Messungen zu den Vibrations- und Zweiquasiteilchenzuständen in172Yb

The Coster-Kronig and Auger spectrum of theL ₁ shell of gaseous argon has been investigated with an electrostatical spectrometer. The ionization in theL ₁ shell of argon was caused by electron impact. Absolute energies and relative intensities of all the Coster-Kronig and Auger transitions have been determined. The relative intensities of transitions within the groupsL ₁ L _{2, 3} M ₁,L ₁ L _{2, 3} M _{2, 3} andL ₁ MM agree fairly well with the theoretical values, calculated byRubenstein for extreme Russel-Saunders coupling, if intermediate coupling theory is used properly. Via the widthγ(L ₁) of theL ₁ level of argon, found in this experiment to be (1.84±0.2) eV, the following absolute group transition probabilities were determined (in units of 10¹⁴ sec^?1):W(L₁ L _{2, 3} M ₁)=(5.5±1.0),W(L₁ L _{2, 3} M _{2, 3})=(20.8±2.8),W(L₁ MM)=(1.44±0.16). The theoretical values are 21.0, 20.4 and 1.27. The possible reason for the large discrepancy between the experimental and theoretical value ofW(L₁ L _{2, 3} M ₁) is the use of the incorrect value of 287 eV for the binding energyE(L₁) byRubenstein. From the energies of theL ₁ MM transitions this value has been determined to beE(L₁)=(326.5±0.5) eV. This is the first direct measurement ofE(L₁) of argon.     

TheL 2 MM andL 3 MM spectra of argon

Expressions for the line intensities in theL ₂ MM andL ₃ MM spectra of elements of lowZ are given. For such elements the inner shell vacancy is given inj-j notation whereas the final double vacancy in the outer shell is given in Russell-Saunders coupling. Line intensities in theL ₂ MM andL ₃ MM spectra of argon are calculated using the transition amplitudes computed byRubenstein. No configuration interaction is considered.     

DasKLL- Auger-Spektrum von Chlor

TheKLL Auger spectrum of chlorine in CCl₄ has been investigated with an electrostatic energy analyzer. The ionization in theK shell of chlorine was caused by electron impact. Absolute energies and relative intensities of transitionsKL ₁ L ₁(¹ S,KL ₁ L _2,3(¹ P),KL ₁ L _2,3(³ P) andKL _2,3 L _2,3(¹ D) have been determined. Via the width of theK level of chlorine also experimental values of absolute transition probabilities have been calculated. While the relative intensities deviate strongly from theoretical values, the absolute transition probabilities agree better with theoretical values, especially with those calculated byRubenstein. — In an appendix the natural line widths of theKLL components of argon have been calculated theoretically.     

Relative internal conversion electron intensities of the 113 keV transition in177Hf

The intensities of the internal conversion lines of the 113 keVM1 +E2 transition in¹⁷⁷Hf have been measured. From comparison with theoretical conversion coefficients the transition has been found to be (95.2 ± 0.5)%E2 corresponding to ¦δ¦=4.5 ± 0.3. The theoreticalL _I andM _I conversion coefficients used in the comparison have been increased by 5% according to the result that for pureE2 transitions in the deformed region theL _I/L _II,L _I/L _III,M _I/M _II, andM _I/M _III theoretical ratios are too low (～5%). Moreover, the present result indicates that theL _II/L _III andM _II/M _III ratios obtained from the tabulations by Hager and Seltzer and from the computer program by Pauli are too high (1–2%).     

An experimental investigation of the onset of theL 2-L 3 M 4 andL 2-L 3 M 5 Coster-Kronig transitions forZ>90

L-M coincidence measurements were made on x rays from the radioactive decays of ₉₆ ²⁴⁴ Cm, ₉₄ ²³⁸ Pu, and ₉₂ ²³² U. The observation ofM x rays in coincidence with theL ₃ N _{4, 5} transition indicates that the onset of theL ₂-L ₃ M ₅ Coster-Kronig transition takes place atZ=91 or 92. The measured ratio of theM x-ray counting rates, coincident with theL ₃ N _{4, 5} andL ₂ M ₄ transitions, establishes that both theL ₂-L ₃ M ₄ and theL ₂-L ₃ M ₅ transitions are energetically possible forZ≧94, but the results do not rule out the possibility that these transitions begin as low asZ=92. The measurement ofL-M x-ray coincidences, together with relative Coster-Kronig electron intensities from theory or experiment, provides a new way to measure the totalL ₂-L ₃ Coster-Kronig transition probability,f ₂₃, at highZ for radioactive sources where the primary vacancies are created primarily in theL ₂ andL ₃ subshells. The present result atZ=94 indicates that the theoretical calculations of McGuire of the relative partial Coster-Kronig transition rates forL ₂-L ₃ M _4,5 are accurate to within 10 percent.     

