Das K-Auger-Spektrum von Neon

TheKLL-Auger spectrum of neon was investigated with an electrostatic spectrometer with an energy resolution of 0.12%. The ionization in theK-shell was caused by electron impact. The use of a gaseous target made it possible to measure the Auger electrons without any energy loss. The relative intensities of the KLL-lines were determined to be:KL ₁ L ₁(¹ S ₀)=1.0;KL ₁ L _2,3(¹ P ₁)=3.06±0.07;KL ₁ L _2,3(³ P _0,1,2)=0.98±0.05;KL _2,3 L _2,3(¹ S ₀)=1.67±0.08;KL _2,3 L _2,3(¹ D ₂)=13.1±0.6;KL _2,3 L _2,3(² P _0,2)=0. This is in agreement with an earlier measurement byKörber andMehlhorn but disagrees with all theoretical values calculated nonrelativistically for low Z. It is shown that agreement may be achieved by applying quantitatively the configuration interaction, introduced very recently byAsaad, and using improved wave functions for the calculation of the transition amplitudes. As a consequence of the ionization by electron impact also theKL-LLL Auger spectrum was caused. 10 lines of this spectrum were measured and identified. Moreover, from the Auger energies measured, the binding energyE(K) of neon was calculated to be E(K)=(870.0±0.4) eV.     

Finite-size scaling of correlation functions in finite systems

We propose the finite-size scaling of correlation functions in finite systems near their critical points.At a distance r in a ddimensional finite system of size L,the correlation function can be written as the product of|r|~(-(d-2+η))and a finite-size scaling function of the variables r/L and tL~(1/ν),where t=(T-T_c)/T_c,ηis the critical exponent of correlation function,andνis the critical exponent of correlation length.The correlation function only has a sigificant directional dependence when|r|is compariable to L.We then confirm this finite-size scaling by calculating the correlation functions of the two-dimensional Ising model and the bond percolation in two-dimensional lattices using Monte Carlo simulations.We can use the finite-size scaling of the correlation function to determine the critical point and the critical exponentη.     

Why <Emphasis Type="Italic">X</Emphasis>(3872) is not a molecule

We discuss the scenario where the X(3872) resonance is the \(c\bar c\) = χ_c1(2P) charmonium which “sits on” the D*⁰\({\bar D^0}\) threshold. We explain the shift of the mass of the X(3872) resonance with respect to the prediction of a potential model for the mass of the χ_c1(2P) charmonium by the contribution of the virtual D*\(\bar D\) + c.c. intermediate states into the self energy of the X(3872) resonance. This allows us to estimate the coupling constant of the X(3872) resonance with the D*⁰\({\bar D^0}\) channel, the branching ratio of the X(3872) → D*⁰\({\bar D^0}\) + c.c. decay, and the branching ratio of the X(3872) decay into all non-D*⁰\({\bar D^0}\) + c.c. states. We predict a significant number of unknown decays of X(3872) via two gluon: X(3872) → gluongluon → hadrons. We suggest a physically clear program of experimental researches for verification of our assumption.     

A Note on Holographic Dark Energy with Varying <Emphasis Type="Italic">c</Emphasis><Superscript>2</Superscript> Term

We reconsider the holographic dark energy (HDE) model with a slowly time varying c ²(z) parameter in the energy density, namely \(\rho _{D}=3{M_{p}^{2}} c^{2}(z)/L^{2}\), where L is the IR cutoff and z is the redshift parameter. As the system’s IR cutoff we choose the Hubble radius and the Granda-Oliveros (GO) cutoffs. The latter inspired by the Ricci scalar curvature. We derive the evolution of the cosmological parameters such as the equation of state and the deceleration parameters as the explicit functions of the redshift parameter z. Then, we plot the evolutions of these cosmological parameters in terms of the redshift parameter during the history of the universe. Interestingly enough, we observe that by choosing L = H ^?1 as the IR cutoff for the HDE with time varying c ²(z) term, the present acceleration of the universe expansion can be achieved, even in the absence of interaction between dark energy and dark matter. This is in contrast to the usual HDE model with constant c ² term, which leads to a wrong equation of state, namely that for dust w _D =0, when the IR cutoff is chosen the Hubble radius.     

