用相位分析方法计算交流Stark效应

定态波函数的相位变化极其简单。当原子受到含时间的微扰作用时，任－叠加态中各定态波函数的振幅和相位都随时间作复杂变化。     

用二能级理论解释交流Stark效应

用二能级理论的Ｒａｂｉ解说明交流Ｓｔａｒｋ效应，既从原子电偶极矩随外场变化的角度，也从原子光跃迁的角度解释交流Ｓｔａｒｋ效应。     

量子场作用下二能级原子的AC Stark效应

计算了处在粒子数态的单模量子场与二级原子相互作用时能级ＡＣ Ｓｔａｒｋ移动,平均能级移动值随场模波频变变化呈色散线型,随场模中光子数的增加会逐渐达到饱和。另外,还发现即使是场模中光子数为零,量子场仍能通过ＡＣ Ｓｔａｒｋ效应使原子能级发生移动。     

Stark效应对双模压缩真空场与原子耦合系统腔场谱的影响

研究了Stark效应对两模双光子J-C模型腔场谱的影响,推导计算出了腔场处于压缩真空态时腔场谱的计算公式和数值结果,讨论了Stark效应和初始场强对腔场谱的影响.发现初始场较弱时,Stark效应主要影响谱线的频率,对峰的强度影响不大;初始场n1=n2≥2后,Stark效应对主峰有较强的强化作用,对边峰产生抑制作用;在初始场较强时,对谱强度的影响显著.改变Stark移动参数和初始场的强度,可得到各式各样的腔场谱结构.     

Stark效应对J-C模型腔场谱的影响

研究了计及Stark效应的J-C模型的腔场谱,通过求解本征方程导出了腔场谱的计算公式,给出了腔场处于光子数态时的数值结果,讨论了Stark效应和初始场强对标准J-C模型腔场谱的影响.发现在初始场为真空场时,两个Rabi峰的高度相等,随着Stark位移参数的增大,两峰都向低频方向移动,且频差逐渐增大;在初始场较强的情况下,Stark移动参数增大时会导致双峰的对称性消失,通过测量两峰的相对高度也可确定Stark位移参数的大小;在Stark效应较强初始场递增的情况下两峰仍向左移,但峰间距越来越小;在弱场情况下,Stark效应使两峰呈现左高右低或左低右高的峰结构.总之,改变Stark位移参数β1、β2的大小以及初始场强的强弱,可得到不同的谱线结构.     

Stark效应对双光子Jaynes-Gummings模型中原子辐射谱的影响

本文研究了Stark效应对双光子Jaynes-Cummings模型中原子辐射谱的影响,结果表明:Stark效应使得原子的辐射谱偏离关于中心频率的对称性,各峰的相对高度发生了明显的变化。     

Stark效应对双光子Jaynes－Gummings模型中原子辐射谱的影响

本文研究了Ｓｔａｒｋ效应对双光子Ｊａｙｎｅｓ－Ｃｕｍｍｉｎｇｓ模型中原子辐射谱的影响，结果表明：Ｓｔａｒｋ效应使得原子的辐射谱偏离关于中心频率的对称性，各峰的相对高度发生了明显的变化。     

不同微场分布函数对Stark线型的影响

利用不同的微场分布函数研究了其对Stark加宽光谱线型的影响.根据Stark加宽理论,考虑到等离子体中的离子碰撞,Stark加宽本质上是一种非对称的光谱线型,其中微场分布函数对光谱线型起着非常关键的作用.研究结果表明,总体上Holtsmark分布和Nearest-Neighbor场分布下的Stark光谱线型差别不太大,但是Mayer模型对Stark加宽光谱线型影响较大.并且随着离子加宽参数的减小,三种不同的微场分布函数对Stark光谱线型的影响逐渐减小;随着电子加宽参数的减小,不同的微场分布函数对Stark光谱线型的影响也逐渐减小;同时发现,当离子加宽参数减小到一定程度时,不同微场分布函数对整个光谱线型的影响基本相似,这也正说明离子间碰撞剧烈时对光谱线型的影响很大.     

氢原子一级Stark效应能级的解析式

根据简并态微扰论、球坐标系中氢原子波函数的性质,得到任意能级下氢原子一级Stark效应能级计算的简单方法,并计算了n=5的能级修正值,由此得到了氢原子一级Stark能级的解析式。     

Stark效应对双光子Jaynes-Cummings模型中原子的压缩效应的影响

本文研究了包括Stark效应时任意初态的双光子Jaynes-CUmmings模型的一般演化规律,应用到具体问题,讨论了初始时刻有效二能级原子处于基态而光场为二项式分布时原子的压缩效应。     

Calculation of the Dynamic Stark Effect in the Many-Level Approximation

A new method for calculating the dynamic Stark effect in a circular polarized electric field of arbitrary strength and frequency is proposed. The basic equations of the method are given. By way of illustration the results of calculation of the shift and splitting of energy levels of a He atom in a circular polarized electric field are considered.     

光子统计特性对原子能级AC Stark移动的影响

以相干态单模场和单模热光场引起的原子能级ACStark移动为例,分析了光子统计特性对能级移动规律的影响,能级AC Stark移动中包含了光场统计特性信息,这表明可以通过AC Stark效应研究场的统计性质。     

Far-Infrared Laser Stark Spectroscopy of 1,1 Difluoroethylene

The far-infrared laser Stark spectrum of 1,1 difluoroethylene (H₂C=CF₂) has been investigated with the 311 m line of the hydrogen cyanide (HCN) laser. Numerous families of absorption lines have been observed for both parallel and perpendicular polarizations up to 60 000 V/cm. Three families of resonances have been identified as J(K_a,K_c) = 41(35,7) 40(33,8), 40(36,5) 39(34,6) and 43(35,8) 42(33,9). The Stark shift for the first two transitions can be adequately explained by quasi-first-order calculations, whereas the Stark shift for the third transition requires second-order corrections. The zero-field frequencies for these transitions have been experimentally determined and are reported with fractional uncertainties up to a few parts in 10⁶.     

