Second order elastic anomalies in barium titanate from orthorhombic to rhombohedral phase transition

The anomalies in second order elastic constants have been derived for barium titanate for the phase transition from orthorhombic to rhombohedral state. The equilibrium values of order parameter, strain variables and fluctuations in order parameter have been derived using stability conditions and Landau-Khalatnikov equations respectively. Expression for shift in specific heat is obtained. All the anomalies in second order elastic constants have been derived and relations among them reported. The numerical values of anomalies in the individual constants are calculated and their variation is represented graphically. Changes in elastic constants occur over a range of temperature of the order 10⁻²K.     

大块金属玻璃Zr41Ti14Cu12.5Ni10Be22.5的流变行为研究

采用静态拉伸方法在连续升温条件下动态地测量了大块金属玻璃Zr41Ti14Cu12.5Ni10Be22.5（Vit1）的黏度随温度的变化关系.在应变速率与温度的关系曲线中，观测到了与玻璃转变和晶化过程相联系的多个应变速率峰.在玻璃转变温度Tg以上，大块金属玻璃Zr41Ti14Cu12.5Ni10Be22.5的过冷液体呈现Newton流体特征，其黏度与温度的关系符合Vogel Fulcher-Tammann (VFT)关系式，拟合得到脆度D*＝36，VFT温度T0＝319K，脆度参数m＝30，这说明Zr41T 关键词： 大块金属玻璃 应变速率 剪切黏度 自由体积     

The synergetic theory of the glass transition in liquids

The glass transition is treated as a spontaneous emergence of the shear components of strain and stress elastic fields upon cooling a liquid at a rate exceeding the critical value. The stationary elastic strains and stresses and the effective relaxation time are determined within the adiabatic approximation. It is shown that the glass transition process occurs through the mechanism of a first-order kinetic transition with allowance made for the strain dependence of the shear modulus. The critical cooling rate turns out to be proportional to the thermal diffusivity and unrelaxed shear modulus and inversely proportional to the temperature derivative of the relaxed shear modulus and the square of the heat conductivity length of the sample.     

Anomalies in second order elastic constants and gyrotropic constants of triglycine sulphate near phase transition

The anomalies in second order elastic constants and gyrotropic constants have been considered for the phase transition of triglycine sulphate. Expressions have been derived for the equilibrium values of order parameter and strain variables in both phases. Using Landau-Khalatnikov equation the fluctuation in order parameter is expressed in terms of fluctuations in strain variables. Substitution of these in free energy gives anomalies arising from Landau and coupling energies in second order elastic constants. The real part of the anomalies decreases steeply across the transition temperature and thereafter flatly tend to ferroelectric values. The anomalies in the components of the gyrotropic tensor have been derived and their temperature variation discussed.     

Second order elastic anomalies in barium titanate from cubic to tetragonal phase transition

The anomalies of the second order elastic constants have been derived for barium titanate for the phase transition from cubic to tetragonal. The equilibrium values of the components of the order parameter and the strain variables have been obtained from the stability conditions. The fluctuations in the order parameter have been derived from the Landau-Khalatnikov equations. Expression for the shift in the zero point energy in the tetragonal phase is obtained and is shown to be proportional to (T −T _c)². The anomalies for all the second order elastic constants have been derived and relations among them reported. It is shown that the second order elastic anomalies suffer a discontinuity at the transition temperature.     

External field in Landau theory of the weakly-first-order phase transition. Effect of uniaxial pressure on the orientational ordering in solid C70

The effect of the external conjugate field on a weakly discontinuous first-order phase transition is analyzed within Landau theory. The third-degree term in the Ginzburg-Landau expansion is shown to preserve the phase transition for some external fields, in contrast with the second-order case. The free-energy expansion is shown to correspond to a second-order phase transition under the influence of an “effective” external field that depends on both the temperature and the real field. The case of the orientational phase transition in solid C₇₀ is considered, and the transition thermoelastic phenomena caused by the coupling of order parameter with elastic strain are analyzed. It is shown that the uniaxial mechanical pressure along the direction of the 3-fold axis appears to be an external conjugate field for orientational ordering in crystalline C₇₀. Pis’ma Zh. éksp. Teor. Fiz. 63, No. 8, 594–599 (25 April 1996) Published in English in the original Russian journal. Edited by Steve Torstveit.     

Phase transitions in materials with thermal memory

A model for thermally induced phase transitions in materials with thermal memory is explored. From a general starting point of the thermodynamics of materials with memory, field equations with an order parameter, temperature and temperature gradient are derived. The heat flux is given by an integral over the history of the temperature gradient. Asymptotic analysis yields that to leading order, there is a relation connecting the discontinuity in the temperature field with the normal velocity of the transition zone. The temperature discontinuity is negligible for low transition zone velocity. The latent heat must depend on velocity and becomes negligible compared with the specific heat as the normal velocity approaches the speed of propagation of thermal disturbances. There is also a condition which is different from the Stefan condition connecting discontinuities in the temperature gradient with velocity, but reduces to this form, under certain approximations, in the low transition zone velocity limit. The circumstances where the transition zone velocity may exceed the speed of thermal disturbances are discussed.     

