Hyperfine interaction of Ce and La in 3-d ferromagnets

NMR/ON measurements on¹⁴¹CeFe show the sign of the hyperfine field of CeFe to be negative. For the¹⁴¹Ce nucleus a g-factor of ¦g_N¦=0.311±0.011 is found. With this g-value a hyperfine field of H_hf=?41±2 T for CeFe is derived. Low temperature nuclear orientation experiments on¹⁴¹CeCo and¹⁴⁰LaFe yield ¦H_hf¦=30±3 T and ¦H_hf¦=46±5 T respectively. The valence of cerium impurities in Fe, Co and Ni is discussed.     

Lebensdauer- und Hyperfeinstrukturmessungen an einigen angeregten Zuständen der Konfiguration 4d 9 5p im Pd I-Spektrum mit der Level-crossing-Methode

Lifetimes and hfs coupling constants of some excited states of the 4d ⁹ 5p configuration of Pd I have been determined in a level crossing experiment by observing the field dependence of the polarization of the fluorescence radiation in a magnetic field. From the halfwidths of the measured zero field level crossing signals one obtains the mean lifetimes of the following fine structure states:τ(³P ₁ ⁰ )=(7.46±0.32)nsec;τ(³ P ₂ ⁰ )=(6.9±0.76)nsecτ(³P ₁ ⁰ )=(4.99±0.35)nsec;τ(³ D ₁ ⁰ )=(4.89±0.40)nsecτ((³D ₃ ⁰ )=(6.99±0.49)nsec;τ(³ F ₄ ⁰ )=(7.09±0.46)nsec.Δm=2 crossing signals were detected in the³ P ₁ ⁰ ,³D ₃ ⁰ and³F ₄ ⁰ -states of the odd isotope¹⁰⁵Pd. A detailed analysis of the experimental curves yields the hfs coupling constantsA andB of these states:A(³P ₁ ⁰ )=?(133±2) Mc/sec;B(³ P ₁ ⁰ )=(140±30) Mc/secA(³D ₃ ⁰ )=?(120±10) Mc/sec;B(³ D ₃ ⁰ )=?(660±100) Mc/secA(³F ₄ ⁰ )=?(87±2) Mc/sec;B(³ F ₄ ⁰ )=?(330±30) Mc/sec. A theoretical calculation of the hfs constants is given on the basis of reduced matrix elements. Within the limit of the errors these values agree with the experimental ones. The nuclear electric quadrupole moment deduced from the measuredB values isQ (¹⁰⁵Pd)=(0.8±0.3)·10^?24 cm² (without corrections).     

Mößbauereffekt in157Gd und155Gd

Using the Mössbauer technique electric hyperfine interactions of the first excited non-rotational states at 64 keV in¹⁵⁷Gd and at 86.5 keV in¹⁵⁵Gd have been determined in GdF₃ and GdCl₃· 6H₂O. For the ratio of quadrupolmoments the ratiosQ ₆₄ ¹⁵⁷ /Q _g ¹⁵⁷ =1.74±0.04,Q _86.5 ¹⁵⁵ /Q _g ¹⁵⁷ =?0.07 ± 0.21 andQ _g ¹⁵⁵ /Q _g ¹⁵⁷ =0.78 ± 0.06 were found. In addition isomer shifts were observed from which a ratio δ〈r²〉 ₆₄ ¹⁵⁷ /δ〈r²〉 _86.5 ¹⁵⁵ =?2.6±0.15 can be inferred.     

Hyperfine fields in the 5sp series studied by the low temperature nuclear orientation of83Rb,83Sr,85Sr and85Ym in iron

The hyperfine fields B_hf (RbFe), B_hf (SrFe) and B_hf (YFe) have been determined by the low temperature nuclear orientation of dilute samples of⁸³Rb,^83,85Sr and⁸⁵Y^m in an iron lattice to be B_hf (RbFe)=+54 (10) kG, B_hf (SrFe)=(?)100 (30) kG and B_hf (YFe)=?226 (10) kG. These results are compared with recent calculations for these fields (1), (2).     