Stark Hole-Burning Spectroscopy of Cresylviolet Perchlorate in Amorphous Hosts

Stark hole-burning spectroscopy is used to investigate the effective dipole moment change of cresylviolet perchlorate (CVP) in various glass and polymer hosts such as ethanol:methanol (EM), polyvinyl alcohol (PVA), poly (2-hydroxyethyl) methacrylate (PHEMA), polyvinylbutyral (PVB), and formamide. The strong correlation between effective dipole moment change of the guest molecule and the holeburning efficiencies of the host matrices illustrates the sensitivity of the dipole moment change as a direct measure of guest-host interactions. Hole-burning is found to be more efficient as the dipole induced reaction field increases. This relationship is discussed in terms of the unusual hole-burning mechanism suggested for this molecule. The effective dipole moment change of cresylviolet perchlorate ranges from 0.14 to 0.59 Debye.     

利用真空紫外脉冲场电离-光电子方法研究三氯乙烯阳离子振动光谱

在 76 4 0 0～ 796 5 0cm-1的能量范围内测量了三氯乙烯的真空紫外脉冲场电离 光电子 (VUV PFI PE)谱 .根据量子化学理论计算的频率以及Franck Condon因子 ,对VUV PFI PE谱的振动谱带进行了标定 ,确认了11个三氯乙烯阳离子的振动频率 ,分别为 :ν1+ =14 8cm-1,ν2 + =180cm-1,ν3 + =2 86cm-1,ν4+ =4 0 2cm-1,ν5+=4 72cm-1,ν6+ =6 6 0cm-1,ν7+ =875cm-1,ν8+ =990cm-1,ν9+ =10 38cm-1,ν10 + =12 6 7cm-1,ν11+ =14 0 8cm-1.这些测量和新近用真空紫外 红外光诱导电离确定的ν12 + =30 73cm-1一起 ,提供了三氯乙烯阳离子电子基态的所有 12个振动频率的实验值 .通过对VUV PFI PE谱 (0 ,0 )跃迁带的光谱拟合 ,确定了三氯乙烯的电离能为(76 4 4 1.7± 2 .0 )cm-1((9.4 776± 0 .0 0 0 2 )eV) .     

Coherent control of AC Stark allowed transition in Λ system

A three level Λ system is considered and the coherence established on initially forbidden transition is calculated. It is shown that quantum-interference-related phenomena, such as electromagnetically induced transparency, gain without inversion and enhanced refractive index may occur on such transitions, which became dynamically allowed due to AC Stark effect. Gain/dispersion characteristics of such transitions strongly depend upon the relative phase between the driving and probe fields. Unlike allowed transitions, gain/absorption behavior of forbidden transitions exhibit antisymmetric feature on the Rabi sidebands. Absorption/gain spectra possess extremely narrow sub-natural resonances.     

一种碳纳米管场效应管半经典模型计算方法

基于弹道输运的碳纳米管场效应管半经典模型求解自洽电势通常采用牛顿-拉夫逊迭代法,每次迭代都需要对态密度方程积分计算,运算量巨大.我们用支持向量回归机近似表达自洽电势与载流子密度之间的关系,不需要反复迭代积分,并用梯度下降法求解自洽电势.仿真结果表明,与牛顿-拉夫逊迭代法比较,该方法精度较高,有效降低了运算量,为今后大规模集成电路中碳纳米管器件的设计和应用奠定理论基础.     

光泵分子气体远红外光谱的AC Stark效应

本文应用图论法研究光泵激光气体分子的波谱特性。假定了:1.分子与外来信号场相互作用输运过程中只涉及到六个能级;2.泵场强远大于探测场强。在这些假定下求解密度矩阵方程,获得一套反映受激分子波谱特性的解析表达式。应用这些表达式,可求得不同频率的泵场作用下分子气体的远红外波谱特性。本文特别叙述分子振动基态远红外光谱的AC aStark效应。结果表明:在谐振点AC aStark分裂的值与C.H.Townes所得结果基本相同,在受激发射和吸收共存的情况下,特性曲线的总趋向与他的结果基本一致。调谐曲线有些部份反映发射特性,有些部份反映吸收特性,在发射和吸收的过渡部份,吸收和发射都很小,而且具有特殊的过渡特性。     

Determination of the Dipole Moment of O-18 Methanol by Microwave Stark Spectroscopy

In this paper we report accurate measurements of microwave (MW) frequencies for nine different transitions in the first four torsional states in the ground vibrational state of O-18 substituted methanol, for a wide range of applied dc electric field. The Stark-shifted frequencies were measured with accuracies of about ±10 kHz. The results were analyzed to deduce accurate dipole moment values for the four torsional states involved. Substantial variation of dipole moment was observed as a function of the torsional state. The zero field frequencies have been also determined with much better precision than known before. The dipole moment values for the torsional ground state have been determined to be μ_a= 0.8992(8) and μ_b= 1.4226(3) D. The dipole moment value increases with torsional excitation. These values will be useful for the evaluation of relative intensities of interstellar microwave and millimeter wave transitions and optically pumped far infrared laser lines.