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1.
E. V. Makotchenko I. A. Baidina L. A. Sheludyakova 《Russian Journal of Inorganic Chemistry》2011,56(5):713-720
The (DienH3)[AuCl4]3 · H2O (I) and (DienH3)2[AuCl4]Cl5 (II) compounds were obtained by the reaction of HAuCl4 with diethylenetriamine trihydrochloride (DienH3Cl3) in hydrochloric acid. The compounds were characterized by elemental analysis, X-ray diffraction, thermogravimetry, and IR spectroscopy. Crystals of I and II are monoclinic with space group P21/n. For I, a = 12.2314(3) Å, b = 14.6077(5) Å, c = 13.2680(5) Å, β = 106.7350(10)°, V = 2270.22(13) Å3, Z = 8. For II, a = 6.62990(10) Å, b = 17.9026(5) Å, c = 10.3661(3) Å, β = 101.9230(10)°, V = 1203.83(5) Å3, Z = 2. Both structures are ionic. The gold atoms in I and II have a 4 + 2 coordination environment. The Au-Cl bond lengths are within 2.276–2.294 Å, and the axial Au…Cl contacts are within 3.315–3.405 Å. The diethylenetriammonium cation in I and II has different conformations. 相似文献
2.
A. N. Chekhlov 《Russian Journal of Inorganic Chemistry》2007,52(12):1918-1924
Two complexes, namely, triaqua(18-crown-6)strontium dibromide monohydrate (I) and diaquabromo(18-crown-6)barium bromide (II), are synthesized. Their crystal structures are determined by X-ray diffraction analyses. For complex I, space group C2/c, a = 17.547 Å, b = 10.246 Å, c = 14.786 Å, β = 123.08°, Z = 4. For complex II, space group Pnma, a = 17.753 Å, b = 17.465 Å, c = 6.629 Å, Z = 4. The structures are solved by a direct method and refined by the full-matrix least-squares method in the anisotropic approximation to R = 0.056 (I) and 0.042 (II) for 2696 (I) and 2440 (II) independent reflections (CAD-4 automated diffractometer, λMoK α radiation). Both complex cations—randomly disordered [Sr(18C6)(H2O)3]2+ in complex I and [BaBr(18C6)(H2O)2]+ in complex II—are of the host-guest type. The Sr2+ (Ba2+) cation resides in the cavity of the 18-crown-6 ligand and coordinated by all six O atoms. In the structures complexes I and II, the coordination polyhedra of the Sr2+ and Ba2+ cations (coordination number 9) can be described as distorted hexagonal bipyramids with one apex at the O atom of the water molecule in complex I or at the Br? ligand in complex II and the other split apex at the O atoms of two water molecules. 相似文献
3.
A. V. Oreshkina G. Z. Kaziev A. V. Steblevskii 《Russian Journal of Inorganic Chemistry》2011,56(4):612-615
Hexaamminecadmium hydrogen hexamolybdocobaltate(III) and hydrogen hexamolybdochromate(III) of compositions [Cd(NH3)6] · H[CoMo6O18(OH)6] · 6H2O (I) and [Cd(NH3)6] · H[CrMo6O18(OH)6] · 6H2O (II), respectively, were synthesized and studied by mass spectroscopy, thermo-gravimetry, X-ray powder diffraction, and IR spectroscopy. Crystals of I and II are monoclinic. For I: a = 10.79 Å, b = 3.70 Å, c = 11.95 Å, β = 91.05°, V = 470.12 Å3, ρcalc = 2.37 g/cm3, Z = 2; and for II: a = 10.80 Å, b = 3.68 Å, c = 11.97 Å, β = 91.07°, V = 468.98 Å3, ρcalc = 2.36 g/cm3, Z = 2. 相似文献
4.
