Hyperfine structure of the atomic osmium spectrum: Superposition of configurations and the effect of nucleus volume

The contributions of the superposition of configurations ns ²5d ⁷6s+ns5d ⁷6sn′s+ns5d ⁷6s ² (n=1–5, n′=7–10) to the parameters of the hyperfine structure a _5d ⁰¹ , a _5d ¹² , a _5d ¹⁰ , a _6s ¹⁰ in the spectrum of the osmium atom Os I are calculated. Nonzero contributions are shown to be made only to the parameters a _5d ¹⁰ and a _6s ¹⁰ . This fact justifies the inclusion of the parameter a _5d ¹⁰ in the semiempirical analysis of experimental values of magnetic dipole constants of the hyperfine structure of the 5d ⁷ s configuration in the spectrum of the osmium atom. The effect of nucleus volume on the parameters of the hyperfine structure in the spectra of osmium isotopes ¹⁸⁷Os and ¹⁸⁹Os is estimated.     

Bestimmung der Kernquadrupolmomente der beiden stabilen Europiumisotope aus dem Eu II-Spektrum

The hyperfine structure of the transitions 4f ⁷ 6p ⁹ P _3,4,5?4f ⁷ 6s ⁹ S ₄,⁷ S ₃ in the spark spectrum of europium was investigated by a digital recording double-Fabry-Perot-spectrometer. Enriched samples of¹⁵¹Eu and¹⁵³Eu were used in hollow cathode light sources cooled in liquid air. As the hyperfine splitting of the⁹ P levels was not completely resolved the patterns were analysed by a computer. TheA- andB-values of the⁹ P levels were determined for both isotopes. Together with the experimentalA-values of the⁷ P levels theseA-values were used to check the eigenfunctions ofBordarier, Judd, andKlapisch, which have been calculated for intermediate coupling. Good agreement between observed and calculatedA-values was reached only if the spherical-symmetric part of the magnetic hyperfine interaction operator of the 6p-electron was used as a free parameter. In this way the configuration interaction between 4f ⁷ 6p and 4f ⁶ 6s 6d can be taken into account. Fortunately this mixing does not affect the quadrupole interaction. Therefore the quadrupole moments were derived from the measuredB-values using the unperturbed eigenfunctions. The resultsQ(¹⁵¹Eu)=(1.12 ±0.07) · 10^?24 cm² andQ(¹⁵³Eu)=(2.85 ± 0.18) · 10^?24cm² are in complete agreement with the values obtained byMüller, Steudel, andWalther in the 4f⁷ 6s 6p levels of the arc spectrum of europium. The values found for the hyperfine anomaly agree very well with the values derived from levels in Eu I and Eu III.     

The determination by an independent method ofP k electron capture probabilities in133Ba and139Ce decays gamma decay of133Ba

The electron capture decays of¹³³Ba (10.4 y) and¹³⁹Ce (140 d) were investigated with high resolution Ge(Li) detectors. By x-ray — γ-ray coincidences values of the quantityP _k ω _k ? _k for various transitions in the decay of¹³³Ba and¹³⁹Ce are obtained. The factor ω _k ? _k was measured independently by means ofK-conversion electron-K x-ray coincidences and was then used to determineP _k , theK-capture probability. The independent measurement of the product ω _k ? _k , together with recent accurate values of ω _k , provides a new method for the accurate calibration of semiconductor x-ray detectors. In the decay of¹³⁹Ce, a value ofP _k =0.78±0.03 is found (where the error represents twice the standard deviation) from whichQ _ec =326 _?30 ⁺⁷⁰ keV to the¹³⁹La ground-state is found by use of theory. In¹³³Ba decay, values are found ofP _k 1=0.72±0.04 for theEC transition to the 437 keV level in¹³³Cs,P _k 2=0.80±0.07 to the 384 keV level, and from an independent measurement, the ratioP _k 1/P _k 2=0.87±0.07. From these results the ground-state value ofQ _ec =522 _?10 ⁺²⁰ keV is derived from theory for¹³³Ba decay. The gamma spectrum of¹³³Ba also was remeasured. From the present gamma intensities and previous conversion electron intensities, new values forK-shell conversion coefficients are obtained. Previously reported γ-rays at 35 and 391 keV are not confirmed.     

Electron-lattice interaction in the absorption spectra of thallium doped alkali halides

The electron-lattice interaction of NaCl:Tl⁺, KCl:Tl⁺, KBr:Tl⁺, and KI:Tl⁺ is discussed using the moments of the absorption bands. The discussion is based on a theory ofToyozawa andInoue andHonma. Consistency of the data is found for the absorption measurements. An analysis of the band shift under applied stress shows for theA-band in KCl and KBr and for theA- andB-band in KI that the electronlattice coupling constants derived from these data assuming next neighbour interaction differ considerably from those derived from the second moments of the bands.     