Core vibration of99Tc

The gyromagnetic ratios and the half-lifes of the 141 keV and 181 keV states of⁹⁹Tc have been remeasured. The results,g(141 keV)=+1.280(44);g(181 keV)=+1.446(20) andT _1/2(141 keV)=0.205(4)ns;T _1/2(181 keV)=3.44(3) ns are in only fair agreement with prior published data but more precise. They confirm that both states are members of the ground state core vibration multiplet. The hyperfine field of TcFe has been determined asB _hf ^10K (TcFe)=30.42 (30)T;B _hf ^290K (TcFe)=29.47 (29)T     

Gyromagnetic ratios of excited states in186W

The gyromagnetic ratios of the 4 ₁ ⁺ , 6 ₁ ⁺ , and 2 ₂ ⁺ states in¹⁸⁶W were measured relative to that of the 2 ₁ ⁺ level by means of the transient field implantation perturbedγ-ray angular distribution technique. The nuclei in the states of interest were Coulomb excited using a beam of 220-MeV⁶³Cu projectiles and recoiled swiftly through a thin, polarized Fe foil. The present measurements yielded ratiosg(4 ₁ ⁺ )/g(2 ₁ ⁺ )=1.04±0.07,g(6 ₁ ⁺ )/g(2 ₁ ⁺ )=1.03 ±0.20 andg(2 ₂ ⁺ )/g(2 ₁ ⁺ )=0.63±0.13. The sizable disparity between the measuredg-factors of the ground- and excited-band is examined within the context of the interacting boson approximation model.     

Gyromagnetic ratios of 4+ and 6+ states in156Gd and158Gd

The followingg-factors have been derived from time integral measurements of γ-γ angular correlations in the static magnetic hyperfine field of magnetized gadolinium metal probes:¹⁵⁶Gd:g(4 ₁ ⁺ )=+0.310(19)g(6 ₁ ⁺ )=+0.25(21)g(4 ₃ ⁺ , 1511 keV)=+0.809(27)¹⁵⁸Gd:g(4 ₁ ⁺ )=+0.409(15). The 5.35d ¹⁵⁶Tb sources were produced by the reaction¹⁵⁶Gd(d, 2n)¹⁵⁶Tb in our cyclotron. A carrier-free 150y ¹⁵⁸Tb source was obtained from ISOLDE/CERN. In comparison with the precisely knowng-factors of the 2 ₁ ⁺ states,g(2 ₁ ^su+ ,¹⁵⁶Gd) =+0.386(4) andg(2 ₁ ⁺ ,¹⁵⁸Gd)=0.381(4), we observe a large reduction for the¹⁵⁶Gd 4 ₁ ⁺ state whereasg increases slightly for¹⁵⁸Gd. The half-life of the 4 ₁ ⁺ state of¹⁵⁸Gd was remeasured as¹⁵⁸Gd:T _1/2(4 ₁ ⁺ )=148(2) ps. A measurement of the rotation in the 4 ₃ ⁺ state of¹⁵⁶Gd in external magnetic fields of various strengths up toB _ext=9.5 T did not confirm the anomalous dependence of the magnetic hyperfine field in gadolinium metal on the external field, which has been reported by Persson et al. [29].     

Measurement of theg-factor of the 21 + state of192Pt in an external magnetic field

Theg-factor of the 2₁ ⁺ state of¹⁹²Pt has been measured by the IPAC technique in an external magnetic field as:g(2₁ ⁺,¹⁹²Pt)=+0.287(17). An additional IPAC experiment with an¹⁹²IrFe sample was performed with the same level in order to investigate the hyperfine field. The result:ω _L τ(2₁ ⁺,¹⁹²PtFe)=0.1115(9) gives the hyperfine field:B _hf ^4.2k (PtFe)=126.8(71) T. The result of an LTNO experiment with the same level is compatible with the assumption that 100% of the¹⁹²Ir atoms were on unique sites.     

g-factors of rotational states in 176Hf, 177Hf,and 180Hf

g-factors of rotational states in ¹⁷⁶Hf and ¹⁸⁰Hf were measured with the twelve detector IPAC-apparatus of our laboratory [1]. The natural radioactivity 3.78 · 10¹⁰y ¹⁷⁶Lu and the 5.5 h isomer ^180mHf were used which populate the ground-state rotational bands of ¹⁷⁶Hf and ¹⁸⁰Hf. The integral rotations of γ-γ directional correlations in strong external magnetic fields and in static hyperfine fields of (Lu → Hf)Fe₂ and HfFe₂ were observed. The following results were obtained: The hyperfine field in (Lu → Hf)Fe₂ was calibrated by observing the integral rotation of the 9/2^? first excited state of ¹⁷⁷Hf populated in the decay of 6.7d ¹⁷⁷Lu. The g-factor of this state was redetermined in an external magnetic field as Finally the g-factor of the 2 ₁ ⁺ state of ¹⁷⁶Hf was derived from the measured g(2 ₁ ⁺ ) of ¹⁸⁰Hf by use of the precisely known ratio g(2 ₁ ⁺ , ¹⁷⁶Hf)/g(2₁ ⁺, ¹⁸⁰Hf) [2] as      