Electro-optical properties of strontium-barium niobate crystals and their relation to the domain structure of the crystals

The electro-optical coefficients r _ij and half-wave voltage V_λ/2 of strontium-barium niobate crystals poled in the ferroelectric phase are shown to vary along the polar axis. The r _ij (z) and V_λ/2(z) dependences indicate the presence of a residual domain density D(z) and clearly depend on the sign of the polarizing field, with r _ij being minimum (D being maximum) near the negative electrode. This character of the D(z) distribution and, hence, the r _ij (z) and V_λ/2(z) coordinate dependences can be explained by predominant domain nucleation near the negative electrode, which is revealed when the switching processes are studied using 90° (Rayleigh) light scattering from domain walls.     

The analysis of the densities of <Emphasis Type="Italic">s</Emphasis>-wave neutron resonances separated with respect to spin

The density ratio of s-wave neutron resonances z=ρ(J₁)/ρ(J₂) was analyzed on the basis of the experimental data for 22 atomic nuclei and the Gilbert-Cameron formula for ρ(J). Here, J₁=I_x—1/2 and J₂=I_x+1/2, where I_x denotes the spin of the target nucleus in the ground state. Our aim was to verify whether the factor η(I_x), as a multiplier, can be applied in the expression describing ρ(J₁), with the assumption that ρ(J₂) values remain unchanged, or whether the factor 1η(I_x) can be applied, as a multiplier with ρ(J₂), while the ρ(J₁) values remain unchanged. The final conclusions, e.g., the confirmation or the negation of the fact that it may be necessary to apply the η(I_x) factor, depend on the values of “real” errors Δz of the z variable, which can be calculated if the optimal values of Δρ(J₁) and Δρ(J₂) are known.     

Präzisionsmessung der Hyperfeinstruktur des 52P3/2-Terms und des 62P3/2-Terms von Rb85 und Rb87

To study the modification of the value of the nuclear quadrupole moment obtained without Sternheimer correction from measurements in states with different principal quantum numbers, the hyperfine structure splitting of the 5² P _3/2 and the 6² P _3/2 excited states of Rb I has been investigated with the optical double resonance method. The experiments, in which isotopic enriched samples of Rb⁸⁵ and Rb⁸⁷ were used, have been carried out in the 5² P _3/2 state without a static magnetic field. In the 6² P _3/2 state, a static magnetic field was applied. For the 5² P _3/2 state, the hyperfine structure constants areA(Rb⁸⁵)=25.029(16) Mc/s,B(Rb⁸⁵)=26.032(70) Mc/s,A(Rb⁸⁷)=84.852(30) Mc/s,B(Rb⁸⁷)=12.611(70) Mc/s. The corresponding constants for the 6² P _3/2 state areA(Rb⁸⁵)=8.25(10) Mc/s,B(Rb⁸⁵)=8.16(20) Mc/s,A(Rb⁸⁷)=27.96(35) Mc/s,B(Rb⁸⁷)=3.95(10) Mc/s. The values of the nuclear quadrupole moments, derived from both finestructure states, can be brought into agreement when the Sternheimer core correction is applied. The Landé factor for the 6² P _3/2 state isg _j=1.334(1).     

Low-Prandtl-number Rayleigh-Bénard convection with stress-free boundaries

Results of direct numerical simulations on Rayleigh-Bénard convection in low-Prandtl-number convection with stress-free horizontal boundaries are presented. Simulations are done in a three dimensional rectangular simulation box of dimensions L _x × L _y × 1. Instabilities and the corresponding fluid patterns near onset of convection are investigated by varying the horizontal aspect ratio η = L _y /L _x in a range 1 ≤ η ≤ 4. Fluid patterns are complex and unsteady at the instability onset for η ≥ 2. They consist of wavy rolls, rhombic patterns and oblique wavy rolls. The patterns near onset are time periodic for η < 2. We observe periodic wavy rolls for η = 4 / 3. Homoclinic bifurcations are observed for η = 1 for 0 ≤ Pr ≤ 0.03. We observe spontaneous breaking of a single limit cycle in two and again spontaneous merging of two limit cycles into one in a simulation box with η = 1, as the reduced Rayleigh number r = Ra/R a _c is raised at a fixed value of Pr. The effect of Prandtl number on the homoclinic bifurcations is also investigated. We also present a low-dimensional model, which captures the instability sequence quite accurately for η = 1.     

