In situ observations of unusual drop deformation and wobbling in simple shear flow

Deformation and wobbling of a liquid drop immersed in a liquid matrix were studied under mild shear conditions for various viscosity ratios. In situ visualization experiments were conducted on a homemade transparent Couette cell incorporated to the Paar Physica MCR500 shear rheometer. The effect of drop or matrix elasticity was examined and was found to play a major role in both deformation and wobbling processes. Experimental results were compared to Jackson and Tucker (J Rheol 47:659–682, 2003), Maffettone and Minale (J Non-Newton Fluid Mech 78:227–241, 1998) and Yu and Bousmina (J Rheol 47:1011–1039, 2003) ellipsoidal models. It was found that the agreement between the Newtonian models and the experimental results required an increase in the drop viscosity. Such increment in viscosity was found to scale with the first normal stress difference.     

The interchain pressure effect in shear rheology

Recently, the tube diameter relaxation time in the evolution equation of the molecular stress function (MSF) model (Wagner et al., J Rheol 49: 1317–1327, 2005) with the interchain pressure effect (Marrucci and Ianniruberto, Macromolecules 37:3934–3942, 2004) included was shown to be equal to three times the Rouse time in the limit of small chain stretch. From this result, an advanced version of the MSF model was proposed, allowing modeling of the transient and steady-state elongational viscosity data of monodisperse polystyrene melts without using any nonlinear parameter, i.e., solely based on the linear viscoelastic characterization of the melts (Wagner and Rolón-Garrido 2009a, b). In this work, the same approach is extended to model experimental data in shear flow. The shear viscosity of two polybutadiene solutions (Ravindranath and Wang, J Rheol 52(3):681–695, 2008), of four styrene-butadiene random copolymer melts (Boukany et al., J Rheol 53(3):617–629, 2009), and of four polyisoprene melts (Auhl et al., J Rheol 52(3):801–835, 2008) as well as the shear viscosity and the first and second normal stress differences of a polystyrene melt (Schweizer et al., J Rheol 48(6):1345–1363, 2004), are analyzed. The capability of the MSF model with the interchain pressure effect included in the evolution equation of the chain stretch to model shear rheology on the basis of linear viscoelastic data alone is confirmed.     

Droplet dynamics in sub-critical complex flows

A newly designed eccentric cylinder device has been used to study the deformation and orientation of single Newtonian droplets immersed in an immiscible Newtonian liquid in a controlled complex flow field. Optical microscopy coupled with image acquisition analysis allows monitoring the dynamics of droplets flowing in the gap between the eccentric cylinders. Throughout the experiments, the flow intensity was kept below the critical conditions for droplet break-up. The experimental results are compared with predictions which are obtained using the transient form of the phenomenological model of Maffettone and Minale (J Non-Newtonian Fluid Mech 78:227–241, 1998; J Non-Newtonian Fluid Mech 84:105–106, 1999), incorporating a flow type parameter that accounts for the relative amount of elongational effects in the flow field and adapting the capillary number to mixed flows. For all the sub-critical flows studied here, good agreement was found between model predictions and experimental data, providing, for the first time, a quantitative assessment of drop shape predictions in complex flows.     

Numerical simulation of a drop undergoing large amplitude oscillatory shear

Direct numerical simulations are conducted for a Newtonian drop in a Newtonian matrix subjected to large amplitude oscillatory shear flows. In the experimental study of Guido et al. (in Rheol Acta 43:575–583, 2004), the drop shape is found to oscillate at higher harmonics of the forcing frequency when the capillary number is increased. Their phenomenological model requires a much smaller capillary number for predicting the harmonic nature of the experimental data. In this paper, computational results on the evolution of drop length and inclination angle are obtained at the same fluid and flow properties as the experiments, and are shown to reasonably reproduce the experimental data. In particular, the computed velocity fields around the drop are shown to elucidate the over-rotation, which is a mechanism for the experimentally observed harmonics.     