Dependence of exchange interactions on chemical bond angle in a structural series: Cubic perovskite-rhombic orthoferrite-rhombohedral hematite

Mössbauer spectroscopy is used to study the hyperfine magnetic fields at tin ¹¹⁹Sn ions introduced as an isomorphic impurity in the lattices of the orthoferrites RFeO₃. The large reduction in the field H _Sn ^hf (4.2 K) observed when R is changed from La to Lu correlates with the drop in the Néel point and indicates that the exchange interactions are decreasing over this series. A crystal chemical analysis of the structural series with the general formula ABO₃ shows that the ideal structure of cubic perovskite can be converted to a rhombohedral hematite-corundum structure by simple rotation of the [BO₆] octahedra if the B-O interionic distances remain unchanged. The rhombic distortions are associated with a reduction in the B-O-B bond angle from θ =180° in perovskite to ～132° in hematite. The rare earth orthoferrites RFeO₃ follow the same mechanism for structural transformations and the LaFeO₃-LuFeO₃ series occupies an intermediate position (157°>θ>142°) between the extreme members of the series mentioned above. A reduction in the bond angle leads to weakening of the Fe-O-Fe exchange interaction, which shows up as a drop in the Néel temperature and in the hyperfine magnetic field at the nucleus. An analysis of theoretical models shows that for a suitable choice of the exchange and transfer parameters, the angular variation in the parameters of the exchange interaction is described fairly well by the Moskvin theory over a rather wide range of angles θ. The contributions to the fields H _Sn ^hf and H _Fe ^hf from the t _2g -and e _g -orbitals of neighboring paramagnetic ions in the orthoferrites and orthochromites are examined.     

Electronic properties of charged fullerenes characterized by EPR and Vis-NIR spectroscopy

EPR and Vis-NIR absorption spectra have both been measured for clarification of contradictory statements about the para-and diamagnetic states of fullerenes. Thereby identification of one sharp EPR signal in solution at room temperature to C ₆₀ ^? (g=2.000±4.0001; ΔB=0.07±0.01 mT) could be made upon using different fullerene sources (TechnoCarbo, Hoechst) and methods of anion generation (chemically, electrochemically, and photochemically). This fact is also supported by the similar observation for a monosubstituted derivative (g=1.9999; ΔB=0.10 mT), in which a small broadening of this sharp signal is found originating from additional¹H hyperfine interactions. Furthermore theg-values of the radical anions of C₆₀ increase with charge (g(C ₆₀ ^? <g(C ₆₀ ^2? ) < <g(C ₆₀ ^3? ) <g(C ₆₀ ^5? )) indicating largest contributions from spin-orbit coupling for the monoanion. No diamagnetic states for the dianions of [60]- and [70]- fullerenes could be found so far but biradical species with largest zero field splittingsD=2.7 mT (C ₆₀ ^2? ), andD=3.1 mT (C ₇₀ ^2? ), respectively. The cation formation of C₆₀ (g=2.0023-2.0029; ΔB=0.15-0.20 mT) with antimony pentachloride was controlled by mass spectrometry. Stable cations were found only in methylenechloride. In other solvents like toluene addition reactions seem to occur.     

Gadolinium as a ferromagnetic host for IMPAC experiments

The properties of ferromagnetic Gd as a host for IMPAC measurements have been investigated. The transient and internal magnetic fields at Cd, Nd, Sm, Dy, Er, Yb and Hf nuclei recoil implanted into polarized Gd at 80 K have been studied by the IMPAC technique. All available experimental transient field data for Gd have been analysed in the framework of the Lindhard-Winther theory. Empirical values of the parametersv _p andC _ion C _atom have been deduced which give good agreement between experiments and theory. Internal magnetic fields at rare-earth nuclei in magnetized Gd at 80 K have been deduced. The results areH _h.f. (NdGd)=?1370±440 kG,H _h.f.(SmGd)=?1440±120 kG,H _h.f.(DyGd)=1410±400 kG,H _h.f.(ErGd)=2310±420 kG andH _h.f.(YbGd)=?216±32 kG. The signs of these fields are, except for Yb which is in a 2⁺ ionic state, consistent with a ferromagnetic coupling between the 4f spins of the implanted ion and the Gd host. The deduced internal field at Hf in Gd is ?440±90 kG. The observed time-dependent interactions for rare-earth nuclei in ferromagnetic Gd are consistent with the Abragam-Pound theory. For the Cd isotopes,g-factors of the first 2⁺ states were deduced from the experiments. The results areg(¹¹⁰Cd)=0.49±0.11,g(¹¹⁴Cd)=0.34±0.09 andg(¹¹⁶Cd)=0.41±0.11. The use of transient magnetic fields forg-factor measurements on high-spin rotational states is discussed.     