Internal conversion studies of the 114 keV transition in175Lu

Measurements of the conversion line intensities, the directional correlation and the conversion probability for the 114 keVM1+E2 transition in¹⁷⁵Lu are reported. TheE2 admixture, determined from relativeK andL intensities, is (19.2±0.2)%. The theoreticalL _I internal conversion coefficient is found to be about 8% too low relative theK,L _II andL _III conversion coefficients.     

Korrelationseffekte in den Auger-Spektren von Edelgasen

The possibility of studying correlation effects through Auger electron spectrometry has been shown recently by Krause, Carlson and Moddeman in the case of theK Auger spectrum of neon. As a further example we have measured theM _4,5 Auger spectrum of krypton with high resolution. Correlation effects have been found via the strong deviations of relative intensities of Auger diagram lines (e.g.M _4,5 N ₁ N _2,3(¹ p ₁)) from theoretical values and via the occurence of double Auger transitions, where one electron is emitted and another is excited. A critical examination of high resolution Auger spectra of noble gases, which has been measured so far, has shown that several non diagram lines can be assigned to double Auger transitions of the above kind.     

High resolution studies of transitions in the decay chain146Gd to146Eu to146Sm

Transitions in¹⁴⁶Eu and¹⁴⁶Sm were studied using a double-focussing beta-ray spectrometer and a Ge(Li) detector. Internal conversion and gamma-ray intensities were determined. The internal conversion spectrum of the three 155, 115 and 116 keV cascading transitions in¹⁴⁶Eu was studied for all subshells.K-,L- andM-subshell ratios were determined andE2/M1 mixing ratios were deduced for these three transitions. Intensities from theN- andO+P-shells were determined and compared to theoretical calculations. All internal conversion intensities were found to be in agreement with theoretical data for pureM1 character with smallE2 admixtures for all the three transitions. Selected parts of the internal conversion spectrum of the transitions in¹⁴⁶Sm were restudied at 0.06% momentum resolution. This study was mainly concentrated on four transition doublets feeding and deexciting the close lying levels at 1,380 and 1,381 keV. A new transition with 702.20 keV energy was detected in the 702–703 keV transition group. Internal conversion coefficients were deduced using reported gamma-ray intensities. Multipole characters of the transitions were deduced and used as a basis for a discussion of the spins and parities of the lower lying excited states of¹⁴⁶Sm.     

On the octupole excitation in236U

Measurements of theK,L _I,L _II andM _I conversion lines of the 687.7 keV transition in²³⁶U are evaluated within the electron penetration formalism. The spin-parity assignment of the octupole bandhead is found to be 1^? in accordance with reaction data, and an assignment of 2^? to the 687.7 keV state is ruled out. The penetration matrix element ∥η∥ has the value of 13.5 for theK-shell and increases slightly for higher main shells. An estimate of the anomalous amplitudes is compared with values reported for transitions in the odd even actinide nuclei. Furthermore electron conversion data for the 1^?→2⁺ and 1^?→4⁺ transitions are given. Radioactivity²³⁶U from²³⁵U(n,e ^?); measured: conversion electron decay; deduced: conversion coefficients fromK, L andM shells; evaluated: dynamic matrix elements.     

Anomalous Auger-electron spectra of metallic calcium

A1Kα-excited L_{2, 3}MM and L_{2, 3}MV Auger-electron spectra of Ca have been measured in ultrahigh vacuum from a metallic sample evaporated onto an Ag substrate. An interpretation of the spectra is made by applying a line-fitting procedure. The lineshape and the solid-state—free-atom kinetic-energy shift are also studied. The extrinsic loss structure in the L_{2, 3}MM Auger-electron emission is found to be similar to that in 2p photoelectron emission. Spin—density-functional (SDF) calculations for the singularity index describing the intrinsic lineshape give a value of ～ 0.35 for both processes. Thus the experimental 2p_3/2 photoelectron line broadened from 1.2 to ～ 5 eV FWHM has been used as a standard line in the line fitting of the L_{2, 3}MM transitions. The term splitting of the L_{2, 3}M_{2, 3}M_{2, 3} transition is larger than in the corresponding free-atom spectrum. This result is also supported by the SDF calculations. The L_{2, 3}M_{2, 3}V spectrum is anomalously sharp, probably both because of the structure of the local density of states at the site of the core-ionized atom and because of differences in the transition probabilities into the different parts of the band. The experimental solid-state shift is 20.3 eV for the L_{2, 3}M_2,3M_{2, 3}:¹D transition, and the binding-energy shifts are 8.3 and 6.1 eV for the 2p and 3p levels, respectively. The SDF shifts for the above transitions are 19.9 (configurational average), 9.4 and 8.0 eV, consecutively, in agreement with the experimental values. The calculations also show a localized d-type (atomic-like) structure for the screening of the initial- and final-state core hole (s). This is the origin of the large values of both the singularity index and the solid-state shift.     