Simplified model for mass diffusivity estimation based on dynamic pendant drop volume analysis

We present a simplified correlation for calculating the dissolved gas moles in a pendant drop during the diffusion time, for several drop shapes. After this correlation is determined, the Yang and Gu (Ind Eng Chem Res 44:4474–4483, 2005) dynamic pendant drop volume analysis (DPDVA) method for calculation of mass diffusivity from the pendant drop volume variation against time can be used. We solved the differential equation in cylindrical coordinates for the mass transfer model of the gas diffusion into the liquid inside the pendant drop, using a different characteristic length (L_C), instead of the outer radius of the syringe needle (r_n) used in Yang and Gu (Ind Eng Chem Res 44:4474–4483, 2005) for defining the dimensionless variables. L_C is the relationship between the pendant drop volume and its mass transfer surface area at the initial conditions. The generalized correlation saves time, simplifies the method application and the deviations in the diffusion coefficient calculation respect to the complete Yang and Gu model are below 6%.     

High-speed fiber spinning process with spinline flow-induced crystallization and neck-like deformation

The dynamics and stability of the high-speed fiber spinning process with spinline flow-induced crystallization and neck-like deformation have been studied using a simulation model equipped with governing equations of continuity, motion, energy, and crystallinity, along with the Phan-Thien–Tanner constitutive equation. Despite the fact that a simple one-phase model was incorporated into the governing equations to describe the spinline crystallinity, as opposed to the best-known two-phase model [Doufas et al. J Non-Newton Fluid Mech, 92:27–66, 2000a]; [Kohler et al. J Macromol Sci Phys, 44:185–202, 2005] that treats amorphous and crystalline phases separately in computing the spinline stress, the simulation has successfully portrayed the typical nonlinear characteristic of the high-speed spinning process called neck-like spinline deformation. It has been found that the criterion for the neck-like deformation to occur on the spinline is for the extensional viscosity to decrease on the spinline, so that the spinning is stabilized by the formation of the spinline neck-like deformation. The accompanying linear stability analysis explains this stabilizing effect of the spinline neck-like deformation, corroborating a recent experimental finding [Takarada et al. Int Polym Process, 19:380–387, 2004].This paper was presented at the 2nd Annual European Rheology Conference 2005 on April 21–23, 2005, in Grenoble, France.     

Effects of viscoelasticity on the retraction of a sheared drop

Effects of drop and matrix viscoelasticity on the retraction of a sheared drop are numerically investigated. Retraction of an Oldroyd-B drop in a Newtonian matrix is initially faster and later slower with increasing drop Deborah number. The observed behavior is explained using an ordinary differential equation model representing the dominant balance between various forces during retraction. The initial faster relaxation of viscoelastic drops is due to viscoelastic stresses pulling the drop interface at the tips inward. The later slower retraction is due to the slowly-relaxing viscoelastic forces at the equator, where they act against the capillary force. The drop inclination decreases substantially during retraction unlike in a Newtonian case. Matrix viscoelasticity slows the relaxation of a Newtonian drop because of the increasingly slow relaxation of highly stretched polymers near the drop tip with increasing Deborah number. Increasing the ratio of polymeric to total viscosity further accentuates the viscoelastic effects in both cases. For an Oldroyd-B drop in an Oldroyd-B matrix, a competition between the dispersed and the continuous phase elasticities, represented by their ratio, determines the dynamics; larger values of the ratio leads again to initial faster and later slower retraction.     

Immiscible Newtonian displacement by a viscoplastic material in a capillary plane channel

The immiscible displacement in a capillary plane channel of a Newtonian liquid by a viscoplastic one that obeys a Papanastasiou’s constitutive equation is numerically analyzed. An elliptic mesh generation technique, coupled with the Galerkin finite element method is used to determine the velocity field and the configuration of the interface between the two materials. We investigate the displacement efficiency and the flow patterns of the problem as functions of the dimensionless parameters that govern the problem: the capillary number (Ca), the viscosity ratio of the two fluids (N _η ) and the yield number, (τ′₀). The numerical results showed that for a fixed viscosity ratio, the fraction of mass attached to the wall is a decreasing function of τ′₀. We constructed maps of streamlines in the Cartesian space defined by τ′₀ and Ca for fixed viscosity ratios in order to capture the rough location of bypass and recirculating flow regimes. Higher yield number values induce bypass flow regimes, especially for high Ca. The dimensionless forms of the momentum conservation equation and the force balance at the interface were essential for the understanding of the role played by the dimensionless numbers that govern the problem.     