Nuclear structure and the hyperfine interaction of oriented152Eu,155Eu,and153Gd in gold

Nuclear orientation of^152,155Eu and¹⁵³Gd in Gold has been used to determine the nuclear magnetic moment of¹⁵⁵Eu, (μ¹⁵⁵Eu)=1.93±0.26 n.m., and several mixing ratios of γ and β^? transitions in the decays. The hyperfine field of dilute EuAu alloys was found to beH _hf=134±10 kOe and for GdAu, |μH| was found to be in the range 0 to 1.0×10⁵ Oe·n.m.     

g-factors of the ground state rotational band of158Dy

Theg-factors of the four lowest states of the ground state rotational band of¹⁵⁸Dy have been determined asg(2 ₁ ⁺ )=+0.362(23),g(4 ₁ ^su+ )=+0.340(20),g(6 ₁ ^su+ )=+0.207(36) andg(8 ₁ ^su+ )=+0.21(11). Theg-factors of the 2⁺ and 4⁺ states were measured by the IPAC method with radioactive samples of 2.4 h¹⁵⁸Er in external magnetic fields. To investigate the higher states, for the first time an on-line γ—γ IPAC experiment was performed with the reaction¹⁵⁶Gd(α, 2n)¹⁵⁸Dy by use of the static hyperfine field of DyGd.     

Phenomenology of composite colored weak bosons

In composite models of quarks, leptons and weak bosons whereW-constituents are colored objects, color octet partners ofW ^± andZ ⁰ are predicted. We study in detail the phenomenology of these particles. Independent of the specific model one expects a color octet isotriplet of vector bosons (W ₈ ^± ,Z ₈ ⁰ ) with mass in the range of 100–200 GeV, and a color octet isosinglet vector bosonV ₈ ⁰ with substantially larger mass, due to mixing with the gluon. Moreover, relatively light color octet excitations of the leptons appear, while the existence of “color exotic” partners of the quarks is model dependent. These particles decay mainly into a lepton (quark) and a gluon. We construct the couplings ofW ₈ ^± ,Z ₈ ⁰ andV ₈ ⁰ to ordinary and “color exotic” fermions. The signals of color octet weak bosons in low energy weak reactions are explored in detail. The production cross section ofW ₈ ^± (Z ₈ ⁰ ) in hadron-hadron collisions is calculated for \(0.54TeV \leqq \sqrt s \leqq 20TeV\) . Various decay modes of colored weak bosons are studied. The most prominent decay signatures ofW ₈ ^± andZ ₈ ⁰ are events of the type (l ^+-: charged lepton;j: hadronic jet; : missing transverse momentum). The present CERN \(p\bar p\) collider data on such events are discussed in the light ofW ₈ ^± andZ ₈ ⁰ decays. If colored weak bosons are not found with a mass less than ～250 GeV composite model building will be strongly restricted.     

EPR studies on the di-nitrogen centers with nonequivalent atoms in a reddish-brown plastically deformed diamond

Two new di-nitrogen centers, which were labeled M2 and M3, were found together with known W7 and N4 centers in an unusual reddish-brown natural diamond. The following magnetic hyperfine interaction parameters (expressed in MHz) were determined for the two nitrogen atoms:A ₁ ⁽¹⁾ =117.95(5),A ₁ ⁽²⁾ =A ₁ ⁽³⁾ =84.48(5),A ₂ ⁽¹⁾ =7.1(1),A ₂ ⁽²⁾ =A ₂ ⁽³⁾ =6.6(1) for M2 andA ₁ ⁽¹⁾ =121.55(5),A ₁ ⁽²⁾ =A ₁ ⁽³⁾ =85.90(5),A ₂ ⁽¹⁾ =6.0(1),A ₂ ⁽²⁾ =5.4(1),A ₂ ⁽³⁾ =5.1(1) for M3. Hyperfine interaction tensors for the nitrogen atom N₁ with a larger interaction have axial symmetry about the <111> direction, but those for the other nitrogen atom, N₂, appear to be small, almost isotropic. Probable models of the M2 and M3 centers are suggested and discussed.     