High resolution lmm auger electron spectra of some first row transition elements

Auger spectra have been recorded from elements of the first transition series using a hemispherical analyser. Highly resolved LMM spectra were obtained showing for the first time the composite nature of these peaks for many of the elements studied. The recorded spectra show a general similarity for the elements Sc → Zn but interesting differences emerge. At the beginning of the transition period the L₃ based transitions have the relative intensities L₃ M_2,3, M_2,3 > L₃ M_2,3, M_4,5<> L₃ M_4,5, M_4,5 whereas towards the end of the series the order L₃ M_4,5, M_4,5 > L₃ M_2,3, M_4,5<> L₃ M_2,3, M_2,3 is observed. Pronounced chemical shifts have been observed upon oxidation. The spectra are interpreted in terms of an L -S coupling scheme and the fine structure discussed in terms of effects produced by multiplet splitting.     

Internal conversion coefficients in the Hartree-Fock atomic model. Calculations and experiments for199Hg

The internal conversion coefficients were calculated for the transitions in¹⁹⁹Hg using both Hartree-Fock and Hartree-Fock-Slater atomic models. The relative conversion line intensities were measured with the magnetic spectrometers in Prague and Heidelberg. The multipolarities were determined to be:M1+(0.20±0.03)%E2, pure E2 and M 1+ (13.4 ±0.4)%E2 for the 50, 158 and 208 keV transitions, respectively. Allowing for the nuclear structure effect in M1 component we obtained: M1+(0.15±0.03) %E2,λ = 2.4±1.0 for the 50 keV and M1+ (10.9±0.7)% E2, λ=3.8±0.5 for the 208 keV transitions. Very good agreement was found between theory and experiment for the atomic subshells,K, L_1?3,M _1?5,N, andO + P.     

Many-body effects in l2mm auger electron spectra of Ge(CH3)4 excited by Mg Kα X-rays

The Ge:L₂MM Auger electron spectra excited by Mg Kα X-rays from Ge(CH₃)₄ free molecules have been compared with the corresponding spectra excited by Al Kα X-rays. The Al Kα excited spectra have characteristic features of the diagram Auger transitions, because the excitation energy is far above the L₂ ionization threshold. The energy of Mg Kα photons is 1.21 eV below the Ge:L₂ ionization threshold and thus the Mg Kα excited L₂MM Auger electron spectra indicate many-body effects, post collision interaction (PCI) effects and spectator Auger satellite structures. The L₂M_4,5M_4,5 type spectrum displays both these features but the L₂M_2,3M_4,5 type spectrum has only a spectator Auger satellite structure, because the (3p⁻¹3d⁻¹nl) final state interferes with the (3s) hole state.     

The KLL and KLX auger electrons of arsenic from the 75Se decay

The KLL and KLX spectra for Auger electrons of arsenic (Z = 33) emitted during ⁷⁵Se decay were recorded, with an instrumental resolution of 11 eV, using a combined electrostatic spectrometer. The relative energies and intensities of nine KLL and ten KLX transitions were determined by computer analysis of the spectra. The margins of error were estimated to be 1–4 eV for energies and 2–50% for intensities. Except for the KL₁L₂ (¹P₁) transition, the measured relative intensities of the KLL transitions were found to agree, within 3 standard deviations (σ), with those calculated relativistically using the intermediate coupling approximation with configuration interaction. The discrepancy for the KL₁L₂ (¹P₁) transition amounted to 6σ. The KL₃M_2,3/KL₂M_2,3 transition intensity ratio agreed with the prediction based upon the intermediate coupling scheme but deviated by 7 σ from the value predicted by the jj coupling approximation.     