Polymer thin films and surfaces: Possible effects of capillary waves

It is discussed how the proximity of a free surface or mobile interface may affect the strain relaxation behavior in a viscoelastic material, such as a polymer melt. The eigenmodes of a viscoelastic film are thus derived, and applied in an attempt to explain the experimentally observed substantial shift of the glass transition temperature of sufficiently thin polymer films with respect to the bulk. Based on the idea that the polymer freezes due to memory effects in the material, and exploiting results from mode-coupling theory, the experimental findings of several independent groups can be accounted for quantitatively, with the elastic modulus at the glass transition temperature as the only fitting parameter. The model is finally applied discussing the possibility of polymer surface melting. A surface molten layer is predicted to exist, with a thickness diverging as the inverse of the reduced temperature. A simple model of thin polymer film freezing emerges which accounts for all features observed experimentally so far. Received 8 August 2001     

First-order phase transition in potassium dysprosium tungstate induced by the field renormalization and softening of the elastic moduli in the vicinity of a structural Jahn-Teller-type transition

The magnetostriction of KDy(WO₄)₂ single crystals is measured in an external magnetic field at temperatures below the temperature of a structural phase transition of the Jahn-Teller type. A steplike irreversible variation in the elastic strain is observed to occur with an increase in the magnetic field applied along the a or b axis of the monoclinic cell of the crystal. The residual change in the strain is retained after changing the sign of the magnetic field. The return to the initial state characterized by field-induced jumps in the strain is possible only after thermal cycling well above the structural phase transition temperature. The theory of this phenomenon is developed using a phenomenologically derived thermodynamic potential of the elastic sub-system that takes into account the crystal symmetry and the field renormalization of the elastic moduli. The jumplike transitions are interpreted as being due to the magnetic softening of the elastic moduli in the vicinity of the structural phase transition temperature.     

Pattern formation in Ferroelastic Transitions

We study pattern formation in ferroelastic materials using the Ginzburg–Landau approach. Since ferroelastic transitions are driven by strain, the nonlinear elastic free energy is expressed as an expansion in the appropriate (i.e., order parameter) strain variables. However, the displacement fields are the real independent variables, whereas the components of the strain tensor are related to each other through elastic compatibility relations. These constraints manifest as an anisotropic long-range interaction which drastically influences the underlying microstructure. The evolution of the microstructure is demonstrated for (i) a hexagonal-to-orthorhombic transition using a strain-based approach with explicit long-range interactions; and (ii) a cubic-to-tetragonal transition by solving the force-balance equations for the displacement fields.     

Fluctuation corrections at first order phase transitions: Application to C60

The temperature dependence of the elastic constants in C₆₀ is quite unusual in the vicinity of the order-disorder phase transition at 260 K, in sharp contrast to simple mean-field calculations. The observed deviations seem to be a combination of dynamical processes, the influence of defects and fluctuation effects. The latter are expected to be important, since the Landau free energy admits a third order term in the order parameter. We develop field theoretic perturbation theory for general models of this type. The formalism is applied to a simple scalar model of C₆₀ and the resulting temperature dependence of elastic constants is discussed.     

Thermomechanical properties of graphene: valence force field model approach

Using the valence force field model of Perebeinos and Tersoff (2009 Phys. Rev. B 79 241409(R)), different energy modes of suspended graphene subjected to tensile or compressive strain are studied. By carrying out Monte Carlo simulations it is found that: (i) only for small strains (|ε| 相似文献   

Fluctuations in the paraphase of improper ferroelastics taking into account indirect interactions through the field of elastic deformations

The effect of indirect interactions (through the field of elastic deformations) on the temperature dependences of a two-point correlator of the order parameter of an improper ferroelastic is studied theoretically taking into account the interaction of fluctuations at different spatial points with one another and with defective elastic fields. The latter are accounted for by using a phenomenological field of the sources of defective elastic fields. Analysis is carried out using diagrammatic expansions followed by a transition to the Dyson equation. It is proposed that the Dyson equation be approximately solved nonperturbatively using the ansatz for an exact two-point Green function of the form G_int(k)=T/[α_ij(τ)k _i k _j +β(τ)]. Such an approach makes it possible to reduce the problem to solving a system of nonlinear algebraic equations, which can effectively be solved by numerical methods. The aggregate of the assumptions made is equivalent to the mean field theory, which, however, cannot be reduced in the present case to the Ginzburg-Landau theory in view of the essentially nonlocal character of the indirect interaction via the field of elastic deformations. The results of numerical calculations are considered for a defect-free Hg₂Cl₂ crystal, for which it is shown that parameters of dispersion α_ij acquire a substantial temperature dependence in a temperature range much broader than the width of the critical region of the given crystal.     