Elongational viscosity of LDPE with various structures: employing a new evolution equation in MSF theory

Molecular stress function theory with new strain energy function is used to analyze transient extensional viscosity data of seven low-density polyethylene (LDPE) melts with various molecular structures as published by Stadler et al. (Rheol Acta 48:479–490, 2009) Pivokonsky et al. (J Non Newton Fluid Mech 135:58–67, 2006) and Wagner et al. (J Rheol 47(3):779–793, 2003). The new strain energy function has three nonlinear viscoelastic material parameters and assumes that the total stored energy of a branched molecule is given by different backbone and side chains stretching. The model parameters have been fitted for each LDPE in order to correlate with the supposed macromolecular structure expected from the type of synthesis. Most probable molecular structures for these LDPEs are comb and Cayley tree structures for respectively low- and high-molecular weight parts.     

Application of Rheological Models in Prediction of Turbulent Slurry Flow

The paper deals with fully developed steady turbulent flow of slurry in a circular straight and smooth pipe. The Kaolin slurry consists of very fine solid particles, so the solid particles concentration, and density, and viscosity are assumed to be constant across the pipe. The mathematical model is based on the time averaged momentum equation. The problem of closure was solved by the Launder and Sharma k-ε turbulence model (Launder and Sharma, Lett Heat Mass Transf 1:131–138, 1974) but with a different turbulence damping function. The turbulence damping function, used in the mathematical model in the present paper, is that proposed by Bartosik (1997). The mathematical model uses the apparent viscosity concept and the apparent viscosity was calculated using two- and three-parameter rheological models, namely Bingham and Herschel–Bulkley. The main aim of the paper is to compare measurements and predictions of the frictional head loss and velocity distribution, taking into account two- and three-parameter rheological models, namely Bingham and Herschel–Bulkley, if the Kaolin slurry possesses low, moderate, and high yield stress. Predictions compared with measurements show an observable advantage of the Herschel–Bulkley rheological model over the Bingham model particularly if the bulk velocity decreases.     

The role of dissipation and defect energy in variational formulations of problems in strain-gradient plasticity. Part 1: polycrystalline plasticity

A general set of flow laws and associated variational formulations are constructed for small-deformation rate-independent problems in strain-gradient plasticity. The framework is based on the thermodynamically consistent theory due to Gurtin and Anand (J Mech Phys Solids 53:1624–1649, 2005), and includes as variables a set of microstresses which have both energetic and dissipative components. The flow law is of associative type. It is expressed as a normality law with respect to a convex but otherwise arbitrary yield function, or equivalently in terms of the corresponding dissipation function. Two cases studied are, first, an extension of the classical Hill-Mises or J ₂ flow law and second, a form written as a linear sum of the magnitudes of the plastic strain and strain gradient. This latter form is motivated by work of Evans and Hutchinson (Acta Mater 57:1675–1688, 2009) and Nix and Gao (J Mech Phys Solids 46:411–425, 1998), who show that it leads to superior correspondence with experimental results, at least for particular classes of problems. The corresponding yield function is obtained by a duality argument. The variational problem is based on the flow rule expressed in terms of the dissipation function, and the problem is formulated as a variational inequality in the displacement, plastic strain, and hardening parameter. Dissipative components of the microstresses, which are indeterminate, are absent from the formulation. Existence and uniqueness of solutions are investigated for the generalized Hill-Mises and linear-sum dissipation functions, and for various combinations of defect energy. The conditions for well-posedness of the problem depend critically on the choice of dissipation function, and on the presence or otherwise of a defect energy in the plastic strain or plastic strain gradient, and of internal-variable hardening.     

The Dilute Rheology of Swimming Suspensions: A Simple Kinetic Model

A simple kinetic model is presented for the shear rheology of a dilute suspension of particles swimming at low Reynolds number. If interparticle hydrodynamic interactions are neglected, the configuration of the suspension is characterized by the particle orientation distribution, which satisfies a Fokker-Planck equation including the effects of the external shear flow, rotary diffusion, and particle tumbling. The orientation distribution then determines the leading-order term in the particle extra stress in the suspension, which can be evaluated based on the classic theory of Hinch and Leal (J Fluid Mech 52(4):683–712, 1972), and involves an additional contribution arising from the permanent force dipole exerted by the particles as they propel themselves through the fluid. Numerical solutions of the steady-state Fokker-Planck equation were obtained using a spectral method, and results are reported for the shear viscosity and normal stress difference coefficients in terms of flow strength, rotary diffusivity, and correlation time for tumbling. It is found that the rheology is characterized by much stronger normal stress differences than for passive suspensions, and that tail-actuated swimmers result in a strong decrease in the effective shear viscosity of the fluid.     