A. N. Chekhlov 《Russian Journal of Inorganic Chemistry》2008,53(8):1197-1202
Two crystalline host-guest complexes are synthesized and studied using X-ray diffraction analysis: (18-crown-6)sodium tribromide [Na(18-crown-6)]+ · Br 3 ? (I) and (18-crown-6)potassium tribromide (with an admixture of bromodiiodide) [K(18-crown-6)]+ · (Br0.25I2.75)? (II). The structures of compound I (space group P21/n, a = 8.957 Å, b = 8.288 Å, c = 14.054 Å, β = 104.80°, Z = 2) and compound II (space group Cc, a = 8.417 Å, b = 15.147 Å, c = 17.445 Å, β = 99.01°, Z = 4) are solved by a direct method and refined by the full-matrix least-squares method in the anisotropic approximation to R = 0.098 (I) and 0.036 (II) for all 2311 (I) and 2678 (II) independent measured reflections on a CAD-4 automated diffractometer (λMoK α). Similar crystalline complexes I and II exist as infinite chains of alternating complex cations and trihalide anions linked to each other through weak Na-Br or K-I coordination bonds. In [Na(18-crown-6)]+ and [K(18-crown-6)]+ complex cations, the Na+ or K+ cation (coordination number is eight) is located in the center of the cavity of the 18-crown-6 ligand and coordinated by the six O atoms and two terminal Br or I atoms of two trihalide anions lying on opposite sides of the rms plane of the crown ligand. 相似文献
5.
T. E. Kokina R. F. Klevtsova L. A. Glinskaya S. V. Larionov 《Russian Journal of Inorganic Chemistry》2010,55(1):56-60
Heteroligand complexes [Co2(HMTA)(iso-Bu2PS2)4] (I) (μeff = 4.67 μB) and [Cd2(HMTA)(iso-Bu2PS2)4] (II) have been synthesized. Single crystals of compounds I and II have been obtained. The crystals are monoclinic: a = 32.622(2) Å, b = 9.4891(6) Å, c = 21.7570(13) Å, β = 125.774(1)o, V = 5464.3(6) Å,3, Z = 4, ρcalcd = 1.331 g/cm3 for I; a = 34.6092(7) Å, b = 9.5595(2) Å, c = 22.3473(5) Å, β = 127.144(1)o, V = 5893.5(2) Å, Z = 4, ρcalcd = 1.355 g/cm3 for II; space group for both complexes C2/c. Structures I and II are based on discrete binuclear molecules. The coordination polyhedra of the Co and Cd atoms are distorted tetragonal pyramids NS4, with the bases formed by four S atoms of two bidentate chelating ligand iso-Bu2PS 2 ? and the axial vertices occupied by N atoms of bidentate bridging HMTA ligand. The character of interaction of the molecules in structures I and II is considered. 相似文献
6.
A. N. Chekhlov 《Russian Journal of Coordination Chemistry》2007,33(7):482-487
Two complexes, (2.2.2-cryptand)rubidium chloride and bromide hydrates [Rb(Crypt-222]Hal · 3.5H2O (Hal = Cl (I) and Br (II)), are synthesized. The structures of isomorphic crystals of compounds I and II are studied by X-ray diffraction analysis. The crystals are trigonal: space group P \(\overline 3 \), Z = 2; I: a = 11.810 Å, c = 11.302 Å; II: a = 11.890 Å, c = 11.402 Å. The structures are solved by a direct method and refined by the full-matrix least-squares method in the anisotropic approximation to R = 0.060 (I) and 0.077 (II) for 2650 (I) and 2700 (II) independent reflections (CAD-4 automated diffractometer, λMoK α radiation). In crystals of complexes I and II, the [Rb(Crypt-222)]+ cation of the host-guest type lies on the crystallographic axis 3 and has the approximate symmetry D 3. In complexes I and II, the coordination polyhedron of the Rb+ cation is a two-base-centered trigonal prism somewhat distorted to an antiprism. The crystals of compounds I and II contain H-bonded disordered cubes of the water molecules and Cl? or Br? anions. 相似文献
7.
Yu. V. Mironov O. A. Efremova S. S. Yarovoi V. E. Fedorov 《Russian Journal of Coordination Chemistry》2009,35(5):317-319
The tetranuclear cluster rhenium complexes Cs3H[Re4Q4Cl12] · 3.33H2O (Q = Te (I) and Se (II)) with the Cl atoms as terminal ligands were obtained and structurally characterized. The structures of complexes I and II were determined by X-ray diffraction analysis. Their isostructural crystals are monoclinic; space group C2, Z = 6; a = 26.403(8) Å, b = 16.495(5) Å, c = 11.744(3) Å, β = 91.25(2)°, V = 5113(2) Å3 (I); a = 26.573(3) Å, b = 16.461(3) Å, c = 11.726(2) Å, β = 91.381(4)°, V = 5127.6(14) Å3 (II). 相似文献
8.