Isomerenverhältnis für die Reaktion51V(α,3n)52g,mMn

The isomeric cross-section ratio has been measured for the reaction⁵¹V(α, 3n)^{52 g,m}Mn between 32 and 51 MeV. The experimental results are compared with statistical-model calculations. In these calculations two models for the gamma cascade have been used: the simple dipole cascade model ofVandenbosch andHuizenga, and alternatively the model ofPönitz which includes quadrupole transitions. With the latter model agreement between theory and experiment could be achieved.     

1H MAS, 13C CP/MAS, and 2H NMR spectra studies of piperidinium {\emph{p}}-chlorobenzoate

Anomalous H/D isotope effects were detected in the ¹H MAS NMR spectra of piperidinium p-chlorobenzoate (C₅H₁₀NH $_{2}{^{+}}\cdot $ ClC₆H₄COO^???) upon deuterium substitution of hydrogen atoms which form two kinds of N-H?O H-bonds in the crystal; in contrast to these spectra, only slight chemical shifts were recorded in ¹³C CP/MAS NMR spectra. ²H NMR spectrum of the deuterated sample show quadrupole coupling constants of 148 and 108 kHz, and reveal that there are a few motions contributing to the electric-field modulation of the ²H nucleus. The ¹H MAS NMR spectra of piperidinium p-chlrobenzoate-d ₁₆ (C₅D₁₀ND $_{2}{^{+}}\cdot $ ClC₆D₄COO^???) and -d ₁₄ (C₅D₁₀NH $_{2}{^{+}}\cdot $ ClC₆D₄COO^???) revealed that the change in the envelope is caused by chemical shifts of each signal upon deuteration. Calculations based on the density-functional-theory showed that the N-H distance along the crystallographic a-axis mainly contributes to the anomalous isotope effects on ¹H MAS NMR envelopes.     

Magnetic hyperfine field at Cr site in AgCrO2 given by Perturbed angular correlations

This work presents an electric field gradient and magnetic hyperfine field study, in the AgCrO₂ multiferroic with triangular spin lattice. The temperature dependence of the electric field gradient (efg) and magnetic hyperfine field (mhf) at Cr site was studied at isolde via perturbed angular correlation measurements with the ¹¹¹In probe, at room temperature and below the Néel temperature (T?≤?21 K) down to 12 K. The results show the presence of two distinct local environments. One axial symmetric efg with a very low mhf, and a non axially symmetric efg with a much higher one. The temperature dependences of mhf magnitude and of the angle between the mhf and the principle component of the efg are investigated.     

Determination of theg j -factor in the72 P 3/2-state of133Cs by optical double resonance in a strong magnetic field

The hfs in the 7² P _3/2-state of¹³³Cs has been investigated by optical double resonance in a strong magnetic field. From the positions of the magnetic dipole transitions Δm _j =± 1, Δm _i =0 the magnetic hfs coupling con slanta (7² P _3/2)=16.591(25) MHz and theg _j -factorg _j (7² P _3/2)=1.33410(15) could be derived. Contrarily to recent measurements,g _j agrees well with the value calculated from the Lande formula.     

Hyperfine anomaly in the spectrum of the osmium atom. effect of the spatial distribution of nuclear charge

Contributions of the superposition of configurations ns ²5d ⁸+ns5d ⁸ n′s (n=1–5, n′=6–10) and ns ²5d ⁶+ns5d ⁶ n′s (n=1–6, n′=7–10) to parameters a _5d ⁰¹ , a _5d ¹² , and a _5d ¹⁰ of the hyperfine structure in the spectrum of the osmium atom OsI are calculated. It is shown that the nonzero contribution is made only to a _5d ¹⁰ . The effect of the spatial distribution of nuclear charge on the parameters of the hyperfine structure in the spectra of ¹⁸⁷Os and ¹⁸⁹Os isotopes and on the hyperfine anomaly for the 5d ⁷6s levels in the spectrum of these isotopes is estimated.     

