共查询到20条相似文献,搜索用时 93 毫秒
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Eu(Ⅲ)和Pr(Ⅲ)六氟乙酰丙酮配合物的EXAFS研究陶冶*邵学广赵贵文(中国科技大学应用化学系合肥230026)巨新(中国科学院高能物理所北京100039)作为高效的发光和激光材料,稀土β-二酮类配合物得到广泛研究[1]。80年代末以来,由于它们... 相似文献
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研究了Nd~(3+)和Ho~(3+)的内、外消旋-双(苯基亚砜)乙烷配合物的固体和溶液(非水溶剂)的电子光谱,分析了可见范围的电子光谱并计算了光谱参数(b~(1/2)、δ和Ω_1)和f-f跃迂强度,指出了“超灵敏”跃迁的振子强度与配合物的共价程度及配位数相关。 相似文献
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稀土β-二酮类配合物掺杂硅胶的光声光谱及荧光光谱研究 总被引:4,自引:0,他引:4
用Sol-Gel过程制备了一系列稀土β-二酮类配合物掺杂的SiO2凝胶,测量了这些掺杂SiO2凝胶的光声光谱,与固体配合物相比,掺杂SiO2凝胶的光声光谱吸收峰发生蓝移,荧光发射峰发生红移。从无辐射跃迁角度研究了掺杂凝胶的Eu-β二酮类配合物的分子内能量传递模型。 相似文献
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设计组装了宽时域和宽频域的激光光源分子荧光寿命测试系统。系统中配置了N2分子激光,Nd:YAG激光及其泵浦的染料激光和美国EG&G公司的4400型信号检测和分析系统,通过对硫酸奎宁,荧蒽和稀土络合物典型样品的检测表明该仪器系统性能稳定,结果可靠。 相似文献
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Mithlesh Kumar A. R. Dhobale Mukesh Kumar M. D. Sastry 《Journal of Polymer Science.Polymer Physics》1997,35(1):187-192
Photoacoustic (PA) spectra of Ho3+, Er3+, and Sm3+ doped PVA films were obtained in 350–800 nm range. PA spectra were also obtained for the respective dopant oxides: Ho2O3, Er2O3, and Sm2O3 for comparison. It was found that in PVA the PA sensitivity has increased considerably compared to pure rare earth oxides. The relative intensities of absorption bands at 540 and 637 nm of Ho3+: PVA have shown distinct enhancement, indicating the increase in nonradiative relaxation at these excitations. Furthermore, the PA signals at wavelengths for different PA absorption bands were monitored as a function of chopping frequency. These experiments have shown that PA signal varies w−1 both for oxides and PVA samples, suggesting that they behave as thermally thin samples. © 1997 John Wiley & Sons, Inc. 相似文献
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A pulsed laser photoacoustic (PA) instrument operating under visible and ultraviolet range was reported, which used a YAG pumped dye laser (width 8 ns, repetition rate 10 Hz) as the light source. Photoacoustic spectra of C2H2 overtone excitation and A1Au←X1Σ+g electronic transition were obtained using the instrument and the dependence of PA signal intensity on the sample pressure and the laser energy was measured. The application of pulsed PA to electronic transition was less reported before. Because of the simplification of its theoretical treatment and experimental operation, the pulsed PA instrument can replace resonant (or non-resonant) moderate cw PA instrument in almost all the cases except the ultra high-resolution spectroscopy. The difference between pulsed and cw moderate PA was also discussed in the text. 相似文献
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快扫描傅立叶变换红外光声光谱对SBS/PET双层复合材料的研究 总被引:1,自引:0,他引:1
采用快扫描傅立叶变换红外光声光谱研究了苯乙烯-丁二烯-苯乙烯嵌段共聚物/聚对苯二甲酸乙二醇酯 (SBS/PET)双层复合材料.以碳黑膜作参比,氦气作吹扫气体,分辨率设定为8 cm-1,通过调节干涉仪动镜速率,获得了不同实验条件下的红外光声光谱图.比较了相同和不同速率时单一样品以及样品间的光谱变化.对3种不同表层厚度的样品,在同一动镜速率下,表层SBS越薄,其光谱信息越小,通过对特征吸收峰强度的对比,有效比较了其样品表层的厚度.随着动镜速率的逐渐增大,表层光谱特征被相对加强,同时底层光谱特征相对减弱.研究表明,采用快扫描红外光声光谱,在不破坏、不接触双层样品的情况下,通过改变动镜速率即可对表层和底层材料进行分析,并对表层SBS膜厚度进行区分. 相似文献
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稀土金属有机配合物的红外和拉曼光谱研究 总被引:1,自引:0,他引:1
利用新合成的配体N,N,N′,N′-四正丁基己二酰胺Bu2NCO(CH2)4OCNBu2(TBAA)(Bu=正丁基)与一系列稀土金属硝酸盐反应,得到了一系列配合物Ln2(TBAA)3(NO3)6(Ln=La,Nd,Sm,Eu,Gd,Tb,Dy,Tm,Lu)。研究表明,该系列配合物具有相似的红外和拉曼光谱特性,有机配体以羰基中的氧通过双龄和桥连方式与Ln^3 配位,每个Ln^3 的配位数为9。 相似文献
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重铬酸铵与明胶光化学反应的光声光谱研究陈钢进,杜浩,蔡铁权,方健文(浙江师范大学化学系金华321004)(浙江师范大学物理系金华)关键词重铬酸盐明胶,光化学反应,光声光谱重铬酸盐明胶(DCG)是全息照相的重要材料,全息图的形成过程是六价铬在光的激发下... 相似文献
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