Investigation of the optical constants of arsenic chalcogenide films in the wavelength range 0.5–2.5 μm

Thin films of chalcogenide glasses deposited on quartz glass substrates by thermal evaporation in vacuum have been investigated. The dependences n(λ) and k(λ) for films of different composition have been determined from the transmission spectra. Expressions of the n = A + BL + CL ² + Dλ ² + Eλ ⁴ type (L = (λ ² ? 0.028)^?1 and A, B, C, D, and E are constants) for calculating the refractive indices of As₂Se₃, AsSe₄, AsS₄, and AsS_16.2Se_16.2 films in the wavelength range from 0.5 to 2.5 μm are reported.     

Stabilizer of a function in the gage group

It is proved that, for the dimension d of the stabilizer of an analytic function z(x, y) in the gage pseudogroup G = {z(x, y) → c(z(a(x), b(y))}, there are precisely four possibilities: (1) d = ∞ and the complexity of z is zero, (2) d = 3 and the complexity of z is equal to one, (3) d = 1 and z is equivalent the function r(x + y) ? x of complexity two, (4) d = 0 in all remaining cases.     

Raman scattering in sodium nitrite crystals near the phase transition

Optical Raman spectra of a ferroelectric sodium nitrite crystal have been detected in a wide spectrum range at various temperatures, including the region of the ferroelectric phase transition. A manifestation of a transverse soft polar mode of the A ₁(z) type responsible for the ferroelectric phase transition has been discovered in the spectrum at room temperature. This mode has been found to become overdamped even far from the ferroelectric phase transition temperature. This mode also appears as a central peak under heating. It has been found that the pseudoscalar mode of the A ₂ type has the highest intensity in the Raman spectrum of sodium nitrite. The frequency corresponding to the maximum intensity of this mode in the Raman spectrum varies from 130 cm^–1 at 123 K to 106 cm^–1 at T = 513 K. A fair agreement of the experimental data for the A ₁(z) mode with the Lyddane–Sachs–Teller relation has been established. The polariton curves for the A ₁(z) polar mode and the dispersion curves for axinons has been plotted.     

Polarisationseffekte in der Hyperfeinstruktur von65Cu I, 3d 94s 2 m 2 D

The hyperfinestructure of the transition⁶⁵CuI, 3d ¹⁰4p ² P _3/2—3d ⁹4s ² m ² D _5/2 was investigated by optical interferometric methods. For the hfs-factors the following values were found:A(⁶⁵Cu,m ² D _5/2)=26,79(3) mK andB(⁶⁵Cu,m ² D _5/2)=5,81(10) mK. The core polarization of them ² D-terms and the Sternheimer corrections in the calculation of the quadrupolmoment of copper 65 from theB-factors of the terms 3d ⁹ 4s² m ² D and 3d ¹⁰ 4p ² P _3/2. were discussed.     

Excitons in monoclinic zinc diphosphide: The <Emphasis Type="Italic">A</Emphasis>-exciton series and Fano effect

The A-exciton series in the absorption spectra of β-ZnP₂ monoclinic zinc diphosphide samples is investigated at different directions of the wave vector and different polarization states of radiation. It is shown that the oscillator strengths determined for the observed transitions are adequately described by the relationship F _n ∝n^?3 characteristic of S-type exciton states. The assumption is made that the A-exciton series is associated with the partially allowed dipole transitions to nS states of the orthoexciton with Γ ₂ ^? (x) symmetry at m _s =0. These states are mixed, to a first approximation, with nS states of the Γ ₂ ^? (z) singlet exciton due to the spin-orbit 2 interaction and are split off by the long-range (nonanalytical) part of the exchange interaction. The Fano antiresonances arise in the absorption spectra at resonances of the A-exciton series when the radiation vector E (or the induction vector D) has a component along the crystallographic axis c. These antiresonances are induced by the configurational interaction of discrete exciton states of the A series with the continuum of the exciton-phonon spectrum due to indirect transitions to the 1S band of the singlet exciton with phonon emission.     