The nature of [S III]λλ9096, 9532 emitters at z = 1.34 and 1.23

A study of [S iii]λλ9096, 9532 emitters at z = 1.34 and 1.23 is presented using our deep narrow-band H ₂ S 1 (centered at 2.13 μm) imaging survey of the Extended Chandra Deep Field South (ECDFS). We combine our data with multi-wavelength data of ECDFS to build up spectral energy distributions (SEDs) from the U to the K _s-band for emitter candidates selected with strong excess in H ₂ S 1 ? K _s and derive photometric redshifts, line luminosities, stellar masses and extinction. A sample of 14 [S iii] emitters are identified with H ₂ S 1 < 22.8 and K _s < 24.8 (AB) over 381 arcmin² area, having [S iii] line luminosity L _[SIII] =～ 1041.5–42.6 erg s^?1. None of the [S iii] emitters is found to have X-ray counterpart in the deepest Chandra 4Ms observation, suggesting that they are unlikely powered by AGNs. The HST/ACS F606W and HST/WFC3 F160W images show their rest-frame UV and optical morphologies. About half of the [S iii] emitters are mergers and at least one third are disk-type galaxies. Nearly all [S iii] emitters exhibit a prominent Balmer break in their SEDs, indicating the presence of a significant post-starburst component. Taken together, our results imply that both shock heating in post-starburst and photoionization caused by young massive stars are likely to excite strong [S iii] emission lines. We conclude that the [S iii] emitters in our sample are dominated by star-forming galaxies (SFGs) with stellar mass 8.7 < log(M/M _⊙) < 9.9.     

Determination of the CP violating phase γ by a sum over common decay modes toB s and\bar B_s

To help the difficult determination of the angle γ of the unitarity triangle, Aleksan, Dunietz and Kayser have proposed the modes of the typeK ^? D _s ⁺ , common toB _s and $\bar B_s $ . We point out that it is possible to gain in statistics by a sum over all modes with ground state mesons in the final state, i.e.K ^? D _s ⁺ ,K ^*? D _s ⁺ ,K ^? D _s ^*+ ,K ^* D _s ^* . The delicate point is the relative phase of these different contributions to the dilution factorD of the time dependent asymmetry. Each contribution toD is proportional to a product $F^{cb} F^{ub} f_{D_s } f_K $ whereF denotes form factors andf decay constants. Within a definite phase convention (i.e. for example the one defined by the heavy quark symmetry in the limit of heavy quarks), lattice calculations do not show any change in sign when extrapolating to light quarks the form factors and decay constants. Then, we can show that all modes contribute constructively to the dilution factor, except theP-waveK ^* D _s ^*+ , which is small. Quark model arguments based on wave function overlaps also confirm this stability in sign. By summing over all these models we find a gain of a factor 6 in statistics relatively toK ^? D _s ⁺ . The dilution factor for the sumD _tot is remarkably stable for theoretical schemes that are not in very strong conflict with data onB→ψK(K ^*) or extrapolated from semileptonic charm form factors, givingD _tot≥0.6, always close toD(K ^? D _s ⁺ ).     

Rumpfpolarisation des 4d 9 5s 22 D-Zustandes von Ag I

The hyperfine structure of the transition Ag I, 4d ⁹ 5s ²² D _3/2-4d ¹⁰5p ² P _1/2, λ=19,372 Å has been investigated by means of a photoelectrically recording Fabry-Pérot interferometer using separated isotopes. Evaluating the hfs-pattern by a digital analysis the following values for the magnetic dipole interaction constants have been obtained: $$A_{3/2}^{(109)} (d^9 5s^2 ) = - 12.11(6)mK; A_{1/2}^{(109)} (d^{10} 5p) = - 6.72(10)mK.$$ Using the knownA-factor of the other level of the configurationd ⁹ s ² and the values of the Ms anomalies of the levelsd ⁹ s ²² D _5/2 andd ¹⁰ s ² S _1/2 together with our result, the influence of the core polarization on theA-factors of the configurationd ⁹ s ² is discussed. Assuming that the used relativistic correction factors are correct, the influence of the core polarization cannot be due only to the unpaireds-electrons of the core, but must be described by the three-parameter hfs-Hamiltonian given by Harvey. Consequences for calculating the quadrupole moments from hfs data are mentioned.     

Laser-rf double-resonance hyperfine structure measurements of the metastable 3d 4s 1 D 2 state of43Ca

The hyperfine structure of the (3(d 4s)¹ D ₂metastable state of⁴³Ca has been measured using theABMR-LIRF method (atomic beam magnetic resonance, detected by laser induced resonance fluorescence). The measurements yielded for the magnetic dipole and electric quadrupole constantsA=?17.650(2) MHz andB=?4.642(12) MHz, respectively. From the measuredB factor the spectroscopic electric quadrupole moment (uncorrected for shielding effects) has been calculated to beQ(⁴³Ca)=?0.062(12) barn. In addition, isotope shifts in the lines (3d 4s)¹ D ₂(3d 4p)¹ F ₃ ⁰ and (3d 4s)¹ D ₂(4s 5p)¹ p ₁ ⁰ for the stable calcium isotopes have been obtained by high resolution laser spectroscopy.     