Inner-shell ionization by relativistic electron impact

K-, L andM-shell ionization cross sections have been measured for 23 elements, 12≦Z≦92, after bombardment with relativistic electrons, 15≦E ₀65MeV, by means of high resolution semiconductor detectors and a recently developed gas-scintillation proportional counter. For constant electron bombarding energyE ₀ the ionization cross sections follow a power law dependence,σ∽Z ^?α, and forE ₀=50MeV we deducedα =2.45±0.02 for theK shell andα=3.00 ±0.09 for theL shell. The observedZ dependence exhibits significant systematic deviations from theoretical predictions which exceed the experimental values up to 15 % at lowZ elements for theK shell and on the average about 11% for theL andM shell. The same behaviour of too low experimental values, i.e. an overestimation by the theory, is observed for the energy dependence of the cross sections for all shells. A scaling behaviour describing theZ andE ₀ dependence for allK-, L andM-shell data points is observed which also predicts the experimental values by other groups at lower and higher energies correctly. The comparsion of the measuredLΒ/Lα, andLγ/Lα intensity ratios for highZ elements with the values obtained by other groups in the energy range 0.3≦E₀≦1,000 MeV exhibits an increase with bombarding energy that cannot merely be explained by the energy dependence of the subshellionization cross sections for theL shell. An attempt to explain this effect with the change of the Coster-Kronig transition probability is described.     

Experimental evidence for anomalous L/M conversion ratio of the 2+→0+ transitions in some deformed even-even nuclei

TheL-subshell andM conversion coefficients ratios of the 2⁺→0⁺ transitions in some deformed even-even nuclei have been determined using a high resolution iron free double focusing beta-ray spectrometer. All possible uncertainties in these measurements have been minimized and properly evaluated. TheL ₁+L ₁₁/L ₁₁₁ ratios for the 2⁺→0⁺ E2 transitions in Dy¹⁶⁰, Er¹⁶⁶, Yb¹⁷⁰, Hd¹⁷⁶ and W¹⁸² are found to be in agreement with the theoretical ones within an experimental error of about 4%. However, large deviations from the theory of about two order of magnitude are observed forL/M conversion ratios. The deviations indicate the possibility of considerable approximation in the theoretical calculation of theM-internal conversion coefficients.     

Auger- und Coster-Kronig-Übergänge der M-Schale von Krypton

The Auger spectra of theM ₂,M ₃,M ₄,M ₅ subshells of krypton and the Coster-Kronig spectra of theM ₁,M ₂,M ₃ subshells of krypton were measured with an electrostatical spectrometer. The ionization in theM shells was caused by electron impact. The use of a gaseous target made it possible to measure the Auger lines even at energies as low as 25 eV. The absolute energies and relative intensities of a great number of transitions were determined: 22 of theM _{4, 5} spectrum, 14 of theM _{2, 3} spectrum and 2 of theM ₁ spectrum. Only in the case of theM _{2, 3} spectrum a comparison between the relative intensities, determined experimentally, and those calculated byRubenstein forZ=47 was possible. The agreement is only qualitatively. Moreover, from the Auger electron energies measured, the following binding energies were calculated:E(M ₁)=(292,1±1,0) eV,E(M ₂)=(222,1±0,6) eV,E(M ₃)=(214,6±0,6)eV,E(N ₁ N ₁)=(62,81±0,05) eV.     

K Auger transitions of the free sodium atom

TheK Auger spectrum of the free sodium atom, following electron impact ionization, was measured with 0.16% resolution using a sodium atomic beam as target. The absolute energies and relative intensities ofKLL, KLM and numerous satellite transitions have been determined. The absolute energies of theKLL transitions of the free sodium atom were found to be smaller by 13.1 eV than the corresponding energies found for sodium in Na₂O (relative to the Fermi level) by Fahlmanet al. Also the relativeKLL intensities differed in two cases indicating solid state and/or chemical effects. The present relative intensities agree better with theoretical values calculated by McGuire, Walters and Bhalla, and Chen and Crasemann than those of Na₂O. In an Appendix the natural line widths of theKLL andKM-LLM transitions of sodium have been calculated.     

DasL/K- und dasM/L-Einfangverhältnis von65Zink

We have investigated theL/K- and theL/M-capture ratio of⁶⁵Zn. For the transitions to the first excited state of⁶⁵Cu we obtained (N _L/N _K) _A =0.120±3% and (N _M/N _L) _A =0.153±13% and for both transitions to the groundstate and the first excited state simultaneously we found (N _L/N _K) _G =0.118±3%. The values for (N _L/N _K) agree well with the results of Santos Ocampo and Conway but are higher than the results of Totzek and Hoffmann. All values are discussed in view of the different theoretical values obtainable.