Symmetries of the pseudo-diffusion equation and related topics

We show in details how to determine and identify the algebra g = {A_i} of the infinitesimal symmetry operators of the following pseudo-diffusion equation (PSDE) LQ ≡ \(\left[ {\frac{\partial }{{\partial t}} - \frac{1}{4}\left( {\frac{{{\partial ^2}}}{{\partial {x^2}}} - \frac{1}{{{t^2}}}\frac{{{\partial ^2}}}{{\partial {p^2}}}} \right)} \right]\) Q(x, p, t) = 0. This equation describes the behavior of the Q functions in the (x, p) phase space as a function of a squeeze parameter y, where t = e ^2y. We illustrate how G _i(λ) ≡ exp[λA _i] can be used to obtain interesting solutions. We show that one of the symmetry generators, A ₄, acts in the (x, p) plane like the Lorentz boost in (x, t) plane. We construct the Anti-de-Sitter algebra so(3, 2) from quadratic products of 4 of the A _i, which makes it the invariance algebra of the PSDE. We also discuss the unusual contraction of so(3, 1) to so(1, 1)? h². We show that the spherical Bessel functions I ₀(z) and K ₀(z) yield solutions of the PSDE, where z is scaling and “twist” invariant.     

From Atiyah Classes to Homotopy Leibniz Algebras

A celebrated theorem of Kapranov states that the Atiyah class of the tangent bundle of a complex manifold X makes T _X [?1] into a Lie algebra object in D ⁺ (X), the bounded below derived category of coherent sheaves on X. Furthermore, Kapranov proved that, for a Kähler manifold X, the Dolbeault resolution \({\Omega^{\bullet-1}(T_X^{1, 0})}\) of T _X [?1] is an L _∞ algebra. In this paper, we prove that Kapranov’s theorem holds in much wider generality for vector bundles over Lie pairs. Given a Lie pair (L, A), i.e. a Lie algebroid L together with a Lie subalgebroid A, we define the Atiyah class α _E of an A-module E as the obstruction to the existence of an A-compatible L-connection on E. We prove that the Atiyah classes α _L/A and α _E respectively make L/A[?1] and E[?1] into a Lie algebra and a Lie algebra module in the bounded below derived category \({D^+(\mathcal{A})}\) , where \({\mathcal{A}}\) is the abelian category of left \({\mathcal{U}(A)}\) -modules and \({\mathcal{U}(A)}\) is the universal enveloping algebra of A. Moreover, we produce a homotopy Leibniz algebra and a homotopy Leibniz module stemming from the Atiyah classes of L/A and E, and inducing the aforesaid Lie structures in \({D^+(\mathcal{A})}\) .     

Electron paramagnetic resonance of Cr<Superscript>3+</Superscript>-Li<Superscript>+</Superscript> centers in (Cr,Li): Mg<Subscript>2</Subscript>SiO<Subscript>4</Subscript> synthetic forsterite

Synthetic single crystals of chromium-and lithium-doped forsterite, namely, (Cr,Li): Mg₂SiO₄, are studied using electron paramagnetic resonance spectroscopy. It is revealed that, apart from the known centers Cr³⁺(M1) and Cr³⁺(M2) (with local symmetries C_i and C_s, respectively), these crystals involve two new types of centers with C₁ symmetry, namely, Cr³⁺(M1)′ and Cr³⁺(M2)′ centers. The standard parameters D and E in a zero magnetic field [zero-field splitting (ZFS) parameters expressed in GHz] and principal components of the g tensor are determined as follows: D=31.35, E=8.28, and g=(1.9797, 1.9801, 1.9759) for Cr³⁺(M1)′ centers and D=15.171, E=2.283, and g=(1.9747, 1.9769, 1.9710) for Cr³⁺(M2)′ centers. It is found that the lowsymmetric effect of misalignment of the principal axes of the ZFS and g tensors most clearly manifests itself (i.e., its magnitude reaches 19°) in the case of Cr³⁺(M2)′ centers. The structural models Cr³⁺(M1)-Li⁺(M2) and Cr³⁺(M2)-Li⁺(M1) are proposed for the Cr³⁺(M1)′ and Cr³⁺(M2)′ centers, respectively. The concentrations of both centers are determined. It is demonstrated that, upon the formation of Cr³⁺-Li⁺ ion pairs, the M1 position for chromium appears to be two times more preferable than the M2 position. Reasoning from the results obtained, the R₁ line (the ²E → ⁴A₂ transition) observed in the luminescence spectra of (Cr,Li): Mg₂SiO₄ crystals in the vicinity of 699.6 nm is assigned to the Cr³⁺(M1)′ center.     