Elongational and shear rheology of carbon nanotube suspensions

Rheological behavior of concentrated suspensions of chemical vapor deposition carbon nanotubes in uniaxial elongation and simple shear is studied experimentally and theoretically. Nanotubes are suspended in viscous host liquids—castor oil or its blends with n-decane. The elongational measurements are performed by analyzing self-thinning (due to surface tension effect) liquid threads of nanotube suspensions. A quasi-one-dimensional model is used to describe the self-thinning process, whereas corrections accounting for thread nonuniformity and necking are introduced a posteriori. The effects of nanotube concentration and aspect ratio, viscosity of the suspending liquid, and initial diameter of the self-thinning thread in uniaxial elongation are elucidated. The results for uniaxial elongation are compared with those for simple shear. The correspondence in the results of the shear and elongational measurements is addressed and interpreted. The results conform to the Herschel–Bulkley rheological constitutive equation (i.e., power law fluids with yield stress). However, the yield stress in elongation is about 40% higher than in simple shear flow, which suggests that the original Herschel–Bulkley model need modification with the yield stress being a function of the second invariant of the deviatoric stress tensor. The present effort is the first to study capillary self-thinning of Herschel–Bulkley liquids, which are exemplified here by suspensions of carbon nanotubes.     

Droplet deformation of a strongly shear thinning dense suspension of polymeric micelles

We investigated the deformation of a strong shear thinning droplet undergoing simple shear flow in a Newtonian liquid. The droplet was an aqueous solution of poly(ethylene oxide) end capped with an alkyl group that forms spherical micelles in aqueous solution. At high concentrations and below a critical temperature, the jammed micelles showed strong shear thinning behaviour, and neither a yield stress nor a Newtonian viscosity was observed. At small shear rates, the droplet rotated and aligned in the flow, but did not deform or only very weakly. At high shear rates, the droplet deformation increased with increasing shear rate. The deformed droplet did not relax after the shear was stopped except for a modest rounding of the edges. For each shear rate, an apparent viscosity, η _ad, of the equivalent Newtonian droplet was calculated assuming affine deformation. η _ad showed a power law dependence on the capillary number Ca with an exponent of − 1.8 and was larger than the shear viscosity of the micelle suspension at the same shear rates. The results were explained by the existence of a strong gradient of the viscosity inside the droplet leading to a very low viscosity fluid layer near the droplet/matrix interface.     

A correlation for yield stress fluid flow through packed beds

Relatively few correlations are available for non-Newtonian fluid flows through packed beds, even though such fluids are frequently used in industry. In this paper, a correlation is presented for yield stress fluid flow through packed beds. The correlation is developed by introducing the yield stress model in place of the Newtonian model used in deriving Erguns equation. The resulting model has three parameters that are functions of the geometry and roughness of the particle surfaces. Two of the parameters can be deduced in the limit as the yield stress becomes negligible and the model reduces to Erguns equation for Newtonian fluids. The third model parameter is determined from experimental data. The correlation relates a defined friction factor to the dimensionless Reynolds and Hedstrom numbers and can be used to predict pressure drop for flow of a yield stress fluid through a packed bed of spherical particles. Conditions for flow or no-flow are also determined in the correlation. Comparison of model calculations, between a Newtonian and a yield stress fluid for flow penetration into a packed bed of spheres, shows the yield stress fluid initially performs similar to the Newtonian fluid, at large Reynolds numbers. At lower Reynolds numbers the yield stress effect becomes important and the flow rate significantly decreases when compared to the Newtonian fluid.     