Influence of radiative heat flux in nonlinear convection of quartic order in Casson fluid past a vertical permeable plate with variable suction and Hall current

The current study centralizes on unsteady free convection slip flow of Casson fluid past a vertical permeable plate with Hall current, radiative heat flux, and variable suction. The nonlinear convection is subjected to quartic order. Perturbation method is used to convert the non-linear coupled partial differential equation of the momentum and energy to a system of ordinary differential equations. The dimensionless governing equations are solved analytically for velocity and temperature profiles. The graphs are plotted for sundry parameters for variations in the distinct flow fields w.r.t distance from the plate. Variation in the skin friction for the axial and transverse cases are presented in the form of graphs for various parameters. It is observed that with the increase in the order of non-linear convection and value of radiation parameter, the velocity field increases in Casson fluid. The increase in heat absorption parameter and Prandtl number decreases the temperature profile and increase in radiative heat flux parameter increases the temperature profile.     

向列液晶表面弹性能K13项的物理效应及检验方法

通过解析推导和数值计算的方法，得到了平衡态指向矢满足的微分方程和边界条件.研究了表面弹性能K13项对磁场作用下的弱锚定向列液晶盒Fréedericksz转变性质的影响.结果表明，表面弹性能K13项的存在对液晶系统的自由能有很大的影响，从而改变转变的性质，诱导液晶盒在阈值点发生一级Fréedericksz转变.给出了发生一级转变的物理条件，它除了与液晶的结构和材料有关外，还依赖于液晶表面弹性能K13项，同时给出了由此判断K13项是否存在的检验方法. 关键词： 表面弹性能K13项 弱锚定 Fréedericksz转变     

MHD Maxwell flow modeled by fractional derivatives with chemical reaction and thermal radiation

Heat transfer in a time-dependent flow of incompressible viscoelastic Maxwell fluid induced by a stretching surface has been investigated under the effects of heat radiation and chemical reaction. The magnetic field is applied perpendicular to the direction of flow. Velocity, temperature, and concentration are functions of z and t for the modeled boundary-layer flow problem. To have a hereditary effect, the time-fractional Caputo derivative is incorporated. The pressure gradient is assumed to be zero. The governing equations are non-linear, coupled and Boussinesq approximation is assumed for the formulation of the momentum equation. To solve the derived model numerically, the spatial variables are discretized by employing the finite element method and the Caputo-time derivatives are approximated using finite difference approximations. It reveals that the fractional derivative strengthens the flow field. We also observe that the magnetic field and relaxation time suppress the velocity. The lower Reynolds number enhances the viscosity and thus motion weakens slowly. The velocity initially decreases with increasing unsteadiness parameter δ. Temperature is an increasing function of heat radiation parameter but a decreasing one for the volumetric heat absorption parameter. The increasing value of the chemical reaction parameter decreases concentration. The Prandtl and Schmidt numbers adversely affect the temperature and concentration profiles respectively. The fractional parameter changes completely the velocity profiles. The Maxwell fluids modeled by the fractional differential equations flow faster than the ordinary fluid at small values of the time t but become slower for large values of the time t.     

A fractional calculus approach to nonlocal elasticity

If the attenuation function of strain is expressed as a power law, the formalism of fractional calculus may be used to handle Eringen nonlocal elastic model. Aim of the present paper is to provide a mechanical interpretation to this nonlocal fractional elastic model by showing that it is equivalent to a discrete, point-spring model. A one-dimensional geometry is considered; the static, kinematic and constitutive equations are presented and the governing fractional differential equation highlighted. Two numerical procedures to solve the fractional equation are finally implemented and applied to study the strain field in a finite bar under given edge displacements.     

Brittle and Ductile Character of Amorphous Solids

Common silicate glasses are among the most brittle of the materials. However, on warming beyond the glass transition temperature $T_g$ glass transforms into one of the most plastic known materials. Bulk metallic glasses exhibit similar phenomenology, indicating that it rests on the disordered structure instead on the nature of the chemical bonds. The micromechanics of a solid with bulk amorphous structure is examined in order to determine the most basic conditions the system must satisfy to be able of plastic flow. The equations for the macroscopic flow, consistent with the constrictions imposed at the atomic scale, prove that a randomly structured bulk material must be either a brittle solid or a liquid, but not a ductile solid. The theory permits to identify a single parameter determining the difference between the brittle solid and the liquid. However, the system is able of perfect ductility if the plastic flow proceeds in two dimensional plane layers that concentrate the strain. Insight is gained on the nature of the glass transition, and the phase occurring between glass transition and melting.     

Generalized Langevin equations with time-dependent temperature

A generalized Langevin equation describing the evolution of a particle in a heat bath with a time-dependent temperature is derived for a simple model. The temperature is controlled by introducing dissipative terms in the dynamical equations of the heat bath particles. The Langevin equation contains a term that is specifically associated with the variation of the temperature.