S. N. Vorob’eva I. A. Baidina A. V. Belyaev N. I. Alferova 《Journal of Structural Chemistry》2012,53(1):125-131
The crystal structures of compounds of the composition [Rh(H2O)6]2(SO4)3·5H2O (I) and [Rh(H2O)6]PO4 (II) are determined. Crystallographic data for I: a = 7.272(9) Å, b = 27.047(1) Å, c = 12.464(9) Å, β = 97.038(10)°, P21 space group, Z = 4, d x = 2.184 g/cm3; for II: a = 9.746(6)Å, b = 6.877(7) Å, c = 23.623(6) Å, β = 100.601(10)°, C2/c space group, Z = 8, d x = 2.611 g/cm3. Compounds are analyzed by IR spectroscopy and powder XRD. Crystalline phase I is well soluble in water, whereas II is almost insoluble. 相似文献
9.
A. S. Antsyshkina G. G. Sadikov I. A. Solonina M. N. Rodnikova 《Russian Journal of Inorganic Chemistry》2007,52(10):1561-1566
Two ethylenediamine derivatives—N-(2-ammoniumethyl)carbamate HN(COO?)CH2CH2N+H3 (I) and tetraacetylethylenediamine (H3CC(O))2NCH2CH2N(C(O)CH3)2 (II) (synthesized for the first time)—have been synthesized and characterized by X-ray crystallography. Compounds I and II are isolated as minor admixtures upon an attempt to synthesize ethylenediamine complexes of lanthanum and neodymium nitrates, respectively. The crystals of I and II are monoclinic: a = 7.778 Å, b = 8.060 Å, c = 7.568 Å, β = 95.73°, Z = 4, space group P21/c (I); a = 5.946, b = 10.255, c = 9.343 Å, β = 95.72°, Z = 2, space group P21/c (II). The bond lengths and bond angles lie within the corresponding standard values. Compounds I and II have different conformations of the N-C-C-N ethylenediamine moiety: gauche in I and trans in II, and the corresponding torsion angles are equal to 66.6° and 180°, respectively. 相似文献
10.
T. G. Cherkasova I. Yu. Bagryanskaya N. V. Pervukhina N. V. Kurat’eva V. V. Medvedev E. S. Tatarinova E. V. Cherkasova 《Russian Journal of Inorganic Chemistry》2017,62(6):760-765
New double complexes [Co(DMSO)6][SiF6] ? 2H2O (I) and [Co(DMF)3(H2O)3][SiF6] ? DMF (II) have been synthesized and studied by IR spectroscopy and X-ray diffraction. Crystals of complex I belong to the tetragonal symmetry system, space group R3?, Z = 3, a = 11.8232(3) Å, c = 18.4699(5) Å, V = 2235.97(10) Å3, ρcalc = 1.573 g/cm3. Crystals of complex II are triclinic, space group P1?, Z = 2, a = 8.6264(4) Å, b = 10.1419(4) Å, c = 13.9657(6) Å, α = 100.847(2)°, β = 98.549(2)°, γ = 93.479(2)°, V = 1181.71(9) Å3, ρcalc = 1.539 g/cm3. 相似文献
11.