Winkelkorrelationsmessungen an88Sr

The γγ ande _? ^KL γ directional correlations have been measured for the (898–1836) keV cascade in⁸⁸Sr following the decay of⁸⁸Y. The observed correlation coefficients areA ₂₂(γγ)=?0.0784±0.0042 andA ₂₂(e _? ^KL γ)=0.0102±0.0046. The γγ experiment is consistent with a mixing ratio δ(γ)=0.009±0.005 for the 898 keV transition. Using the result of thee _? ^KL γ experiment the most probable value of the ratio of the penetration matrix element to the normal γ-ray matrix element was determined to be η=0.03±0.30 showing a normal conversion process. This penetration parameter agrees with a hindrance factorH _W(E1)=2.1 · 10^?3 for theE1 transition.     

Pulse ENDOR studies on the radical pair P 700 +· A 1 ·− and the photoaccumulated quinone acceptor A 1 ·− of photosystem I

The secondary acceptor A₁ of the electron transport chain(s) of photosystem (PS) I is a phylloquinone (vitamin K₁, VK₁). Pulse electron paramagnetic resonance and electron nuclear double resonance (ENDOR) experiments at X-band frequencies were performed on the photoaccumulated acceptor radical A ₁ ^·? and the radical pair state P ₇₀₀ ^·+ A ₁ ^·? in PS I ofThermosynechococcus elongatus. The data obtained were compared with data from the respective radical anion of VK₁ in organic solvents. The unusualg tensor magnitude of A ₁ ^·? is explained by the hydrophobic binding pocket of this radical. The hyperfine couplings and the spin (and charge) density distribution is very different for A ₁ ^.? in PS I and VK ₁ ^·? in frozen alcoholic solution. This is attributed to a rather strong one-sided hydrogen bond to A ₁ ^·? . The presence of a hydrogen bond to A ₁ ^·? has only a minor effect ong. The hyperfine coupling constants of A ₁ ^·? determined from the radical pair spectra deviate only slightly from those derived from photoaccumulated A ₁ ^·? in PS I treated with dithionite at high pH. ENDOR resonances of the proton in a H bond were detected and an estimate of the strength and geometry of this bond to A ₁ ^·? was obtained. The significance of the hydrogen bond and other (hydrophobic) interactions of A₁ with the surrounding are briefly discussed.     

Pion photoproduction on197Au to ground and isomeric states in197Hg

The lifetime of the 331.3 keV 0 ₂ ⁺ state in¹⁰⁰Zr has been measured at the gas-filled recoil separator for fission products JOSEF. By observing the delayed coincidences between theβ-particles populating the level and theE0 conversion electrons from its decay into the ground state, a half-life of 3.37±0.30 ns has been obtained. From the measured lifetime and the relative intensities of the 0 ₂ ⁺ →0 ₁ ⁺ and 0 ₂ ⁺ →2 ₁ ⁺ transitions, values of 0.493±0.015 for theE0 strength parameterρ, and of 16 single particle units forB(E2,2 ₁ ⁺ → 0 ₂ ⁺ ) have been deduced. The enhanced nature of theE0 transitions suggests mixing of the 0 ₁ ⁺ and 0 ₂ ⁺ states which may be estimated by comparing the experimentalB(E2) values for the 2 ₁ ⁺ →0 ₁ ⁺ and 2 ₁ ⁺ →0 ₂ ⁺ transitions with the predictions of the asymmetric VMI model.     

Untersuchung der vier ersten angeregten Zustände des6Li-Kernes durch Elektronenstreuung

Inelastic electron scattering cross sections were measured for energies below 60 MeV and momentum transfersq between 0.2 and 0.6 fm^?1. Ground state radiative widths Γ _γ ⁰ and transition radiiR _tr were deduced. 2.18 MeV: Γ _γ ⁰ (E2)=(4.40±0.34) · 10^?4 eV,R _tr=(4.28±0.39)fm; 3.56MeV: Γ _γ ⁰ (M1)=(8.31±0.36)eV,R _tr=(2.90±0.10)fm; 4.27 MeV: Γ _γ ⁰ (E2)=(5.4±2.8) · 10^?3 eV,R _tr=(3.4±1.2) fm. The excitation of the 5.37 MeV level shows a transverse angular dependence.