Über Kristallstruktur und elektrische Eigenschaften der Wismutselenide Bi2Se2 und Bi2Se3

The properties of bismuth triselenide (Bi₂Se₃) are already known to a certain extent through the work of several authors, while it was still an open question whether there exists an individual solid phase of BiSe. Further information on this subject could be obtained by the successful growth and investigation of single crystals of both Bi₂Se₃ and Bi₂Se₂. X-ray analysis by means of goniometry, Weißenberg, Laue, and Debye-Scherrer diagrams confirmed the known crystal structure of Bi₂Se₃ (ditrigonal scalenohedral;D _3d ⁵ ?R—m; with the hexagonal axes:a=4·15 Å andc=28·55 Å, and 3 molecules per unit cell). As to Bi₂Se₂ it can be shown that it belongs to the same class but to a different space group (D _3d ¹ ?P— 1m orD _3d ³ ?P—m 1; hexagonal axes:a=4·15 Å,c=22·84 Å, unit cell: 3 molecules, if the formula Bi₂Se₂ is adopted). Common to both is a subcell with the dimensions:a′=a=4·15 Å andc′=5·71 Å. The temperature dependence of electrical conductivity and Hall coefficient was measured on several specimens having different crystal orientations. The most striking difference is the high anisotropy of Bi₂Se₃ (σ _a σ _c =10) as compared with Bi₂Se₂ (σ _a /σ _c <2). All specimens turned out to ben-type. The room temperature carrier concentration observed was:n (Bi₂Se3)=8·10¹⁸ cm^?3 andn (Bi₂Se₂)=4·10²⁰ cm^?3, the carrier mobility:μ(Bi₂Se3)=2·10³ cm²/V·s andμ(Bi₂Se₃)=20 cm²/V·s.     

Influence of the dimension of a polycrystalline film and the optical anisotropy of crystallites on the effective dielectric constant of the film

The dimension D of a polycrystalline film and the optical anisotropy m = ε_z/ε_x of uniaxial crystallites with the principal components ε_x = ε_y and ε_z of the tensor of the dielectric constant have been shown to produce a strong influence on the effective dielectric constant ε_D^* and the effective refractive index n_D^* = (ε_D^*)^1/2 of the film in the optical transparency region, as well as on the boundaries of the intervals B_Dl ≤ ε_D^* ≤ B_Du. The intervals Δ₂(m) = B_2l–B_2u and Δ₃(m) = B_3l–B_3u are separated by a gap for m in the range 1 < m < 2, whereas the theoretical dependence ε₂^*(m) is separated by a gap from the interval Δ₃(m) for m in the range 1 < m < 4. This is confirmed by a comparison of the experimental (n_oP) and theoretical (n_D^*) ordinary refractive indices for uniaxial polycrystalline films of the conjugated polymer poly(p-phenylene vinylene) (PPV) with uniaxial crystallites and appropriate values of m. In the visible transparency region of the PPV films with a change in m(λ) in the range 2 < m(λ) < 3 due to the dependence of the components ε_x,z(λ) on the light wavelength λ, the refractive indices n_oP²(λ) = ε_oP(λ) are consistent with the theoretical values of ε₂^*(λ) and lie outside the interval Δ₃(m). For m(λ) > 3 near the electronic absorption band of the crystallites, the values of ε_oP(λ) lie in the region of the overlap of the intervals Δ₂(m) and Δ₃(m). The boundaries mc of the range 1 < m < m_c are determined, for which the interval Δ₂(m) is separated by a gap from the dependences ε₃^*(m) corresponding to the effective medium theory with spherical crystallites and hierarchical models of a polycrystal, as well as from the proposed new dependence ε₃^*(m).