A. N. Chekhlov 《Russian Journal of Inorganic Chemistry》2008,53(9):1470-1475
Two complexes with similar compositions are synthesized: (18-crown-6)(nitrato-O,O′)potassium (I) and (18-crown-6)(nitrato-O,O′)potassium(0.91)silver(0.09) (II). Their isomorphic orthorhombic crystals (space group P212121, Z = 4) are studied by X-ray diffraction analysis. Structure I (a = 8.553 Å, b = 11.967 Å, c = 17.871 Å) and structure II (a = 8.540 Å, b = 11.956 Å, c = 17.867 Å) are solved by a direct method and refined by the full-matrix least-squares method in the anisotropic approximation to R = 0.044 (I) and 0.055 (II) for all 2385 (I) and 2379 (II) measured independent reflections. Complex molecules [K(NO3)(18-crown-6)] in structure I and [K0.91Ag0.09(NO3)(18-crown-6)] in compound II are of the host-guest type and rather similar in structure. Their 18-crown-6 and NO 3 ? ligands are disordered over two orientations. The K+ cation in complex I and the mixed cation (K0.91Ag0.09)+ in complex II reside in the cavity of the disordered 18-crown-6 ligand and is coordinated by its six O atoms and by two disordered O atoms of the NO 3 ? . ligand. The coordination polyhedron (CN = 8) of the K+ cation in complex I and that of (K0.91Ag0.09)+ cation in complex II is a distorted hexagonal pyramid with a base of six O atoms of the 18-crown-6 ligand and a split vertex at two O atoms of the NO 3 ? ligand. 相似文献
12.
L. Kh. Minacheva I. S. Ivanova V. E. Baulin E. N. Pyatova V. S. Sergienko A. Yu. Tsivadze 《Russian Journal of Inorganic Chemistry》2009,54(10):1571-1576
The synthesis, vibrational spectra, and X-ray diffraction analysis results for 2-(diphenylphosphinylmethoxy) aniline, 2-[(C6H5)2P(O)OCH2]C6H4NH2(I), are described. The crystals are monoclinic: a = 18.4515(17) Å, b = 10.5421(12) Å, c = 17.897(2) Å, β = 104.479(8)°, V = 3370.7(6) Å3, Z = 8, space group P21/c, R = 0.0546 for 1770 reflections with I > 2σ(I). The unit cell contains two crystallographically independent molecules Ia and Ib joined by an N-H …O hydrogen bond between a hydrogen atom of the amino group of aniline in molecule Ia (Ib) and the phosphoryl oxygen atom of molecule Ib (Ia) (O…H 2.18 and 2.19 Å, N…O, 2.979(5) and 3.000(5) Å; NHO angle, 154° and 157°). 相似文献
13.
A. N. Chekhlov 《Russian Journal of Inorganic Chemistry》2009,54(2):280-286
Two new complexes were synthesized, namely, 7: 2 (2.2.2-cryptand)potassium chloride and (2.2.2-cryptand)ammonium bromide(0.75)chloride(0.25) hydrates: [M(Crypt-222)]+ · Hal? · 3.5H2O, where M = K, Hal = Cl (I) and M = NH4, Hal = Br0.75Cl0.25 (II). The structures of two isomorphous crystals were studied by X-ray diffraction analysis. Trigonal (space group P \(\bar 3\), Z = 2) structures I (a = 11.763 Å, c = 11.262 Å) and II (a = 11.945 Å, c = 11.337 Å) were solved by direct methods and refined by the full-matrix least-squares method in the anisotropic approximation to R = 0.057 (I) and 0.065 (II) for all 2626 (I) and 1654 (II) independent measured reflections (CAD-4 automated diffractometer, λMoK α). In structures I and II, the host-guest [M(Crypt-222)]+ complex cation lies on the threefold crystallographic axis and has the approximate D 3 symmetry. In complex I, the coordination polyhedron of the K+ cation (CN = 8) is a bicapped trigonal prism somewhat distorted toward an antiprism. Complexes I and II contain H-bonded disordered cubes of the water molecules and the Cl? or Br? anions. 相似文献
14.
N. N. Golovnev M. S. Molokeev M. K. Lesnikov 《Russian Journal of Inorganic Chemistry》2018,63(10):1315-1321
The structures of catena-[K(μ6-Hba?O,O,O,O′,O′,O″)] (I) and catena-[Cs(μ6-Hba–O,O,O′,O′,O″,O″)] (II), where Н2ba is barbituric acid C4H4N2O3, were characterized by powder X-ray diffraction. Crystallographic data: a = 14.1603 (4) Å, b = 3.68977 (9) Å, c = 10.9508 (3) Å, β = 82.226 (1)°, V = 566.90 (3) Å3, space group P21/n, Z = 4 for I; a = 14.652 (1) Å, b = 11.7275 (7) Å, c = 3.8098 (3) Å, β = 79.140 (6)°, V = 642.90 (8) Å3, space group C2/m, Z = 4 for II. The structural topologies of alkali metal complexes with barbituric acid and some its derivatives were compared. The thermal stability of complexes I and II in an air atmosphere was studied. 相似文献
15.