MC-Simulation of the Transverse Double Spin Asymmetry for RHIC

We give a leading order estimate of the hadronic transverse double spin asymmetry in the Drell-Yan process at RHIC using Sphinx tt,anew polarized version ofthe Monte Carlo Pythia 5.6. We also calculate the statistical error to next to leading order with Pythia 5.7. Both quantities are of the same order if one assumes that the transversity weighted parton distributions equal the helicity weighted ones at some low perturbative scale Q ₀ ² .     

Zur Definition von Relaxationszeit und Korrelationszeit in magnetischen Resonanzexperimenten

Kubo's general definition of relaxation and correlation times in magnetic spin systems, applicable to non-exponential processes, is evaluated for several non-exponential relaxation and correlation functions known from nmr experiments. The new definition eliminates the arbitrary factors usually encountered in the time constants of nonexponential irreversible processes. For the correlation time of the well-known “translational two-spin model”, three different values are used in the literature; our definition leads toτ _t =1/5 d²/D (d=distance of closest approach between the two spins,D=diffusion coefficient of the related molecules), which is an intermediate value to the conventional abbreviationsτ _t =1/5d ²/D andτ _t =1/6d ²/D.     

Das kritische Magnetfeld Hc∥ von dünnen supraleitenden Filmen

Thin superconducting films in a surface parallel magnetic field are considered, assuming that the order parameter is constant in space. Without any further restrictions on the film thickness,a, an equation for the critical field is derived. In the clean limit, this equation is valid only in the vicinity of T_c, but in the dirty limit it is valid for all temperatures. Our results, for specular reflection, are identical with those obtained byThompson andBaratoff. But for not too thin films we find essential differences between the results for specular and for diffus reflection. For very thin films (a?v/2πT _c), considered in detail byde Gennes andTinkham and byShapoval, our results are in agreement with those obtained byShapoval. In the opposit limit (a?v/2π T _c), the most essential corrections to the Ginzburg-Landau result obtained byLüders are rederived.     

Infrared and raman studies of some naphthols

Vibrational spectra of α-naphthol,β-naphthol andβ-naphthol-OD have been recorded in the solid and solution phases. A number of bands, common to all the three compounds, have been correlated with earlier naphthalene assignments and an attempt has been made to identify certain frequencies with vibrational modes that are centred in the substituentsOH andOD. TheC _s symmetry is assumed for each molecule.     

Spezifischer Energieverlust von schweren Ionen in Aluminium,Silber und Gold

Using a Cf²⁵²-fission source and two semiconductor detectors in 180°-position the specific energy loss of heavy ions in A1-, Ag-, and Au-foils was measured. The agreement with the results ofMoak andBrown, and ofKahn andForgue is better than 15%. The energy loss predicted byLindhard is 10–25% lower than the measured values. A better agreement — especially for absorbers with low atomic numberZ — is achieved by a semiempirical formula proposed byMünzel.     

An analysis of Cabibbo-favored two-body decays of charmed mesons withη orη′ in the final state

We have carried out a study of Cabbibbo-favored two-body decays ofD ⁰ andD _s ⁺ involving η and η′ in the final state, $D^0 \to (\eta ,\eta ')\bar K^0 , D^0 \to (\eta ,\eta ')\bar K*^0 $ andD _s ⁺ →(η,η′)π ⁺,D _s ⁺ →(η,η′)ρ ⁺. We have introduced an annihilation term wherever admissible, and investigated its size if it were to bridge the gap between theory and experiment in each case. We have also related the semileptonic rates forD _s ⁺ →(η,η′)e ⁺ v to those of the hadronic rates forD _s ⁺ →(η,η′)π ⁺ and unveiled a puzzle. We offer a possible solution.     

Investigation of the two quasiparticle rotational band at 1172 keV in172Yb and determination of theg R -factor of the 3+ 3 band head

Investigations of the rotational band based on the 3⁺ 3 two quasiparticle state in¹⁷²Yb have shown that some of its properties can be well described by the collective model of Bohr and Mottelson. As a result of these investigations we have derived the ratio (g _k – g _R )/Q _o =? (0.0136 ± 0.0007). The magneticg-factor of the band head has also been determined by an integral angular correlation measurement perturbed by an external magnetic field. As a result we foundg=0.201 ± 0.030. Using this value and our result of (g _k – g _R )/Q _o we have calculated theg _R -factor of the two quasiparticle state asg _R =0.283 ± 0.018 which is out of the errors smaller than theg _R -factor of the ground state rotational band. An analysis of our angular correlation experiments gave for the mixing parameter δ of theK-forbidden 1094 keV intraband transition: δ=? (3.63 _?0.06 ^+0.14 ) in agreement with the results of other authors.