Application of the method of direct separation of motions to the parametric stabilization of an elastic wire

The paper considers the application of the method of direct separation of motions to the investigation of distributed systems. An approach is proposed which allows one to apply the method directly to the initial equation of motion and to satisfy all boundary conditions, arising for both slow and fast components of motion. The methodology is demonstrated by means of a classical problem concerning the so-called Indian magic rope trick (Blekhman et al. in Selected topics in vibrational mechanics, vol. 11, pp. 139–149, [2004]; Champneys and Fraser in Proc. R. Soc. Lond. A 456:553–570, [2000]; in SIAM J. Appl. Math. 65(1):267–298, [2004]; Fraser and Champneys in Proc. R. Soc. Lond. A 458:1353–1373, [2002]; Galan et al. in J. Sound Vib. 280:359–377, [2005]), in which a wire with an unstable upper vertical position is stabilized due to vertical vibration of its bottom support point. The wire is modeled as a heavy Bernoulli–Euler beam with a vertically vibrating lower end. As a result of the treatment, an explicit formula is obtained for the vibrational correction to the critical flexural stiffness of the nonexcited system.     

A Study of the Behavior of Implicit Pressure Explicit Saturation (IMPES) Schedules for Two-phase Flow in Dynamic Pore Network Models

We focus on the numerical difficulties that typify implicit pressure explicit saturation (IMPES) schedules in dynamic “ball-and-stick” pore network models for two-phase flow. We show that a time stepping procedure based on a prescribed maximum variation of the local capillary pressure rather than on a (usual) maximum variation of the local saturation along with the addition in the solution algorithm of suitable “flow constraints” (in Koplik and Lasseter, Soc. Pet. Eng. J. 25(1):89–100, 1985) provide more stability and a significant run time speed up. In particular, the slow convergence and the oscillatory behavior that typify IMPES schemes at low Ca values due to capillary pinning are efficiently suppressed.     

On the averaging principle for one-frequency systems. Seminorm estimates for the error

We extend some previous results of our work (Morosi and Pizzocchero in J. Phys. A: Math. Gen. 39:3673–3702, 2006) on the error of the averaging method, in the one-frequency case. The new error estimates apply to any separating family of seminorms on the space of the actions; they generalize our previous estimates in terms of the Euclidean norm. For example, one can use the new approach to get separate error estimates for each action coordinate. An application to rigid body under damping is presented. In a companion paper (Morosi and Pizzocchero, 2006), the same method will be applied to the motion of a satellite around an oblate planet.     

Sharp Observability Estimates for Heat Equations

The goal of this article is to derive new estimates for the cost of observability of heat equations. We have developed a new method allowing one to show that when the corresponding wave equation is observable, the heat equation is also observable. This method allows one to describe the explicit dependence of the observability constant on the geometry of the problem (the domain in which the heat process evolves and the observation subdomain). We show that our estimate is sharp in some cases, particularly in one space dimension and in the multi-dimensional radially symmetric case. Our result extends those in Fattorini and Russell (Arch Rational Mech Anal 43:272–292, 1971) to the multi-dimensional setting and improves those available in the literature, namely those by Miller (J Differ Equ 204(1):202–226, 2004; SIAM J Control Optim 45(2):762–772, 2006; Atti Accad Naz Lincei Cl Sci Fis Mat Natur Rend Lincei (9) Mat Appl 17(4):351–366, 2006) and Tenenbaum and Tucsnak (J Differ Equ 243(1):70–100, 2007). Our approach is based on an explicit representation formula of some solutions of the wave equation in terms of those of the heat equation, in contrast to the standard application of transmutation methods, which uses a reverse representation of the heat solution in terms of the wave one. We shall also explain how our approach applies and yields some new estimates on the cost of observability in the particular case of the unit square observed from one side. We will also comment on the applications of our techniques to controllability properties of heat-type equations.     

Breakup of a capillary bridge of suspensions

The breakup of liquid bridges under the action of capillary forces is used for studying the rheology of suspensions under stretching. The experiments were performed with suspensions of finegrained (3–30 μm) sand in glycerin for sand volume fractions up to 0.465. The bridge thinning process was registered using an electro-optical measuring device and videofilming. The results were analyzed on the basis of a theory developed earlier for the thinning of a liquid bridge under the action of capillary forces. It is found that, for fairly slow stretching realized in the initial stage of the thinning, the rheological behavior of the suspensions considered agrees with the model of a Newtonian viscous fluid. Along with this, the measured effective viscosity of the suspension turned out to be approximately two-fold greater than the suspension viscosity under shear. The origin of this discrepancy is analyzed. With increase in the stretching rate, in the final stage of the thinning, the weakening of the suspension occurs, which is manifested in the formation of a local rapidly thinning neck in the bridge, similar to that observed in the breakup of plastic materials.