P. A. Stabnikov G. I. Zharkova N. I. Alferova A. P. Zubareva E. A. Shusharina N. V. Pervukhina 《Journal of Structural Chemistry》2011,52(2):371-375
Single crystal X-ray diffraction is used to investigate two synthesized β-diketonate complexes of copper(II) with aminopyridine: Cu(4-NH2Py)(aa)2 (I) and Cu(4-NH2Py)(hfa)2 (II). The crystals of I and II have a monoclinic system; the unit cell parameters of I are: P21/n space group, a = 8.2921(3) Å, b = 14.7243(5) Å, c = 13.4970(4) Å, β = 102.426(1)°, V = 1609.32(9) Å3, Z = 4; for II: C2/c space group, a = 23.5704(5) Å, b = 11.4977(2) Å, c = 16.0285(3) Å, β = 109.265(1)°, V = 4100.6(1) Å3, Z = 8. The structures of I and II are molecular; they are composed of isolated molecules. The coordination polyhedron of the copper atom is formed by the O atoms of two acetylacetonate ligands (Cu-O 1.940(2)–2.171(2) I and the O atoms of two hexafluoroacetylacetonate ligands (Cu-O 1.940(2)–2.215(3) Å) in II. The molecules of 4-NH2Py are bonded to the copper atom via the nitrogen atom of the aromatic ring (Cu-N 2.008(2) Å in I and Cu-N 1.978(3) Å in II). Noncoordinated amino groups join the molecules of the complexes together by means of N-H…O hydrogen bonds. 相似文献
16.
Double complex salts (DCS) [RuNO(NH3)4(H2O)]2[MCl4]Cl4·2H2O, M = Pt (I) and Pd (II), are prepared and characterized using IR spectroscopy, single crystal and powder X-ray diffraction, and thermogravimetric analysis. Crystalline phases of I and II are isostructural (P2(1)/n space group) and have the following crystallographic characteristics: a = 6.689 Å, b = 15.609 Å, c = 12.348 Å, V = 1289.1 Å3, Z = 2, d x = 2.425 g/cm3 (I) and a = 6.637 Å, b = 15.521 Å, c = 12.244 Å, V = 1261.2 Å3, Z = 2, d x = 2.255 g/cm3 (II). The thermolysis of the obtained DCS in the hydrogen atmosphere affords two-phase mixtures of limited solid solutions of the metals: hcp for ruthenium-based ones and fcc for Pt or Pd based solutions. On decomposition in the helium atmosphere the products contain a minor amount of RuO2. For the phases obtained during thermolysis the parameters are determined and the compositions are estimated. The heating of I to 400°C in the helium-air atmosphere yields a nanocrystalline composite Pt+RuO2 with CSR of ~20 nm. 相似文献
17.
E. V. Cherkasova N. V. Pervukhina N. V. Kuratieva I. Yu. Bagryanskaya T. G. Cherkasova 《Russian Journal of Inorganic Chemistry》2018,63(5):626-630
Double ionic complexes [M(C5H5NCOO)3(H2O)2][Cr(NCS)6] · nH2O, where M = Eu (I), n = 1.15; Dy (II), Er (III), n = 1.5; M = Yb (IV), n = 2, have been synthesized by the reaction between M(NO3)3, M = Eu, Dy, Er, Yb, K3[Cr(NCS)6], and nicotinic acid (C5H5NCOO) in an aqueous solution and studied by chemical analysis, IR spectroscopy, and X-ray diffraction. Crystals of complexes I–IV are monoclinic, space group P21/n, Z = 4; a = 9.5358(2) Å, b = 25.4871(5) Å, c = 15.4303(4) Å, β = 105.513(1)°, V = 3613.6(1) Å3, ρcalcd = 1.799 g/cm3 for I, a = 9.5901(5) Å, b = 25.8599(15) Å, c = 15.6316(9) Å, β = 106.829(2)°, V = 3710.6(4) Å3, ρcalcd = 1.782 g/cm3 for II, a = 9.5640(3) Å, b = 25.8936(11) Å, c = 15.6498(7) Å, β = 106.895(2)°, V = 3708.3(3) Å3, ρcalcd = 1.791 g/cm3 for III, and a = 9.5049(2) Å, b = 25.6378(4) Å, c = 15.5120(3) Å, β = 106.934(1)°, V = 3616.1(1) Å3, ρcalcd = 1.864 g/cm3 for IV. 相似文献
18.
