution of the BOXCARS geometry, from an insufficient dynamic range of the diode array detector, and from a memory effect of the detector in the case of measurements in highly turbulent flame areas with strong intermittency. Some information is given on the computerized acquisition and on the evaluation of the large amounts of data that are necessary for extensive investigations in large combustion systems.     

New theoretical and experimental results in fresnel optics with applications to matter-wave and X-ray interferometry

We present new methods and formulae for calculating the image amplitude and image spatial power spectral density produced by monochromatic point-source illumination of a finite (and/or infinite) periodic complex transmission grating. At specific finite-width resonances the image amplitude is seen to display periodic complex amplitude self-imaging of the grating, with interlaced alias images. The finite width grating resonances (as a function of spatial frequency) are broadened (from zero width) and displaced in frequency relative to those produced by an infinite grating, although the finite resonance width relative to illumination wavelength variation persists with infinite gratings. In the Fresnel domain the self images are generalizations of the Talbot and von Lau effects, while in the Fraunhofer to Fresnel transition domain, our formulae demonstrate the formation of these structures from Fraunhofer diffraction order side-lobes. Using these results, design criteria are provided for constructing lens-free three-grating interferometers with spatially diffuse illumination and detection. Such interferometers have a wide variety of applications for both X-rays and matter-waves, including a phase sensitive imaging device and/or narrow-band interference filter. For wavelengths in the Ångstrom to sub-Ångstrom range they feature high throughput and ease of fabrication. Experimental results using light with such an interferometer are presented. Our results conclusively demonstrate interference and image aliasing in such a device with spatially diffuse illumination and detection. The experiment is readily reproducible in any undergraduate physics laboratory.Work supported by ONR Grant N00014-90-J-1475, by the firm J. F. Clauser & Assoc., and (MWR) by a U.S. Dept. of Education Fellowship