A. V. Oreshkina G. Z. Kaziev T. Yu. Glazunova 《Russian Journal of Inorganic Chemistry》2008,53(10):1552-1556
Tetramminenickel hydrogen hexamolybdoaluminate and hexamolybdogallate(III) of compositions [Ni(NH3)4] · H[AlMo6O18(OH)6] · 10H2O (I) and [Ni(NH3)4] · H[GaMo6O18(OH)6] · 10H2O (II) were synthesized and characterized by mass spectrometry, thermogravimetry, X-ray powder diffraction, and IR spectroscopy. Their crystals are triclinic. For compound I, a= 17.30 Å, b= 14.69 Å, c= 10.45 Å, α = 129.07, β = 65.91°, γ = 138.01°, V = 1338.7l Å3, ρcalcd = 2.75g/cm3, Z = 2; for compound II, a = 17.38 Å, b= 14.75 Å, c= 10.51 Å, α = 131.38°, β= 65.96°, γ = 138.09, V = 1338.15 Å3, ρcalcd = 2.68 g/cm3, Z = 2. 相似文献
19.
Yu. V. Kokunov V. V. Kovalev Yu. E. Gorbunova S. A. Kozyukhin S. G. Sakharov 《Russian Journal of Inorganic Chemistry》2016,61(12):1538-1544
The complexes [AgL2(NO3)] (I) and [AgL2(CH3SO3)] · H2O (II) (L is 2-methylquinoline, C10H9N) have been synthesized and structurally characterized by single-crystal X-ray diffraction. Crystals of I are monoclinic, space group P21/n, a = 9.296(1) Å, b = 13.495(1) Å, c = 14.931(1) Å, β = 95.06(1)°, V = 1865.8(3) Å3, ρcalc = 1.624 g/cm3, Z = 4. Crystals of II are monoclinic, space group P21/n, a = 13.147(1) Å, b = 11.767(1) Å, c = 13.814(1) Å, β = 96.06(1)°, V = 2124.3(3) Å3, ρcalc = 1.599 g/cm3, Z = 4. Compounds I and II are composed of discrete complexes of similar structure but with different orientation of the methyl groups of ligand L (trans and cis arrangement, respectively). Both anions, NO 3 - and CH3SO 3 - function as a chelating weakly bound ligand for the Ag+ ion. The presence of water molecules in II is favorable for the formation of dimeric supramolecular moieties between the centrosymmetrically arranged Ag+ complexes with 2-methylquinoline. The luminescence spectra of solid complexes I and II showed a bathochromic shift as compared to the spectrum of L in acetonitrile. Complexes I and II have been characterized by 1H and 13C{H} NMR spectra in CD3CN. 相似文献
20.
A. V. Oreshkina G. Z. Kaziev A. V. Steblevskii E. I. Myasnikova 《Russian Journal of Inorganic Chemistry》2010,55(3):368-369
Tetraamminecobalt hydrogen hexamolybdochromate [Co(NH3)4] · H[CrMo6O18(OH)6] · 6H2O (I) was synthesized and studied by mass spectrometry, thermogravimetry, IR spectroscopy, and X-ray diffraction. Crystals of I are monoclinic; a = 16.27 Å, b = 5.61 Å, c = 12.36 Å, β = 119.89°, V = 1100.12 Å3, ρcalcd = 2.29 g/cm3, and Z = 1. 相似文献